In view of complex geological characteristics and alternating loading conditions associated with cyclic large amount of gas injection and withdrawal in underground gas storage(UGS) of China, a series of key gas storag...In view of complex geological characteristics and alternating loading conditions associated with cyclic large amount of gas injection and withdrawal in underground gas storage(UGS) of China, a series of key gas storage construction technologies were established, mainly including UGS site selection and evaluation, key index design, well drilling and completion, surface engineering and operational risk warning and assessment, etc. The effect of field application was discussed and summarized. Firstly, trap dynamic sealing capacity evaluation technology for conversion of UGS from the fault depleted or partially depleted gas reservoirs. A key index design method mainly based on the effective gas storage capacity design for water flooded heterogeneous gas reservoirs was proposed. To effectively guide the engineering construction of UGS, the safe well drilling, high quality cementing and high pressure and large flow surface injection and production engineering optimization suitable for long-term alternate loading condition and ultra-deep and ultra-low temperature formation were developed. The core surface equipment like high pressure gas injection compressor can be manufactured by our own. Last, the full-system operational risk warning and assessment technology for UGS was set up. The above 5 key technologies have been utilized in site selection, development scheme design, engineering construction and annual operations of 6 UGS groups, e.g. the Hutubi UGS in Xinjiang. To date, designed main indexes are highly consistent with actural performance, the 6 UGS groups have the load capacity of over 7.5 billion cubic meters of working gas volume and all the storage facilities have been running efficiently and safely.展开更多
It presented a comparative consideration of General Motors long-term activities on the current subject of fuel-cell-powered electric vehicles vs Toyota Mirai recent results, relevant to prospects on more efficient and...It presented a comparative consideration of General Motors long-term activities on the current subject of fuel-cell-powered electric vehicles vs Toyota Mirai recent results, relevant to prospects on more efficient and safe technologies of the hydrogen on-board storage. It also presented a call on the project International cooperation. The main aim of this paper is to attract attention of General Motors, Toyota and/or other large car companies to a real possibility of developing and using, in the nearest future, of the break-through hydrogen on-board storage technology based on the solid H2 intercalation into graphite nanostructures.展开更多
In response to the actual demands of the energy storage type organic Rankine power generation cycle,this study proposes a new type of jacketed shell and tube heat exchanger with integrated cold storage and heat exchan...In response to the actual demands of the energy storage type organic Rankine power generation cycle,this study proposes a new type of jacketed shell and tube heat exchanger with integrated cold storage and heat exchange.N-tedecane is selected as the phase change material for cold storage,low-temperature water as the cold source,and R134a as the heat source.The phase change material for cold storage is filled inside the jacket tube of the heat exchanger.Cold fluid is introduced into the inner tube to cause the phase change material to condense and store cold.After the cold storage is completed,R134a flows in from the shell side and condenses through heat exchange with the solidified phase change material for energy storage.This study discusses the influence laws of different cold water mass flow rates and temperatures on the cold storage performance of this heat exchanger,and analyzes the condensation effect of R134a.The results show that when the mass flow rate is 0.5 kg/s and the cold water temperature is between 3 and 4℃,the average power of the energy storage heat exchanger in the condensation experiment is 80W,and the average convective heat transfer coefficient is 110.73 W/(m^(2)⋅K).This research provides an experimental basis for the development of energy storage organic Rankine power generation cycles.展开更多
As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental mode...As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
Artificial intelligence(AI)based models have been used to predict the structural,optical,mechanical,and electrochemical properties of zinc oxide/graphene oxide nanocomposites.Machine learning(ML)models such as Artific...Artificial intelligence(AI)based models have been used to predict the structural,optical,mechanical,and electrochemical properties of zinc oxide/graphene oxide nanocomposites.Machine learning(ML)models such as Artificial Neural Networks(ANN),Support Vector Regression(SVR),Multilayer Perceptron(MLP),and hybrid,along with fuzzy logic tools,were applied to predict the different properties like wavelength at maximum intensity(444 nm),crystallite size(17.50 nm),and optical bandgap(2.85 eV).While some other properties,such as energy density,power density,and charge transfer resistance,were also predicted with the help of datasets of 1000(80:20).In general,the energy parameters were predicted more accurately by hybrid models.The hydrothermal method was used to synthesize graphene oxide(GO)and zinc oxide(ZnO)nanocomposites.The increased surface area,conductivity,and stability of graphene oxide in zinc oxide nanoparticles make the composite an ideal option for energy storage.X-ray diffraction(XRD)confirmed the crystallite size of 17.41 nm for the nanocomposite and the presence of GO(12.8○)peaks.The scanning electron microscope(SEM)showed anchored wrinkled GO sheets on zinc oxide with an average particle size of 2.93μm.Energy-dispersive X-ray spectroscopy(EDX)confirmed the elemental composition,and Fouriertransform infrared spectroscopy(FTIR)revealed the impact of GO on functional groups and electrochemical behavior.Photoluminescence(PL)wavelength of(439 nm)and band gap of(2.81 eV)show that the material is suitable for energy applications in nanocomposites.Smart nanocomposite materials with improved performance in energy storage and related applications were fabricated by combining synthesis,characterization,fuzzy logic,and machine learning in this work.展开更多
Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, ...Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, battery technologies are desirable energy storage devices for GLEES due to their easy modularization, rapid response, flexible installation, and short construction cycles. In general, battery energy storage technologies are expected to meet the requirements of GLEES such as peak shaving and load leveling, voltage and frequency regulation, and emergency response, which are highlighted in this perspective. Furthermore, several types of battery technologies, including lead–acid, nickel–cadmium, nickel–metal hydride, sodium–sulfur, lithium-ion, and flow batteries, are discussed in detail for the application of GLEES. Moreover, some possible developing directions to facilitate efforts in this area are presented to establish a perspective on battery technology, provide a road map for guiding future studies, and promote the commercial application of batteries for GLEES.展开更多
Recent worldwide foodborne outbreaks emphasize the need for the development of rapid and accurate method for pathogen detection. To address such issues, a new colony based label-free detection method working on the pr...Recent worldwide foodborne outbreaks emphasize the need for the development of rapid and accurate method for pathogen detection. To address such issues, a new colony based label-free detection method working on the principles of elastic light scattering was introduced. In order to build libraries of scattering images for bacterial pathogens, it is pertinent to determine the effect of preparation and storage of the agar media on the scatter patterns. Scatter patterns of three Escherichia coli serovars (O26, O111 and O157) were studied and used in a model system, after growth on Sorbitol-MacConkey agar plates that were prepared and stored at different conditions in the laboratory. Quantitative image processing software was used to analyze variation in scatter patterns of the same serovar on media prepared under various standard laboratory conditions and to generate a cross-validation matrix for comparison. Based on the results, it was determined that attention should be given during preparation of media so that the agar plates are not air-dried more than 10 - 20 min after solidification at room temperature. The plates could be stored in sealed bags in cold room (4oC - 10oC) for up to a month before use. The findings of this study should provide guidelines in preparation, storage, and handling of media for generation of reproducible scatter patterns of bacterial colonies with the light scattering sensor for pathogen detection.展开更多
The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurat...The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurations. As a part of this investigation, the melting process is simulated from the onset of phase change to the offset involving physics of natural convection in PCM fluid pool. The investigation is carried out by ANSYS Fluent code, which is an efficient numerical analysis tool for investigating fluid flow and convective heat transfer phenomena during PCM melting process. The attention is mainly focused on the extension of contact area between the PCM body and cylindrical capsule to enhance heat transfer rates to PCM bodies during the melting process by employing longitudinal fins in the enclosed capsule. Two commercial PCMs: RT50 and C58, are introduced in a 2D cylindrical pipe with their thermo-physical properties as input for modelling. The selected modelling approach is validated against experimental result with respect to the total enthalpy changes that qualify our model to run in the proceeding calculation. It is ensured that an isothermal boundary condition (373 K) is applied to the inner pipe throughout the series of simulation cases and the corresponding Rayleigh number (Ra) ranges from 104 - 105 and Prandtl number (Pr) 0.05 - 0.07. Finally, parametric study is carried out to evaluate the effect of length, thickness and number of longitudinal fins on the thermal performance of PCM-LHTES (Latent Heat Thermal Energy Storage) system associated with the physics of natural convection process during PCM melting.展开更多
With the development of cloud computing, the mutual understandability among distributed data access control has become an important issue in the security field of cloud computing. To ensure security, confidentiality a...With the development of cloud computing, the mutual understandability among distributed data access control has become an important issue in the security field of cloud computing. To ensure security, confidentiality and fine-grained data access control of Cloud Data Storage (CDS) environment, we proposed Multi-Agent System (MAS) architecture. This architecture consists of two agents: Cloud Service Provider Agent (CSPA) and Cloud Data Confidentiality Agent (CDConA). CSPA provides a graphical interface to the cloud user that facilitates the access to the services offered by the system. CDConA provides each cloud user by definition and enforcement expressive and flexible access structure