Isotropic pyrolytic carbon(IPC)is renowned for its robust mechanical,biological,and tribological prop-erties.However,the current mechanisms for modulating IPC microstructure are insufficient to achieve higher performa...Isotropic pyrolytic carbon(IPC)is renowned for its robust mechanical,biological,and tribological prop-erties.However,the current mechanisms for modulating IPC microstructure are insufficient to achieve higher performance.Herein,this study provides nanoscale insights into the formation and property reg-ulation of the core-shell structure of the IPC,integrating simulation and experimental approaches.Large-scale reactive molecular dynamics simulations elucidate the microstructural evolution and assembly pro-cesses from precursors to nanoparticles and intertwined graphene networks.Simulation process charac-terization enable versatile adjustment of IPC microstructural features and one-step deposition of hybrid structures with disordered cores and ordered shell layers.Compared to Pyrolytic carbon(PyC)with lam-inated graphene arrangement,the prepared hybrid structure enables rapid assembly of large-size stan-dalone carbon components.Moreover,the hybrid architecture effectively improves the core-shell phase connection and significantly increases the interfacial shear stress within the intertwined graphene shell layers.Consequently,it greatly improves load transfer efficiency and enhances crack-bridging toughening effect.The endeavor to establish precise microstructure formation and property regulation in IPC materi-als promises to steer high-performance carbon materials toward distinct developmental trajectories.展开更多
Four kinds of carbon/carbon (C/C) composites, including the needled carbon fiber felt/the pyrolytic carbon (two different pyrolytic carbon microstructures), the chopped carbon fiber/the resin + pyrolytic carbon (PyrC)...Four kinds of carbon/carbon (C/C) composites, including the needled carbon fiber felt/the pyrolytic carbon (two different pyrolytic carbon microstructures), the chopped carbon fiber/the resin + pyrolytic carbon (PyrC), and the carbon cloth/PyrC, named as the composites 1#, 4#, 2#, and 3#, are prepared respectively. Effects of the preform and pyrolytic carbon structure on the thermophysical properties of 2D C/C composites are studied. The C/C composites possess low coefficient of thermal expansion (CTE). In a range of some temperatures, the negative expansion emerges in x-y direction for four C/C composites. From 0 to 900℃, the CTE is small and almost linear with the temperatures. The C/C composites have high thermal conductivities (TCs). As a function of temperature, TCs of the C/C composites are varied with the structures of preform and pyrc as well as the direction of heat transfer. In x-y and z direction, TCs differ greatly and that in x-y direction (25.6-174 W/m·K) is several times larger than that in z direction(3.5-50 W/m·K).展开更多
The influence of reaction temperature on the preparation of SiC coating on carbon fibers by the reaction of silicon monoxide with the deposited pyrolytic carbon(PyC)layer has been discussed.With rising reaction temper...The influence of reaction temperature on the preparation of SiC coating on carbon fibers by the reaction of silicon monoxide with the deposited pyrolytic carbon(PyC)layer has been discussed.With rising reaction temperature,the thickness of SiC layer increases and the SiC grain is coarsening.The apparent activation energy for the synthesis of SiC layer is about 103.3 kJ/mol.The oxidation resistance of carbon fiber can be improved by the SiC/PyC layers significantly.The initial oxidation temperature of the SiC/PyC coated carbon fiber is about 300℃higher than that of the uncoated carbon fiber.The oxidation of the SiC/PyC coated carbon fiber is owing to the diffusion of oxygen through the cracks generated by the mismatch of thermal expansion.展开更多
The density functional theory has been successfully applied in analyzing pyrolytic carbon deposition by methane pyrolysis from the view of thermodynamics and kinetics based on a total number of 39 elementary reactions...The density functional theory has been successfully applied in analyzing pyrolytic carbon deposition by methane pyrolysis from the view of thermodynamics and kinetics based on a total number of 39 elementary reactions.M06-2X/def2-TZVP level was employed to optimize species structures and locate the transition states.The enthalpy changes and Gibbs free energy changes of all the reactions in the temperature range of 298.15–1800K were derived with optimized species.Results show that the reacting temperature should be above 1200 K based on the equilibrium constant analysis,which is consistent with the typical reaction temperature adopted in experiments.Potential energy surface profiles report that radical attacking reactions have lower energy barriers than those direct decomposition reactions,especially hydrogen radical attacking reactions.The energy barriers of the first steps,dehydrogenations of methane and ethylene,are 272.4 kJ·mol^(-1)and 288.9 kJ·mol^(-1)at 1200 K,which are very close to the experimental activation energy for methane pyrolysis.The most favorable decomposition reaction path is the path of hydrogen radical attacking reactions.The highest energy barrier of the path at 1200K is 185.7kJ·mol^(-1)presented by the C–H bond breaking in ethynyl attacked by hydrogen radical.展开更多
