Photoinitiators(PIs), as the key substances for photopolymerized antibacterial film(PAF), affect the cure rate and color of PAF. Herein, two enone dyes were designed and synthesized by a facile approach. Among the can...Photoinitiators(PIs), as the key substances for photopolymerized antibacterial film(PAF), affect the cure rate and color of PAF. Herein, two enone dyes were designed and synthesized by a facile approach. Among the candidates, BDO1 has demonstrated the ability to initiate polymerization of acrylate monomers as single-component PI with the advantages of low mobility, outstanding photobleaching, excellent cytocompatibility, and suitability for light emitting diode(LED) light sources above 365 nm. Taking BDOs as examples, a novel method based on theoretical calculations aiming to assess the potential of enone molecules as single-component PIs was proposed. Finally, under the initiation of BDO1, tannic acid was photopolymerized to a colorless and transparent antibacterial film with high antibacterial ability, which indicated that BDO1 was expected to be used in environmentally friendly PAF.展开更多
In recent years,research on industrial innovation and development has primarily focused on industrial automation and intelligent manufacturing.Within the field of integrating mechatronics and intelligent control,analy...In recent years,research on industrial innovation and development has primarily focused on industrial automation and intelligent manufacturing.Within the field of integrating mechatronics and intelligent control,analyzing the efficient control of mechatronic systems enabled by generative AI for single-chip microcomputers can further highlight the value and significance of promoting AI technology applications.This paper examines the technical characteristics of generative AI in data generation,multimodal fusion,and dynamic adaptation,proposing lightweight model deployment strategies that compress large generative models to a range compatible with single-chip microcomputers,ensuring local real-time inference capabilities.It constructs an edge intelligent control architecture,enabling generative AI to directly participate in decision-making instruction generation,forming a new working system of perception,decision-making,and execution.Additionally,it designs a collaborative optimization training mechanism that leverages federated learning to overcome single-machine data limitations and enhance model generalization performance.At the application level,an intelligent fault prediction system is developed for early identification of equipment anomalies,an adaptive parameter optimization module is constructed for dynamically adjusting control strategies,and a multi-device collaborative scheduling engine is established to optimize production processes,providing technical support for embedded intelligent control in Industry 4.0 scenarios.展开更多
In recent years,the application of various advanced technologies,such as digitization and informatization,has become the primary tool for innovation in education and teaching.For traditional single-chip microcomputer ...In recent years,the application of various advanced technologies,such as digitization and informatization,has become the primary tool for innovation in education and teaching.For traditional single-chip microcomputer course teaching,it is necessary to emphasize the introduction and application of high-tech innovations in its path of innovative development.This course is a typical representative of multidisciplinary teaching,involving multiple disciplines such as electronic engineering,automation,and computer science.In response to issues faced in traditional teaching,such as rigid organization of teaching content that struggles to keep pace with technological advancements,resulting in a noticeable lag in knowledge transfer,and monotonous teaching methods that fail to precisely meet the diverse learning needs of students,analyzing the innovative applications of this course under the empowerment of AI technology holds significant practical relevance.In this regard,the study relies on AI technology empowerment to analyze the application paths for the deep integration of AI technology and single-chip microcomputer courses,constructing a new teaching model to provide references for enhancing teaching quality and stimulating students’innovative potential.展开更多
A DC regulated power supply with numerical control based on single chip microcomputer （SCM） is designed. SCM is the main controller and output voltage o{ DC power supply can be set by keyboard. The analog voltage ca...A DC regulated power supply with numerical control based on single chip microcomputer （SCM） is designed. SCM is the main controller and output voltage o{ DC power supply can be set by keyboard. The analog voltage can be obtained through D/A converter （DAC0832） so that different voltages can be provided by operational amplifier. The output voltage varies from 0 V to 12 V with the incremental value of 0. 1 V. The actual output voltage is shown in the nixietube. This DC regulated power supply is characterized by simple structure and easy operation.展开更多
