The water-quenched(WQ)2195 Al−Li alloy was subjected to stretching at different temperatures,from room temperature(RT)to−196℃(CT),to investigate the effect of cryogenic deformation on the aging precipitation behavior...The water-quenched(WQ)2195 Al−Li alloy was subjected to stretching at different temperatures,from room temperature(RT)to−196℃(CT),to investigate the effect of cryogenic deformation on the aging precipitation behaviors and mechanical properties.The precipitation kinetics of the T1 phase and the microstructures in peak aging state were investigated through the differential scanning calorimetric(DSC)tests and electron microscopy observation.The results show that−196℃deformation produces a high dislocation density,which promotes the precipitation of the T1 phase and refines its sizes significantly.In addition,the grain boundary precipitates(GBPs)of−196℃-stretched samples are suppressed considerably due to the high dislocation density in the grain interiors,which increases the ductility.In comparison,the strength remains nearly constant.Thus,it is indicated that cryogenic forming has the potential to provide the shape and property control for the manufacture of critical components of aluminum alloys.展开更多
Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cat...Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cation (A = Ba2+). However, the corner-shared CuO2 plaquettes of the infinite network suffer a topotactic rearrangement forming edge-connected units, for instance Cu18O24 cages (polyhedron notation [4641238]) with 2 compound (space group P4/ nmm) will be discussed. The possibility to construct a cuprate super-cage with m3m symmetry (polyhedron notation [4641242438]) is being reported. This super-cage still consists of edge-connected CuO2 plaquettes when fully decorated with copper ions, but with different curvatures, arranged in circles of 9.39 ? of diameter with 139.2° Cu-O-Cu antiferromagnetic super-exchange interaction. On the one hand, the realization of such a quite stable cuprate super-cage as a candidate for high-Tc superconductivity depends on whether a template of suitable size such as the cation or C(CH3)4 enables its formation, and on the other hand the cage can further be stabilized by highly charged cations located along the [111] direction. Synthesis options will be proposed based on suggested cage formation pathways. An X-ray powder pattern was calculated for a less dense cluster structure of Im3m space group with a lattice parameter of a = 14.938 ? and two formula units of Cu46O51 to facilitate future identification. Characteristic X-ray scattering features as identification tool were obtained when the electron distribution of the hollow polyhedron was approximated with electron density in a spherical shell.展开更多
Multiple myeloma(MM),one of the most common hemato logical neoplasms worldwide,originates from malignant plasma cells in the bone marrow.MM remains an incurable disease,although continued treatment advancements have m...Multiple myeloma(MM),one of the most common hemato logical neoplasms worldwide,originates from malignant plasma cells in the bone marrow.MM remains an incurable disease,although continued treatment advancements have markedly increased overall survival.Many patients with MM eventually experience relapse or become treatment-refractory1.Patients with relapsed or refractory multiple myeloma(RRMM)become progressively more challenging to manage and have poor prognosis2.展开更多
The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano cry...The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.展开更多
The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by us...The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by use of optical microscope,electron probe microanalysis and X--ray diffraction.It has been found that there existed the T'phase in the seven alloys.Consequently,it was testified that the T'phase was stable at room temperature.At the same time,the phase relationship was not locally right for the isothermal section of 20℃of Al--Zn--Cu system of the ASM published in 1997.展开更多
Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of di...Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of different phases on the EMW absorbing performance,such as 1T and 2H phase,is still not studied.In this work,micro-1T/2H MoS_(2) is achieved via a facile one-step hydrother-mal route,in which the 1T phase is induced by the intercalation of vip molecules and ions.The EMW absorption mechanism of single MoS_(2) is revealed by presenting a comparative study between 1T/2H MoS_(2) and 2H MoS_(2).As a result,1T/2H MoS_(2) with the matrix loading of 15%exhibits excellent microwave absorption property than 2H MoS_(2).Furthermore,taking the advantage of 1T/2H MoS_(2),a flexible EMW absorbers that ultrathin 1T/2H MoS_(2)grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%.This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.展开更多