Pyrolytic carbon(PyC) coatings are deposited on the Nextel-440 fiber fabrics by chemical vapor deposition(CVD).The dielectric properties of the Nextel-440 fiber fabrics with PyC coatings(Nextel-440/PyC) are investigat...Pyrolytic carbon(PyC) coatings are deposited on the Nextel-440 fiber fabrics by chemical vapor deposition(CVD).The dielectric properties of the Nextel-440 fiber fabrics with PyC coatings(Nextel-440/PyC) are investigated in a temperature range from room temperature to 700℃ in X-band. Compared with the permittivity of the original Nextel-440 received,the complex permittivity of the Nextel-440/PyC(the real part εand the imaginary part ε), is significantly improved: εof the Nextel-440/PyC has a positive temperature coefficient, in contrast, εof the Nextel-440/PyC exhibits a negative temperature coefficient. Moreover, the reflection loss in units of d B is calculated. The results indicate that the microwave absorbing properties of the Nextel-440/PyC coatings is enhanced at 700℃ compared with that at lower temperatures.展开更多
A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon sour...A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.展开更多
This study aims to observe the durability of a pyrolytic carbon bileaflet mechanical valve prosthesis. The mechanical valves prosthesis was tested in vitro by the durability test instrument of valve prosthesis. Then i...This study aims to observe the durability of a pyrolytic carbon bileaflet mechanical valve prosthesis. The mechanical valves prosthesis was tested in vitro by the durability test instrument of valve prosthesis. Then in vivo, the durability of the implanted valves was observed with animal experiments and elinieal application. In the impact test for 5 min and durability test of 380 million eyeles in vitro, there was no the phenomenon of flyer, perforation and fracture observed, as well as no wear or pit found on the surface of valve leaflets. The valve leaflets could normally be turned on or off. The weight of the valve was（1.0031 ± 0.0004） g for 23 mm and（1.6003 ± 0.0002） g for 27 mm. The hydrodynamies test demonstrated that the valve prosthesis had still exeellent hemodynamic performance after the durability test. The animal autopsy showed that the valve leaflets could normally be turned on or off, and no wear was found. By follow-up of 62 patients implanted the valves, all patients had long-terms survival, no complication caused by valve was found. The age of the longest survival was more than 10 years. This study demonstrates that the new meehanieal valve prosthesis have excellent durable performance.展开更多
The functionality of wood has evolved with time to adapt to the emerging needs of society.Carbonized wood-based composites have attracted tremendous interest in the fields of aerospace,military power,electric power,an...The functionality of wood has evolved with time to adapt to the emerging needs of society.Carbonized wood-based composites have attracted tremendous interest in the fields of aerospace,military power,electric power,and system electronic devices,especially at high temperatures.Nevertheless,their electrical conductivity and thermal stability characteristics are still far from satisfactory.Herein,an innova-tive wood-derived carbon-carbon nanotubes-pyrolytic carbon composites(WDC-CNTs-PyCs)is successfully fabricated by chemical vapor deposition and chemical vapor infiltration.The combination of wood-derived carbon(WDC),carbon nanotubes(CNTs),and pyrolytic carbon(PyC)has never been reported in any previous work.We have innovatively introduced PyC into the WDC by chemical vapor infiltration.CNTs promote the continuous deposition of PyC to form dense structures.WDC-CNTs-PyC demonstrates significant compressive strength(85.4 MPa)and excellent electrical conductivity(632 S cm^(-1)).The weight loss rate of WDC-CNTs-PyC is 6%after heating at 500℃ for 10 min in the air atmosphere.Furthermore,WDC-CNTs-PyC could resist oxyacetylene ablation above 2300℃ for 15 s.With excellent electrical conductivity,outstanding thermal stability,and mechanical properties,WDC-CNTs-PyC opens up a surprising strategy for efficiently fabricating various high-performance electronic device composites that could be used in high-temperature fields.展开更多
Chemical Vapor Infiltration (CVI) processes are the essential techniques for fabrication of high performance carbon carbon composites. Based on the polarized light and scanning electron analysis, the authors study th...Chemical Vapor Infiltration (CVI) processes are the essential techniques for fabrication of high performance carbon carbon composites. Based on the polarized light and scanning electron analysis, the authors study the micro morphology and texture characteristics of pyrolytic carbon deposited in CVI process, as well as the growth behavior of pyrolytic carbon. The research shows that Rough Laminar (RL) texture has the hierarchical and self similar structural features, which reflects the stage growth and self similar behavior during the growth course of pyrolytic carbon. According to the two growth features, a laminated growth model of pyrolytic carbon is proposed with the concept of Cone Growth Units (CGU). The laminated growth model can provide a fine description for the growth course of RL pyrolytic carbon. The model indicates that formation, developing and combination of local high order structures (such as CGU structures) are the essential factors for the growth of RL texture. Smooth Laminar (SL) texture and ISO carbon come into being with long range orderliness and isotropy structure respectively, which no local high orderliness intermediate involves in.展开更多
