This paper studies high order compact finite volume methods on non-uniform meshes for one-dimensional elliptic and parabolic differential equations with the Robin boundary conditions.An explicit scheme and an implicit...This paper studies high order compact finite volume methods on non-uniform meshes for one-dimensional elliptic and parabolic differential equations with the Robin boundary conditions.An explicit scheme and an implicit scheme are obtained by discretizing the equivalent integral form of the equation.For the explicit scheme with nodal values,the algebraic system can be solved by the Thomas method.For the implicit scheme with both nodal values and their derivatives,the system can be implemented by a prediction-correction procedure,where in the correction stage,an implicit formula for recovering the nodal derivatives is introduced.Taking two point boundary value problem as an example,we prove that both the explicit and implicit schemes are convergent with fourth order accuracy with respect to some standard discrete norms using the energy method.Two numerical examples demonstrate the correctness and effectiveness of the schemes,as well as the indispensability of using non-uniform meshes.展开更多
When a ceramic ionic-crystal nanocluster is group-substituted with polymer chain segments to form an ionomeric aggregate,is the ordered structure maintained within the sterically hindered nanocluster?We observed,for N...When a ceramic ionic-crystal nanocluster is group-substituted with polymer chain segments to form an ionomeric aggregate,is the ordered structure maintained within the sterically hindered nanocluster?We observed,for Na-salt sulfonated polystyrene ionomer,the electron-diffraction lattice fringes of the nanoclusters,which proved their internal crystalline ordering driven by electrostatic attractions overcoming steric hindrance.Kinetically,the nanoclusters'enhanced melting endotherm upon aging indicate their quasi-,slow-ordering character.Extended tight binding molecular dynamics simulations provide an insight into the mechanism underlying the ionic-group aggregation during nanoclustering.We hence proposed an uncommon state of order,polymer-bound ceramic quasicrystal,supplementary to the order phenomena in crystalline ceramics.展开更多
Molecular dynamics simulations were carried out to study the effect of chemical short-range order(CSRO)on the primary radiation damage in TiVTaNb high-entropy alloys(HEAs).We have performed displacement cascade simula...Molecular dynamics simulations were carried out to study the effect of chemical short-range order(CSRO)on the primary radiation damage in TiVTaNb high-entropy alloys(HEAs).We have performed displacement cascade simulations to explore the CSRO effect on the generation and evolution behaviors of irradiation defects.The results demonstrate that CSRO can suppress the formation of Frenkel pairs in TiVTaNb HEAs,with the suppression effect becoming more pronounced as the degree of CSRO increases.CSRO can change the types of interstitial defects generated during cascade collisions.Specifically,as the degree of CSRO increases,the proportion of Ti-related interstitials shows a marked enhancement,primarily evidenced by a significant rise in Ti–Ti dumbbells accompanied by a corresponding decrease in Ti–V dumbbells.CSRO exhibits negligible influence on defect clustering and the nucleation and evolution of dislocation loops.Regardless of CSRO conditions,TiVTaNb HEAs preserve exceptional radiation tolerance throughout the cascade damage process,suggesting that the intrinsic properties of this multi-principal element system dominate its radiation response.These findings provide fundamental insights into the CSRO effect on defect formation and evolution behaviors in HEAs,which may provide new design strategies for high-entropy alloys.展开更多
While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor ...While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.展开更多
To address the issue that hybrid flow shop production struggles to handle order disturbance events,a dynamic scheduling model was constructed.The model takes minimizing the maximum makespan,delivery time deviation,and...To address the issue that hybrid flow shop production struggles to handle order disturbance events,a dynamic scheduling model was constructed.The model takes minimizing the maximum makespan,delivery time deviation,and scheme deviation degree as the optimization objectives.An adaptive dynamic scheduling strategy based on the degree of order disturbance is proposed.An improved multi-objective Grey Wolf(IMOGWO)optimization algorithm is designed by combining the“job-machine”two-layer encoding strategy,the timing-driven two-stage decoding strategy,the opposition-based learning initialization population strategy,the POX crossover strategy,the dualoperation dynamic mutation strategy,and the variable neighborhood search strategy for problem solving.A variety of test cases with different scales were designed,and ablation experiments were conducted to verify the effectiveness of the improved strategies.The results show that each improved strategy can effectively enhance the performance of the IMOGWO.Additionally,performance analysis was conducted by comparing the proposed algorithm with three mature and classical algorithms.The results demonstrate that the proposed algorithm exhibits superior performance in solving the hybrid flow-shop scheduling problem(HFSP).Case validations were conducted for different types of order disturbance scenarios.The results demonstrate that the proposed adaptive dynamic scheduling strategy and the IMOGWO algorithm can effectively address order disturbance events.They enable rapid response to order disturbance while ensuring the stability of the production system.展开更多