In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating ...In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.展开更多
In this study, we report newly found strongly retrograded eclogite blocks in the Kekesu Valley, eastern segment of southwestern Tianshan, northwestern China. Based on detailed petrographi- cal studies and mineral chem...In this study, we report newly found strongly retrograded eclogite blocks in the Kekesu Valley, eastern segment of southwestern Tianshan, northwestern China. Based on detailed petrographi- cal studies and mineral chemistry analyses, we constrain P-T evolution of two representative samples via phase equilibrium modeling method using THERMOCALC software. The peak stage is evidenced by the primary inclusions of omphacite＋glaucophane＋lawsonite （inferred）＋chlorite＋white mica in garnet. Using grossular and pyrope isopleth thermobarometry in garnet, the P peak conditions for this stage were con- strained to be -23 kbar, 480-500℃ and the T peak conditions were constrained to be 19-20 kbar, 500-520℃. Subsequent exhumation led to the transformation of lawsonite to epidote. Using Si-in- phengite barometry, the P was constrained to be 16-20 kbar at T of 500-520 ℃ for this stage. Further retrograde stage was evidenced by the mineral assemblages of glaucophane＋garnet＋epidote＋paragonite＋ chlorite＋white mica＋quartz. Later stage retrogression is evidenced by glaucophane＋epidote＋chlorite＋ quartz＋white mica＋albite＋aetinolite with P of 5-9 kbar when T〈490 ~C, indicating the eclogite may have been exhumed to the middle crust level and overprinted by blueschist-greenschist facies metamorphism. The results show that eclogite at the eastern segment of SW Tianshan shares similar P-T path to the HP rocks from the western segment, implying a similar P-T evolution for these rocks.展开更多
The high-pressure （HP） eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in disp...The high-pressure （HP） eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in dispute. Generally, HP eclogite involves garnet, omphacite, hornblendes and quartz, with or without glaucophane, zoisite and phengite. The garnet has compositional zoning with XMg increase, XCa and XMn decrease from core to rim, which indicates a progressive metamorphism. The phase equilibria of the HP eclogite modeled by the P-T pseudosection method developed recently showed the following： （1） the growth zonation of garnet records a progressive metamorphic PT path from pre-peak condition of 1.9-2.1 GPa at 508~C-514~C to a peak one of 2.3-2.5 GPa at 528~C-531~C for the HP eclogite; （2） the peak mineral assemblage is garnet＋omphacite＋glaucophane＋quartz_＋phengite, likely paragenetic with lawsonite; （3） the extensive hornblendes derive mainly from glaucophane, partial omphacite and even a little garnet due to the decompression with some heating during the post-peak stage, mostly representing the conditions of about 1.4-1.6 GPa and 580~C-640~C, and their growth is favored by the dehydration of lawsonite into zoisite or epidote, but most of the garnet, omphacite or phengite in the HP eclogite still preserve their compositions at peak condition, and they are not obviously equilibrious with the hornblendes.展开更多
The alloys were prepared in Mg-rich corner of Mg-Zn-Ce system. Partial phase equilibrium relationships of these alloys at 350 ℃ were identified by using scanning electron microscopy(SEM), electron probe microanalysis...The alloys were prepared in Mg-rich corner of Mg-Zn-Ce system. Partial phase equilibrium relationships of these alloys at 350 ℃ were identified by using scanning electron microscopy(SEM), electron probe microanalysis(EPMA), X-ray diffraction(XRD) analysis and selected area electron diffraction(SAED) pattern analysis of transmission electron microscopy(TEM). Partial isothermal section of Mg-Zn-Ce system in Mg-rich corner was identified. The results show that there is one ternary compound (T-phase) in Mg-Zn-Ce system. The T-phase is a linear ternary compound in which the content of Ce is about 7.7% (molar fraction); while the content of Zn is changed from 19.3% to 43.6% (molar fraction). The crystal structure of T-phase is C-centered orthorhombic. In addition, one two-phase region of Mg+T-phase and one three-phase region of Mg+T-phase+MgZn(Ce) exist in the Mg-rich corner of Mg-Zn-Ce system at 350 ℃.展开更多
