Slag movement on SiO2-based prism refractories in different slag systems was observed. The cross section shape evolution mechanism was discussed. Two types of shape evolution appear. For PbO-SiO2 slag whose surface te...Slag movement on SiO2-based prism refractories in different slag systems was observed. The cross section shape evolution mechanism was discussed. Two types of shape evolution appear. For PbO-SiO2 slag whose surface tension improves with SiO2 concentration, slag film flows up along four edges under axial Marangoni shear force and wettability. Then, it flows down along four lateral faces under gravity. Corrosion rate at edges is larger than that on lateral faces due to different SiO2 solubilities of ascending and descending flow. Prism cross section shape changes from square to round. For FetO-SiO2 slag whose surface tension reduces with the increase of SiO2 concentration, slag film flows up under the inflence of wettability. Then, it flows down under Marangoni shear force and gravity. Compared to four edges, slag is mainly up and down on four lateral faces due to larger surface tension and size. So, prism cross section shape keeps square.展开更多
The activity of VO in molten ternary CaO-SiO_2-VO Slag has been determined by chemical equilibrium method, using tin as the solvent metal. The relation between the activity and the content of VO, as well as the effect...The activity of VO in molten ternary CaO-SiO_2-VO Slag has been determined by chemical equilibrium method, using tin as the solvent metal. The relation between the activity and the content of VO, as well as the effect of slag basicity on activity of VO. are discussed.展开更多
A multi-phase slag containing Na2O is potential to efficiently dephosphorize high-P hot metal.After dephosphorization,the generated slag with high P2O5 content is regarded as a P resource.Because P2O5 was mainly conce...A multi-phase slag containing Na2O is potential to efficiently dephosphorize high-P hot metal.After dephosphorization,the generated slag with high P2O5 content is regarded as a P resource.Because P2O5 was mainly concentrated in the 2CaO SiO2-3CaO P2O5 solid solution,the recovery of P from dephosphorization slag primarily depends on the separation of the solid solution from other phases.The distribution ratios of P2O5 between solid solution and liquid phase in the CaOSiO2-FeO-P2O5-Nslag system were investigated.The results indicated that the addition of Na2O facilitated the enrichment of P2O5 in the solid solution because it increased not only the distribution ratio of P2O5 but also the mass fraction of the solid solution.The distribution ratio of P2O5 was independent of the P2O5 content in slag.A higher P2O5 content in slag resulted in higher P2O5 and Na2O contents in the solid solution.The distribution ratio of P2O5 increased with the total Fe content in the liquid phase,regardless of the valence of Fe.An increase in the FeO content in slag brought a higher P2O5 content in the solid solution.As slag basicity increased,the distribution ratio of P2O5 increased,but the P2O5 content in the solid solution decreased.展开更多
研究了高温条件下用碳还原含 Si O2 合成渣的过程。结果表明 :温度是使氧化物 ( Si O2 ,Mg O和 Al2 O3)还原的重要因素。在较高的温度和碳过剩条件下 ,控制适当的熔渣碱度和增加 Mg O含量 ,可增加渣中还原 Si O2 所生成的 Si C并减少所...研究了高温条件下用碳还原含 Si O2 合成渣的过程。结果表明 :温度是使氧化物 ( Si O2 ,Mg O和 Al2 O3)还原的重要因素。在较高的温度和碳过剩条件下 ,控制适当的熔渣碱度和增加 Mg O含量 ,可增加渣中还原 Si O2 所生成的 Si C并减少所形成的 Si O,实现在较高温度条件下抑制渣中 Si O2被还原的目的。展开更多
A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application ...A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.展开更多
The investigation results of the bonding structure of CaO-SiO2 slag by means of molecular dynamics simulation are presented. The characteristics of partial radial distribution function gij(r) are in good agreement wit...The investigation results of the bonding structure of CaO-SiO2 slag by means of molecular dynamics simulation are presented. The characteristics of partial radial distribution function gij(r) are in good agreement with the measurement of X-ray diffraction, and the variation of Qn with different SiO4 tetrahedra following the change of Xcao is consistent with the results of Raman spectroscopy, The partial vibrational density of states Fsi(ω) shows that two bands appear in the range of 636-737 cm-1 and 800? 200 cm-1 respectively which are also consistent with Raman spectroscopy.展开更多