as a logic formula over cloud data file attributes. This new access control is named as Formula-Based Cloud Data Access Control (FCDAC). Our proposed FCDAC based on MAS architecture consists of four layers: interface layer, existing access control layer, proposed FCDAC layer and CDS layer as well as four types of entities of Cloud Service Provider (CSP), cloud users, knowledge base and confidentiality policy roles. FCDAC, it’s an access policy determined by our MAS architecture, not by the CSPs. A prototype of our proposed FCDAC scheme is implemented using the Java Agent Development Framework Security (JADE-S). Our results in the practical scenario defined formally in this paper, show the Round Trip Time (RTT) for an agent to travel in our system and measured by the times required for an agent to travel around different number of cloud users before and after implementing FCDAC.展开更多
Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes canno...Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.展开更多
The ultracold neutron(UCN)transport code,MCUCN,designed initially for simulating UCN transportation from a solid deuterium(SD_2)source and neutron electric dipole moment experiments,could not simulate UCN storage and ...The ultracold neutron(UCN)transport code,MCUCN,designed initially for simulating UCN transportation from a solid deuterium(SD_2)source and neutron electric dipole moment experiments,could not simulate UCN storage and transportation in a superfluid^(4)He(SFHe,He-Ⅱ)source accurately.This limitation arose from the absence of an^(4)He upscattering mechanism and the absorption of^(3)He.And the provided source energy distribution in MCUCN is different from that in SFHe source.This study introduced enhancements to MCUCN to address these constraints,explicitly incorporating the^(4)He upscattering effect,the absorption of^(3)He,the loss caused by impurities on converter wall,UCN source energy distribution in SFHe,and the transmission through negative optical potential.Additionally,a Python-based visualization code for intermediate states and results was developed.To validate these enhancements,we systematically compared the simulation results of the Lujan Center Mark3 UCN system by MCUCN and the improved MCUCN code(iMCUCN)with UCNtransport simulations.Additionally,we compared the results of the SUN1 system simulated by MCUCN and iMCUCN with measurement results.The study demonstrates that iMCUCN effectively simulates the storage and transportation of ultracold neutrons in He-Ⅱ.展开更多
MXene derivatives are notable two-dimensional nanomaterials with numerous prospective applications in the domains of energy development.MXene derivative,MBene,diversifies its focus on energy storage and harvesting due...MXene derivatives are notable two-dimensional nanomaterials with numerous prospective applications in the domains of energy development.MXene derivative,MBene,diversifies its focus on energy storage and harvesting due to its exceptional electrical conductivity,structural flexibility,and mechanical properties.This comprehensive review describes the sandwich-like structure of the synthesized MBene,derived from its multilayered parent material and its distinct chemical framework to date.The fields of focus encompass the investigation of novel MBenes,the study of phase-changing mechanisms,and the examination of hex-MBenes,ortho-MBenes,tetra-MBenes,tri-MBenes,and MXenes with identical transition metal components.A critical analysis is also provided on the electrochemical mechanism and performance of MBene in energy storage(Li/Na/Mg/Ca/Li–S batteries and supercapacitors),as well as conversion and harvesting(CO_(2) reduction,and nitrogen reduction reactions).The persistent difficulties associated with conducting experimental synthesis and establishing artificial intelligence-based forecasts are extensively deliberated alongside the potential and forthcoming prospects of MBenes.This review provides a single platform for an overview of the MBene’s potential in energy storage and harvesting.展开更多
Shared energy storage helps lower user investment costs and enhances energy efficiency,which is considered a pivotal driver in accelerating the green transition of energy sectors.In view of the increasing demand for h...Shared energy storage helps lower user investment costs and enhances energy efficiency,which is considered a pivotal driver in accelerating the green transition of energy sectors.In view of the increasing demand for hydrogen,this paper proposes a bi-level optimization of configurations and scheduling for combined cooling,heating,and power(CCHP)microgrid systems considering shared hybrid electric-hydrogen energy storage service.The upper-level model addresses the capacity allocation problem of energy storage stations,while the lower-level model optimizes the operational strategies for the multi-microgrid system(MMS).To resolve the complexity of the coupled bi-level problem,Karush-Kuhn-Tucker(KKT)conditions and the Big-M method are applied to reformulate it into a solvable mixed-integer linear programming(MILP)model,compatible with CPLEX.The economic viability and rationality of the proposed approach are verified through comparisons of three cases.Numerical results show that the proposed approach reduces user annual costs by 20.15%compared to MMS without additional energy storage equipment and achieves 100%renewable absorption.For operators,it yields 5.71 M CNY annual profit with 3.02-year payback.Compared to MMS with electricity sharing,it further cuts user costs by 3.84%,boosts operator profit by 60.71%,and shortens payback by 15.88%.展开更多