The isothermal section of the Ho-Fe-In system at 773 K has been constructed by X-ray powder diffraction.One known structure ternary compound Er_(12)Fe_(2) In_(3)-type Ho_(12)Fe_(2) In_(3) has been confirmed.At the sam...The isothermal section of the Ho-Fe-In system at 773 K has been constructed by X-ray powder diffraction.One known structure ternary compound Er_(12)Fe_(2) In_(3)-type Ho_(12)Fe_(2) In_(3) has been confirmed.At the same time,solid solutions are not detected in Ho-Fe-In system at 773 K.The magnetic transition and magnetocaloric effect of Ho_(12)Fe_(2.08)In_(2.92) alloy with Er_(12)Fe_(2) In_(3)-type structure were investigated by magnetic susceptibility and isothermal magnetization measurements.One normal antiferromagnetic-paramagnetic transition and another abnormal one are discovered at 18 and 76 K in ground state,respectively.Owing to a first-order field-induced metamagnetic transition(antiferromagnetic-ferromagnetic) at/below the Neel temperature of 18 K),the negative entropy changes are observed at corresponding temperature.There is only a second-order ferromagnetic-paramagnetic transition near Curie temperature(TC),the maximum entropy change(Δ_(Smax)) values are-6.14 J·kg^(-1)·K^(-1) at 3 K and 7.88 J·kg^(-1)·K^(-1) at 28 K in a field range of 0-7 T.The reversible relative cooling power corresponding to negative entropy change can reach about 600 J·kg^(-1) in an wide operating temperature region Δ_(Tcycl)=74 K from 16 to90 K,which suggests that Ho_(12)Fe_(2.08)In_(2.92) could be a potential material for magnetic refrigeration in the corresponding temperature range.展开更多
Fluorinated smectic liquid crystals each with a biphenyl benzoate rigid core are investigated. Molecular structures of the studied compounds have difference only in fluorine position and the length of the carbon chain...Fluorinated smectic liquid crystals each with a biphenyl benzoate rigid core are investigated. Molecular structures of the studied compounds have difference only in fluorine position and the length of the carbon chain. Dielectric relaxation study and electro-optical measurements are carried out with the classical SSFLC geometry. The field-induced phase transitions are studied and the（E,T） phase diagram is established.展开更多
The Precambrian lower crust rocks at the southeastern margin of the North China Craton （NCC） are mainly exposed as granulite xenoliths hosted by Mesozoic dioritic porphyry and metamorphic terrains in the Xuzhou-Suzh...The Precambrian lower crust rocks at the southeastern margin of the North China Craton （NCC） are mainly exposed as granulite xenoliths hosted by Mesozoic dioritic porphyry and metamorphic terrains in the Xuzhou-Suzhou area. Garnet amphiholites and garnet granulites are two kinds of typical lower-crustal xenoliths and were selected to reconstruct different stages of the metamorphic process. In this study, in view of multistage metamorphic evolution and reworking, phase equilibria modeling was used for the first time to better constrain peak P-T conditions of the xenoliths. Some porphyroblastic garnets have a weak zonal structure in composition with homogeneous cores and were surrounded by thin rims with an increase in XMg and a decrease in X Ca （or X Mg）- Clinopyroxene contain varying amounts of Na2O and Al2O3 as well as amphibole of TiO2, while plagioclases are different in calcium contents. Peak metamorphic P-T conditions are calculated by the smallest garnet x（g） （Fe2＋/（Fe2＋＋Mg）） contours and the smallest plagioclase ca（pl） （Ca/（Ca＋Na）） contours in NCFMASHTO （Na2O-CaO-FeO-MgO-Al2O3-SiO2- H20-TiO2-Fe2O3） system, which are consistent with those estimated by conventional geothermobarometry. The new results show that the peak and decompressional P-T conditions for the rocks are 850-900 ℃/ 1.4-1.6 GPa and 820-850 ℃/0.9-1.3 GPa, respectively, suggestive of high and middle-low pressure granulite-facies metamorphism. Combined with previous zircon U-Pb dating and conventional geothermobarometry data, it is indicated that the xenoliths experienced a clockwise P-T-t evolution with nearisothermal deeompressional process, suggestive of the Paleoproterozoic subduction-collision setting. In this regard, the studied region together with Jiao-Liao-Ji belt is further documented to make up a Paleopro- terozoic collisional orogen in the eastern block of the NCC.展开更多
Grinding-induced tm phase transformation and the resultant texture in ceria-yttria-doped tetragonal zirconia polycrystals with varied tetragonality have been studied by XRD. It is observed that the reversible tm phase...Grinding-induced tm phase transformation and the resultant texture in ceria-yttria-doped tetragonal zirconia polycrystals with varied tetragonality have been studied by XRD. It is observed that the reversible tm phase transformation occurs during grinding and the intensity ratio of I(002)t/I(200)t increases with the transformability. The author proposes that the texture induced by grinding at low temperatures is due to the tetragonal variant reorientation via cyclic,reversible tm phase transformation, termed 'transformational domain switching', instead of the ferroelastic one展开更多
