Focusing on the ultralow expansion functionality of the crystalized glass containing the cordierite crystal phase with the molar composition 20.7MgO·20.7Al_(2)O_(3)·51.6SiO_(2)·7.0TiO_(2),we systematica...Focusing on the ultralow expansion functionality of the crystalized glass containing the cordierite crystal phase with the molar composition 20.7MgO·20.7Al_(2)O_(3)·51.6SiO_(2)·7.0TiO_(2),we systematically investigated impacts of thermal treatment protocols on T dependence of coefficients of thermal expansion(CTE).Except for the phase compositions,morphology is identified as another important factor to control the T dependence of CTE.By using X-ray diffraction and scanning electron microscope,various modes of T dependence of CTE for crystallized glasses are ascribed to their different phase compositions and microstructure with finely dispersed nanoparticles.These understanding contributes to the further modification of CTE of the crystalized glass by altering their thermal treatment scenarios.展开更多
Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive perform...Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive performance of materials,but the processing difficulty,especially in ceramics forming,limits the control and innovation of material architecture.Here,combined with 3D printing and squeeze infiltration technology,two precisely controllable architectures of AZ91/Al_(2)O_(3)interpenetrating phase composites(IPC)with ceramic scaffold were prepared.The interface,properties and impact of different architecture on IPC performance were studied by experiments and finite element simulation.The metallurgical bonding of the interface was realized with the formation of MgAl_(2)O_(4)reaction layer.The IPC with 1 mm circular hole scaffold(1C-IPC)exhibited significantly improved elastic modulus of 164 GPa,high compressive strength of 680 MPa,and good CTE of 12.91×10^(-6)K^(−1),which were 3.64 times,1.98 times and 55%of the Mg matrix,respectively.Their elastic modulus,compressive strength,and CTE were superior to the vast majority of Mg alloys and Mg based composites.The reinforcement and matrix were bicontinuous and interpenetrating each other,which played a critical role in ensuring the potent strengthening effect of the Al_(2)O_(3)reinforcement by efficient load transfer.Under the same volume fraction of reinforcements,compared to IPC with 1 mm hexagonal hole scaffold(1H-IPC),the elastic modulus and compressive strength of 1C-IPC increased by 15%and 28%,respectively,which was due to the reduced stress concentration and more uniform stress distribution of 1C-IPC.It shows great potential of architecture design in improving the performance of composites.This study provides architectural design strategy and feasible preparation method for the development of high performance materials.展开更多
Introduction The predominant characteristics of high-altitude climates include low air pressure,low humidity,and large diurnal temperature fluctuations.In practical engineering scenarios in high-altitude regions,many ...Introduction The predominant characteristics of high-altitude climates include low air pressure,low humidity,and large diurnal temperature fluctuations.In practical engineering scenarios in high-altitude regions,many pier surface cracks only appear several months after erection,and cyclic thermal stress is identified as the main trigger for such cracking.The thermal stress in concrete structures has been investigated for decades but remains incompletely understood.Structural engineers typically regard concrete as an isotropic material and calculate the thermal stress using code-specified coefficients of thermal expansion(CTEs)along with temperature conditions and constraints.Because the CTE of hardened cement paste is more than twice that of many aggregates,reducing the CTE of coarse aggregates can further exacerbate the thermal deformation incompatibility between the coarse aggregate and mortar matrix.In this paper,a comprehensive thermal-elastic mechanics model for pier concrete was developed to analysis the temperature-induced surface stress.Methods A series of mechanical and thermophysical tests were conducted on the diorite aggregate,ITZ cement paste,and mortar,and concrete.A test pier was constructed on open ground near the Yarlung Zangbo River at an altitude of 3800 m.The pier had a diameter of 1.8 m and height of 2 m.Temperature sensors were embedded in the cross-section at a height of 1 m,positioned along the southnorth and east-west directions.The embedding depths(distances from the pier surface)were 0,1.5,3,4.5,6,7.5,9,12,15,20,25,30,35,40,50,60,70,80 cm,and 90 cm.A model of the bridge pier concrete for surface-level analysis was constructed.The model consists of a concrete unit formed as a sphere-shell-shell composite,including the aggregate,ITZ,and mortar layers,embedded in the surface layer of a bridge pier.Outside this unit,the pier concrete was treated as an isotropic,homogeneous elastic material.The real-time internal temperature fields of high-altitude concrete bridge piers,measured on-site,were incorporated into the model.By applying thermoelastic mechanics theory and finite element solutions for plane strain problems,the three-dimensional thermal stresses on the surface layer of high-altitude bridge piers were analyzed Results and discussion During the experimental period,the lowest and highest temperatures on the bridge pier in the high-altitude region were 9.6 ℃ and 42.6 ℃,respectively.These occurred before sunrise and sunset on sunny days,respectively,corresponding to the local maximum temperature gradients during the surface heating and cooling stages,as well as the maximum temperature difference between the surface and center during these stages.The thermal stress on the pier concrete surface was obtained by superimposing the stresses caused by the uneven distribution of the internal temperature field and those caused by the incompatible thermal deformation among the different components in the surface concrete Before the erection of the upper structures,the absolute values of the tangential and vertical stresses were the same;therefore,only one curve was observed.From 22:00 to 8:00,the pier concrete surface was in tension,whereas from 11:00 to 22:00,the pier concrete surface was in compression.The surface of the pier concrete was subjected to biaxial forces of equal magnitude with a maximum compressive stress of 12.52 MPa and maximum tensile stress of 2.15 MPa,respectively at 18:00 and 8:00.According to the fatigue equation,the concrete was predicted to crack after 21 d of temperature cycling.Moreover,if humidity-induced stress is added on top of this,the tensile stress may approach or even exceed the concrete's tensile strength,thereby posing a significant risk of cracking.After the erection of upper structures,the tangential and vertical stresses no longer coincide because the upper structures have been erected.The curve of the tangential stress is unchanged,whereas the curve of the vertical stress is translated downwards by 1.57 MPa due to the structural deadweight.Therefore,the maximum tangential compressive stress remained 12.52 MPa,whereas the maximum vertical compressive stress increased to 14.09 MPa.Additionally,the maximum tangential tensile stress was 2.15 MPa,and the maximum vertical tensile stress was 0.58 MPa.According to Appendix C of GB/T 50010 and the fatigue equation,stresses are unlikely to cause cracking of the pier concrete surface.Although a higher CTE of the coarse aggregate slightly increased the maximum compressive stress,the differences among the three groups of concrete were minimal and could be ignored.Specifically,the maximum compressive stresses on the pier concrete surface were 12.54,12.45 MPa,and 12.56 MPa when using diorite,limestone,and basalt,respectively.By contrast,a lower CTE of the coarse aggregate results in a greater maximum tensile stress on the pier concrete surface.For example,when using limestone,which has a low CTE,the maximum tensile stress on the pier concrete surface is 2.28 MPa,compared to 2.17 MPa when using diorite and 2.14 MPa when using basalt.The finite element