The synchrotron radiation beamline BL17B of the National Facility for Protein Science(NFPS)in Shanghai,situated at the Shanghai Synchrotron Radiation Facility(SSRF),was originally designed for diffraction experiments ...The synchrotron radiation beamline BL17B of the National Facility for Protein Science(NFPS)in Shanghai,situated at the Shanghai Synchrotron Radiation Facility(SSRF),was originally designed for diffraction experiments and accommodates techniques including single-crystal diffraction,powder diffraction,and grazing-incidence wide-angle X-ray scattering(GIWAXS)to enable the characterization of long-range ordered atomic structures.The academic community associated with BL17B engages in research domains encompassing biology,environment,energy,and materials,and a pronounced demand for characterizing short-range ordered structures exists.To address these requirements,BL17B established an advanced X-ray absorption fine structure(XAFS)experimental platform that enabled it to address a wide range of systems,from crystalline to amorphous and from long-range order to short-range order.The XAFS platform allows simultaneous XAFS data acquisition for both the transmission and fluorescence modes within an energy range of 5-23 keV,encompassing the K-edges of titanium to ruthenium and the L3-edges of cesium to bismuth.The platform exemplifies high levels of automation achieved through automated sample assessment and data collection based on large-capacity sample wheels that facilitate remote sample loading.When integrated with a highly integrated control system that simplifies experimental preparation and data collection,the XAFS platform significantly bolsters experimental efficiency and enhances user experience.Notably,the platform boasts an impressively low extended X-ray absorption fine structure(EXAFS)detection limit of 0.04 wt%for dilute copper phthalocyanine(CuPc)samples and an even more remarkable X-ray absorption near edge structure(XANES)detection threshold of 0.01 wt%.These results demonstrate the methodology?s reliability in low-concentration sample analysis,confirming its capability to generate high-quality XAFS data.展开更多
To enhance the prediction accuracy of unsteady wakes behind wind turbines,a novel reduced-order model is proposed by integrating a multifunctional recurrent fuzzy neural network(MFRFNN)and proper orthogonal decom-posi...To enhance the prediction accuracy of unsteady wakes behind wind turbines,a novel reduced-order model is proposed by integrating a multifunctional recurrent fuzzy neural network(MFRFNN)and proper orthogonal decom-position(POD).First,POD is employed to reduce the di-mensionality of the wind field data,extracting spatiotempo-rally correlated modal coefficients and modes.These reduced-order variables can effectively capture the essential features of unsteady wake behaviors.Next,MFRFNN is utilized to predict the time series of modal coefficients.Fi-nally,by combining the predicted modal coefficients with their corresponding modes,a flow field is reconstructed,al-lowing accurate prediction of unsteady wake dynamics.The predicted wake data exhibit high consistency with large eddy simulation results in both the near-and far-wake re-gions and outperform existing data-driven methods.This ap-proach offers significant potential for optimizing wind farm design and provides a new solution for the precise prediction of wind turbine wake behavior.展开更多
The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this stu...The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this study,molecular dynamics(MD)simulations are employed to examine mineral-like model surfaces with varying degrees of hydrophobicity,modulated by surface charges,to elucidate the adsorption behavior of nanobubbles at the interface.Our findings not only contribute to the fundamental understanding of nanobubbles but also have potential applications in the mining industry.We observed that as the surface charge increases,the contact angle of the nanobubbles increases accordingly with shape transformation from a pancake-like gas film to a cap-like shape,and ultimately forming a stable nanobubble upon an ordered water monolayer.When the solid–water interactions are weak with a small partial charge,the hydrophobic gas(N_(2))molecules accumulate near the solid surfaces.However,we have found,for the first time,that gas molecules assemble a nanobubble on the water monolayer adjacent to the solid surfaces with large partial charges.Such phenomena are attributed to the formation of a hydrophobic water monolayer with a hydrogen bond network structure near the surface.展开更多
Two novel out-of-plane ordered quaternary borides M'_(4)VSiB_(2) (M'=Nb and Mo) have been synthesized. The out-of-plane ordered characteristic has been confirmed by the X-ray diffraction, the neutron powder di...Two novel out-of-plane ordered quaternary borides M'_(4)VSiB_(2) (M'=Nb and Mo) have been synthesized. The out-of-plane ordered characteristic has been confirmed by the X-ray diffraction, the neutron powder diffraction and the scanning transmission electron microscopy with high-angle angular dark field images. By adjusting the stoichiometric ratio of Mo and V, the 16l site preferentially occupied by relatively larger atom and 4c site by relatively smaller atom have been confirmed. The further first-principle calculation demonstrates the dynamical and thermodynamical stability of Mo_(4)VSiB_(2) o-T2 phase. This work confirms the transition metal occupation strategy of o-T2 phase and enriches the out-of-plane ordered laminated borides family.展开更多