A method which is especially suitable for microcomputer calculation of the true orientation distribution function (ODF) according to the maximum-entropy estimate is proposed for hexagonal system polycrystalline materi...A method which is especially suitable for microcomputer calculation of the true orientation distribution function (ODF) according to the maximum-entropy estimate is proposed for hexagonal system polycrystalline materials with physical symmetry.The resultant computational software system has been also designed and first carried out in a microcomputer PANAFACOM-U1200 being on line with the X-ray diffractometer D/max-3A.The simu- lated calculation shows that the method is concisely pragmatic and easily popularized,while the results obtained are trust worthy.展开更多
Pump controlled motor electrohydraulic servo systems are much used in circumstances where high power drive is needed. This kind of system has the advantage of energy-saving. But, it also has some defects that have to ...Pump controlled motor electrohydraulic servo systems are much used in circumstances where high power drive is needed. This kind of system has the advantage of energy-saving. But, it also has some defects that have to be improved. Microcomputer control of a pump controlled motor electrohydraulic servo system is studied. A PID controller is first adopted on the closed loop control system, and experimental results are obtained. Then, a model reference adaptive controller is designed and realised on the same system applying a single board microcomputer. Experimental results show that the dynamic properties of the adaptive control system is much better than those of the PID system under different inertia load conditions.展开更多
With principles of reliability, independence, practicality and economical effi- ciency, a set of intelligent fire alarm system based on AVRmega128 single chip microcomputer was designed to solve problems of fire alarm...With principles of reliability, independence, practicality and economical effi- ciency, a set of intelligent fire alarm system based on AVRmega128 single chip microcomputer was designed to solve problems of fire alarm system in many large- scale warehouses. Using advanced flame sensor, 485 bus communication, computer interactive software and related peripheral devices, this intelligent fire alarm system has functions of sound-light alarm and intelligent fire extinguishing. The human-com- puter interactive software was adopted for the remote control of the alarm main control panel through the 485 bus communication. This design of intelligent fire alarm system shows high reference and practical value to the development of intel- ligent alarm products with high integration and high reliability.展开更多
Presents a one grade adaptive controller with one reference model which is built according to δ MRACS adaptive control theory and used to control an actual high order hydraulic system, and the whole hardware system u...Presents a one grade adaptive controller with one reference model which is built according to δ MRACS adaptive control theory and used to control an actual high order hydraulic system, and the whole hardware system used, which includes a AT89C51 single chip microcomputer, 74Ls373 flip latch, 6116 store, eight bit ADC0809, and so on, and the satisfactory results obtained in study on hydraulic control system.展开更多
The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component P...The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.展开更多
A new method of synthesizing single-component molecular conductor [Ni(dmit)2] by the reaction 2(Me4N)[Ni(dmit)2]2 [Ni(dmit)2] + (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2] exhibits a semiconductive behavior above 167...A new method of synthesizing single-component molecular conductor [Ni(dmit)2] by the reaction 2(Me4N)[Ni(dmit)2]2 [Ni(dmit)2] + (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2] exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity.展开更多
In this work,semirigid linkers of the alkyl-thiophene-alkyl structure are developed to construct double-cable polymers.Three alkyl units,propyl(C3H6),hexyl(C6H12),and dodecyl(C12H24),are applied as semirigid linkers,y...In this work,semirigid linkers of the alkyl-thiophene-alkyl structure are developed to construct double-cable polymers.Three alkyl units,propyl(C3H6),hexyl(C6H12),and dodecyl(C12H24),are applied as semirigid linkers,yielding three double-cable polymers:PBC6-T,PBC12-T,and PBC24-T,respectively.PBC12-T which uses C6H12-thiophene-C6H12 linkers is found to exhibit the best device efficiency of 5.56%,while PBC6-T and PBC24-T with shorter or longer linkers yield device efficiencies of only 2.65%and 1.09%in single-component organic solar cells(SCOSCs).Further studies reveal that PBC12-T exhibits higher crystallinity and improved charge transport,resulting in better efficiencies.Our work provides an approach to construct double-cable conjugated polymers with long alkyl linkers,and it shows the importance of the linker length for the photovoltaic performance of SCOSCs.展开更多