An annealing process was developed for the practical recover of a purified py-rolytic carbon (PPyC) surface from damage, such as color change and peeling, due to fluorination during exposure to chlorine trifluoride ga...An annealing process was developed for the practical recover of a purified py-rolytic carbon (PPyC) surface from damage, such as color change and peeling, due to fluorination during exposure to chlorine trifluoride gas at high tempera-tures for the cleaning of a silicon carbide chemical vapor deposition reactor. The PPyC surface was annealed at 900</span><span style="color:#4F4F4F;font-family:Verdana;">°</span><span style="font-family:Verdana;"></span><span style="font-family:Verdana;">C for 10 min in ambient nitrogen con-taining oxygen at the concentrations of 0.01% - 20%. The rainbow-like colored surface returned to the dark gray color of the original PPyC. Simultaneously, the thin peeled films disappeared. The Raman spectra showed that the PPyC surface chemical bonding returned to that of the original one. The oxygen concentration as low as 0.01% could recover the PPyC surface along with re-ducing the surface pit formation, when the combination of the exposure to chlorine trifluoride gas and the recovery was repeated.展开更多
The growth process of pyrolytic carbon(PyC)over zirconia microspheres was investigated at length scales starting from 10^(−10)m to 10^(−6)m using Transmission and Scanning Electron Microscopy,Raman spectroscopy,Small ...The growth process of pyrolytic carbon(PyC)over zirconia microspheres was investigated at length scales starting from 10^(−10)m to 10^(−6)m using Transmission and Scanning Electron Microscopy,Raman spectroscopy,Small Angle X-ray and Neutron Scattering.The extent of multiphase reactions which evolved through the formation of nano-crystalline carbon have been studied here right from the formation of the disc shaped crystallites of about 3–4 nm in diameter to fused lumps comprising of spherical stacks ca.of 100 nm diameter.The observations have been correlated with the deposition conditions,which affect reaction mechanisms.Based on these observations,a plausible mechanism for the deposition of PyC coatings at different length scales has been proposed with a novel concept of role of thermal boundary layer adjacent to the deposition surface.Pore volume measurement further validated our proposed growth mechanism at a length scale of 10^(−6)m.Analysis of residence time of the acetylene precursor within the solid bed of zirconia microspheres has shown to have great potential in exploring growth mechanism of multiphase reactions.展开更多
The effect of pyrolytic carbon(PyC) thickness on the tensile property of mini T800 carbon fiber reinforced SiC matrix composites(C/SiC) was studied. PyC interphase was prepared by chemical vapor infiltration(CVI) proc...The effect of pyrolytic carbon(PyC) thickness on the tensile property of mini T800 carbon fiber reinforced SiC matrix composites(C/SiC) was studied. PyC interphase was prepared by chemical vapor infiltration(CVI) process using C3H6–Ar as gas source, the PyC thickness was adjusted from 0 to 400 nm, and then the SiC matrix was prepared by CVI process using methyltrichlorosilane(MTS)–H2–Ar as precursor and gas source. The results showed that the tensile strength of mini T800-C/SiC increased first and then decreased with the increase of the PyC thickness. When the thickness of PyC was 100 nm, the average strength reached the maximum value of 393 ± 70 MPa. The Weibull modulus increased from 2.0 to 8.06 with the increase of PyC thickness, and the larger the Weibull modulus, the smaller the dispersion, which indicated that the regulation of PyC thickness was conducive to improve tensile properties.展开更多
This paper reported the facile preparation of pyrolytic carbon derived from spent coffee grounds and the evaluation of its electrochemical performance when used as anode in sodium-ion battery.X-ray diffraction analys...This paper reported the facile preparation of pyrolytic carbon derived from spent coffee grounds and the evaluation of its electrochemical performance when used as anode in sodium-ion battery.X-ray diffraction analysis,scanning electron microscope,Brunauer–Emmett–Teller were employed to characterize the structure of pyrolytic carbon.Electrochemical performances were tested by constant current charge–discharge,cyclic voltammetry and electrochemical impedance spectroscopy.Results showed that the pyrolytic carbon possess a porous structure(1–2 lm)and a specific surface area of 94.35 m2 g1.When used as anodes in sodium-ion batteries,a reversible capacity of 154.2 mA h g1 at a current density of 200 mA g1 after 50 cycles was obtained.Several electrolytes were evaluated and their electrochemical performances were compared.The result indicated that this material has excellent storage capacity and good cycling stability.Our method provided a preparation of pyrolytic carbon from environmentally friendly resources.展开更多
The preferred orientation of pyrolytic carbon coating is an important performance parameter for the safe use of artificial mechanical heart valve.In this paper,the selected area electron diffraction(SAED)analysis of p...The preferred orientation of pyrolytic carbon coating is an important performance parameter for the safe use of artificial mechanical heart valve.In this paper,the selected area electron diffraction(SAED)analysis of pyrolytic carbon coating samples of artificial heart valve was carried out by transmission electron microscopy(TEM),and the experimental method of characterizing the preferred orientation of pyrolytic carbon by electron diffraction spectrum,namely bacon anisotropy factor(BAF),was described,and the orientation angle and BAF corresponding to the electron diffraction spectrum were measured.The results show that the BAF value can directly reflect the anisotropy of pyrolytic carbon in the selected area.The BAF value range is from 1 to infinity,and the higher the preferred orientation is,the greater the value is.The BAF value decreases exponentially with the increase of orientation angle.When the pyrolytic carbon tends to be isotropic,the orientation angle tends to 180 and the BAF value tends to 1.展开更多