The rare earth based hydrogen storage alloys MmxM1 1 - x ( Ni3.55 Co0.75 Mn0.4 A10.3 ) ( x = 0 ~ 0.5 ) were investigated in this work.Adjusted Ml: Mm ratio to change the content of La,Ce,Pr and Nd in the alloys and t...The rare earth based hydrogen storage alloys MmxM1 1 - x ( Ni3.55 Co0.75 Mn0.4 A10.3 ) ( x = 0 ~ 0.5 ) were investigated in this work.Adjusted Ml: Mm ratio to change the content of La,Ce,Pr and Nd in the alloys and then to change the phase structure, the influences of phase structure on the electrochemical properties were analyzed.The results indicate that the main phase of all alloys is LaNi5 with CaCu5 type structure and the crystal lattices constants of LaNi5 are changed with increasing x value, i.e, decreased a-axis, increased c-axis and axis ratio and nonlinear decreased crystal volume.The crystal volume of the alloy with x = 0.3 is larger than others.There is second phase A1LaNi4 in alloys when x≥0.3, which decrease the discharge capacity, but increase the cycling stability and high rate discharge ability.Compared comprehensively, the alloy with x = 0.3 shows the higher discharge capacity and the better cycling stability.展开更多
The main objective of the present study is to characterize cap rock formation used for geological storage of carbon dioxide (CO2). The petrophysical properties of several rocks were studied before CO2 injection. This ...The main objective of the present study is to characterize cap rock formation used for geological storage of carbon dioxide (CO2). The petrophysical properties of several rocks were studied before CO2 injection. This step is necessary for an understanding of CO2-brine-rock interactions. The mineralogical composition of several clay samples collected from real storage sites located in the south of Tunisia was determined by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) coupled to a probe EDS, infrared spectroscopy, thermal analysis and fluorescence spectra. The obtained experimental results reveal that illite, calcite and quartz are the dominant clay minerals. Dolomite and albite are also present. Besides, SEM analysis shows laminated structure for these samples which suggests low crystallinity. This sample contains a higher content of Fe, Cl, Ca and O. The clay cover may also be useful in storage process by immobilizing the migration of CO2 outer of the geological site and activating the process of mineral sequestration.展开更多
With certain controllability of various distribution energy resources (DERs) such as battery energy storage system (BESS), demand response (DR) and distributed generations (DGs), virtual power plant (VPP) can suitably...With certain controllability of various distribution energy resources (DERs) such as battery energy storage system (BESS), demand response (DR) and distributed generations (DGs), virtual power plant (VPP) can suitably regulate the powers access to the distribution network. In this paper, an optimal VPP operating problem is used to optimize the charging/discharging schedule of each BESS and the DR scheme with the objective to maximize the benefit by regulating the supplied powers over daily 24 hours. The proposed solution method is composed of an iterative dynamic programming optimal BESS schedule approach and a particle swarm optimization based (PSO-based) DR scheme approach. The two approaches are executed alternatively until the minimum elec-tricity cost of the whole day is obtained. The validity of the proposed method was confirmed with the obviously decreased supplied powers in the peak-load hours and the largely reduced electricity cost.展开更多
Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for opti...Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for optimized utilization,a lot of research has been focusing on how to use the energy efficiently and gain sustainable benefits.The energy storage system is an alternative because it not only deals with regenerative braking energy but also smooths drastic fluctuation of load power profile and optimizes energy management.In this work,we propose a co-phase traction power supply system with super capacitor(CSS_SC)for the purpose of realizing the function of energy management and power quality management in electrified railways.Besides,the coordinated control strategy is presented to match four working modes,including traction,regenerative braking,peak shaving and valley filling.A corresponding simulation model is built in MATLAB/Simulink to verify the feasibility of the proposed system under dynamic working conditions.The results demonstrate that CSS_SC is flexible to deal with four different working conditions and can realize energy saving within the allowable voltage unbalance of 0.008%in simulation in contrast to 1.3%of the standard limit.With such a control strategy,the performance of super capacitor is controlled to comply with efficiency and safety constraints.Finally,a case study demonstrates the improvement in power fluctuation with the valley-to-peak ratio reduced by 20.3%and the daily load factor increased by 17.9%.展开更多
In order to measure the thermophysical properties of ammoniated salt (CaCl2.mNH3: m = 4, 8) as an energy storage system utilizing natural resources, the measurement unit was developed, and the thermophysical propertie...In order to measure the thermophysical properties of ammoniated salt (CaCl2.mNH3: m = 4, 8) as an energy storage system utilizing natural resources, the measurement unit was developed, and the thermophysical properties (effective thermal conductivity and thermal diffusivity) of CaCl2.mNH3 and CaCl2.mNH3 with heat transfer media (Ti: titanium) were measured by the any heating method. The effective thermal conductivities of CaCl2.4NH3 + Ti and CaCl2.8NH3 + Ti were 0.14 - 0.17 and 0.18 - 0.20 W/(m.K) in the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.5 - 2.2 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The effective thermal diffusivities were 0.22 - 0.24 × 10-6 and 0.18 - 0.19 × 10-6 m2/sin the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.3 - 1.5 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The obtained results show that the thermophysical properties have a dependence on the bulk densities and specific heats of CaCl2.mNH3 and CaCl2.mNH3 + Ti. It reveals that the thermophysical properties in this measurement would be the valuable design factors to develop energy and H2 storage systems utilizing natural resources such as solar energy.展开更多