Single-component organic solar cells(SCOSCs)with high stability and simplified fabrication process are supposed to accelerate the commercialization of organic photovoltaics.However,the types of photo-active materials ...Single-component organic solar cells(SCOSCs)with high stability and simplified fabrication process are supposed to accelerate the commercialization of organic photovoltaics.However,the types of photo-active materials and photovoltaic performance of SCOSCs are still far lagging behind the bulk-heterojunction type organic solar cells(BHJ OSCs).It is still an arduous task to introduce new photo-active materials into SCOSCs,aiming to improve the efficiencies of SCOSCs.One feasible way is to construct double-cable polymers with new structures and tune conformation,morphology and mobility for the improvement in power conversion efficiencies(PCEs).Hence,in this work,we constructed a new double-cable polymer PBTT-BPTI by introducing fused core 5,7-dibromo-2,3-bis(2-ethylhexyl)benzo[1,2-b:4,5-c’]dithiophene-4,8-dione(TTDO)into the main backbone and benzo[ghi]-perylene triimide(BPTI)unit into the side chain.Both of the two units show strong electron-withdrawing property,which are expected to broaden absorption spectra and enhance intermolecular interaction.The double-cable polymer exhibited a broad absorption in the range of 300-700 nm with an optical band gap(E_(g))of 1.79 eV.The PCE of PBTT-BPTI-based SCOSCs was 2.15%,which may be limited by the unconstructed efficient electron transporting channels.展开更多
In this work,the“functionalization-polymerization”(FP)method has been used to construct fullerene-contained double-cable conjugated polymers with“donor-acceptor”backbones.It was realized via synthesizing a fullere...In this work,the“functionalization-polymerization”(FP)method has been used to construct fullerene-contained double-cable conjugated polymers with“donor-acceptor”backbones.It was realized via synthesizing a fullerene-contained monomer and performing Stille polymerization.With this method,a series of double-cable conjugated polymers with different fullerene contents were developed and applied into single-component organic solar cells.The power conversion efficiencies(PCEs)based on these polymers increased from 0.71%to 1.71%with the enhanced fullerene contents.The relatively low PCEs might be originated from the poor microstructure in these polymers.These new conjugated polymers with molecular heterojunction would show potential application in organic electronic devices.展开更多
In this paper, a microcomputer program package for pharmacokinetics and biopharmaceutics (PKBP) was presented. This package is applicable to various calculations for pharmacokinetics and biopharmaceutics. Some mathema...In this paper, a microcomputer program package for pharmacokinetics and biopharmaceutics (PKBP) was presented. This package is applicable to various calculations for pharmacokinetics and biopharmaceutics. Some mathematical models and computing methods were developed. It has been used over 200 users.展开更多
This paper presents a microcomputer program system for the three-dimensional non-linear finite element method (FEM), which is developed for applications in mining engineering, such as excavation, filling, caving, damm...This paper presents a microcomputer program system for the three-dimensional non-linear finite element method (FEM), which is developed for applications in mining engineering, such as excavation, filling, caving, damming, etc. Our attention is focused on some of the key aspects of the programing techniques for an applicable microcomputer program, such as the structure of the program, data processing in the core, communication between the core and mass storage, input and output systems, etc. In the last part of this paper, two test examples are presented verifying the computational accuracy of this programing system and illustrating its applicability in practical engineering.展开更多
This paper describes the statistical methods of the comparison of the incidence or mortality rates in cancer registry and descriptive epidemiology, and the features of microcomputer program (CANTEST) which was designe...This paper describes the statistical methods of the comparison of the incidence or mortality rates in cancer registry and descriptive epidemiology, and the features of microcomputer program (CANTEST) which was designed to perform the methods. The program was written in IBM BASIC language. Using the program CANTEST we presented here the user can do several statistical tests or estimations as follow: 1. the comparison of the adjusted rates which were calculated by directly or indirectly standardized methods, 2. the calculation of the slope of regression line for testing the linear trends of the adjusted rates, 3. the estimation of the 95% or 99%conndence intervals of the directly adjusted rates, of the cumulative rates (0-64 and 0-74), and of the cumulative risk. Several examples are presented for testing the performances of the program.展开更多