simulation results indicated that the maximum compressive stress on the pier concrete surface was 11.72 MPa,whereas the maximum tensile stress was 2.10 MPa.These results are approximately consistent with the theoretical calculations.This consistency provides mutual verification.Conclusions Surface cracking in pier concrete occurs predominantly before the erection of upper structures.Under sunny conditions,the orthogonal decomposition of the superficial stress revealed that the maximum compressive stress during the day was approximately 12.52 MPa,whereas the maximum tensile stress was approximately 2.15 MPa.This tensile stress approached the tensile strength of the C35 concrete under biaxial tension.The risk of cracking increased significantly when humidity-induced stress was considered.After the erection of upper structures,the maximum tangential tensile stress on the pier surface remained at 2.15 MPa while the maximum vertical stress decreased to 0.58 MPa,both of which are well below the tensile strength of C35 concrete under biaxial tension.Although the use of coarse aggregates with a lower coefficient of thermal expansion reduced the tensile stress induced by temperature gradients,it increased the stress owing to material deformation incompatibility,leading to a slight increase in the maximum tensile stress on the pier concrete surface.展开更多
Twisted polymer artificial muscles activated by thermal heating represent a new class of soft actuators capable of generating torsional actuation.The thermal torsion effect,characterized by the reversible untwisting o...Twisted polymer artificial muscles activated by thermal heating represent a new class of soft actuators capable of generating torsional actuation.The thermal torsion effect,characterized by the reversible untwisting of twisted fibers as temperature increases due to greater radial than axial thermal expansion,is crucial to the actuation performance of these artificial muscles.This study explores the thermal torsion effect of polymer muscles made of twisted Nylon 6 fibers in experimental and theoretical aspects,focusing on the interplay between material properties and temperature.It is revealed that the thermal torsion effect enhances the actuation performance of the twisted polymer actuator while the thermal softening effect diminishes it.A thermal-mechanical model incorporating both the thermal torsion effect and thermal softening effect is used to predict the recovered torque of the twisted polymer actuators.An optimal bias angle and operating temperature are identified to maximize the recovered torque.Analysis of strain and stress distributions in the cross-section of the twisted polymer fiber shows that the outer layers of the fiber predominantly contribute to the torsional actuation.This work aids in the precise control and structural optimization of the thermally-activated twisted polymer actuators.展开更多
Dilute Mg alloys processed by the rapidly solidified ribbon consolidation(RSRC)technique are candidate materials for structural applications due to their enhanced mechanical performance.The thermal stability of the st...Dilute Mg alloys processed by the rapidly solidified ribbon consolidation(RSRC)technique are candidate materials for structural applications due to their enhanced mechanical performance.The thermal stability of the structure in these alloys strongly influences their mechanical performance at elevated temperatures.In this study,an RSRC-processed Mg-1%Ca-0.5%Zn-0.1%Y-0.03%Mn(at%)alloy was heated at a constant rate up to 833 K,and concurrently in situ X-ray diffraction(XRD)measurements were performed using synchrotron radiation in order to monitor the changes in the structure.In addition,ex situ electron microscopy investigations were carried out before and after annealing to complete the XRD study.On the basis of XRD results,the stages of the microstructure evolution during heating were identified.In addition,the thermal expansion coefficients of the matrix and the Mg_(2)Ca secondary phase were determined.Between 299 and 400 K,the lattice constants of both the matrix and the Mg_(2)Ca phase increased due to thermal expansion.In the temperature range of 400-673 K,the increase of the lattice constants with increasing the temperature continued,but their rate was different for the two phases which can induce thermal stresses.Between 673 and 753 K,the lattice constants of the secondary phase did not change most probably due to the compensating effects of the thermal expansion and the decrease of the Ca content.In the temperature range of 753-793 K,the Mg_(2)Ca phase started to dissolve.Between 793 and 833 K the dissolution continued,and additionally the matrix was partially melted.展开更多
Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and compos...Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and composition of the mulite and glass phases,which are related to the chemical composition of the MSRG composites based on clay.In the present work,the relationship between the phase and the chemical composition of the MSRG composites,and the effects of the chemical composition of the glass phase on the viscosity and coefficient of thermal expansion(CTE)of the glass phase were discussed on the basis of the measurements on 17 MSRG composite samples produced from clay.It is found that the Al_(2)O_(3)/SiO_(2) ratio(AS ratio)in clay strongly affects the amount of the mullite and glass phases in the MSRG composites,and the distributions of SiO_(2),TiO_(2)and Al_(2)O_(3) contents in the mullite and glass phases.With the increase of the A/S ratio of clay,the mullite content increases but the the glass phase content decreases in the MSRG composites.The viscosity and CTE of the glass phase depend on its A/S ratio and the amount of impurity oxides.When the A/S ratio in the glass phase is less than 0.15,the viscosity of the liquid formed by the melting of the glass phase at elevated temperatures rapidly increases with the decrease in the A/S ratio.The CTE of the glass phase depends on the contents of Si0_(2)and(K_(2)O+Na_(2)O).展开更多
The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green's function theory. On the basis of these results, the form...The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green's function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.展开更多
On the basis of the uniform design method, six kinds of martensitic hot work die steels were designed. The phase transformation temperatures including Ac1 , Ac3 , and Ms were measured by DIL805A quenching dilatometer....On the basis of the uniform design method, six kinds of martensitic hot work die steels were designed. The phase transformation temperatures including Ac1 , Ac3 , and Ms were measured by DIL805A quenching dilatometer. The influences of the main elements on phase transformation temperatures were analyzed by quadratic stepwise regression analysis, and three corresponding equations were obtained. These equations, in which the interactions of the elements were considered, showed more effectiveness than the traditional ones. In addition, the thermal expansion coefficients of these steels in annealed state and quenched state were also obtained during the tests. The influences of chemical composition and temperature on the thermal expansion coefficient were analyzed; the equations obtained were verified by using several kinds of steels. The predicted values were in accordance with the results of the experiments.展开更多
Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solutio...Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solution if the macrostructure is large enough to comprise an infinite number of unit cells. In this paper, a novel implementation algorithm of asymptotic homogenization (NIAH) is developed to calculate the effective CTE of periodic composite materials. Compared with the previous implementation of AH, there are two obvious advantages. One is its implementation as simple as representative volume element (RVE). The new algorithm can be executed easily using commercial finite element analysis (FEA) software as a black box. The detailed process of the new implementation of AH has been provided. The other is that NIAH can simultaneously use more than one element type to discretize a unit cell, which can save much computational cost in predicting the CTE of a complex structure. Several examples are carried out to demonstrate the effectiveness of the new implementation. This work is expected to greatly promote the widespread use of AH in predicting the CTE of periodic composite materials.展开更多