In order to understand the influence of ordering behaviors on the thermodynamic and mechanical properties of multi-principal element alloys(MPEAs),the temperature-dependent thermodynamic properties and mechanical prop...In order to understand the influence of ordering behaviors on the thermodynamic and mechanical properties of multi-principal element alloys(MPEAs),the temperature-dependent thermodynamic properties and mechanical properties of FCC_CoNiV MPEAs were comparatively predicted,where the alloys were modeled as the ordered configurations based on our previously predicted site occupying fractions(SOFs),as well as disordered configuration based on traditional special quasi-random structure(SQS).The ordering behavior not only improves the thermodynamic stability of the structure,but also increases the elastic properties and Vickers hardness.For example,at 973 K,the predicted bulk modulus(B),shear modulus(G),Young’s modulus(E),and Vickers hardness(HV)of FCC_CoNiV MPEA based on SOFs configuration are 187.82,79.03,207.93,and 7.58 GPa,respectively,while the corresponded data are 172.58,57.45,155.14,and 4.64 GPa for the SQS configuration,respectively.The Vickers hardness predicted based on SOFs agrees considerably well with the available experimental data,while it is underestimated obviously based on SQS.展开更多
In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order hom...In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order homogenization(ROH)approach.The ROH method typically involves solving multiple finite element problems under periodic conditions to evaluate elastic strain and eigenstrain influence functions in an‘off-line’stage,which offers substantial cost savings compared to direct computational homogenization methods.Due to the unique structure of the fibrous unit cell,“off-line”stage calculation can be eliminated by influence functions obtained analytically.Introducing the standard solid model to the ROH method enables the creation of a comprehensive analytical homogeneous viscoelastic constitutive model.This method treats fibrous composite materials as homogeneous,anisotropic viscoelastic materials,significantly reducing computational time due to its analytical nature.This approach also enables precise determination of a homogenized anisotropic relaxation modulus and accurate capture of various viscoelastic responses under different loading conditions.Three sets of numerical examples,including unit cell tests,three-point beam bending tests,and torsion tests,are given to demonstrate the predictive performance of the homogenized viscoelastic model.Furthermore,the model is validated against experimental measurements,confirming its accuracy and reliability.展开更多
In this paper,we delve into a generalized higher order Camassa-Holm type equation,(or,an ghmCH equation for short).We establish local well-posedness for this equation under the condition that the initial data uo belon...In this paper,we delve into a generalized higher order Camassa-Holm type equation,(or,an ghmCH equation for short).We establish local well-posedness for this equation under the condition that the initial data uo belongs to the Sobolev space H'(R)for some s>2.In addition,we obtain the weak formulation of this equation and prove the existence of both single peakon solution and a multi-peakon dynamic system.展开更多
In this paper,we give a complete characterization of all self-adjoint domains of odd order differential operators on two intervals.These two intervals with all four endpoints are singular(one endpoint of each interval...In this paper,we give a complete characterization of all self-adjoint domains of odd order differential operators on two intervals.These two intervals with all four endpoints are singular(one endpoint of each interval is singular or all four endpoints are regulars are the special cases).And these extensions yield"new"self-adjoint operators,which involve interactions between the two intervals.展开更多
Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometri...Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.展开更多
Guided by the fundamental principles of the whole petroleum system,the control of tectonism,sedimentation,and diagenesis on hydrocarbon accumulation in a rifted basin is studied using the data of petroleum geology and...Guided by the fundamental principles of the whole petroleum system,the control of tectonism,sedimentation,and diagenesis on hydrocarbon accumulation in a rifted basin is studied using the data of petroleum geology and exploration of the second member of the Paleogene Kongdian Formation(Kong-2 Member)in the Cangdong Sag,Bohai Bay Basin,China.It is clarified that the circle structure and circle effects are the marked features of a continental fault petroliferous basin,and they govern the orderly distribution of conventional and unconventional hydrocarbons in the whole petroleum systems of the rifted basin.Tectonic circle zones control sedimentary circle zones,while sedimentary circle zones and diagenetic circle zones control the spatial distribution of favorable reservoirs,thereby determining the orderly distribution of hydrocarbon accumulations in various circles.A model for the integrated,systematic accumulation of conventional and unconventional hydrocarbons under a multi-circle structure of the whole petroleum system of continental rifted basin has been developed.It reveals that each sag of the rifted basin is an independent whole petroleum system and circle system,which encompasses multiple orderly circles of conventional and unconventional hydrocarbons controlled by the same source kitchen.From the outer circle to the middle circle and then to the inner circle,there is an orderly transition from structural and stratigraphic reservoirs,to lithological and structural-lithological reservoirs,and finally to tight oil/gas and shale oil/gas enrichment zones.The significant feature of the whole petroleum system is the orderly control of hydrocarbons by multi-circle stratigraphic coupling,with the integrated,orderly distribution of conventional and unconventional reserves being the inevitable result of the multi-layered interaction within the whole petroleum system.This concept of multi-circle stratigraphic coupling for the orderly,integrated accumulation of conventional and unconventional hydrocarbons has guided significant breakthroughs in the overall,three-dimensional exploration and shale oil exploration in the Cangdong Sag.展开更多
Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applica...Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applications.The distinct electronic configurations and tunable attributes of two-dimensional materials position them as a quintessential platform for the realization of second-order topological insulators(SOTIs).This article provides an overview of the research progress in SOTIs within the field of two-dimensional electronic materials,focusing on the characterization of higher-order topological properties and the numerous candidate materials proposed in theoretical studies.These endeavors not only enhance our understanding of higher-order topological states but also highlight potential material systems that could be experimentally realized.展开更多
In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introduc...In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introducing only one additional evaluation of the function in each step.Furthermore,some new efficient methods with a higher-order of convergence are obtained by using only a single matrix inversion in each iteration.Analyses of convergence properties and computational efficiency of these new methods are made and testified by several numerical problems.By comparison,the new schemes are more efficient than the corresponding existing ones,particularly for large problem sizes.展开更多
The search for novel carbons has been an important research topic for developing high-performance anodes of lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs).In this study,we fabricated a new carbon,long-range...The search for novel carbons has been an important research topic for developing high-performance anodes of lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs).In this study,we fabricated a new carbon,long-range ordered porous carbon(LOPC),by inducing covalent bonds between face-centered cubic C_(60)(fcc C_(60))cages in a molecular crystal via electron injection under vacuum at~520°C.The LOPC maintains the periodic lattice of the fcc C_(60)molecular crystal but has improved structural stability and electrical conductivity because of the sp^(2)bonding formed between C_(60)molecules.Compared with fcc C_(60),which has a much greater specific surface area(327.1 m^(2)·g^(−1)),LOPC has a specific capacity of 820.9 mA·h·g^(−1)or 292.9 mA·h·g^(−1)as an anode for LIBs or SIBs,both of which are measured at a current density of 0.1 A·g^(−1).This porous yet ordered carbon may open new opportunities for anode materials in electrochemical energy storage.展开更多
In the third quarter of 2025,the orders index for textile machinery-compiled by ACIMIT's Economics Department(the Association of Italian Textile Machinery Manufacturers)-recorded a16%decrease compared to the same ...In the third quarter of 2025,the orders index for textile machinery-compiled by ACIMIT's Economics Department(the Association of Italian Textile Machinery Manufacturers)-recorded a16%decrease compared to the same period in 2024.In absolute terms,the index stood at 41.8 points(base year2021=100).The decline reflects negative performances in both the domestic and foreign markets.Specifically,on the domestic market,orders fell by 17%compared to the same quarter of the previous year,with the absolute index value reaching49.9points.展开更多
Dear Editor,In this letter,a constrained networked predictive control strategy is proposed for the optimal control problem of complex nonlinear highorder fully actuated(HOFA)systems with noises.The method can effectiv...Dear Editor,In this letter,a constrained networked predictive control strategy is proposed for the optimal control problem of complex nonlinear highorder fully actuated(HOFA)systems with noises.The method can effectively deal with nonlinearities,constraints,and noises in the system,optimize the performance metric,and present an upper bound on the stable output of the system.展开更多
文摘This paper studies high order compact finite volume methods on non-uniform meshes for one-dimensional elliptic and parabolic differential equations with the Robin boundary conditions.An explicit scheme and an implicit scheme are obtained by discretizing the equivalent integral form of the equation.For the explicit scheme with nodal values,the algebraic system can be solved by the Thomas method.For the implicit scheme with both nodal values and their derivatives,the system can be implemented by a prediction-correction procedure,where in the correction stage,an implicit formula for recovering the nodal derivatives is introduced.Taking two point boundary value problem as an example,we prove that both the explicit and implicit schemes are convergent with fourth order accuracy with respect to some standard discrete norms using the energy method.Two numerical examples demonstrate the correctness and effectiveness of the schemes,as well as the indispensability of using non-uniform meshes.
