This paper reports the results of spectral measurements and a theoretical analysis of the temporal and spatial evolution of laser-produced Cu plasma in vacuum in the range of 8–14 nm.The time dependence of the extrem...This paper reports the results of spectral measurements and a theoretical analysis of the temporal and spatial evolution of laser-produced Cu plasma in vacuum in the range of 8–14 nm.The time dependence of the extreme ultraviolet band spectrum at different positions near the target surface was obtained and found to be dominated by three broad-band features.The 3p and 3d excitations of Cu5+–Cu9+ions were calculated using the Hartree–Fock theory with configuration interactions.The characteristics of the spectral line distribution for the 3p–nd and 3d–nf transition arrays were analyzed.Based on the steady-state collisional radiation model and the normalized Boltzmann distribution,the complex spectral structure in the band of 13–14 nm is accurately explained through consistency comparisons and benchmarking between the experimental and theoretical simulation spectra,demonstrating that the structure mainly stems from the overlapping contribution of the 3d–4f and 3p–3d transition arrays for the Cu5+–Cu9+ions.These results may help in studying the radiation characteristics of isoelectronic series highly-charged ions involving the 3d excitation process.展开更多
We report the luminescence and magnetic properties of the mononuclear Dy(Ⅲ)complex[DyTp_(2)Acac](Tp=tris-pyrazolylborohydride and Acac=2,4-pentanedionate).This complex displays peculiar slow magnetisation dynamics at...We report the luminescence and magnetic properties of the mononuclear Dy(Ⅲ)complex[DyTp_(2)Acac](Tp=tris-pyrazolylborohydride and Acac=2,4-pentanedionate).This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field,which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.展开更多
基金supported by National Natural Science Foundation of China(Nos.12064040,11874051,11904293,11864036)the Science and Technology Project of Gansu Province(Nos.21JR7RA122,20JR5RA530)the Funds for Innovative Fundamental Research Group Project of Gansu Province(No.20JR5RA541)。
文摘This paper reports the results of spectral measurements and a theoretical analysis of the temporal and spatial evolution of laser-produced Cu plasma in vacuum in the range of 8–14 nm.The time dependence of the extreme ultraviolet band spectrum at different positions near the target surface was obtained and found to be dominated by three broad-band features.The 3p and 3d excitations of Cu5+–Cu9+ions were calculated using the Hartree–Fock theory with configuration interactions.The characteristics of the spectral line distribution for the 3p–nd and 3d–nf transition arrays were analyzed.Based on the steady-state collisional radiation model and the normalized Boltzmann distribution,the complex spectral structure in the band of 13–14 nm is accurately explained through consistency comparisons and benchmarking between the experimental and theoretical simulation spectra,demonstrating that the structure mainly stems from the overlapping contribution of the 3d–4f and 3p–3d transition arrays for the Cu5+–Cu9+ions.These results may help in studying the radiation characteristics of isoelectronic series highly-charged ions involving the 3d excitation process.
基金ANR(REDIVALAN ANR-15-CE29-0019-02 and SCOSIMLIGHT ANR-13-BS07-0022-01).
文摘We report the luminescence and magnetic properties of the mononuclear Dy(Ⅲ)complex[DyTp_(2)Acac](Tp=tris-pyrazolylborohydride and Acac=2,4-pentanedionate).This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field,which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.