In this paper,we have proposed a novel structure of Ka-band based phased array antenna with calibration function.In the design of Kaband antenna,the active phased array system is adopted and the antenna would work in ...In this paper,we have proposed a novel structure of Ka-band based phased array antenna with calibration function.In the design of Kaband antenna,the active phased array system is adopted and the antenna would work in the dual polarization separation mode.We have given out the schematic diagram for the proposed Ka-band antenna,where the Kaband antenna is in the form of waveguide slot array antenna,with 96 units in azimuth and 1 unit in distance.Each group of units is driven by a singlechannel Transmitter/Receiver(T/R)component,and the whole array contains 192 T/R components in total.The size of the T/R component is 55mm(length)×50mm(width)×5.8mm(height),3 Sub-micro Sub-Miniature Push-on(SSMP)blind sockets and a 21-core low-frequency socket are designed on the two sides of the T/R component.In order to meet the technical specifications of phased array antenna,the Ka-band transceiver component is designed based on Low Temperatrue Co-fired Ceramic(LTCC)technology to achieve miniaturization and lightweight.In our approach,the feed network includes two parts:transceiver network and calibration network.The transceiver network consists of 241:8 time-delay power dividers,12 two-way power dividers and 2 six-way time-delay power dividers.The power supply required by theKaband antenna unit is provided to each active component by the power module after Ka band wavelet control distribution.Simulation and measurement results are given in the form of standing wave and scanning capability.展开更多
In this paper, we study the stability of locally rotationally symmetric （LRS） Bianchi I universe model in f（T） gravity through phase space analysis. We assume that the f（T） gravity can be treated as effective da...In this paper, we study the stability of locally rotationally symmetric （LRS） Bianchi I universe model in f（T） gravity through phase space analysis. We assume that the f（T） gravity can be treated as effective dark energy behaving like perfect fluid, and suggest that there are interactions between pressureless matter as well as dark energy. We construct the corresponding autonomous system of equations to check the stability of the model for non phantom, vacuum and phantom phases. It is concluded that critical points remain more stable in phantom phase as compared to non phantom and vacuum cases. Finaily, we discuss the cosmological behavior of the model through some cosmological parameters.展开更多
Phase engineering is an efficient strategy for enhancing the kinetics of electrocatalytic reactions.Herein,phase engineering was employed to prepare high‐performance phosphorous‐doped biphase(1T/2H)MoS_(2)(P‐BMS)na...Phase engineering is an efficient strategy for enhancing the kinetics of electrocatalytic reactions.Herein,phase engineering was employed to prepare high‐performance phosphorous‐doped biphase(1T/2H)MoS_(2)(P‐BMS)nanoflakes for hydrogen evolution reaction(HER).The doping of MoS_(2)with P atoms modifies its electronic structure and optimizes its electrocatalytic reaction kinetics,which significantly enhances its electrical conductivity and structural stability,which are verified by various characterization tools,including X‐ray photoelectron spectroscopy,high‐resolution transmission electron microscopy,X‐ray absorption near‐edge spectroscopy,and extended X‐ray absorption fine structure.Moreover,the hierarchically formed flakes of P‐BMS provide numerous catalytic surface‐active sites,which remarkably enhance its HER activity.The optimized P‐BMS electrocatalysts exhibit low overpotentials(60 and 72 mV at 10 mA cm^(−2))in H_(2)SO_(4)(0.5 M)and KOH(1.0 M),respectively.The mechanism of improving the HER activity of the material was systematically studied using density functional theory calculations and various electrochemical characterization techniques.This study has shown that phase engineering is a promising strategy for enhancing the H*adsorption of metal sulfides.展开更多
基金financially supported by the National Key Research and Development Program of China (No. 2019YFA0708801)the National Natural Science Foundation of China (No. 51875125)。
文摘The water-quenched(WQ)2195 Al−Li alloy was subjected to stretching at different temperatures,from room temperature(RT)to−196℃(CT),to investigate the effect of cryogenic deformation on the aging precipitation behaviors and mechanical properties.The precipitation kinetics of the T1 phase and the microstructures in peak aging state were investigated through the differential scanning calorimetric(DSC)tests and electron microscopy observation.The results show that−196℃deformation produces a high dislocation density,which promotes the precipitation of the T1 phase and refines its sizes significantly.In addition,the grain boundary precipitates(GBPs)of−196℃-stretched samples are suppressed considerably due to the high dislocation density in the grain interiors,which increases the ductility.In comparison,the strength remains nearly constant.Thus,it is indicated that cryogenic forming has the potential to provide the shape and property control for the manufacture of critical components of aluminum alloys.