For the first time, the split-unit experimental design was used in simulating free muscle transplantation by microneurovascular anastomoses on the rectus femoris of rabbits, and 12 functional indexes of contractile pr...For the first time, the split-unit experimental design was used in simulating free muscle transplantation by microneurovascular anastomoses on the rectus femoris of rabbits, and 12 functional indexes of contractile properties and the correlation between these indexes were analyzed with a microcomputer. The results showed that the maximum tetanic tension (TET) of grafted muscle would not return to normal level in the same animal until 1 year after operation (P>0.05), and, in our opinion,in view of tension balance between two sides, this was also the optimal time to appreciate the muscle function. It was found that the fatigue rate (FR) in each group was less than 25%, without any significant difference compared with that in the normal control side (F<F0.05, P>0.05). This was the functional evidence for the finding that the constituent ratio of 3 types of muscle fibers did not change in our study series. Therefore, the main character of fast contraction of the whole grafted muscles remained the same. There was a positive correlation between FR and TeT (r>r0.01), i.e. whenever TeT increased by 1 N, FR increased 0.12%.展开更多
he present paper covers a model involving Donnan memhrane equilibrium andadsorption eluilibrium to describe the retention process for diprotic organic acids inion-exclusion chromatography. On this basis the microcompu...he present paper covers a model involving Donnan memhrane equilibrium andadsorption eluilibrium to describe the retention process for diprotic organic acids inion-exclusion chromatography. On this basis the microcomputer simulation of elu-tion behaviour for dicarboxylic acids was investigated. Influences of eluent acidityand sample concentration on the retention value were studied. The theoreticallypredicted results are in reasonable agreement with the experimental data.展开更多
A microcomputerized measurement system is developed.This system automatically acquiresan I-V characteristic curve in 5 seconds with the accuracy of 0.05％ FSR(full scale range).The Schottkyextrapolation field-free emi...A microcomputerized measurement system is developed.This system automatically acquiresan I-V characteristic curve in 5 seconds with the accuracy of 0.05％ FSR(full scale range).The Schottkyextrapolation field-free emission,the inflection-point emission,the flection-point emission,the average effec-tive work function.the Richardson work function,the work function distribution at the operation tempera-ture and other important information that reflects properties of cathodes are obtained by this system.The re-sults of analysing four types of cathodes demonstrate that this system is very suitable for measuring the activi-ty changes of the cathode in the processes of activation,ageing,poisoning and life test.It is proved that thissystem can also be used to monitor the actlvity of the cathode in the assembled tube by measuring a gridcontrolled travelling-wave tube.展开更多
In this paper, a successfully studied and developed master - slave muld - microcomputers control system based on PC - BUS for hollow spindle fancy yarn spinning machine, mainly Its overall scheme, software and hardwar...In this paper, a successfully studied and developed master - slave muld - microcomputers control system based on PC - BUS for hollow spindle fancy yarn spinning machine, mainly Its overall scheme, software and hardware construction, is introduced. Spinning experiments show that the system achieves satisfactory result. This system can solve the diftkultles of mechatronical fusion between domestic hollow splndk fancy yarn spuming muchine and its microcomputer control technology.展开更多
基金financially supported by National Natural Science Foundation of China (Nos. 21925802, 22338005)Liaoning Binhai Laboratory (No. LBLB-2023–03)the Fundamental Research Funds for the Central Universities (No. DUT22LAB601)。
文摘Photoinitiators(PIs), as the key substances for photopolymerized antibacterial film(PAF), affect the cure rate and color of PAF. Herein, two enone dyes were designed and synthesized by a facile approach. Among the candidates, BDO1 has demonstrated the ability to initiate polymerization of acrylate monomers as single-component PI with the advantages of low mobility, outstanding photobleaching, excellent cytocompatibility, and suitability for light emitting diode(LED) light sources above 365 nm. Taking BDOs as examples, a novel method based on theoretical calculations aiming to assess the potential of enone molecules as single-component PIs was proposed. Finally, under the initiation of BDO1, tannic acid was photopolymerized to a colorless and transparent antibacterial film with high antibacterial ability, which indicated that BDO1 was expected to be used in environmentally friendly PAF.