Silicon-alloyed isotropic pyrolytic carbon(Si-IPyC)was prepared by steady-state fluidized bed chemical vapor deposition(SFBCVD).The effects of deposition temperature and propane concentration on the microstructure and...Silicon-alloyed isotropic pyrolytic carbon(Si-IPyC)was prepared by steady-state fluidized bed chemical vapor deposition(SFBCVD).The effects of deposition temperature and propane concentration on the microstructure and deposition process of Si-IPyC were investigated using X-ray diffraction(XRD),X-ray energy dispersive spectrometer(EDS)and scanning electron microscope(SEM).The results show that the Si-IPyC with different silicon content is composed of both spherical granular and laminar structures,and silicon element is uniformly dispersed in pyrolytic carbon in the form of β-SiC.The deposition temperature and propane concentration have a great influence on the microstructure of Si-IPyC,with the increase of deposition temperature or propane concentration,the laminar structure in Si-IPy C decreases gradually,spherical granular morphology becomes increasingly obvious and the density decreases with the deposition model changing from surficial growth mechanism to gaseous nucleation mechanism.For getting a faster average coating rate,deposition temperature and propane concentration should not be too high.展开更多
Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of ...Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of PCB have been developed. One of the most significant applications for modified PCB is to reinforce the rubber matrix to obtain high added values. The transverse relaxation and the chain dynamics of vulcanized rubber networks with PCB and modified PCB were studied and compared with those of the commercial carbon blacks using selective 1H transverse relaxation (T2) experiments and dipolar correlation effect (DCE) experiments on the stimulated echo. Demineralization and coupling agent modification not only intensified the interactions between the modified PCB and the neighboring polyisoprene chains, but also increased the chemical cross-link density of the vulcanized rubber with modified PCB. The mechanical testing of the rubbers with different kinds of carbon blacks showed that the maximum strain of the rubber with modified PCB was improved greatly. The mechanical testing results confirmed the conclusion obtained by nuclear magnetic resonance (NMR). PCB modified by the demineralization and NDZ-105 titanate coupling agent could be used to replace the commercial semi-reinforcing carbon black.展开更多
Carbon filaments with diameter from several to hundreds deposition of methane without catalyst. The morphology micrometers were synthesized by chemical vapor microstructure and mechanical properties of the carbon fila...Carbon filaments with diameter from several to hundreds deposition of methane without catalyst. The morphology micrometers were synthesized by chemical vapor microstructure and mechanical properties of the carbon filament were investigated by scanning electronic microscopy, optical microscopy, X-ray diffraction and mechanical testing. The results show that the carbon filament is inverted cone shape and grows up along the gas flow direction. The stem of it is formed of annular carbon layers arranged in a tree ring structure while the head is made up of concentrical layers. The tensile strength of the carbon filament is increased after graphitization for the restructuring and growing large of graphene. The growth mechanism of carbon filament was proposed according to the results of two series of experiments with different deposition time and intermittent deposition cycles.展开更多
Ni-doped phenol resin was prepared with 1∶100 mass ratio of Ni（ NO_3）_2·6H_2O to thermosetting phenol resin to optimize the structure and properties of pyrolytic carbon derived from phenol resin and increase i...Ni-doped phenol resin was prepared with 1∶100 mass ratio of Ni（ NO_3）_2·6H_2O to thermosetting phenol resin to optimize the structure and properties of pyrolytic carbon derived from phenol resin and increase its carbon yield. The specimens were cured at 200 ℃ and carbonized under different atmospheres（ carbon-embedded atmosphere and Ar atmosphere） and at different temperatures（ 600,800,1000 and 1200 ℃） for3 h,respectively. The carbon yield was measured. Thermal decomposition characteristics of Ni-doped phenol resin,and the oxidation resistance,phase composition and microstructure of pyrolytic carbon were characterized by differential scanning calorimetry,X-ray diffraction,energy dispersive spectroscopy, scanning electron microscopy and transmission electron microscopy. The results show that the carbon yield of Ni-doped phenol resin carbonized at800 or 1 000 ℃ is increased significantly,compared with that without any dopants. The graphitization degree of pyrolytic carbon structure derived from Ni-doped phenol resin increases with the increase of carbonization temperature. The massive multi-wall carbon nanotubes of 50-100 nm in diameter and of micrometre scale in length are generated at 1000 ℃. Compared with the carbonembedded atmosphere,carbon nanotubes can be more easily generated in Ar atmosphere,resulting in higher carbon yield and degree of crystallinity of the pyrolyticcarbon derived from Ni-doped phenol resin. The oxidation resistance of the pyrolytic carbon derived from Ni-doped phenol resin at 1200 ℃ is improved significantly and its highest oxidation temperature is increased by about 84℃,compared with that from Ni free phenol resin.展开更多