Usually the thermal expansion coefficients (TEC) of metals are higher than that of porcelains. In order to match the TECs in the case of coating porcelains on metals, high TEC porcelains are needed. In this research, ...Usually the thermal expansion coefficients (TEC) of metals are higher than that of porcelains. In order to match the TECs in the case of coating porcelains on metals, high TEC porcelains are needed. In this research, the high TEC phase leucite (KAlSi2 O6) in the high TEC porcelain was prepared by sol-gel method. The crystal size of leucite made by sol-gel is about 77nm through controlling the process parameters. The process from xerogel to leucite was investigated by means of DSC (differential scanning calorimetry), TG (thermogravimetry), XRD ( X-ray diffraction) and IR (infrared absorption spectrum). Leucite had been detected after the gel was treated at 900℃, this formation temperature is about 250℃ lower than that of melting method. The porcelain made from 50% of the leucite powder and 50% of low fused temperature frit has an average TEC of 19.2×10-6/℃ C from room temperature to 450℃, which is much higher than the common porcelains.展开更多
This study evaluated the adhesion of zirconia core ceramics with their corresponding veneering ceramics, having different thermal expansion coefficients （TECs）, when zirconia ceramics were coloured at green stage. Z...This study evaluated the adhesion of zirconia core ceramics with their corresponding veneering ceramics, having different thermal expansion coefficients （TECs）, when zirconia ceramics were coloured at green stage. Zirconia blocks （N=240; 6 mm x 7 mm x 7 mm） were manufactured from two materials namely, ICE Zirconia （Group 1） and Prettau Zirconia （Group 2）. In their green stage, they were randomly divided into two groups. Half of the specimens were coloured with colouring liquid （shade A2）, Three different veneering ceramics with different TEC （ICE Ceramic, GC Initial Zr and IPS e.max Ceram） were fired on both coloured and non-coloured zirconia cores. Specimens of high noble alloys （Esteticor Plus） veneered with ceramic （VM 13） （n= 16） acted as the control group. Core-veneer interface of the specimens were subjected to shear force in the Universal Testing Machine （0.5 mm-min-1）. Neither the zirconia core material （P=0.318） nor colouring （P=0.188） significantly affected the results （three-way analysis of variance, Tukey＇s test）. But the results were significantly affected by the veneering ceramic （P=0.000）. Control group exhibited significantly higher mean bond strength values （45.7__.8） MPa than all other tested groups （（27.1__.4.1）-（39.7__.4.7） and （27.4__.5.6）-（35.9___4.7） MPa with and without colouring, respectively） （P^0.001）. While in zirconia-veneer test groups, predominantly mixed type of failures were observed with the veneering ceramic covering ~ 1/3 of the substrate surface, in the metal-ceramic group, veneering ceramic was left adhered 1/3 of the metal surface. Colouring zirconia did not impair adhesion of veneering ceramic, but veneering ceramic had a significant influence on the core-veneer adhesion. Metal-ceramic adhesion was more reliable than all zirconia-veneer ceramics tested.展开更多
The law of microstructure evolution and mechanical properties of hot roll bonded Cu/Mo/Cu clad sheets were systematically investigated and the theoretical prediction model of the coefficient of thermal expansion(CTE)o...The law of microstructure evolution and mechanical properties of hot roll bonded Cu/Mo/Cu clad sheets were systematically investigated and the theoretical prediction model of the coefficient of thermal expansion(CTE)of Cu/Mo/Cu clad sheets was established successfully.The results show that the deformation of Cu and Mo layers was gradually coherent with an increase in rolling reduction and temperature and excellent interface bonding was achieved under the condition of a large rolling reduction.The development of the microstructure and texture through the thickness of Cu and Mo layers was inhomogeneous.This phenomenon can be attributed to the friction between the roller and sheet surface and the uncoordinated deformation between Cu and Mo.The tensile strength of the clad sheets increased with increasing rolling reduction and the elongation was gradually decreased.The CTE of Cu/Mo/Cu clad sheets was related to the volume fraction of Mo.The finite element method can simulate the deformation and stress distribution during the thermal expansion process.The simulation result indicates that the terminal face of the clad sheets was sunken inward.展开更多
We present the thermal expansion coefficient （TEC） measurement technology of compensating for the effect of variations in the refractive index based on a Nd： YA G laser feedback system, the beam frequency is shifte...We present the thermal expansion coefficient （TEC） measurement technology of compensating for the effect of variations in the refractive index based on a Nd： YA G laser feedback system, the beam frequency is shifted by a pair of aeousto-optic modulators and then the heterodyne phase measurement technique is used. The sample measured is placed in a muffle furnace with two coaxial holes opened on the opposite furnace walls. The measurement beams hit perpendicularly and coaxially on each surface of the sample. The reference beams hit on the reference mirror and the high-refiectivity mirror, respectively. By the heterodyne configuration and computing, the influences of the vibration, distortion of the sample supporter and the effect of variations in the refractive index are measured and largely minimized. For validation, the TECs of aluminum samples are determined in the temperature range of 29-748K, confirming not only the precision within 5 × 10-7 K-1 and the accuracy within 0.4% from 298K to 448K but also the high sensitivity non-contact measurement of the lower reflectivity surface induced by the sample oxidization from 448 K to 748 K.展开更多
Thermal expansion is a common phenomenon in both metals and alloys, which is important for metallic material applications in modern industry, especially in nuclear and aerospace industries. A lower thermal expansion c...Thermal expansion is a common phenomenon in both metals and alloys, which is important for metallic material applications in modern industry, especially in nuclear and aerospace industries. A lower thermal expansion coefficient may cause lower thermal stress and higher accuracy. A new Zr-based alloy is developed and presented.The XRD diffraction results demonstrate that only a close-packed hexagonal phase（α or α＇ phase） exists in the microstructure. The thermal expansion and mechanical properties are studied. According to the experimental results, the new Zr-based alloy presents a low thermal expansion coefficient and good mechanical properties.Also,its thermal expansion coefficient is stable through solution treatment.展开更多
The basic glass of Li2O-Al2O3-SiO2 system using P2O5 as nucleator was prepared by means of conventional melt quenching technology, and the heat-treatment process was determined by using differential thermal analysis. ...The basic glass of Li2O-Al2O3-SiO2 system using P2O5 as nucleator was prepared by means of conventional melt quenching technology, and the heat-treatment process was determined by using differential thermal analysis. The crystalline phases and the microstructure of the glass-ceramics were investigated by using X-ray diffraction and scanning electron microscopy. The results show that the glass based on Li2O-Al2O3-SiO2 oxides using P2O5 as nucleator can be prepared at lower melt temperature of 1 450 ℃ and the glass-ceramics with lower thermal expansion coefficient of 21.6×10-7 ℃-1 can also be obtained at 750 ℃. The glass-ceramics contain a few crystal phases in which the main crystal phase is β-quartz solid solution and the second crystal phase is β-spodumene solid solution. When the heat treatment temperature is not higher than 650 ℃, the transparent glass-ceramics containing β-quartz solid solution can be prepared. β-quartz solid solution changes into β-spodumene solid solution at about 750 ℃. And the appearance of the glass-ceramics changes from translucent, part opaque to complete opaque with increasing （temperature.）展开更多