文摘Convex polyhedral cuprate clusters are being formed through lateral frustration when the a and c lattice parameters of the tetragonal ACuO2 infinite layer structure will become identical by substitution of a large cation (A = Ba2+). However, the corner-shared CuO2 plaquettes of the infinite network suffer a topotactic rearrangement forming edge-connected units, for instance Cu18O24 cages (polyhedron notation [4641238]) with 2 compound (space group P4/ nmm) will be discussed. The possibility to construct a cuprate super-cage with m3m symmetry (polyhedron notation [4641242438]) is being reported. This super-cage still consists of edge-connected CuO2 plaquettes when fully decorated with copper ions, but with different curvatures, arranged in circles of 9.39 ? of diameter with 139.2° Cu-O-Cu antiferromagnetic super-exchange interaction. On the one hand, the realization of such a quite stable cuprate super-cage as a candidate for high-Tc superconductivity depends on whether a template of suitable size such as the cation or C(CH3)4 enables its formation, and on the other hand the cage can further be stabilized by highly charged cations located along the [111] direction. Synthesis options will be proposed based on suggested cage formation pathways. An X-ray powder pattern was calculated for a less dense cluster structure of Im3m space group with a lattice parameter of a = 14.938 ? and two formula units of Cu46O51 to facilitate future identification. Characteristic X-ray scattering features as identification tool were obtained when the electron distribution of the hollow polyhedron was approximated with electron density in a spherical shell.
基金supported by grant from the National Natural Science Foundation of China(Grant No.82300231).
文摘Multiple myeloma(MM),one of the most common hemato logical neoplasms worldwide,originates from malignant plasma cells in the bone marrow.MM remains an incurable disease,although continued treatment advancements have markedly increased overall survival.Many patients with MM eventually experience relapse or become treatment-refractory1.Patients with relapsed or refractory multiple myeloma(RRMM)become progressively more challenging to manage and have poor prognosis2.
文摘The transformation from graphite to turbostratic graphite by means of the treatment with high energy ball milling was investigated by X ray powder diffraction method. It is believed that the size effect of nano crystal leads to this transformation. A possible transformation mechanism is proposed from the change of the eletronic structure of the hexagonal plane of the carbon atoms.
基金This work was supported by National Natural Science Foundation of China(No.50171019)
文摘The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by use of optical microscope,electron probe microanalysis and X--ray diffraction.It has been found that there existed the T'phase in the seven alloys.Consequently,it was testified that the T'phase was stable at room temperature.At the same time,the phase relationship was not locally right for the isothermal section of 20℃of Al--Zn--Cu system of the ASM published in 1997.
基金the National Natural Science Foundation of China(No.51672222)Joint Fund Project-Enterprise-Shaanxi Coal Joint Fund Project(2019JLM-32)+2 种基金Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(CX202054)the Graduate innovation team of Northwestern Polytechnical Universitythe Analysis and Testing Center of Northwestern Polytechnical University for their technical assistance in SEM(Verios G4).