The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as ...The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as the representative of small organics. The effects of phenol on adsorption equilibrium, kinetics and thermodynamics were studied systematically. The results indicate that APTC is a potential adsorbent for MG. The presence of phenol decreases the adsorption capacity of APTC for MG, but improves the rate of adsorption, while the adsorption characteristics, such as equilibrium, kinetics and thermodynamics are not affected by phenol. The adsorption equilibrium data follow Langmuir isotherm and the kinetic data are well described by the pseudo-second-order kinetic model. The adsorption process follows intra-particle diffusion model and the adsorption rate is determined by more than one process. Thermodynamic study shows that the adsorption is an endothermic and spontaneous physisorption process.展开更多
A novel silicon-carbon composite with a 3D pore-nest structure denoted as Si@SiO_(x)/CNTs@C was prepared and studied.The results showed that agglomeration of nano-silicon particles is effectively inhibited by the addi...A novel silicon-carbon composite with a 3D pore-nest structure denoted as Si@SiO_(x)/CNTs@C was prepared and studied.The results showed that agglomeration of nano-silicon particles is effectively inhibited by the addition of a surfactant;meanwhile,surfactant pyrolytic carbon(SPC)and a relatively dense SiO_(x) mechanical binding layer on the surface of Si magnificently restrain the volume expansion during the lithiation process and are conducive to the formation of a stable SEI film.In addition,a 3D electron pathway was constituted by CNTs,graphite and SPC on the surface of Si to enhance the conductivity.The results showed that the capacity of the Si@SiO_(x)/CNTs@C composite anode can be maintained at above 1740 mA h g^(-1) at a current density of 0.42 A g^(-1) after 700 cycles without capacity loss compared to the initial charge capacity,which indicated the excellent cycle performance of the composite material.Furthermore,a rule of thumb has been perceived by means of CV,cell charging/discharging measurements and their differential capacity analyses,which is characteristic of an electrode made of silicon as an active material.The finding contributes to the in-depth comprehension and general elucidation of the degradation mechanism of Si-based anode materials.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52293371,52222204 and 52172103).
文摘Isotropic pyrolytic carbon(IPC)is renowned for its robust mechanical,biological,and tribological prop-erties.However,the current mechanisms for modulating IPC microstructure are insufficient to achieve higher performance.Herein,this study provides nanoscale insights into the formation and property reg-ulation of the core-shell structure of the IPC,integrating simulation and experimental approaches.Large-scale reactive molecular dynamics simulations elucidate the microstructural evolution and assembly pro-cesses from precursors to nanoparticles and intertwined graphene networks.Simulation process charac-terization enable versatile adjustment of IPC microstructural features and one-step deposition of hybrid structures with disordered cores and ordered shell layers.Compared to Pyrolytic carbon(PyC)with lam-inated graphene arrangement,the prepared hybrid structure enables rapid assembly of large-size stan-dalone carbon components.Moreover,the hybrid architecture effectively improves the core-shell phase connection and significantly increases the interfacial shear stress within the intertwined graphene shell layers.Consequently,it greatly improves load transfer efficiency and enhances crack-bridging toughening effect.The endeavor to establish precise microstructure formation and property regulation in IPC materi-als promises to steer high-performance carbon materials toward distinct developmental trajectories.
文摘Four kinds of carbon/carbon (C/C) composites, including the needled carbon fiber felt/the pyrolytic carbon (two different pyrolytic carbon microstructures), the chopped carbon fiber/the resin + pyrolytic carbon (PyrC), and the carbon cloth/PyrC, named as the composites 1#, 4#, 2#, and 3#, are prepared respectively. Effects of the preform and pyrolytic carbon structure on the thermophysical properties of 2D C/C composites are studied. The C/C composites possess low coefficient of thermal expansion (CTE). In a range of some temperatures, the negative expansion emerges in x-y direction for four C/C composites. From 0 to 900℃, the CTE is small and almost linear with the temperatures. The C/C composites have high thermal conductivities (TCs). As a function of temperature, TCs of the C/C composites are varied with the structures of preform and pyrc as well as the direction of heat transfer. In x-y and z direction, TCs differ greatly and that in x-y direction (25.6-174 W/m·K) is several times larger than that in z direction(3.5-50 W/m·K).