The accurate measurement on the compressibility and thermal expansion coefficients of density standard liquid at 2329kg/m3（DSL-2329） plays an important role in the quality control for silicon single crystal manufact...The accurate measurement on the compressibility and thermal expansion coefficients of density standard liquid at 2329kg/m3（DSL-2329） plays an important role in the quality control for silicon single crystal manufacturing. A new method is developed based on hydrostatic suspension principle in order to determine the two coefficients with high measurement accuracy. Two silicon single crystal samples with known density are immersed into a sealed vessel full of DSL-2329. The density of liquid is adjusted with varying liquid temperature and static pressure, so that the hydrostatic suspension of two silicon single crystal samples is achieved. The compression and thermal expansion coefficients are then calculated by using the data of temperature and static pressure at the suspension state. One silicon single crystal sample can be suspended at different state, as long as the liquid temperature and static pressure function linearly according to a certain mathematical relationship. A hydrostatic suspension experimental system is devised with the maximal temperature control error ±50 μK; Silicon single crystal samples can be suspended by adapting the pressure following the PID method. By using the method based on hydrostatic suspension principle, the two key coefficients can be measured at the same time, and measurement precision can be improved due to avoiding the influence of liquid surface tension. This method was further validated experimentally, where the mixture of 1, 2, 3-tribromopropane and 1,2-dibromoethane is used as DSL-2329. The compressibility and thermal expansion coefficients were measured, as 8.5′10–4 K–1 and 5.4′10–10 Pa–1, respectively.展开更多
In the present work, the coefficients of thermal expansion（CTEs） of unidirectional（UD）fiber-reinforced composites are studied. First, an attempt is made to propose a model to predict both longitudinal and transver...In the present work, the coefficients of thermal expansion（CTEs） of unidirectional（UD）fiber-reinforced composites are studied. First, an attempt is made to propose a model to predict both longitudinal and transverse CTEs of UD composites by means of thermo-elastic mechanics analysis. The proposed model is supposed to be a concentric cylinder with a transversely isotropic fiber embedded in an isotropic matrix, and it is subjected to a uniform temperature change. Then a concise and explicit formula is offered for each CTE. Finally, some finite element（FE） models are created by a finite element program MSC. Patran according to different material systems and fiber volume fractions. In addition, the available experimental data and results of other analytical solutions of CTEs are presented. Comparisons are made among the results of the cylinder model,the finite element method（FEM）, experiments, and other solutions, which show that the predicted CTEs by the new model are in good agreement with the experimental data. In particular, transverse CTEs generally offer better agreements than those predicted by most of other solutions.展开更多
To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the ...To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the porosity in 2.5D C/SiC composites. The fiber direction of warp is defined by cosine function to simulate the undulation of warp, and based on uniform strain assumption, analytical model of the elastic modulus and coefficient of thermal expansion （CTE） for 2.5D C/SiC composites were established by using dual- scale model. The result is found to correlate reasonably well with the predicted results and experimental results. The parametric study also demonstrates the effects of the fiber volume fraction, distance of warp yarn, and porosity in micro-scale on the mechanical properties and the coefficients of thermal expansion.展开更多
Firstly,the relation between the coefficient of thermal expansion(CTE)and the volume fraction of TiO_(2) was investigated, and also the influence of relative density of ceramic on the CTE was studied.The results show ...Firstly,the relation between the coefficient of thermal expansion(CTE)and the volume fraction of TiO_(2) was investigated, and also the influence of relative density of ceramic on the CTE was studied.The results show that the volume fraction of TiO_(2) and the relative density both make influence on the CTE of ZrO_(2)-TiO_(2) ceramic.According to the results,the ZrO_(2)-TiO_(2)(volume fraction of TiO_(2) is 27%)ceramic die with the similar CTE(8.92×10^(-6) ℃^(-1))to Ti6Al4V was fabricated.Secondly,to evaluate the dimensional accuracy of the workpiece superplastically formed,the Ti6Al4V impression experiment was performed.The result shows that the dimensional inaccuracy of workpiece is 0.003.Thirdly,in order to evaluate the practicability,the experiment of superplastic forming Ti6Al4V using ZrO_(2)-TiO_(2) cylinder ceramic die was carried out.The Ti6Al4V cylinder shows good shape retention and surface quality,and high dimensional accuracy.The ceramic dies seem to be adequate for superplastic forming the high accuracy Ti6Al4V, and the trials have confirmed the potential of the ZrO_(2)-TiO_(2) ceramic die.展开更多
The coefficients of linear thermal expansions （CLEs） of magnetic elements Fe, Co and Ni were assessed from experimental information using theoretical models combined with MATLAB calculations. Model parameters can be...The coefficients of linear thermal expansions （CLEs） of magnetic elements Fe, Co and Ni were assessed from experimental information using theoretical models combined with MATLAB calculations. Model parameters can be determined accurately, and the assessed data are in good agreement with the experimental results. To facilitate the assessments, theories of thermal expansion were applied to separate CLEs into its nonmagnetic and magnetic components. The calculations of nonmagnetic contribution to CLEs were based on the modified Gruineisen- Debye model, in which the Debye temperature was regarded as an undetermined constant. In order to put the prediction of CLEs at the magnetic transition region on a sound physical basis, two kinds of theoretical models were innovatively used to calculate the magnetic contribution to CLEs, i.e., the Bragg-Williams model and the Fermi-Dirac distribution function. Model parameters were evaluated from experimental data using least square method. Detailed comparisons were made with the published experimental data and the calculated total CLEs. A satisfactory agreement is reached.展开更多
基金Funded by National Natural Science Foundation of China(No.52172007)Jiangsu Science and Technology Innovation Project for Carbon Peaking and Carbon Neutrality(No.BE2022035)。
文摘Focusing on the ultralow expansion functionality of the crystalized glass containing the cordierite crystal phase with the molar composition 20.7MgO·20.7Al_(2)O_(3)·51.6SiO_(2)·7.0TiO_(2),we systematically investigated impacts of thermal treatment protocols on T dependence of coefficients of thermal expansion(CTE).Except for the phase compositions,morphology is identified as another important factor to control the T dependence of CTE.By using X-ray diffraction and scanning electron microscope,various modes of T dependence of CTE for crystallized glasses are ascribed to their different phase compositions and microstructure with finely dispersed nanoparticles.These understanding contributes to the further modification of CTE of the crystalized glass by altering their thermal treatment scenarios.