In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-...In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-level energy storage systems because of their rapid response,modularization,and flexible installation.Among several battery technologies,lithium-ion batteries(LIBs)exhibit high energy efficiency,long cycle life,and relatively high energy density.In this perspective,the properties of LIBs,including their operation mechanism,battery design and construction,and advantages and disadvantages,have been analyzed in detail.Moreover,the performance of LIBs applied to grid-level energy storage systems is analyzed in terms of the following grid services:(1)frequency regulation;(2)peak shifting;(3)integration with renewable energy sources;and(4)power management.In addition,the challenges encountered in the application of LIBs are discussed and possible research directions aimed at overcoming these challenges are proposed to provide insight into the development of grid-level energy storage systems.展开更多
基金Supported by the CNPC Science and Technology Major Project(2015E-4002)
文摘In view of complex geological characteristics and alternating loading conditions associated with cyclic large amount of gas injection and withdrawal in underground gas storage(UGS) of China, a series of key gas storage construction technologies were established, mainly including UGS site selection and evaluation, key index design, well drilling and completion, surface engineering and operational risk warning and assessment, etc. The effect of field application was discussed and summarized. Firstly, trap dynamic sealing capacity evaluation technology for conversion of UGS from the fault depleted or partially depleted gas reservoirs. A key index design method mainly based on the effective gas storage capacity design for water flooded heterogeneous gas reservoirs was proposed. To effectively guide the engineering construction of UGS, the safe well drilling, high quality cementing and high pressure and large flow surface injection and production engineering optimization suitable for long-term alternate loading condition and ultra-deep and ultra-low temperature formation were developed. The core surface equipment like high pressure gas injection compressor can be manufactured by our own. Last, the full-system operational risk warning and assessment technology for UGS was set up. The above 5 key technologies have been utilized in site selection, development scheme design, engineering construction and annual operations of 6 UGS groups, e.g. the Hutubi UGS in Xinjiang. To date, designed main indexes are highly consistent with actural performance, the 6 UGS groups have the load capacity of over 7.5 billion cubic meters of working gas volume and all the storage facilities have been running efficiently and safely.
文摘It presented a comparative consideration of General Motors long-term activities on the current subject of fuel-cell-powered electric vehicles vs Toyota Mirai recent results, relevant to prospects on more efficient and safe technologies of the hydrogen on-board storage. It also presented a call on the project International cooperation. The main aim of this paper is to attract attention of General Motors, Toyota and/or other large car companies to a real possibility of developing and using, in the nearest future, of the break-through hydrogen on-board storage technology based on the solid H2 intercalation into graphite nanostructures.
基金the the basic scientific research Funds project of Heilongjiang Universities[grant numbers 2024-KYYWF-0554].
文摘In response to the actual demands of the energy storage type organic Rankine power generation cycle,this study proposes a new type of jacketed shell and tube heat exchanger with integrated cold storage and heat exchange.N-tedecane is selected as the phase change material for cold storage,low-temperature water as the cold source,and R134a as the heat source.The phase change material for cold storage is filled inside the jacket tube of the heat exchanger.Cold fluid is introduced into the inner tube to cause the phase change material to condense and store cold.After the cold storage is completed,R134a flows in from the shell side and condenses through heat exchange with the solidified phase change material for energy storage.This study discusses the influence laws of different cold water mass flow rates and temperatures on the cold storage performance of this heat exchanger,and analyzes the condensation effect of R134a.The results show that when the mass flow rate is 0.5 kg/s and the cold water temperature is between 3 and 4℃,the average power of the energy storage heat exchanger in the condensation experiment is 80W,and the average convective heat transfer coefficient is 110.73 W/(m^(2)⋅K).This research provides an experimental basis for the development of energy storage organic Rankine power generation cycles.
基金Supported by the China National Science and Technology Major Project(2017ZX05036,2017ZX05036001).
文摘As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
基金extend their gratitude to the Deanship of Scientific Research,Vice Presidency for Graduate Studies and Scientific Research,King Faisal University,Saudi Arabia,for funding the publication of this work under the Ambitious Researcher program(Project No.KFU253806).