基金supported by the National Natural Science Foundation of China under Grant No.50832004the"111"Project under Grant No.B08040
文摘The influence of reaction temperature on the preparation of SiC coating on carbon fibers by the reaction of silicon monoxide with the deposited pyrolytic carbon(PyC)layer has been discussed.With rising reaction temperature,the thickness of SiC layer increases and the SiC grain is coarsening.The apparent activation energy for the synthesis of SiC layer is about 103.3 kJ/mol.The oxidation resistance of carbon fiber can be improved by the SiC/PyC layers significantly.The initial oxidation temperature of the SiC/PyC coated carbon fiber is about 300℃higher than that of the uncoated carbon fiber.The oxidation of the SiC/PyC coated carbon fiber is owing to the diffusion of oxygen through the cracks generated by the mismatch of thermal expansion.
基金supported by the National Natural Science Foundation of China(51821091 and 51472203)the “111”Project of China(Grant No.B08040)the Research Fund of State Key Laboratory of Solidification Processing(NWPU)of China(Grant No.142-TZ-2016)。
文摘The density functional theory has been successfully applied in analyzing pyrolytic carbon deposition by methane pyrolysis from the view of thermodynamics and kinetics based on a total number of 39 elementary reactions.M06-2X/def2-TZVP level was employed to optimize species structures and locate the transition states.The enthalpy changes and Gibbs free energy changes of all the reactions in the temperature range of 298.15–1800K were derived with optimized species.Results show that the reacting temperature should be above 1200 K based on the equilibrium constant analysis,which is consistent with the typical reaction temperature adopted in experiments.Potential energy surface profiles report that radical attacking reactions have lower energy barriers than those direct decomposition reactions,especially hydrogen radical attacking reactions.The energy barriers of the first steps,dehydrogenations of methane and ethylene,are 272.4 kJ·mol^(-1)and 288.9 kJ·mol^(-1)at 1200 K,which are very close to the experimental activation energy for methane pyrolysis.The most favorable decomposition reaction path is the path of hydrogen radical attacking reactions.The highest energy barrier of the path at 1200K is 185.7kJ·mol^(-1)presented by the C–H bond breaking in ethynyl attacked by hydrogen radical.
基金supported by the National Natural Science Foundation of China(Grant No.51072165)the Fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University,China(Grant Nos.KP201307 and SKLSP201313)
文摘Pyrolytic carbon(PyC) coatings are deposited on the Nextel-440 fiber fabrics by chemical vapor deposition(CVD).The dielectric properties of the Nextel-440 fiber fabrics with PyC coatings(Nextel-440/PyC) are investigated in a temperature range from room temperature to 700℃ in X-band. Compared with the permittivity of the original Nextel-440 received,the complex permittivity of the Nextel-440/PyC(the real part εand the imaginary part ε), is significantly improved: εof the Nextel-440/PyC has a positive temperature coefficient, in contrast, εof the Nextel-440/PyC exhibits a negative temperature coefficient. Moreover, the reflection loss in units of d B is calculated. The results indicate that the microwave absorbing properties of the Nextel-440/PyC coatings is enhanced at 700℃ compared with that at lower temperatures.
基金Funded by the National Natural Science Foundation of China(51165006)
文摘A new method of fabricating C/C composite materials, namely electric heating CVD method, was used, which electrified the carbon fiber directly by using the conductivity of itself. Acetylene was used as the carbon source with nitrogen as dilution gas, and the pyrolytic carbon started to deposit on the carbon fiber surface when the deposition temperature was reached. The morphology of pyrolytic carbon was characterized by SEM, and the surface properties of carbon fibers before and after CVD were characterized by Raman spectroscopy. The experimental results show that the electric heating method is a novel method to fabricate C/C composite materials, which can form a dense C/C composite material in a short time. The order degree and the average crystallite size of the carbon fiber surface were decreased after the experiment.
文摘This study aims to observe the durability of a pyrolytic carbon bileaflet mechanical valve prosthesis. The mechanical valves prosthesis was tested in vitro by the durability test instrument of valve prosthesis. Then in vivo, the durability of the implanted valves was observed with animal experiments and elinieal application. In the impact test for 5 min and durability test of 380 million eyeles in vitro, there was no the phenomenon of flyer, perforation and fracture observed, as well as no wear or pit found on the surface of valve leaflets. The valve leaflets could normally be turned on or off. The weight of the valve was（1.0031 ± 0.0004） g for 23 mm and（1.6003 ± 0.0002） g for 27 mm. The hydrodynamies test demonstrated that the valve prosthesis had still exeellent hemodynamic performance after the durability test. The animal autopsy showed that the valve leaflets could normally be turned on or off, and no wear was found. By follow-up of 62 patients implanted the valves, all patients had long-terms survival, no complication caused by valve was found. The age of the longest survival was more than 10 years. This study demonstrates that the new meehanieal valve prosthesis have excellent durable performance.