基金Single-Chip Microcomputer and Interface Technology Project(Project No.:SYSJ2025032)。
文摘In recent years,research on industrial innovation and development has primarily focused on industrial automation and intelligent manufacturing.Within the field of integrating mechatronics and intelligent control,analyzing the efficient control of mechatronic systems enabled by generative AI for single-chip microcomputers can further highlight the value and significance of promoting AI technology applications.This paper examines the technical characteristics of generative AI in data generation,multimodal fusion,and dynamic adaptation,proposing lightweight model deployment strategies that compress large generative models to a range compatible with single-chip microcomputers,ensuring local real-time inference capabilities.It constructs an edge intelligent control architecture,enabling generative AI to directly participate in decision-making instruction generation,forming a new working system of perception,decision-making,and execution.Additionally,it designs a collaborative optimization training mechanism that leverages federated learning to overcome single-machine data limitations and enhance model generalization performance.At the application level,an intelligent fault prediction system is developed for early identification of equipment anomalies,an adaptive parameter optimization module is constructed for dynamically adjusting control strategies,and a multi-device collaborative scheduling engine is established to optimize production processes,providing technical support for embedded intelligent control in Industry 4.0 scenarios.
基金Single-Chip Microcomputer and Interface Technology Project(Project No.:SYSJ2025032)。
文摘In recent years,the application of various advanced technologies,such as digitization and informatization,has become the primary tool for innovation in education and teaching.For traditional single-chip microcomputer course teaching,it is necessary to emphasize the introduction and application of high-tech innovations in its path of innovative development.This course is a typical representative of multidisciplinary teaching,involving multiple disciplines such as electronic engineering,automation,and computer science.In response to issues faced in traditional teaching,such as rigid organization of teaching content that struggles to keep pace with technological advancements,resulting in a noticeable lag in knowledge transfer,and monotonous teaching methods that fail to precisely meet the diverse learning needs of students,analyzing the innovative applications of this course under the empowerment of AI technology holds significant practical relevance.In this regard,the study relies on AI technology empowerment to analyze the application paths for the deep integration of AI technology and single-chip microcomputer courses,constructing a new teaching model to provide references for enhancing teaching quality and stimulating students’innovative potential.
文摘A DC regulated power supply with numerical control based on single chip microcomputer （SCM） is designed. SCM is the main controller and output voltage o{ DC power supply can be set by keyboard. The analog voltage can be obtained through D/A converter （DAC0832） so that different voltages can be provided by operational amplifier. The output voltage varies from 0 V to 12 V with the incremental value of 0. 1 V. The actual output voltage is shown in the nixietube. This DC regulated power supply is characterized by simple structure and easy operation.
文摘A method which is especially suitable for microcomputer calculation of the true orientation distribution function (ODF) according to the maximum-entropy estimate is proposed for hexagonal system polycrystalline materials with physical symmetry.The resultant computational software system has been also designed and first carried out in a microcomputer PANAFACOM-U1200 being on line with the X-ray diffractometer D/max-3A.The simu- lated calculation shows that the method is concisely pragmatic and easily popularized,while the results obtained are trust worthy.
基金The Project Supported by Doctoral Programme Foundation of Institution of Higher Education
文摘Pump controlled motor electrohydraulic servo systems are much used in circumstances where high power drive is needed. This kind of system has the advantage of energy-saving. But, it also has some defects that have to be improved. Microcomputer control of a pump controlled motor electrohydraulic servo system is studied. A PID controller is first adopted on the closed loop control system, and experimental results are obtained. Then, a model reference adaptive controller is designed and realised on the same system applying a single board microcomputer. Experimental results show that the dynamic properties of the adaptive control system is much better than those of the PID system under different inertia load conditions.
基金Supported by the National Natural Science Foundation of China(11275164)~~
文摘With principles of reliability, independence, practicality and economical effi- ciency, a set of intelligent fire alarm system based on AVRmega128 single chip microcomputer was designed to solve problems of fire alarm system in many large- scale warehouses. Using advanced flame sensor, 485 bus communication, computer interactive software and related peripheral devices, this intelligent fire alarm system has functions of sound-light alarm and intelligent fire extinguishing. The human-com- puter interactive software was adopted for the remote control of the alarm main control panel through the 485 bus communication. This design of intelligent fire alarm system shows high reference and practical value to the development of intel- ligent alarm products with high integration and high reliability.
文摘Presents a one grade adaptive controller with one reference model which is built according to δ MRACS adaptive control theory and used to control an actual high order hydraulic system, and the whole hardware system used, which includes a AT89C51 single chip microcomputer, 74Ls373 flip latch, 6116 store, eight bit ADC0809, and so on, and the satisfactory results obtained in study on hydraulic control system.