文摘Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide(MoS_(2)).MoS_(2)-based composites are usually used for the electromagnetic wave(EMW)absorber,but the effect of different phases on the EMW absorbing performance,such as 1T and 2H phase,is still not studied.In this work,micro-1T/2H MoS_(2) is achieved via a facile one-step hydrother-mal route,in which the 1T phase is induced by the intercalation of vip molecules and ions.The EMW absorption mechanism of single MoS_(2) is revealed by presenting a comparative study between 1T/2H MoS_(2) and 2H MoS_(2).As a result,1T/2H MoS_(2) with the matrix loading of 15%exhibits excellent microwave absorption property than 2H MoS_(2).Furthermore,taking the advantage of 1T/2H MoS_(2),a flexible EMW absorbers that ultrathin 1T/2H MoS_(2)grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%.This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.
基金supported by the Natural Science Foundation of Henan Province(Grant No.152107000047)
文摘In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.
基金supported by the National Natural Science Foundation of China (No. 41502043)China Postdoctoral Science Foundation (No. 2016T90742)
文摘In this study, we report newly found strongly retrograded eclogite blocks in the Kekesu Valley, eastern segment of southwestern Tianshan, northwestern China. Based on detailed petrographi- cal studies and mineral chemistry analyses, we constrain P-T evolution of two representative samples via phase equilibrium modeling method using THERMOCALC software. The peak stage is evidenced by the primary inclusions of omphacite＋glaucophane＋lawsonite （inferred）＋chlorite＋white mica in garnet. Using grossular and pyrope isopleth thermobarometry in garnet, the P peak conditions for this stage were con- strained to be -23 kbar, 480-500℃ and the T peak conditions were constrained to be 19-20 kbar, 500-520℃. Subsequent exhumation led to the transformation of lawsonite to epidote. Using Si-in- phengite barometry, the P was constrained to be 16-20 kbar at T of 500-520 ℃ for this stage. Further retrograde stage was evidenced by the mineral assemblages of glaucophane＋garnet＋epidote＋paragonite＋ chlorite＋white mica＋quartz. Later stage retrogression is evidenced by glaucophane＋epidote＋chlorite＋ quartz＋white mica＋albite＋aetinolite with P of 5-9 kbar when T〈490 ~C, indicating the eclogite may have been exhumed to the middle crust level and overprinted by blueschist-greenschist facies metamorphism. The results show that eclogite at the eastern segment of SW Tianshan shares similar P-T path to the HP rocks from the western segment, implying a similar P-T evolution for these rocks.
基金funded by the National Natural Science Foundation of China (No.40525006 and 40372032).
文摘The high-pressure （HP） eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in dispute. Generally, HP eclogite involves garnet, omphacite, hornblendes and quartz, with or without glaucophane, zoisite and phengite. The garnet has compositional zoning with XMg increase, XCa and XMn decrease from core to rim, which indicates a progressive metamorphism. The phase equilibria of the HP eclogite modeled by the P-T pseudosection method developed recently showed the following： （1） the growth zonation of garnet records a progressive metamorphic PT path from pre-peak condition of 1.9-2.1 GPa at 508~C-514~C to a peak one of 2.3-2.5 GPa at 528~C-531~C for the HP eclogite; （2） the peak mineral assemblage is garnet＋omphacite＋glaucophane＋quartz_＋phengite, likely paragenetic with lawsonite; （3） the extensive hornblendes derive mainly from glaucophane, partial omphacite and even a little garnet due to the decompression with some heating during the post-peak stage, mostly representing the conditions of about 1.4-1.6 GPa and 580~C-640~C, and their growth is favored by the dehydration of lawsonite into zoisite or epidote, but most of the garnet, omphacite or phengite in the HP eclogite still preserve their compositions at peak condition, and they are not obviously equilibrious with the hornblendes.