基金Projects(U1738101,51804023)supported by the National Natural Science Foundation of ChinaProjects(FRF-TP-18-007A1,FRF-MP-18-007)supported by Fundamental Research Funds for the Central Universities,ChinaProject(2019M650489)supported by China Postdoctoral Science Foundation
文摘Slag movement on SiO2-based prism refractories in different slag systems was observed. The cross section shape evolution mechanism was discussed. Two types of shape evolution appear. For PbO-SiO2 slag whose surface tension improves with SiO2 concentration, slag film flows up along four edges under axial Marangoni shear force and wettability. Then, it flows down along four lateral faces under gravity. Corrosion rate at edges is larger than that on lateral faces due to different SiO2 solubilities of ascending and descending flow. Prism cross section shape changes from square to round. For FetO-SiO2 slag whose surface tension reduces with the increase of SiO2 concentration, slag film flows up under the inflence of wettability. Then, it flows down under Marangoni shear force and gravity. Compared to four edges, slag is mainly up and down on four lateral faces due to larger surface tension and size. So, prism cross section shape keeps square.
文摘The activity of VO in molten ternary CaO-SiO_2-VO Slag has been determined by chemical equilibrium method, using tin as the solvent metal. The relation between the activity and the content of VO, as well as the effect of slag basicity on activity of VO. are discussed.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51704010,51604003,U1760117)Key Laboratory Open Project Fund of Metallurgical Emission Reduction and Resources Recycling(Anhui University of Technology)Ministry of Education(JKF18-02).
文摘A multi-phase slag containing Na2O is potential to efficiently dephosphorize high-P hot metal.After dephosphorization,the generated slag with high P2O5 content is regarded as a P resource.Because P2O5 was mainly concentrated in the 2CaO SiO2-3CaO P2O5 solid solution,the recovery of P from dephosphorization slag primarily depends on the separation of the solid solution from other phases.The distribution ratios of P2O5 between solid solution and liquid phase in the CaOSiO2-FeO-P2O5-Nslag system were investigated.The results indicated that the addition of Na2O facilitated the enrichment of P2O5 in the solid solution because it increased not only the distribution ratio of P2O5 but also the mass fraction of the solid solution.The distribution ratio of P2O5 was independent of the P2O5 content in slag.A higher P2O5 content in slag resulted in higher P2O5 and Na2O contents in the solid solution.The distribution ratio of P2O5 increased with the total Fe content in the liquid phase,regardless of the valence of Fe.An increase in the FeO content in slag brought a higher P2O5 content in the solid solution.As slag basicity increased,the distribution ratio of P2O5 increased,but the P2O5 content in the solid solution decreased.
文摘研究了高温条件下用碳还原含 Si O2 合成渣的过程。结果表明 :温度是使氧化物 ( Si O2 ,Mg O和 Al2 O3)还原的重要因素。在较高的温度和碳过剩条件下 ,控制适当的熔渣碱度和增加 Mg O含量 ,可增加渣中还原 Si O2 所生成的 Si C并减少所形成的 Si O,实现在较高温度条件下抑制渣中 Si O2被还原的目的。
文摘A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.
基金Project supported by Shanghai Natural Science Foundation
文摘The investigation results of the bonding structure of CaO-SiO2 slag by means of molecular dynamics simulation are presented. The characteristics of partial radial distribution function gij(r) are in good agreement with the measurement of X-ray diffraction, and the variation of Qn with different SiO4 tetrahedra following the change of Xcao is consistent with the results of Raman spectroscopy, The partial vibrational density of states Fsi(ω) shows that two bands appear in the range of 636-737 cm-1 and 800? 200 cm-1 respectively which are also consistent with Raman spectroscopy.
