Suspensions of a latosol with a clay concentration of 30 g kg^(-1) wereprepared from electrodialyzed clay fractions, less than 2 μm in diameter, five nitrate solutionswith a concentration of 1 X 10^(04)/z mol L^(-1),...Suspensions of a latosol with a clay concentration of 30 g kg^(-1) wereprepared from electrodialyzed clay fractions, less than 2 μm in diameter, five nitrate solutionswith a concentration of 1 X 10^(04)/z mol L^(-1), where z is the valence, and five sodium saltsolutions with a concentration of 3.3 X 10^(-5)/2 mol L^(-1). The direct current (DC) electricalconductivities (ECs) of the colloidal suspensions were measured at a constant temperature of 25 ℃,using a newly established method of measuring the Wien effect in soil suspensions at field strengthsranging from 13.5 to 150 kV cm^(-1), to determine their electrical conductivity-field strengthrelationships and to infer the order of the bonding strength (retaining force) between soilparticles and various ions. The measurements with the latosol suspensions in NaNO_3, KNO_3,Ca(NO_3)_2, Mg(NO_3)_2 and Zn(NO_3)_2 solutions resulted in increments of the suspension ECs, ΔECs,of 7.9, 5.0, 7.1, 7.0 and 5.8 μS cm^(-1), respectively, when the applied field strength increasedfrom 14.5 to 142 kV cm^(-1). As for the suspensions in NaNO_3, NaCl, Na_2SO_4, Na_3PO_4 andNa_3AsO_4 solutions, the ΔECs were 6.2, 5.3, 4.1, 4.0 and 3.7μS cm^(-1), respectively, when theapplied field strength increased from 13.5 to 90 kV cm^(-1). Thus, it can be deduced that theretaining forces of the clay fraction of the latosol for the cations were in the descending orderK^+ > Zn^(2+) > Mg^(2+) ≥ Ca^(2+) > Na^+, and for the anions in the descending order H_2AsO_4^- >H_2PO_4^-≥ SO_4^(2-) > Cl^- > NO_3~ -.展开更多
The wastes used to amend soils sometimes have high concentrations of metals such as nickel(Ni), lead(Pb) and zinc(Zn). To determine the capacity of soils to retain these metals, the sorption capacities of different mi...The wastes used to amend soils sometimes have high concentrations of metals such as nickel(Ni), lead(Pb) and zinc(Zn). To determine the capacity of soils to retain these metals, the sorption capacities of different mine soils with and without reclamation treatments(tree vegetation and waste amendment) for Ni, Pb and Zn in individual and competitive situations were evaluated using the batch sorption technique. The untreated settling pond soil had low capacity for Ni, Pb and Zn retention. The site amended with wastes(sewage sludges and paper mill residues) increased the sorption capacity most, probably because of the higher concentrations of soil components with high retention capacity such as carbon and clay fraction. No significant competition was observed between metals in the competitive sorption experiment, indicating that the maximum of sorption was not achieved by adding 0.5 mmol L^(-1) of metal. We can conclude that, despite the possible additions of Ni, Pb and Zn from wastes to degraded soils, sewage sludges and paper mill residues have a high sorption capacity that would prevent the metals from being in a mobile form.展开更多
基金Project supported by the National Natural Science Foundation of China (Nos. 49771046 and 49831005) the Center for International Cooperation, Ministry of Foreign Affairs, State of Israel.
文摘Suspensions of a latosol with a clay concentration of 30 g kg^(-1) wereprepared from electrodialyzed clay fractions, less than 2 μm in diameter, five nitrate solutionswith a concentration of 1 X 10^(04)/z mol L^(-1), where z is the valence, and five sodium saltsolutions with a concentration of 3.3 X 10^(-5)/2 mol L^(-1). The direct current (DC) electricalconductivities (ECs) of the colloidal suspensions were measured at a constant temperature of 25 ℃,using a newly established method of measuring the Wien effect in soil suspensions at field strengthsranging from 13.5 to 150 kV cm^(-1), to determine their electrical conductivity-field strengthrelationships and to infer the order of the bonding strength (retaining force) between soilparticles and various ions. The measurements with the latosol suspensions in NaNO_3, KNO_3,Ca(NO_3)_2, Mg(NO_3)_2 and Zn(NO_3)_2 solutions resulted in increments of the suspension ECs, ΔECs,of 7.9, 5.0, 7.1, 7.0 and 5.8 μS cm^(-1), respectively, when the applied field strength increasedfrom 14.5 to 142 kV cm^(-1). As for the suspensions in NaNO_3, NaCl, Na_2SO_4, Na_3PO_4 andNa_3AsO_4 solutions, the ΔECs were 6.2, 5.3, 4.1, 4.0 and 3.7μS cm^(-1), respectively, when theapplied field strength increased from 13.5 to 90 kV cm^(-1). Thus, it can be deduced that theretaining forces of the clay fraction of the latosol for the cations were in the descending orderK^+ > Zn^(2+) > Mg^(2+) ≥ Ca^(2+) > Na^+, and for the anions in the descending order H_2AsO_4^- >H_2PO_4^-≥ SO_4^(2-) > Cl^- > NO_3~ -.
文摘The wastes used to amend soils sometimes have high concentrations of metals such as nickel(Ni), lead(Pb) and zinc(Zn). To determine the capacity of soils to retain these metals, the sorption capacities of different mine soils with and without reclamation treatments(tree vegetation and waste amendment) for Ni, Pb and Zn in individual and competitive situations were evaluated using the batch sorption technique. The untreated settling pond soil had low capacity for Ni, Pb and Zn retention. The site amended with wastes(sewage sludges and paper mill residues) increased the sorption capacity most, probably because of the higher concentrations of soil components with high retention capacity such as carbon and clay fraction. No significant competition was observed between metals in the competitive sorption experiment, indicating that the maximum of sorption was not achieved by adding 0.5 mmol L^(-1) of metal. We can conclude that, despite the possible additions of Ni, Pb and Zn from wastes to degraded soils, sewage sludges and paper mill residues have a high sorption capacity that would prevent the metals from being in a mobile form.