基金The Fundamental Research Funds for the Central Research Institute (No. 2020-9054)。
文摘The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.
基金supported by the National Natural Science Foundation of China(No.20172034)Foundation for Univemity Key Teacher by Ministry of Educationthe grant for the State Key Program of China.
文摘A new method of synthesizing single-component molecular conductor [Ni(dmit)2] by the reaction 2(Me4N)[Ni(dmit)2]2 [Ni(dmit)2] + (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2] exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity.
基金the Beijing Natural Science Foundation(No.JQ21006)the Ministry of Science and Technology(No.2018YFA0208504)+3 种基金the National Natural Science Foundation(Nos.92163128,52073016,21905018)of Chinathe Fundamental Research Funds for the Central Universities(Nos.buctrc201828,XK1802-2)Open Project of State Key Laboratory of Organic-Inorganic Composites(No.oic-202201006)Open Project of State Key Laboratory of Supramolecular Structure and Materials(No.sklssm202209).
文摘In this work,semirigid linkers of the alkyl-thiophene-alkyl structure are developed to construct double-cable polymers.Three alkyl units,propyl(C3H6),hexyl(C6H12),and dodecyl(C12H24),are applied as semirigid linkers,yielding three double-cable polymers:PBC6-T,PBC12-T,and PBC24-T,respectively.PBC12-T which uses C6H12-thiophene-C6H12 linkers is found to exhibit the best device efficiency of 5.56%,while PBC6-T and PBC24-T with shorter or longer linkers yield device efficiencies of only 2.65%and 1.09%in single-component organic solar cells(SCOSCs).Further studies reveal that PBC12-T exhibits higher crystallinity and improved charge transport,resulting in better efficiencies.Our work provides an approach to construct double-cable conjugated polymers with long alkyl linkers,and it shows the importance of the linker length for the photovoltaic performance of SCOSCs.
基金jointly supported by National Key R&D Program of China(Nos.2018YFA0208504,2017YFA0204702)National Natural Science Foundation of China(Nos.51773207,21574138,21905018)+2 种基金Natural Science Foundation of Hebei Province(No.B2020201032)further supported by the Fundamental Research Funds for the Central Universities(No.XK1802-2)Open Project of State Key Laboratory of Supramolecular Structure and Materials(No.sklssm202043)。
文摘Single-component organic solar cells(SCOSCs)with high stability and simplified fabrication process are supposed to accelerate the commercialization of organic photovoltaics.However,the types of photo-active materials and photovoltaic performance of SCOSCs are still far lagging behind the bulk-heterojunction type organic solar cells(BHJ OSCs).It is still an arduous task to introduce new photo-active materials into SCOSCs,aiming to improve the efficiencies of SCOSCs.One feasible way is to construct double-cable polymers with new structures and tune conformation,morphology and mobility for the improvement in power conversion efficiencies(PCEs).Hence,in this work,we constructed a new double-cable polymer PBTT-BPTI by introducing fused core 5,7-dibromo-2,3-bis(2-ethylhexyl)benzo[1,2-b:4,5-c’]dithiophene-4,8-dione(TTDO)into the main backbone and benzo[ghi]-perylene triimide(BPTI)unit into the side chain.Both of the two units show strong electron-withdrawing property,which are expected to broaden absorption spectra and enhance intermolecular interaction.The double-cable polymer exhibited a broad absorption in the range of 300-700 nm with an optical band gap(E_(g))of 1.79 eV.The PCE of PBTT-BPTI-based SCOSCs was 2.15%,which may be limited by the unconstructed efficient electron transporting channels.
基金This study was financially supported by Beijing Natural Science Foundation of China.(No.JQ21006)the National Natural Science Foundation of China(Nos.92163128,52073016,51773207,21905018 and 21905158)of China+2 种基金This work was further financially supported by the Fundamental Research Funds for the Central Universities(Nos.buctrc201828 and XK1802-2)the opening Foundation of State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology(No.oic-202201006)Jiangxi Provincial Department of Science and Technology(No.20192ACB20009).