基金supported by the National Key Research and Development Program of China(No.2022YFB3708400)the National Natural Science Foundation of China(No.52305158)+1 种基金the Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001)the Science Innovation Foundation of Shanghai Academy of Spaceflight Technology(No.USCAST2021-18).
文摘Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive performance of materials,but the processing difficulty,especially in ceramics forming,limits the control and innovation of material architecture.Here,combined with 3D printing and squeeze infiltration technology,two precisely controllable architectures of AZ91/Al_(2)O_(3)interpenetrating phase composites(IPC)with ceramic scaffold were prepared.The interface,properties and impact of different architecture on IPC performance were studied by experiments and finite element simulation.The metallurgical bonding of the interface was realized with the formation of MgAl_(2)O_(4)reaction layer.The IPC with 1 mm circular hole scaffold(1C-IPC)exhibited significantly improved elastic modulus of 164 GPa,high compressive strength of 680 MPa,and good CTE of 12.91×10^(-6)K^(−1),which were 3.64 times,1.98 times and 55%of the Mg matrix,respectively.Their elastic modulus,compressive strength,and CTE were superior to the vast majority of Mg alloys and Mg based composites.The reinforcement and matrix were bicontinuous and interpenetrating each other,which played a critical role in ensuring the potent strengthening effect of the Al_(2)O_(3)reinforcement by efficient load transfer.Under the same volume fraction of reinforcements,compared to IPC with 1 mm hexagonal hole scaffold(1H-IPC),the elastic modulus and compressive strength of 1C-IPC increased by 15%and 28%,respectively,which was due to the reduced stress concentration and more uniform stress distribution of 1C-IPC.It shows great potential of architecture design in improving the performance of composites.This study provides architectural design strategy and feasible preparation method for the development of high performance materials.
文摘Introduction The predominant characteristics of high-altitude climates include low air pressure,low humidity,and large diurnal temperature fluctuations.In practical engineering scenarios in high-altitude regions,many pier surface cracks only appear several months after erection,and cyclic thermal stress is identified as the main trigger for such cracking.The thermal stress in concrete structures has been investigated for decades but remains incompletely understood.Structural engineers typically regard concrete as an isotropic material and calculate the thermal stress using code-specified coefficients of thermal expansion(CTEs)along with temperature conditions and constraints.Because the CTE of hardened cement paste is more than twice that of many aggregates,reducing the CTE of coarse aggregates can further exacerbate the thermal deformation incompatibility between the coarse aggregate and mortar matrix.In this paper,a comprehensive thermal-elastic mechanics model for pier concrete was developed to analysis the temperature-induced surface stress.Methods A series of mechanical and thermophysical tests were conducted on the diorite aggregate,ITZ cement paste,and mortar,and concrete.A test pier was constructed on open ground near the Yarlung Zangbo River at an altitude of 3800 m.The pier had a diameter of 1.8 m and height of 2 m.Temperature sensors were embedded in the cross-section at a height of 1 m,positioned along the southnorth and east-west directions.The embedding depths(distances from the pier surface)were 0,1.5,3,4.5,6,7.5,9,12,15,20,25,30,35,40,50,60,70,80 cm,and 90 cm.A model of the bridge pier concrete for surface-level analysis was constructed.The model consists of a concrete unit formed as a sphere-shell-shell composite,including the aggregate,ITZ,and mortar layers,embedded in the surface layer of a bridge pier.Outside this unit,the pier concrete was treated as an isotropic,homogeneous elastic material.The real-time internal temperature fields of high-altitude concrete bridge piers,measured on-site,were incorporated into the model.By applying thermoelastic mechanics theory and finite element solutions for plane strain problems,the three-dimensional thermal stresses on the surface layer of high-altitude bridge piers were analyzed Results and discussion During the experimental period,the lowest and highest temperatures on the bridge pier in the high-altitude region were 9.6 ℃ and 42.6 ℃,respectively.These occurred before sunrise and sunset on sunny days,respectively,corresponding to the local maximum temperature gradients during the surface heating and cooling stages,as well as the maximum temperature difference between the surface and center during these stages.The thermal stress on the pier concrete surface was obtained by superimposing the stresses caused by the uneven distribution of the internal temperature field and those caused by the incompatible thermal deformation among the different components in the surface concrete Before the erection of the upper structures,the absolute values of the tangential and vertical stresses were the same;therefore,only one curve was observed.From 22:00 to 8:00,the pier concrete surface was in tension,whereas from 11:00 to 22:00,the pier concrete surface was in compression.The surface of the pier concrete was subjected to biaxial forces of equal magnitude with a maximum compressive stress of 12.52 MPa and maximum tensile stress of 2.15 MPa,respectively at 18:00 and 8:00.According to the fatigue equation,the concrete was predicted to crack after 21 d of temperature cycling.Moreover,if humidity-induced stress is added on top of this,the tensile stress may approach or even exceed the concrete's tensile strength,thereby posing a significant risk of cracking.After the erection of upper structures,the tangential and vertical stresses no longer coincide because the upper structures have been erected.The curve of the tangential stress is unchanged,whereas the curve of the vertical stress is translated downwards by 1.57 MPa due to the structural deadweight.Therefore,the maximum tangential compressive stress remained 12.52 MPa,whereas the maximum vertical compressive stress increased to 14.09 MPa.Additionally,the maximum tangential tensile stress was 2.15 MPa,and the maximum vertical tensile stress was 0.58 MPa.According to Appendix C of GB/T 50010 and the fatigue equation,stresses are unlikely to cause cracking of the pier concrete surface.Although a higher CTE of the coarse aggregate slightly increased the maximum compressive stress,the differences among the three groups of concrete were minimal and could be ignored.Specifically,the maximum compressive stresses on the pier concrete surface were 12.54,12.45 MPa,and 12.56 MPa when using diorite,limestone,and basalt,respectively.By contrast,a lower CTE of the coarse aggregate results in a greater maximum tensile stress on the pier concrete surface.For example,when using limestone,which has a low CTE,the maximum tensile stress on the pier concrete surface is 2.28 MPa,compared to 2.17 MPa when using diorite and 2.14 MPa when using basalt.The finite element simulation results indicated that the maximum compressive stress on the pier concrete surface was 11.72 MPa,whereas the maximum tensile stress was 2.10 MPa.These results are approximately consistent with the theoretical calculations.This consistency provides mutual verification.Conclusions Surface cracking in pier concrete occurs predominantly before the erection of upper structures.Under sunny conditions,the orthogonal decomposition of the superficial stress revealed that the maximum compressive stress during the day was approximately 12.52 MPa,whereas the maximum tensile stress was approximately 2.15 MPa.This tensile stress approached the tensile strength of the C35 concrete under biaxial tension.The risk of cracking increased significantly when humidity-induced stress was considered.After the erection of upper structures,the maximum tangential tensile stress on the pier surface remained at 2.15 MPa while the maximum vertical stress decreased to 0.58 MPa,both of which are well below the tensile strength of C35 concrete under biaxial tension.Although the use of coarse aggregates with a lower coefficient of thermal expansion reduced the tensile stress induced by temperature gradients,it increased the stress owing to material deformation incompatibility,leading to a slight increase in the maximum tensile stress on the pier concrete surface.