基金Project(50471025) supported by the National Natural Science Foundation of ChinaProject(20052028) supported by the Natural Science Foundation of Liaoning Province, ChinaProject(2006BAE04B09-7) supported by the National Key Technology R&D Program during the 11th Five-Year Plan Period
文摘The alloys were prepared in Mg-rich corner of Mg-Zn-Ce system. Partial phase equilibrium relationships of these alloys at 350 ℃ were identified by using scanning electron microscopy(SEM), electron probe microanalysis(EPMA), X-ray diffraction(XRD) analysis and selected area electron diffraction(SAED) pattern analysis of transmission electron microscopy(TEM). Partial isothermal section of Mg-Zn-Ce system in Mg-rich corner was identified. The results show that there is one ternary compound (T-phase) in Mg-Zn-Ce system. The T-phase is a linear ternary compound in which the content of Ce is about 7.7% (molar fraction); while the content of Zn is changed from 19.3% to 43.6% (molar fraction). The crystal structure of T-phase is C-centered orthorhombic. In addition, one two-phase region of Mg+T-phase and one three-phase region of Mg+T-phase+MgZn(Ce) exist in the Mg-rich corner of Mg-Zn-Ce system at 350 ℃.
基金financially supported by the Department of Science and Technology of Sichuan Province in China(No.2017JY0181)。
文摘The isothermal section of the Ho-Fe-In system at 773 K has been constructed by X-ray powder diffraction.One known structure ternary compound Er_(12)Fe_(2) In_(3)-type Ho_(12)Fe_(2) In_(3) has been confirmed.At the same time,solid solutions are not detected in Ho-Fe-In system at 773 K.The magnetic transition and magnetocaloric effect of Ho_(12)Fe_(2.08)In_(2.92) alloy with Er_(12)Fe_(2) In_(3)-type structure were investigated by magnetic susceptibility and isothermal magnetization measurements.One normal antiferromagnetic-paramagnetic transition and another abnormal one are discovered at 18 and 76 K in ground state,respectively.Owing to a first-order field-induced metamagnetic transition(antiferromagnetic-ferromagnetic) at/below the Neel temperature of 18 K),the negative entropy changes are observed at corresponding temperature.There is only a second-order ferromagnetic-paramagnetic transition near Curie temperature(TC),the maximum entropy change(Δ_(Smax)) values are-6.14 J·kg^(-1)·K^(-1) at 3 K and 7.88 J·kg^(-1)·K^(-1) at 28 K in a field range of 0-7 T.The reversible relative cooling power corresponding to negative entropy change can reach about 600 J·kg^(-1) in an wide operating temperature region Δ_(Tcycl)=74 K from 16 to90 K,which suggests that Ho_(12)Fe_(2.08)In_(2.92) could be a potential material for magnetic refrigeration in the corresponding temperature range.
文摘Fluorinated smectic liquid crystals each with a biphenyl benzoate rigid core are investigated. Molecular structures of the studied compounds have difference only in fluorine position and the length of the carbon chain. Dielectric relaxation study and electro-optical measurements are carried out with the classical SSFLC geometry. The field-induced phase transitions are studied and the（E,T） phase diagram is established.
基金financially supported by the National Natural Science Foundation of China (No. 41773020)the National Basic Research Program of China (No. 2015CB856104)the PhD Foundation of the Ministry of Education of China (No. 20133402130008)
文摘The Precambrian lower crust rocks at the southeastern margin of the North China Craton （NCC） are mainly exposed as granulite xenoliths hosted by Mesozoic dioritic porphyry and metamorphic terrains in the Xuzhou-Suzhou area. Garnet amphiholites and garnet granulites are two kinds of typical lower-crustal xenoliths and were selected to reconstruct different stages of the metamorphic process. In this study, in view of multistage metamorphic evolution and reworking, phase equilibria modeling was used for the first time to better constrain peak P-T conditions of the xenoliths. Some porphyroblastic garnets have a weak zonal structure in composition with homogeneous cores and were surrounded by thin rims with an increase in XMg and a decrease in X Ca （or X Mg）- Clinopyroxene contain varying amounts of Na2O and Al2O3 as well as amphibole of TiO2, while plagioclases are different in calcium contents. Peak metamorphic P-T conditions are calculated by the smallest garnet x（g） （Fe2＋/（Fe2＋＋Mg）） contours and the smallest plagioclase ca（pl） （Ca/（Ca＋Na）） contours in NCFMASHTO （Na2O-CaO-FeO-MgO-Al2O3-SiO2- H20-TiO2-Fe2O3） system, which are consistent with those estimated by conventional geothermobarometry. The new results show that the peak and decompressional P-T conditions for the rocks are 850-900 ℃/ 1.4-1.6 GPa and 820-850 ℃/0.9-1.3 GPa, respectively, suggestive of high and middle-low pressure granulite-facies metamorphism. Combined with previous zircon U-Pb dating and conventional geothermobarometry data, it is indicated that the xenoliths experienced a clockwise P-T-t evolution with nearisothermal deeompressional process, suggestive of the Paleoproterozoic subduction-collision setting. In this regard, the studied region together with Jiao-Liao-Ji belt is further documented to make up a Paleopro- terozoic collisional orogen in the eastern block of the NCC.