文摘Artificial intelligence(AI)based models have been used to predict the structural,optical,mechanical,and electrochemical properties of zinc oxide/graphene oxide nanocomposites.Machine learning(ML)models such as Artificial Neural Networks(ANN),Support Vector Regression(SVR),Multilayer Perceptron(MLP),and hybrid,along with fuzzy logic tools,were applied to predict the different properties like wavelength at maximum intensity(444 nm),crystallite size(17.50 nm),and optical bandgap(2.85 eV).While some other properties,such as energy density,power density,and charge transfer resistance,were also predicted with the help of datasets of 1000(80:20).In general,the energy parameters were predicted more accurately by hybrid models.The hydrothermal method was used to synthesize graphene oxide(GO)and zinc oxide(ZnO)nanocomposites.The increased surface area,conductivity,and stability of graphene oxide in zinc oxide nanoparticles make the composite an ideal option for energy storage.X-ray diffraction(XRD)confirmed the crystallite size of 17.41 nm for the nanocomposite and the presence of GO(12.8○)peaks.The scanning electron microscope(SEM)showed anchored wrinkled GO sheets on zinc oxide with an average particle size of 2.93μm.Energy-dispersive X-ray spectroscopy(EDX)confirmed the elemental composition,and Fouriertransform infrared spectroscopy(FTIR)revealed the impact of GO on functional groups and electrochemical behavior.Photoluminescence(PL)wavelength of(439 nm)and band gap of(2.81 eV)show that the material is suitable for energy applications in nanocomposites.Smart nanocomposite materials with improved performance in energy storage and related applications were fabricated by combining synthesis,characterization,fuzzy logic,and machine learning in this work.
文摘Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, battery technologies are desirable energy storage devices for GLEES due to their easy modularization, rapid response, flexible installation, and short construction cycles. In general, battery energy storage technologies are expected to meet the requirements of GLEES such as peak shaving and load leveling, voltage and frequency regulation, and emergency response, which are highlighted in this perspective. Furthermore, several types of battery technologies, including lead–acid, nickel–cadmium, nickel–metal hydride, sodium–sulfur, lithium-ion, and flow batteries, are discussed in detail for the application of GLEES. Moreover, some possible developing directions to facilitate efforts in this area are presented to establish a perspective on battery technology, provide a road map for guiding future studies, and promote the commercial application of batteries for GLEES.
文摘Recent worldwide foodborne outbreaks emphasize the need for the development of rapid and accurate method for pathogen detection. To address such issues, a new colony based label-free detection method working on the principles of elastic light scattering was introduced. In order to build libraries of scattering images for bacterial pathogens, it is pertinent to determine the effect of preparation and storage of the agar media on the scatter patterns. Scatter patterns of three Escherichia coli serovars (O26, O111 and O157) were studied and used in a model system, after growth on Sorbitol-MacConkey agar plates that were prepared and stored at different conditions in the laboratory. Quantitative image processing software was used to analyze variation in scatter patterns of the same serovar on media prepared under various standard laboratory conditions and to generate a cross-validation matrix for comparison. Based on the results, it was determined that attention should be given during preparation of media so that the agar plates are not air-dried more than 10 - 20 min after solidification at room temperature. The plates could be stored in sealed bags in cold room (4oC - 10oC) for up to a month before use. The findings of this study should provide guidelines in preparation, storage, and handling of media for generation of reproducible scatter patterns of bacterial colonies with the light scattering sensor for pathogen detection.
文摘The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurations. As a part of this investigation, the melting process is simulated from the onset of phase change to the offset involving physics of natural convection in PCM fluid pool. The investigation is carried out by ANSYS Fluent code, which is an efficient numerical analysis tool for investigating fluid flow and convective heat transfer phenomena during PCM melting process. The attention is mainly focused on the extension of contact area between the PCM body and cylindrical capsule to enhance heat transfer rates to PCM bodies during the melting process by employing longitudinal fins in the enclosed capsule. Two commercial PCMs: RT50 and C58, are introduced in a 2D cylindrical pipe with their thermo-physical properties as input for modelling. The selected modelling approach is validated against experimental result with respect to the total enthalpy changes that qualify our model to run in the proceeding calculation. It is ensured that an isothermal boundary condition (373 K) is applied to the inner pipe throughout the series of simulation cases and the corresponding Rayleigh number (Ra) ranges from 104 - 105 and Prandtl number (Pr) 0.05 - 0.07. Finally, parametric study is carried out to evaluate the effect of length, thickness and number of longitudinal fins on the thermal performance of PCM-LHTES (Latent Heat Thermal Energy Storage) system associated with the physics of natural convection process during PCM melting.
文摘With the development of cloud computing, the mutual understandability among distributed data access control has become an important issue in the security field of cloud computing. To ensure security, confidentiality and fine-grained data access control of Cloud Data Storage (CDS) environment, we proposed Multi-Agent System (MAS) architecture. This architecture consists of two agents: Cloud Service Provider Agent (CSPA) and Cloud Data Confidentiality Agent (CDConA). CSPA provides a graphical interface to the cloud user that facilitates the access to the services offered by the system. CDConA provides each cloud user by definition and enforcement expressive and flexible access structure as a logic formula over cloud data file attributes. This new access control is named as Formula-Based Cloud Data Access Control (FCDAC). Our proposed FCDAC based on MAS architecture consists of four layers: interface layer, existing access control layer, proposed FCDAC layer and CDS layer as well as four types of entities of Cloud Service Provider (CSP), cloud users, knowledge base and confidentiality policy roles. FCDAC, it’s an access policy determined by our MAS architecture, not by the CSPs. A prototype of our proposed FCDAC scheme is implemented using the Java Agent Development Framework Security (JADE-S). Our results in the practical scenario defined formally in this paper, show the Round Trip Time (RTT) for an agent to travel in our system and measured by the times required for an agent to travel around different number of cloud users before and after implementing FCDAC.