基金support from the National Natural Science Foundation of China(Grant No.12272146)the Fundamental Research Funds for the Central Universities(Grant No.2024BRA009)the Young Top-notch Talent Cultivation Program of Hubei Province,is appreciated.
文摘Twisted polymer artificial muscles activated by thermal heating represent a new class of soft actuators capable of generating torsional actuation.The thermal torsion effect,characterized by the reversible untwisting of twisted fibers as temperature increases due to greater radial than axial thermal expansion,is crucial to the actuation performance of these artificial muscles.This study explores the thermal torsion effect of polymer muscles made of twisted Nylon 6 fibers in experimental and theoretical aspects,focusing on the interplay between material properties and temperature.It is revealed that the thermal torsion effect enhances the actuation performance of the twisted polymer actuator while the thermal softening effect diminishes it.A thermal-mechanical model incorporating both the thermal torsion effect and thermal softening effect is used to predict the recovered torque of the twisted polymer actuators.An optimal bias angle and operating temperature are identified to maximize the recovered torque.Analysis of strain and stress distributions in the cross-section of the twisted polymer fiber shows that the outer layers of the fiber predominantly contribute to the torsional actuation.This work aids in the precise control and structural optimization of the thermally-activated twisted polymer actuators.
基金supported by the International Visegrad Fund(project V4-Japan Joint Research Program,Ref.JP3936)the National Research,Development and Innovation Office(Contract No.:2019-2.1.7-ERA-NET-2021-00030)+1 种基金Support by the Ministry of Education,Youth and Sports of Czech Republic in the framework of Visegrad Group(V4)-Japan Joint Research Program-Advanced Materials under grant No 8F21011 is gratefully acknowledged by K.M.,D.D.and A.Fsupported by JST SICORP Grant Number JPMJSC2109,Japan.
文摘Dilute Mg alloys processed by the rapidly solidified ribbon consolidation(RSRC)technique are candidate materials for structural applications due to their enhanced mechanical performance.The thermal stability of the structure in these alloys strongly influences their mechanical performance at elevated temperatures.In this study,an RSRC-processed Mg-1%Ca-0.5%Zn-0.1%Y-0.03%Mn(at%)alloy was heated at a constant rate up to 833 K,and concurrently in situ X-ray diffraction(XRD)measurements were performed using synchrotron radiation in order to monitor the changes in the structure.In addition,ex situ electron microscopy investigations were carried out before and after annealing to complete the XRD study.On the basis of XRD results,the stages of the microstructure evolution during heating were identified.In addition,the thermal expansion coefficients of the matrix and the Mg_(2)Ca secondary phase were determined.Between 299 and 400 K,the lattice constants of both the matrix and the Mg_(2)Ca phase increased due to thermal expansion.In the temperature range of 400-673 K,the increase of the lattice constants with increasing the temperature continued,but their rate was different for the two phases which can induce thermal stresses.Between 673 and 753 K,the lattice constants of the secondary phase did not change most probably due to the compensating effects of the thermal expansion and the decrease of the Ca content.In the temperature range of 753-793 K,the Mg_(2)Ca phase started to dissolve.Between 793 and 833 K the dissolution continued,and additionally the matrix was partially melted.
基金Research Project of Hubei Provincial Department of Science and Technology(Grant no.2024CSA075)Key Project of the National Natural Science Foundation of China(Grant No.U21A2058)for fnancially supporting this work.
文摘Mullite-silica rich glass(MSRG)composites are a more efficient material than chamotte for industrial utilization of clay in refractory applications.The properties of the MSRG composites depend on the amount and composition of the mulite and glass phases,which are related to the chemical composition of the MSRG composites based on clay.In the present work,the relationship between the phase and the chemical composition of the MSRG composites,and the effects of the chemical composition of the glass phase on the viscosity and coefficient of thermal expansion(CTE)of the glass phase were discussed on the basis of the measurements on 17 MSRG composite samples produced from clay.It is found that the Al_(2)O_(3)/SiO_(2) ratio(AS ratio)in clay strongly affects the amount of the mullite and glass phases in the MSRG composites,and the distributions of SiO_(2),TiO_(2)and Al_(2)O_(3) contents in the mullite and glass phases.With the increase of the A/S ratio of clay,the mullite content increases but the the glass phase content decreases in the MSRG composites.The viscosity and CTE of the glass phase depend on its A/S ratio and the amount of impurity oxides.When the A/S ratio in the glass phase is less than 0.15,the viscosity of the liquid formed by the melting of the glass phase at elevated temperatures rapidly increases with the decrease in the A/S ratio.The CTE of the glass phase depends on the contents of Si0_(2)and(K_(2)O+Na_(2)O).
文摘The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green's function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.
基金Item Sponsored by Shanghai Leading Academic Discipline Project(T0101)Science and Technology Commission of Shanghai Municipality(065211028)
文摘On the basis of the uniform design method, six kinds of martensitic hot work die steels were designed. The phase transformation temperatures including Ac1 , Ac3 , and Ms were measured by DIL805A quenching dilatometer. The influences of the main elements on phase transformation temperatures were analyzed by quadratic stepwise regression analysis, and three corresponding equations were obtained. These equations, in which the interactions of the elements were considered, showed more effectiveness than the traditional ones. In addition, the thermal expansion coefficients of these steels in annealed state and quenched state were also obtained during the tests. The influences of chemical composition and temperature on the thermal expansion coefficient were analyzed; the equations obtained were verified by using several kinds of steels. The predicted values were in accordance with the results of the experiments.