基金Funded by the Hubei Province Key Research Foundation for Water Resources,China(No.HBSLKY2023035)as well as by the Technology Foundation for Selected Overseas Scholars,Ministry of Human Resources and Social Security,China(No.[2013]277)+2 种基金the Natural Science Foundation of the Hubei Province of China(No.2014CFA094)the Overseas High-level Talents Scientific-research Starting Fund of Hubei University of Technology,China(HBUTscience-[2005]2)the National Natural Science Foundation of China(No.51703053)。
文摘When a ceramic ionic-crystal nanocluster is group-substituted with polymer chain segments to form an ionomeric aggregate,is the ordered structure maintained within the sterically hindered nanocluster?We observed,for Na-salt sulfonated polystyrene ionomer,the electron-diffraction lattice fringes of the nanoclusters,which proved their internal crystalline ordering driven by electrostatic attractions overcoming steric hindrance.Kinetically,the nanoclusters'enhanced melting endotherm upon aging indicate their quasi-,slow-ordering character.Extended tight binding molecular dynamics simulations provide an insight into the mechanism underlying the ionic-group aggregation during nanoclustering.We hence proposed an uncommon state of order,polymer-bound ceramic quasicrystal,supplementary to the order phenomena in crystalline ceramics.
基金Project supported by the Youth Program of the National Natural Science Foundation of China(Grant No.12405324)the CNNC Science Fund for Talented Young Scholars(Grant No.24940)the CNNC Basic Science Fund(Grant No.24851)。
文摘Molecular dynamics simulations were carried out to study the effect of chemical short-range order(CSRO)on the primary radiation damage in TiVTaNb high-entropy alloys(HEAs).We have performed displacement cascade simulations to explore the CSRO effect on the generation and evolution behaviors of irradiation defects.The results demonstrate that CSRO can suppress the formation of Frenkel pairs in TiVTaNb HEAs,with the suppression effect becoming more pronounced as the degree of CSRO increases.CSRO can change the types of interstitial defects generated during cascade collisions.Specifically,as the degree of CSRO increases,the proportion of Ti-related interstitials shows a marked enhancement,primarily evidenced by a significant rise in Ti–Ti dumbbells accompanied by a corresponding decrease in Ti–V dumbbells.CSRO exhibits negligible influence on defect clustering and the nucleation and evolution of dislocation loops.Regardless of CSRO conditions,TiVTaNb HEAs preserve exceptional radiation tolerance throughout the cascade damage process,suggesting that the intrinsic properties of this multi-principal element system dominate its radiation response.These findings provide fundamental insights into the CSRO effect on defect formation and evolution behaviors in HEAs,which may provide new design strategies for high-entropy alloys.
基金funding supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB1140000)National Natural Science Foundation of China(22379156,U23A20141)+1 种基金Qingdao New Energy Shandong Laboratory(QIBEBT/SEI/QNESL S202305)Key R&D Program of Shandong Province,China(2024SFGC0102)。
文摘While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.
基金funded by National Key Research and Development Program Projects of China under Grant No.2020YFB1713500.
文摘To address the issue that hybrid flow shop production struggles to handle order disturbance events,a dynamic scheduling model was constructed.The model takes minimizing the maximum makespan,delivery time deviation,and scheme deviation degree as the optimization objectives.An adaptive dynamic scheduling strategy based on the degree of order disturbance is proposed.An improved multi-objective Grey Wolf(IMOGWO)optimization algorithm is designed by combining the“job-machine”two-layer encoding strategy,the timing-driven two-stage decoding strategy,the opposition-based learning initialization population strategy,the POX crossover strategy,the dualoperation dynamic mutation strategy,and the variable neighborhood search strategy for problem solving.A variety of test cases with different scales were designed,and ablation experiments were conducted to verify the effectiveness of the improved strategies.The results show that each improved strategy can effectively enhance the performance of the IMOGWO.Additionally,performance analysis was conducted by comparing the proposed algorithm with three mature and classical algorithms.The results demonstrate that the proposed algorithm exhibits superior performance in solving the hybrid flow-shop scheduling problem(HFSP).Case validations were conducted for different types of order disturbance scenarios.The results demonstrate that the proposed adaptive dynamic scheduling strategy and the IMOGWO algorithm can effectively address order disturbance events.They enable rapid response to order disturbance while ensuring the stability of the production system.