基金supported by the under Grant No.51872232,the Key Scientific and Technological Innovation Research Team of Shaanxi Province(No.2022TD-31)the Key R&D Program of Shaanxi Province(No.2021ZDLGY14-04)+2 种基金the National Training Program of Innovation and Entrepreneurship for Undergraduates(Grand No.XN2022023)the Joint Funds of the National Natural Science Foundation of China(Grant No.U21B2067)the Research Fund of the State Key Laboratory of Solidification Processing(NWPU),China(Grant No.136-QP-2015).
文摘The functionality of wood has evolved with time to adapt to the emerging needs of society.Carbonized wood-based composites have attracted tremendous interest in the fields of aerospace,military power,electric power,and system electronic devices,especially at high temperatures.Nevertheless,their electrical conductivity and thermal stability characteristics are still far from satisfactory.Herein,an innova-tive wood-derived carbon-carbon nanotubes-pyrolytic carbon composites(WDC-CNTs-PyCs)is successfully fabricated by chemical vapor deposition and chemical vapor infiltration.The combination of wood-derived carbon(WDC),carbon nanotubes(CNTs),and pyrolytic carbon(PyC)has never been reported in any previous work.We have innovatively introduced PyC into the WDC by chemical vapor infiltration.CNTs promote the continuous deposition of PyC to form dense structures.WDC-CNTs-PyC demonstrates significant compressive strength(85.4 MPa)and excellent electrical conductivity(632 S cm^(-1)).The weight loss rate of WDC-CNTs-PyC is 6%after heating at 500℃ for 10 min in the air atmosphere.Furthermore,WDC-CNTs-PyC could resist oxyacetylene ablation above 2300℃ for 15 s.With excellent electrical conductivity,outstanding thermal stability,and mechanical properties,WDC-CNTs-PyC opens up a surprising strategy for efficiently fabricating various high-performance electronic device composites that could be used in high-temperature fields.
基金National Natural Science F oundation of China !( No.5 9882 0 0 4)
文摘Chemical Vapor Infiltration (CVI) processes are the essential techniques for fabrication of high performance carbon carbon composites. Based on the polarized light and scanning electron analysis, the authors study the micro morphology and texture characteristics of pyrolytic carbon deposited in CVI process, as well as the growth behavior of pyrolytic carbon. The research shows that Rough Laminar (RL) texture has the hierarchical and self similar structural features, which reflects the stage growth and self similar behavior during the growth course of pyrolytic carbon. According to the two growth features, a laminated growth model of pyrolytic carbon is proposed with the concept of Cone Growth Units (CGU). The laminated growth model can provide a fine description for the growth course of RL pyrolytic carbon. The model indicates that formation, developing and combination of local high order structures (such as CGU structures) are the essential factors for the growth of RL texture. Smooth Laminar (SL) texture and ISO carbon come into being with long range orderliness and isotropy structure respectively, which no local high orderliness intermediate involves in.
文摘An annealing process was developed for the practical recover of a purified py-rolytic carbon (PPyC) surface from damage, such as color change and peeling, due to fluorination during exposure to chlorine trifluoride gas at high tempera-tures for the cleaning of a silicon carbide chemical vapor deposition reactor. The PPyC surface was annealed at 900</span><span style="color:#4F4F4F;font-family:Verdana;">°</span><span style="font-family:Verdana;"></span><span style="font-family:Verdana;">C for 10 min in ambient nitrogen con-taining oxygen at the concentrations of 0.01% - 20%. The rainbow-like colored surface returned to the dark gray color of the original PPyC. Simultaneously, the thin peeled films disappeared. The Raman spectra showed that the PPyC surface chemical bonding returned to that of the original one. The oxygen concentration as low as 0.01% could recover the PPyC surface along with re-ducing the surface pit formation, when the combination of the exposure to chlorine trifluoride gas and the recovery was repeated.
基金carried out in Bhabha Atomic Research Centre with full financial support,as a part of High Temperature Materials program,Department of Atomic Energy,Govt.of India.
文摘The growth process of pyrolytic carbon(PyC)over zirconia microspheres was investigated at length scales starting from 10^(−10)m to 10^(−6)m using Transmission and Scanning Electron Microscopy,Raman spectroscopy,Small Angle X-ray and Neutron Scattering.The extent of multiphase reactions which evolved through the formation of nano-crystalline carbon have been studied here right from the formation of the disc shaped crystallites of about 3–4 nm in diameter to fused lumps comprising of spherical stacks ca.of 100 nm diameter.The observations have been correlated with the deposition conditions,which affect reaction mechanisms.Based on these observations,a plausible mechanism for the deposition of PyC coatings at different length scales has been proposed with a novel concept of role of thermal boundary layer adjacent to the deposition surface.Pore volume measurement further validated our proposed growth mechanism at a length scale of 10^(−6)m.Analysis of residence time of the acetylene precursor within the solid bed of zirconia microspheres has shown to have great potential in exploring growth mechanism of multiphase reactions.