基金supported by the National Natural Science Foundation of China (Grants 11332004, 11572071)the Program for Changjiang Scholars and Innovative Research Team in Dalian University of Technology (PCSIRT)+2 种基金111 Project (Grant B14013)the CATIC Industrial Production Projects (Grant CXY2013DLLG32)the Fundamental Research Funds for the Central Universities (Grant DUT15ZD101)
文摘Asymptotic homogenization (AH) is a general method for predicting the effective coefficient of thermal expansion (CTE) of periodic composites. It has a rigorous mathematical foundation and can give an accurate solution if the macrostructure is large enough to comprise an infinite number of unit cells. In this paper, a novel implementation algorithm of asymptotic homogenization (NIAH) is developed to calculate the effective CTE of periodic composite materials. Compared with the previous implementation of AH, there are two obvious advantages. One is its implementation as simple as representative volume element (RVE). The new algorithm can be executed easily using commercial finite element analysis (FEA) software as a black box. The detailed process of the new implementation of AH has been provided. The other is that NIAH can simultaneously use more than one element type to discretize a unit cell, which can save much computational cost in predicting the CTE of a complex structure. Several examples are carried out to demonstrate the effectiveness of the new implementation. This work is expected to greatly promote the widespread use of AH in predicting the CTE of periodic composite materials.
基金This research was funded by the National High Technology Research and Development Program of China(Grant No.2002AA302204)Science and Technology Program of Guangdong Provrince of China(Grant No.2001A1070102).
文摘Usually the thermal expansion coefficients (TEC) of metals are higher than that of porcelains. In order to match the TECs in the case of coating porcelains on metals, high TEC porcelains are needed. In this research, the high TEC phase leucite (KAlSi2 O6) in the high TEC porcelain was prepared by sol-gel method. The crystal size of leucite made by sol-gel is about 77nm through controlling the process parameters. The process from xerogel to leucite was investigated by means of DSC (differential scanning calorimetry), TG (thermogravimetry), XRD ( X-ray diffraction) and IR (infrared absorption spectrum). Leucite had been detected after the gel was treated at 900℃, this formation temperature is about 250℃ lower than that of melting method. The porcelain made from 50% of the leucite powder and 50% of low fused temperature frit has an average TEC of 19.2×10-6/℃ C from room temperature to 450℃, which is much higher than the common porcelains.
文摘This study evaluated the adhesion of zirconia core ceramics with their corresponding veneering ceramics, having different thermal expansion coefficients （TECs）, when zirconia ceramics were coloured at green stage. Zirconia blocks （N=240; 6 mm x 7 mm x 7 mm） were manufactured from two materials namely, ICE Zirconia （Group 1） and Prettau Zirconia （Group 2）. In their green stage, they were randomly divided into two groups. Half of the specimens were coloured with colouring liquid （shade A2）, Three different veneering ceramics with different TEC （ICE Ceramic, GC Initial Zr and IPS e.max Ceram） were fired on both coloured and non-coloured zirconia cores. Specimens of high noble alloys （Esteticor Plus） veneered with ceramic （VM 13） （n= 16） acted as the control group. Core-veneer interface of the specimens were subjected to shear force in the Universal Testing Machine （0.5 mm-min-1）. Neither the zirconia core material （P=0.318） nor colouring （P=0.188） significantly affected the results （three-way analysis of variance, Tukey＇s test）. But the results were significantly affected by the veneering ceramic （P=0.000）. Control group exhibited significantly higher mean bond strength values （45.7__.8） MPa than all other tested groups （（27.1__.4.1）-（39.7__.4.7） and （27.4__.5.6）-（35.9___4.7） MPa with and without colouring, respectively） （P^0.001）. While in zirconia-veneer test groups, predominantly mixed type of failures were observed with the veneering ceramic covering ~ 1/3 of the substrate surface, in the metal-ceramic group, veneering ceramic was left adhered 1/3 of the metal surface. Colouring zirconia did not impair adhesion of veneering ceramic, but veneering ceramic had a significant influence on the core-veneer adhesion. Metal-ceramic adhesion was more reliable than all zirconia-veneer ceramics tested.
基金financial supports from the National Natural Science Foundation of China (No.51421001)the Fundamental Research Funds for the Central Universities,China (Nos.2019CDQY CL001,2019CDCGCL204,2020CDJDPT001)the Research Project of State Key Laboratory of Vehicle NVH and Safety Technology,China (No.NVHSKL-201706)。
文摘The law of microstructure evolution and mechanical properties of hot roll bonded Cu/Mo/Cu clad sheets were systematically investigated and the theoretical prediction model of the coefficient of thermal expansion(CTE)of Cu/Mo/Cu clad sheets was established successfully.The results show that the deformation of Cu and Mo layers was gradually coherent with an increase in rolling reduction and temperature and excellent interface bonding was achieved under the condition of a large rolling reduction.The development of the microstructure and texture through the thickness of Cu and Mo layers was inhomogeneous.This phenomenon can be attributed to the friction between the roller and sheet surface and the uncoordinated deformation between Cu and Mo.The tensile strength of the clad sheets increased with increasing rolling reduction and the elongation was gradually decreased.The CTE of Cu/Mo/Cu clad sheets was related to the volume fraction of Mo.The finite element method can simulate the deformation and stress distribution during the thermal expansion process.The simulation result indicates that the terminal face of the clad sheets was sunken inward.
基金Supported by the National Natural Science Foundation of China under Grant No F050306
文摘We present the thermal expansion coefficient （TEC） measurement technology of compensating for the effect of variations in the refractive index based on a Nd： YA G laser feedback system, the beam frequency is shifted by a pair of aeousto-optic modulators and then the heterodyne phase measurement technique is used. The sample measured is placed in a muffle furnace with two coaxial holes opened on the opposite furnace walls. The measurement beams hit perpendicularly and coaxially on each surface of the sample. The reference beams hit on the reference mirror and the high-refiectivity mirror, respectively. By the heterodyne configuration and computing, the influences of the vibration, distortion of the sample supporter and the effect of variations in the refractive index are measured and largely minimized. For validation, the TECs of aluminum samples are determined in the temperature range of 29-748K, confirming not only the precision within 5 × 10-7 K-1 and the accuracy within 0.4% from 298K to 448K but also the high sensitivity non-contact measurement of the lower reflectivity surface induced by the sample oxidization from 448 K to 748 K.
基金Supported by the Postdoctoral Science Foundation of Hebei Province under Grant No B2017003008the National Natural Science Foundation of China under Grant Nos 51531005,51671166,51571174 and 51604241the Natural Science Foundation of Hebei Province under Grant No E2016203395
文摘Thermal expansion is a common phenomenon in both metals and alloys, which is important for metallic material applications in modern industry, especially in nuclear and aerospace industries. A lower thermal expansion coefficient may cause lower thermal stress and higher accuracy. A new Zr-based alloy is developed and presented.The XRD diffraction results demonstrate that only a close-packed hexagonal phase（α or α＇ phase） exists in the microstructure. The thermal expansion and mechanical properties are studied. According to the experimental results, the new Zr-based alloy presents a low thermal expansion coefficient and good mechanical properties.Also,its thermal expansion coefficient is stable through solution treatment.