基金supported by the Chinese Academy of Science(CAS)Key Technology Talent Program(No.2021000022)。
文摘The synchrotron radiation beamline BL17B of the National Facility for Protein Science(NFPS)in Shanghai,situated at the Shanghai Synchrotron Radiation Facility(SSRF),was originally designed for diffraction experiments and accommodates techniques including single-crystal diffraction,powder diffraction,and grazing-incidence wide-angle X-ray scattering(GIWAXS)to enable the characterization of long-range ordered atomic structures.The academic community associated with BL17B engages in research domains encompassing biology,environment,energy,and materials,and a pronounced demand for characterizing short-range ordered structures exists.To address these requirements,BL17B established an advanced X-ray absorption fine structure(XAFS)experimental platform that enabled it to address a wide range of systems,from crystalline to amorphous and from long-range order to short-range order.The XAFS platform allows simultaneous XAFS data acquisition for both the transmission and fluorescence modes within an energy range of 5-23 keV,encompassing the K-edges of titanium to ruthenium and the L3-edges of cesium to bismuth.The platform exemplifies high levels of automation achieved through automated sample assessment and data collection based on large-capacity sample wheels that facilitate remote sample loading.When integrated with a highly integrated control system that simplifies experimental preparation and data collection,the XAFS platform significantly bolsters experimental efficiency and enhances user experience.Notably,the platform boasts an impressively low extended X-ray absorption fine structure(EXAFS)detection limit of 0.04 wt%for dilute copper phthalocyanine(CuPc)samples and an even more remarkable X-ray absorption near edge structure(XANES)detection threshold of 0.01 wt%.These results demonstrate the methodology?s reliability in low-concentration sample analysis,confirming its capability to generate high-quality XAFS data.
基金The National Natural Science Foundation of China (No. 51908107)。
文摘To enhance the prediction accuracy of unsteady wakes behind wind turbines,a novel reduced-order model is proposed by integrating a multifunctional recurrent fuzzy neural network(MFRFNN)and proper orthogonal decom-position(POD).First,POD is employed to reduce the di-mensionality of the wind field data,extracting spatiotempo-rally correlated modal coefficients and modes.These reduced-order variables can effectively capture the essential features of unsteady wake behaviors.Next,MFRFNN is utilized to predict the time series of modal coefficients.Fi-nally,by combining the predicted modal coefficients with their corresponding modes,a flow field is reconstructed,al-lowing accurate prediction of unsteady wake dynamics.The predicted wake data exhibit high consistency with large eddy simulation results in both the near-and far-wake re-gions and outperform existing data-driven methods.This ap-proach offers significant potential for optimizing wind farm design and provides a new solution for the precise prediction of wind turbine wake behavior.
基金supported by the National Natural Science Foundation of China(Grant Nos.12022508,12074394,and 22125604)Shanghai Supercomputer Center of ChinaShanghai Snowlake Technology Co.Ltd.
文摘The stable nanobubbles adhered to mineral surfaces may facilitate their efficient separation via flotation in the mining industry.However,the state of nanobubbles on mineral solid surfaces is still elusive.In this study,molecular dynamics(MD)simulations are employed to examine mineral-like model surfaces with varying degrees of hydrophobicity,modulated by surface charges,to elucidate the adsorption behavior of nanobubbles at the interface.Our findings not only contribute to the fundamental understanding of nanobubbles but also have potential applications in the mining industry.We observed that as the surface charge increases,the contact angle of the nanobubbles increases accordingly with shape transformation from a pancake-like gas film to a cap-like shape,and ultimately forming a stable nanobubble upon an ordered water monolayer.When the solid–water interactions are weak with a small partial charge,the hydrophobic gas(N_(2))molecules accumulate near the solid surfaces.However,we have found,for the first time,that gas molecules assemble a nanobubble on the water monolayer adjacent to the solid surfaces with large partial charges.Such phenomena are attributed to the formation of a hydrophobic water monolayer with a hydrogen bond network structure near the surface.
基金supported by the National Youth Talent Support Program(No.QNBJ-2022-03)the National Natu-ral Science Foundation of China(No.52371180)the Fundamental Research Funds for the Central Universities(Nos.N2209005 and N2309001).
文摘Two novel out-of-plane ordered quaternary borides M'_(4)VSiB_(2) (M'=Nb and Mo) have been synthesized. The out-of-plane ordered characteristic has been confirmed by the X-ray diffraction, the neutron powder diffraction and the scanning transmission electron microscopy with high-angle angular dark field images. By adjusting the stoichiometric ratio of Mo and V, the 16l site preferentially occupied by relatively larger atom and 4c site by relatively smaller atom have been confirmed. The further first-principle calculation demonstrates the dynamical and thermodynamical stability of Mo_(4)VSiB_(2) o-T2 phase. This work confirms the transition metal occupation strategy of o-T2 phase and enriches the out-of-plane ordered laminated borides family.