基金support of the National Natural Science Foundation of China(No.52574411)Beijing Natural Science Foundation(No.2242043).
文摘Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.
基金the National Key R&D Program of China(No.2024YFE0110001)the National Natural Science Foundation of China(U1932219)the Mobility Programme endorsed by the Joint Committee of the Sino-German Center(M0728)。
文摘The ultracold neutron(UCN)transport code,MCUCN,designed initially for simulating UCN transportation from a solid deuterium(SD_2)source and neutron electric dipole moment experiments,could not simulate UCN storage and transportation in a superfluid^(4)He(SFHe,He-Ⅱ)source accurately.This limitation arose from the absence of an^(4)He upscattering mechanism and the absorption of^(3)He.And the provided source energy distribution in MCUCN is different from that in SFHe source.This study introduced enhancements to MCUCN to address these constraints,explicitly incorporating the^(4)He upscattering effect,the absorption of^(3)He,the loss caused by impurities on converter wall,UCN source energy distribution in SFHe,and the transmission through negative optical potential.Additionally,a Python-based visualization code for intermediate states and results was developed.To validate these enhancements,we systematically compared the simulation results of the Lujan Center Mark3 UCN system by MCUCN and the improved MCUCN code(iMCUCN)with UCNtransport simulations.Additionally,we compared the results of the SUN1 system simulated by MCUCN and iMCUCN with measurement results.The study demonstrates that iMCUCN effectively simulates the storage and transportation of ultracold neutrons in He-Ⅱ.
基金supported by the National Natural Science Foundation of China(No.52302241 and 22225801)the Major Science and Technology Programs of Henan Province(241100240200)the China Postdoctoral Science Foundation(No.2023M730940).
文摘MXene derivatives are notable two-dimensional nanomaterials with numerous prospective applications in the domains of energy development.MXene derivative,MBene,diversifies its focus on energy storage and harvesting due to its exceptional electrical conductivity,structural flexibility,and mechanical properties.This comprehensive review describes the sandwich-like structure of the synthesized MBene,derived from its multilayered parent material and its distinct chemical framework to date.The fields of focus encompass the investigation of novel MBenes,the study of phase-changing mechanisms,and the examination of hex-MBenes,ortho-MBenes,tetra-MBenes,tri-MBenes,and MXenes with identical transition metal components.A critical analysis is also provided on the electrochemical mechanism and performance of MBene in energy storage(Li/Na/Mg/Ca/Li–S batteries and supercapacitors),as well as conversion and harvesting(CO_(2) reduction,and nitrogen reduction reactions).The persistent difficulties associated with conducting experimental synthesis and establishing artificial intelligence-based forecasts are extensively deliberated alongside the potential and forthcoming prospects of MBenes.This review provides a single platform for an overview of the MBene’s potential in energy storage and harvesting.
文摘Shared energy storage helps lower user investment costs and enhances energy efficiency,which is considered a pivotal driver in accelerating the green transition of energy sectors.In view of the increasing demand for hydrogen,this paper proposes a bi-level optimization of configurations and scheduling for combined cooling,heating,and power(CCHP)microgrid systems considering shared hybrid electric-hydrogen energy storage service.The upper-level model addresses the capacity allocation problem of energy storage stations,while the lower-level model optimizes the operational strategies for the multi-microgrid system(MMS).To resolve the complexity of the coupled bi-level problem,Karush-Kuhn-Tucker(KKT)conditions and the Big-M method are applied to reformulate it into a solvable mixed-integer linear programming(MILP)model,compatible with CPLEX.The economic viability and rationality of the proposed approach are verified through comparisons of three cases.Numerical results show that the proposed approach reduces user annual costs by 20.15%compared to MMS without additional energy storage equipment and achieves 100%renewable absorption.For operators,it yields 5.71 M CNY annual profit with 3.02-year payback.Compared to MMS with electricity sharing,it further cuts user costs by 3.84%,boosts operator profit by 60.71%,and shortens payback by 15.88%.
文摘The rare earth based hydrogen storage alloys MmxM1 1 - x ( Ni3.55 Co0.75 Mn0.4 A10.3 ) ( x = 0 ~ 0.5 ) were investigated in this work.Adjusted Ml: Mm ratio to change the content of La,Ce,Pr and Nd in the alloys and then to change the phase structure, the influences of phase structure on the electrochemical properties were analyzed.The results indicate that the main phase of all alloys is LaNi5 with CaCu5 type structure and the crystal lattices constants of LaNi5 are changed with increasing x value, i.e, decreased a-axis, increased c-axis and axis ratio and nonlinear decreased crystal volume.The crystal volume of the alloy with x = 0.3 is larger than others.There is second phase A1LaNi4 in alloys when x≥0.3, which decrease the discharge capacity, but increase the cycling stability and high rate discharge ability.Compared comprehensively, the alloy with x = 0.3 shows the higher discharge capacity and the better cycling stability.