文摘The basic glass of Li2O-Al2O3-SiO2 system using P2O5 as nucleator was prepared by means of conventional melt quenching technology, and the heat-treatment process was determined by using differential thermal analysis. The crystalline phases and the microstructure of the glass-ceramics were investigated by using X-ray diffraction and scanning electron microscopy. The results show that the glass based on Li2O-Al2O3-SiO2 oxides using P2O5 as nucleator can be prepared at lower melt temperature of 1 450 ℃ and the glass-ceramics with lower thermal expansion coefficient of 21.6×10-7 ℃-1 can also be obtained at 750 ℃. The glass-ceramics contain a few crystal phases in which the main crystal phase is β-quartz solid solution and the second crystal phase is β-spodumene solid solution. When the heat treatment temperature is not higher than 650 ℃, the transparent glass-ceramics containing β-quartz solid solution can be prepared. β-quartz solid solution changes into β-spodumene solid solution at about 750 ℃. And the appearance of the glass-ceramics changes from translucent, part opaque to complete opaque with increasing （temperature.）
基金Supported by National Natural Science Foundation of China(Grant No.51105347)National Key Technology R&D Program of Ministry of Science and Technology of China(Grant No.2011BAI02B03)
文摘The accurate measurement on the compressibility and thermal expansion coefficients of density standard liquid at 2329kg/m3（DSL-2329） plays an important role in the quality control for silicon single crystal manufacturing. A new method is developed based on hydrostatic suspension principle in order to determine the two coefficients with high measurement accuracy. Two silicon single crystal samples with known density are immersed into a sealed vessel full of DSL-2329. The density of liquid is adjusted with varying liquid temperature and static pressure, so that the hydrostatic suspension of two silicon single crystal samples is achieved. The compression and thermal expansion coefficients are then calculated by using the data of temperature and static pressure at the suspension state. One silicon single crystal sample can be suspended at different state, as long as the liquid temperature and static pressure function linearly according to a certain mathematical relationship. A hydrostatic suspension experimental system is devised with the maximal temperature control error ±50 μK; Silicon single crystal samples can be suspended by adapting the pressure following the PID method. By using the method based on hydrostatic suspension principle, the two key coefficients can be measured at the same time, and measurement precision can be improved due to avoiding the influence of liquid surface tension. This method was further validated experimentally, where the mixture of 1, 2, 3-tribromopropane and 1,2-dibromoethane is used as DSL-2329. The compressibility and thermal expansion coefficients were measured, as 8.5′10–4 K–1 and 5.4′10–10 Pa–1, respectively.
文摘In the present work, the coefficients of thermal expansion（CTEs） of unidirectional（UD）fiber-reinforced composites are studied. First, an attempt is made to propose a model to predict both longitudinal and transverse CTEs of UD composites by means of thermo-elastic mechanics analysis. The proposed model is supposed to be a concentric cylinder with a transversely isotropic fiber embedded in an isotropic matrix, and it is subjected to a uniform temperature change. Then a concise and explicit formula is offered for each CTE. Finally, some finite element（FE） models are created by a finite element program MSC. Patran according to different material systems and fiber volume fractions. In addition, the available experimental data and results of other analytical solutions of CTEs are presented. Comparisons are made among the results of the cylinder model,the finite element method（FEM）, experiments, and other solutions, which show that the predicted CTEs by the new model are in good agreement with the experimental data. In particular, transverse CTEs generally offer better agreements than those predicted by most of other solutions.
基金Funded by the National Basic Research Program of China,National Natural Science Foundation of China(No.51075204)Aeronautical Science Foundation of China(No.2012ZB52026)+1 种基金Research Fund for the Doctoral Program of Higher Education of China(No.20070287039)NUAA Research Funding(No.NZ2012106)
文摘To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the porosity in 2.5D C/SiC composites. The fiber direction of warp is defined by cosine function to simulate the undulation of warp, and based on uniform strain assumption, analytical model of the elastic modulus and coefficient of thermal expansion （CTE） for 2.5D C/SiC composites were established by using dual- scale model. The result is found to correlate reasonably well with the predicted results and experimental results. The parametric study also demonstrates the effects of the fiber volume fraction, distance of warp yarn, and porosity in micro-scale on the mechanical properties and the coefficients of thermal expansion.
文摘Firstly,the relation between the coefficient of thermal expansion(CTE)and the volume fraction of TiO_(2) was investigated, and also the influence of relative density of ceramic on the CTE was studied.The results show that the volume fraction of TiO_(2) and the relative density both make influence on the CTE of ZrO_(2)-TiO_(2) ceramic.According to the results,the ZrO_(2)-TiO_(2)(volume fraction of TiO_(2) is 27%)ceramic die with the similar CTE(8.92×10^(-6) ℃^(-1))to Ti6Al4V was fabricated.Secondly,to evaluate the dimensional accuracy of the workpiece superplastically formed,the Ti6Al4V impression experiment was performed.The result shows that the dimensional inaccuracy of workpiece is 0.003.Thirdly,in order to evaluate the practicability,the experiment of superplastic forming Ti6Al4V using ZrO_(2)-TiO_(2) cylinder ceramic die was carried out.The Ti6Al4V cylinder shows good shape retention and surface quality,and high dimensional accuracy.The ceramic dies seem to be adequate for superplastic forming the high accuracy Ti6Al4V, and the trials have confirmed the potential of the ZrO_(2)-TiO_(2) ceramic die.
基金financially supported by China Postdoctoral Science Foundation(No.2009045110)
文摘The coefficients of linear thermal expansions （CLEs） of magnetic elements Fe, Co and Ni were assessed from experimental information using theoretical models combined with MATLAB calculations. Model parameters can be determined accurately, and the assessed data are in good agreement with the experimental results. To facilitate the assessments, theories of thermal expansion were applied to separate CLEs into its nonmagnetic and magnetic components. The calculations of nonmagnetic contribution to CLEs were based on the modified Gruineisen- Debye model, in which the Debye temperature was regarded as an undetermined constant. In order to put the prediction of CLEs at the magnetic transition region on a sound physical basis, two kinds of theoretical models were innovatively used to calculate the magnetic contribution to CLEs, i.e., the Bragg-Williams model and the Fermi-Dirac distribution function. Model parameters were evaluated from experimental data using least square method. Detailed comparisons were made with the published experimental data and the calculated total CLEs. A satisfactory agreement is reached.