文摘In this work,the“functionalization-polymerization”(FP)method has been used to construct fullerene-contained double-cable conjugated polymers with“donor-acceptor”backbones.It was realized via synthesizing a fullerene-contained monomer and performing Stille polymerization.With this method,a series of double-cable conjugated polymers with different fullerene contents were developed and applied into single-component organic solar cells.The power conversion efficiencies(PCEs)based on these polymers increased from 0.71%to 1.71%with the enhanced fullerene contents.The relatively low PCEs might be originated from the poor microstructure in these polymers.These new conjugated polymers with molecular heterojunction would show potential application in organic electronic devices.
文摘In this paper, a microcomputer program package for pharmacokinetics and biopharmaceutics (PKBP) was presented. This package is applicable to various calculations for pharmacokinetics and biopharmaceutics. Some mathematical models and computing methods were developed. It has been used over 200 users.
文摘This paper presents a microcomputer program system for the three-dimensional non-linear finite element method (FEM), which is developed for applications in mining engineering, such as excavation, filling, caving, damming, etc. Our attention is focused on some of the key aspects of the programing techniques for an applicable microcomputer program, such as the structure of the program, data processing in the core, communication between the core and mass storage, input and output systems, etc. In the last part of this paper, two test examples are presented verifying the computational accuracy of this programing system and illustrating its applicability in practical engineering.
文摘This paper describes the statistical methods of the comparison of the incidence or mortality rates in cancer registry and descriptive epidemiology, and the features of microcomputer program (CANTEST) which was designed to perform the methods. The program was written in IBM BASIC language. Using the program CANTEST we presented here the user can do several statistical tests or estimations as follow: 1. the comparison of the adjusted rates which were calculated by directly or indirectly standardized methods, 2. the calculation of the slope of regression line for testing the linear trends of the adjusted rates, 3. the estimation of the 95% or 99%conndence intervals of the directly adjusted rates, of the cumulative rates (0-64 and 0-74), and of the cumulative risk. Several examples are presented for testing the performances of the program.
文摘For the first time, the split-unit experimental design was used in simulating free muscle transplantation by microneurovascular anastomoses on the rectus femoris of rabbits, and 12 functional indexes of contractile properties and the correlation between these indexes were analyzed with a microcomputer. The results showed that the maximum tetanic tension (TET) of grafted muscle would not return to normal level in the same animal until 1 year after operation (P>0.05), and, in our opinion,in view of tension balance between two sides, this was also the optimal time to appreciate the muscle function. It was found that the fatigue rate (FR) in each group was less than 25%, without any significant difference compared with that in the normal control side (F<F0.05, P>0.05). This was the functional evidence for the finding that the constituent ratio of 3 types of muscle fibers did not change in our study series. Therefore, the main character of fast contraction of the whole grafted muscles remained the same. There was a positive correlation between FR and TeT (r>r0.01), i.e. whenever TeT increased by 1 N, FR increased 0.12%.
文摘he present paper covers a model involving Donnan memhrane equilibrium andadsorption eluilibrium to describe the retention process for diprotic organic acids inion-exclusion chromatography. On this basis the microcomputer simulation of elu-tion behaviour for dicarboxylic acids was investigated. Influences of eluent acidityand sample concentration on the retention value were studied. The theoreticallypredicted results are in reasonable agreement with the experimental data.
文摘A microcomputerized measurement system is developed.This system automatically acquiresan I-V characteristic curve in 5 seconds with the accuracy of 0.05％ FSR(full scale range).The Schottkyextrapolation field-free emission,the inflection-point emission,the flection-point emission,the average effec-tive work function.the Richardson work function,the work function distribution at the operation tempera-ture and other important information that reflects properties of cathodes are obtained by this system.The re-sults of analysing four types of cathodes demonstrate that this system is very suitable for measuring the activi-ty changes of the cathode in the processes of activation,ageing,poisoning and life test.It is proved that thissystem can also be used to monitor the actlvity of the cathode in the assembled tube by measuring a gridcontrolled travelling-wave tube.
文摘In this paper, a successfully studied and developed master - slave muld - microcomputers control system based on PC - BUS for hollow spindle fancy yarn spinning machine, mainly Its overall scheme, software and hardware construction, is introduced. Spinning experiments show that the system achieves satisfactory result. This system can solve the diftkultles of mechatronical fusion between domestic hollow splndk fancy yarn spuming muchine and its microcomputer control technology.