文摘The main objective of the present study is to characterize cap rock formation used for geological storage of carbon dioxide (CO2). The petrophysical properties of several rocks were studied before CO2 injection. This step is necessary for an understanding of CO2-brine-rock interactions. The mineralogical composition of several clay samples collected from real storage sites located in the south of Tunisia was determined by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) coupled to a probe EDS, infrared spectroscopy, thermal analysis and fluorescence spectra. The obtained experimental results reveal that illite, calcite and quartz are the dominant clay minerals. Dolomite and albite are also present. Besides, SEM analysis shows laminated structure for these samples which suggests low crystallinity. This sample contains a higher content of Fe, Cl, Ca and O. The clay cover may also be useful in storage process by immobilizing the migration of CO2 outer of the geological site and activating the process of mineral sequestration.
文摘With certain controllability of various distribution energy resources (DERs) such as battery energy storage system (BESS), demand response (DR) and distributed generations (DGs), virtual power plant (VPP) can suitably regulate the powers access to the distribution network. In this paper, an optimal VPP operating problem is used to optimize the charging/discharging schedule of each BESS and the DR scheme with the objective to maximize the benefit by regulating the supplied powers over daily 24 hours. The proposed solution method is composed of an iterative dynamic programming optimal BESS schedule approach and a particle swarm optimization based (PSO-based) DR scheme approach. The two approaches are executed alternatively until the minimum elec-tricity cost of the whole day is obtained. The validity of the proposed method was confirmed with the obviously decreased supplied powers in the peak-load hours and the largely reduced electricity cost.
文摘Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for optimized utilization,a lot of research has been focusing on how to use the energy efficiently and gain sustainable benefits.The energy storage system is an alternative because it not only deals with regenerative braking energy but also smooths drastic fluctuation of load power profile and optimizes energy management.In this work,we propose a co-phase traction power supply system with super capacitor(CSS_SC)for the purpose of realizing the function of energy management and power quality management in electrified railways.Besides,the coordinated control strategy is presented to match four working modes,including traction,regenerative braking,peak shaving and valley filling.A corresponding simulation model is built in MATLAB/Simulink to verify the feasibility of the proposed system under dynamic working conditions.The results demonstrate that CSS_SC is flexible to deal with four different working conditions and can realize energy saving within the allowable voltage unbalance of 0.008%in simulation in contrast to 1.3%of the standard limit.With such a control strategy,the performance of super capacitor is controlled to comply with efficiency and safety constraints.Finally,a case study demonstrates the improvement in power fluctuation with the valley-to-peak ratio reduced by 20.3%and the daily load factor increased by 17.9%.
文摘In order to measure the thermophysical properties of ammoniated salt (CaCl2.mNH3: m = 4, 8) as an energy storage system utilizing natural resources, the measurement unit was developed, and the thermophysical properties (effective thermal conductivity and thermal diffusivity) of CaCl2.mNH3 and CaCl2.mNH3 with heat transfer media (Ti: titanium) were measured by the any heating method. The effective thermal conductivities of CaCl2.4NH3 + Ti and CaCl2.8NH3 + Ti were 0.14 - 0.17 and 0.18 - 0.20 W/(m.K) in the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.5 - 2.2 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The effective thermal diffusivities were 0.22 - 0.24 × 10-6 and 0.18 - 0.19 × 10-6 m2/sin the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.3 - 1.5 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The obtained results show that the thermophysical properties have a dependence on the bulk densities and specific heats of CaCl2.mNH3 and CaCl2.mNH3 + Ti. It reveals that the thermophysical properties in this measurement would be the valuable design factors to develop energy and H2 storage systems utilizing natural resources such as solar energy.
文摘In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-level energy storage systems because of their rapid response,modularization,and flexible installation.Among several battery technologies,lithium-ion batteries(LIBs)exhibit high energy efficiency,long cycle life,and relatively high energy density.In this perspective,the properties of LIBs,including their operation mechanism,battery design and construction,and advantages and disadvantages,have been analyzed in detail.Moreover,the performance of LIBs applied to grid-level energy storage systems is analyzed in terms of the following grid services:(1)frequency regulation;(2)peak shifting;(3)integration with renewable energy sources;and(4)power management.In addition,the challenges encountered in the application of LIBs are discussed and possible research directions aimed at overcoming these challenges are proposed to provide insight into the development of grid-level energy storage systems.