基金financially supported by the State Administration for Market Regulation,China(No.2021MK050)the National Natural Science Foundation of China(Nos.50971043,51171046,21973012)+3 种基金the Key Research and Development Program of China(Nos.2022YFB3807200,CISRI-21T62450ZD)the Natural Science Foundation of Fujian Province,China(Nos.2021J01590,2020J01351,2018J01754,2020J01474)the Student Research and Training Program(SRTP) of Fuzhou University,China(No.29320)Fujian Provincial Department of Science & Technology,China(No.2021H6011)。
文摘In order to understand the influence of ordering behaviors on the thermodynamic and mechanical properties of multi-principal element alloys(MPEAs),the temperature-dependent thermodynamic properties and mechanical properties of FCC_CoNiV MPEAs were comparatively predicted,where the alloys were modeled as the ordered configurations based on our previously predicted site occupying fractions(SOFs),as well as disordered configuration based on traditional special quasi-random structure(SQS).The ordering behavior not only improves the thermodynamic stability of the structure,but also increases the elastic properties and Vickers hardness.For example,at 973 K,the predicted bulk modulus(B),shear modulus(G),Young’s modulus(E),and Vickers hardness(HV)of FCC_CoNiV MPEA based on SOFs configuration are 187.82,79.03,207.93,and 7.58 GPa,respectively,while the corresponded data are 172.58,57.45,155.14,and 4.64 GPa for the SQS configuration,respectively.The Vickers hardness predicted based on SOFs agrees considerably well with the available experimental data,while it is underestimated obviously based on SQS.
基金support by the National Key R&D Program of China(Grant No.2023YFA1008901)the National Natural Science Foundation of China(Grant Nos.11988102,12172009)is gratefully acknowledged.
文摘In this manuscript,we propose an analytical equivalent linear viscoelastic constitutive model for fiber-reinforced composites,bypassing general computational homogenization.The method is based on the reduced-order homogenization(ROH)approach.The ROH method typically involves solving multiple finite element problems under periodic conditions to evaluate elastic strain and eigenstrain influence functions in an‘off-line’stage,which offers substantial cost savings compared to direct computational homogenization methods.Due to the unique structure of the fibrous unit cell,“off-line”stage calculation can be eliminated by influence functions obtained analytically.Introducing the standard solid model to the ROH method enables the creation of a comprehensive analytical homogeneous viscoelastic constitutive model.This method treats fibrous composite materials as homogeneous,anisotropic viscoelastic materials,significantly reducing computational time due to its analytical nature.This approach also enables precise determination of a homogenized anisotropic relaxation modulus and accurate capture of various viscoelastic responses under different loading conditions.Three sets of numerical examples,including unit cell tests,three-point beam bending tests,and torsion tests,are given to demonstrate the predictive performance of the homogenized viscoelastic model.Furthermore,the model is validated against experimental measurements,confirming its accuracy and reliability.
文摘In this paper,we delve into a generalized higher order Camassa-Holm type equation,(or,an ghmCH equation for short).We establish local well-posedness for this equation under the condition that the initial data uo belongs to the Sobolev space H'(R)for some s>2.In addition,we obtain the weak formulation of this equation and prove the existence of both single peakon solution and a multi-peakon dynamic system.
基金Supported by NSFC (No.12361027)NSF of Inner Mongolia (No.2018MS01021)+1 种基金NSF of Shandong Province (No.ZR2020QA009)Science and Technology Innovation Program for Higher Education Institutions of Shanxi Province (No.2024L533)。
文摘In this paper,we give a complete characterization of all self-adjoint domains of odd order differential operators on two intervals.These two intervals with all four endpoints are singular(one endpoint of each interval is singular or all four endpoints are regulars are the special cases).And these extensions yield"new"self-adjoint operators,which involve interactions between the two intervals.
基金supported by the National Natural Science Foundation(22279036)the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(B21003).
文摘Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.
