A statistical approach is developed, based on a Monte Carlo method, in order to determine the statistical composition of a polyamide-6 sample composed of caprolactam （an AB-type monomer） and of a di-acid （A2 type）...A statistical approach is developed, based on a Monte Carlo method, in order to determine the statistical composition of a polyamide-6 sample composed of caprolactam （an AB-type monomer） and of a di-acid （A2 type） or a tri- acid （A3 type） as coupling agents. For this composition, the linear theological behavior of these systems is predicted using a tube-based theory. This allows us to show that while coupling agents of type A2 can be seen as flow improver, the effect of branching agents of type A3, depending on the synthesis recipe and the conversion level, can lead either to an increase or to a decrease of the viscosity. By adding specific amount of these agents, we also show that it is possible to obtain materials with the same zero-shear viscosity but with different shear thinning behavior. Furthermore, the polydispersity of linear samples of the same average number molecular weight, Mn, is discussed in function of the amount of A2 monomers they contain. Ranging from 2 to 1.5, this difference in polydispersity is expected to have a significant influence on the processing behavior of such materials.展开更多
Based on the data(including radius of maximum winds) from the JTWC(Joint Typhoon Warning Center),the tropical cyclones(TCs) radii of the outermost closed isobar, TCs best tracks from Shanghai Typhoon Institute and the...Based on the data(including radius of maximum winds) from the JTWC(Joint Typhoon Warning Center),the tropical cyclones(TCs) radii of the outermost closed isobar, TCs best tracks from Shanghai Typhoon Institute and the Black Body Temperature(TBB) of the Japanese geostationary meteorological satellite M1 TR IR1, and combining13 tropical cyclones which landed in China again after visiting the island of Taiwan during the period from 2001 to2010, we analyzed the relationship between the number of convective cores within TC circulation and the intensity of TC with the method of convective-stratiform technique(CST) and statistical and composite analysis. The results are shown as follows:(1) The number of convective cores in the entire TC circulation is well corresponding with the outer spiral rainbands and the density of convective cores in the inner core area increases(decreases) generally with increasing(decreasing) TC intensity. At the same time, the number of convective cores within the outer spiral rainbands is more than that within the inner core and does not change much with the TC intensity. However, the density of convective cores within the outer spiral rainbands is lower than that within the inner core.(2) The relationship described above is sensitive to landing location to some extent but not sensitive to the structure of TC.(3) The average value of TBB in the inner core area increases(decreases) generally with increasing(decreasing) of TC intensity, which is also sensitive to landing situation to some extent. At the same time, the average value of TBB within the outer spiral rainbands is close to that within the entire TC circulation, and both of them are more than that within the inner core. However, they do not reflect TC intensity change significantly.(4) The results of statistical composite based on convective cores and TBB are complementary with each other, so a combination of both can reflect the relationship between TC rainbands and TC intensity much better.展开更多
文摘A statistical approach is developed, based on a Monte Carlo method, in order to determine the statistical composition of a polyamide-6 sample composed of caprolactam （an AB-type monomer） and of a di-acid （A2 type） or a tri- acid （A3 type） as coupling agents. For this composition, the linear theological behavior of these systems is predicted using a tube-based theory. This allows us to show that while coupling agents of type A2 can be seen as flow improver, the effect of branching agents of type A3, depending on the synthesis recipe and the conversion level, can lead either to an increase or to a decrease of the viscosity. By adding specific amount of these agents, we also show that it is possible to obtain materials with the same zero-shear viscosity but with different shear thinning behavior. Furthermore, the polydispersity of linear samples of the same average number molecular weight, Mn, is discussed in function of the amount of A2 monomers they contain. Ranging from 2 to 1.5, this difference in polydispersity is expected to have a significant influence on the processing behavior of such materials.
基金National Natural Science Foundation of China(NSFC)(40875025,41175050,41475039 and41475041)Shanghai Natural Science Foundation of China(08ZR1422900)Public Sector(Meteorology)Research of China(GYHY201306012)
文摘Based on the data(including radius of maximum winds) from the JTWC(Joint Typhoon Warning Center),the tropical cyclones(TCs) radii of the outermost closed isobar, TCs best tracks from Shanghai Typhoon Institute and the Black Body Temperature(TBB) of the Japanese geostationary meteorological satellite M1 TR IR1, and combining13 tropical cyclones which landed in China again after visiting the island of Taiwan during the period from 2001 to2010, we analyzed the relationship between the number of convective cores within TC circulation and the intensity of TC with the method of convective-stratiform technique(CST) and statistical and composite analysis. The results are shown as follows:(1) The number of convective cores in the entire TC circulation is well corresponding with the outer spiral rainbands and the density of convective cores in the inner core area increases(decreases) generally with increasing(decreasing) TC intensity. At the same time, the number of convective cores within the outer spiral rainbands is more than that within the inner core and does not change much with the TC intensity. However, the density of convective cores within the outer spiral rainbands is lower than that within the inner core.(2) The relationship described above is sensitive to landing location to some extent but not sensitive to the structure of TC.(3) The average value of TBB in the inner core area increases(decreases) generally with increasing(decreasing) of TC intensity, which is also sensitive to landing situation to some extent. At the same time, the average value of TBB within the outer spiral rainbands is close to that within the entire TC circulation, and both of them are more than that within the inner core. However, they do not reflect TC intensity change significantly.(4) The results of statistical composite based on convective cores and TBB are complementary with each other, so a combination of both can reflect the relationship between TC rainbands and TC intensity much better.