文摘Grinding-induced tm phase transformation and the resultant texture in ceria-yttria-doped tetragonal zirconia polycrystals with varied tetragonality have been studied by XRD. It is observed that the reversible tm phase transformation occurs during grinding and the intensity ratio of I(002)t/I(200)t increases with the transformability. The author proposes that the texture induced by grinding at low temperatures is due to the tetragonal variant reorientation via cyclic,reversible tm phase transformation, termed 'transformational domain switching', instead of the ferroelastic one
文摘In this paper,we have proposed a novel structure of Ka-band based phased array antenna with calibration function.In the design of Kaband antenna,the active phased array system is adopted and the antenna would work in the dual polarization separation mode.We have given out the schematic diagram for the proposed Ka-band antenna,where the Kaband antenna is in the form of waveguide slot array antenna,with 96 units in azimuth and 1 unit in distance.Each group of units is driven by a singlechannel Transmitter/Receiver(T/R)component,and the whole array contains 192 T/R components in total.The size of the T/R component is 55mm(length)×50mm(width)×5.8mm(height),3 Sub-micro Sub-Miniature Push-on(SSMP)blind sockets and a 21-core low-frequency socket are designed on the two sides of the T/R component.In order to meet the technical specifications of phased array antenna,the Ka-band transceiver component is designed based on Low Temperatrue Co-fired Ceramic(LTCC)technology to achieve miniaturization and lightweight.In our approach,the feed network includes two parts:transceiver network and calibration network.The transceiver network consists of 241:8 time-delay power dividers,12 two-way power dividers and 2 six-way time-delay power dividers.The power supply required by theKaband antenna unit is provided to each active component by the power module after Ka band wavelet control distribution.Simulation and measurement results are given in the form of standing wave and scanning capability.
文摘In this paper, we study the stability of locally rotationally symmetric （LRS） Bianchi I universe model in f（T） gravity through phase space analysis. We assume that the f（T） gravity can be treated as effective dark energy behaving like perfect fluid, and suggest that there are interactions between pressureless matter as well as dark energy. We construct the corresponding autonomous system of equations to check the stability of the model for non phantom, vacuum and phantom phases. It is concluded that critical points remain more stable in phantom phase as compared to non phantom and vacuum cases. Finaily, we discuss the cosmological behavior of the model through some cosmological parameters.
基金National Natural Science Foundation of China,Grant/Award Number:NSFC‐U1904215National Research Foundation of Korea,Grant/Award Number:2021R1A2C2012127。
文摘Phase engineering is an efficient strategy for enhancing the kinetics of electrocatalytic reactions.Herein,phase engineering was employed to prepare high‐performance phosphorous‐doped biphase(1T/2H)MoS_(2)(P‐BMS)nanoflakes for hydrogen evolution reaction(HER).The doping of MoS_(2)with P atoms modifies its electronic structure and optimizes its electrocatalytic reaction kinetics,which significantly enhances its electrical conductivity and structural stability,which are verified by various characterization tools,including X‐ray photoelectron spectroscopy,high‐resolution transmission electron microscopy,X‐ray absorption near‐edge spectroscopy,and extended X‐ray absorption fine structure.Moreover,the hierarchically formed flakes of P‐BMS provide numerous catalytic surface‐active sites,which remarkably enhance its HER activity.The optimized P‐BMS electrocatalysts exhibit low overpotentials(60 and 72 mV at 10 mA cm^(−2))in H_(2)SO_(4)(0.5 M)and KOH(1.0 M),respectively.The mechanism of improving the HER activity of the material was systematically studied using density functional theory calculations and various electrochemical characterization techniques.This study has shown that phase engineering is a promising strategy for enhancing the H*adsorption of metal sulfides.