基金Supported by the National Science and Technology Major Project of China(2024ZD1400101)China National Key Research and Development Project(2022YFF0801204)Major Science and Technology Project of CNPC(2023ZZ15YJ01,2021DJ0702)。
文摘Guided by the fundamental principles of the whole petroleum system,the control of tectonism,sedimentation,and diagenesis on hydrocarbon accumulation in a rifted basin is studied using the data of petroleum geology and exploration of the second member of the Paleogene Kongdian Formation(Kong-2 Member)in the Cangdong Sag,Bohai Bay Basin,China.It is clarified that the circle structure and circle effects are the marked features of a continental fault petroliferous basin,and they govern the orderly distribution of conventional and unconventional hydrocarbons in the whole petroleum systems of the rifted basin.Tectonic circle zones control sedimentary circle zones,while sedimentary circle zones and diagenetic circle zones control the spatial distribution of favorable reservoirs,thereby determining the orderly distribution of hydrocarbon accumulations in various circles.A model for the integrated,systematic accumulation of conventional and unconventional hydrocarbons under a multi-circle structure of the whole petroleum system of continental rifted basin has been developed.It reveals that each sag of the rifted basin is an independent whole petroleum system and circle system,which encompasses multiple orderly circles of conventional and unconventional hydrocarbons controlled by the same source kitchen.From the outer circle to the middle circle and then to the inner circle,there is an orderly transition from structural and stratigraphic reservoirs,to lithological and structural-lithological reservoirs,and finally to tight oil/gas and shale oil/gas enrichment zones.The significant feature of the whole petroleum system is the orderly control of hydrocarbons by multi-circle stratigraphic coupling,with the integrated,orderly distribution of conventional and unconventional reserves being the inevitable result of the multi-layered interaction within the whole petroleum system.This concept of multi-circle stratigraphic coupling for the orderly,integrated accumulation of conventional and unconventional hydrocarbons has guided significant breakthroughs in the overall,three-dimensional exploration and shale oil exploration in the Cangdong Sag.
基金supported by the National Natu-ral Science Foundation of China(Grants No.12174220 and No.12074217)the Shandong Provincial Science Foundation for Excellent Young Scholars(Grant No.ZR2023YQ001)+1 种基金the Taishan Young Scholar Program of Shandong Provincethe Qilu Young Scholar Pro-gram of Shandong University.
文摘Higher-order band topology not only enriches our understanding of topological phases but also unveils pioneering lower-dimensional boundary states,which harbors substantial potential for next-generation device applications.The distinct electronic configurations and tunable attributes of two-dimensional materials position them as a quintessential platform for the realization of second-order topological insulators(SOTIs).This article provides an overview of the research progress in SOTIs within the field of two-dimensional electronic materials,focusing on the characterization of higher-order topological properties and the numerous candidate materials proposed in theoretical studies.These endeavors not only enhance our understanding of higher-order topological states but also highlight potential material systems that could be experimentally realized.
基金Supported by the National Natural Science Foundation of China(12061048)NSF of Jiangxi Province(20232BAB201026,20232BAB201018)。
文摘In this paper,a new technique is introduced to construct higher-order iterative methods for solving nonlinear systems.The order of convergence of some iterative methods can be improved by three at the cost of introducing only one additional evaluation of the function in each step.Furthermore,some new efficient methods with a higher-order of convergence are obtained by using only a single matrix inversion in each iteration.Analyses of convergence properties and computational efficiency of these new methods are made and testified by several numerical problems.By comparison,the new schemes are more efficient than the corresponding existing ones,particularly for large problem sizes.
基金supported by the National Key R&D Program of China(2020YFA0711502)the National Natural Science Foundation of China(51972299,52003265,52202052,52273234,52273239,52373310).Fei Pan is supported by the Xiaomi Young Talents Program.
文摘The search for novel carbons has been an important research topic for developing high-performance anodes of lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs).In this study,we fabricated a new carbon,long-range ordered porous carbon(LOPC),by inducing covalent bonds between face-centered cubic C_(60)(fcc C_(60))cages in a molecular crystal via electron injection under vacuum at~520°C.The LOPC maintains the periodic lattice of the fcc C_(60)molecular crystal but has improved structural stability and electrical conductivity because of the sp^(2)bonding formed between C_(60)molecules.Compared with fcc C_(60),which has a much greater specific surface area(327.1 m^(2)·g^(−1)),LOPC has a specific capacity of 820.9 mA·h·g^(−1)or 292.9 mA·h·g^(−1)as an anode for LIBs or SIBs,both of which are measured at a current density of 0.1 A·g^(−1).This porous yet ordered carbon may open new opportunities for anode materials in electrochemical energy storage.
文摘In the third quarter of 2025,the orders index for textile machinery-compiled by ACIMIT's Economics Department(the Association of Italian Textile Machinery Manufacturers)-recorded a16%decrease compared to the same period in 2024.In absolute terms,the index stood at 41.8 points(base year2021=100).The decline reflects negative performances in both the domestic and foreign markets.Specifically,on the domestic market,orders fell by 17%compared to the same quarter of the previous year,with the absolute index value reaching49.9points.
基金supported in part by the National Natural Science Foundation of China(62173255,62188101)Shenzhen Key Laboratory of Control Theory and Intelligent Systems(ZDSYS20220330161800001)
文摘Dear Editor,In this letter,a constrained networked predictive control strategy is proposed for the optimal control problem of complex nonlinear highorder fully actuated(HOFA)systems with noises.The method can effectively deal with nonlinearities,constraints,and noises in the system,optimize the performance metric,and present an upper bound on the stable output of the system.