基金supported by the National Natural Science Foundation of China (Nos. 51702261, 51821091, and 51802263)the Natural Science Foundation of Shaanxi Province (Project No. 2019JQ-634)the Fundamental Research Funds for the Central Universities。
文摘The effect of pyrolytic carbon(PyC) thickness on the tensile property of mini T800 carbon fiber reinforced SiC matrix composites(C/SiC) was studied. PyC interphase was prepared by chemical vapor infiltration(CVI) process using C3H6–Ar as gas source, the PyC thickness was adjusted from 0 to 400 nm, and then the SiC matrix was prepared by CVI process using methyltrichlorosilane(MTS)–H2–Ar as precursor and gas source. The results showed that the tensile strength of mini T800-C/SiC increased first and then decreased with the increase of the PyC thickness. When the thickness of PyC was 100 nm, the average strength reached the maximum value of 393 ± 70 MPa. The Weibull modulus increased from 2.0 to 8.06 with the increase of PyC thickness, and the larger the Weibull modulus, the smaller the dispersion, which indicated that the regulation of PyC thickness was conducive to improve tensile properties.
基金the National Key Research and Development Program(Grant No.2016YFB0100106)the Youth Innovation Promotion Association,Chinese Academy of Sciences(2015239)for financial supports.
文摘This paper reported the facile preparation of pyrolytic carbon derived from spent coffee grounds and the evaluation of its electrochemical performance when used as anode in sodium-ion battery.X-ray diffraction analysis,scanning electron microscope,Brunauer–Emmett–Teller were employed to characterize the structure of pyrolytic carbon.Electrochemical performances were tested by constant current charge–discharge,cyclic voltammetry and electrochemical impedance spectroscopy.Results showed that the pyrolytic carbon possess a porous structure(1–2 lm)and a specific surface area of 94.35 m2 g1.When used as anodes in sodium-ion batteries,a reversible capacity of 154.2 mA h g1 at a current density of 200 mA g1 after 50 cycles was obtained.Several electrolytes were evaluated and their electrochemical performances were compared.The result indicated that this material has excellent storage capacity and good cycling stability.Our method provided a preparation of pyrolytic carbon from environmentally friendly resources.
文摘The preferred orientation of pyrolytic carbon coating is an important performance parameter for the safe use of artificial mechanical heart valve.In this paper,the selected area electron diffraction(SAED)analysis of pyrolytic carbon coating samples of artificial heart valve was carried out by transmission electron microscopy(TEM),and the experimental method of characterizing the preferred orientation of pyrolytic carbon by electron diffraction spectrum,namely bacon anisotropy factor(BAF),was described,and the orientation angle and BAF corresponding to the electron diffraction spectrum were measured.The results show that the BAF value can directly reflect the anisotropy of pyrolytic carbon in the selected area.The BAF value range is from 1 to infinity,and the higher the preferred orientation is,the greater the value is.The BAF value decreases exponentially with the increase of orientation angle.When the pyrolytic carbon tends to be isotropic,the orientation angle tends to 180 and the BAF value tends to 1.
文摘Silicon-alloyed isotropic pyrolytic carbon(Si-IPyC)was prepared by steady-state fluidized bed chemical vapor deposition(SFBCVD).The effects of deposition temperature and propane concentration on the microstructure and deposition process of Si-IPyC were investigated using X-ray diffraction(XRD),X-ray energy dispersive spectrometer(EDS)and scanning electron microscope(SEM).The results show that the Si-IPyC with different silicon content is composed of both spherical granular and laminar structures,and silicon element is uniformly dispersed in pyrolytic carbon in the form of β-SiC.The deposition temperature and propane concentration have a great influence on the microstructure of Si-IPyC,with the increase of deposition temperature or propane concentration,the laminar structure in Si-IPy C decreases gradually,spherical granular morphology becomes increasingly obvious and the density decreases with the deposition model changing from surficial growth mechanism to gaseous nucleation mechanism.For getting a faster average coating rate,deposition temperature and propane concentration should not be too high.
基金Project supported by the National Natural Science Foundation of China (Nos. 20490200 and 20176051), and the Project Based Per-sonnel Exchange Program with the China Scholarship Council and the German Academic Exchange Service
文摘Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of PCB have been developed. One of the most significant applications for modified PCB is to reinforce the rubber matrix to obtain high added values. The transverse relaxation and the chain dynamics of vulcanized rubber networks with PCB and modified PCB were studied and compared with those of the commercial carbon blacks using selective 1H transverse relaxation (T2) experiments and dipolar correlation effect (DCE) experiments on the stimulated echo. Demineralization and coupling agent modification not only intensified the interactions between the modified PCB and the neighboring polyisoprene chains, but also increased the chemical cross-link density of the vulcanized rubber with modified PCB. The mechanical testing of the rubbers with different kinds of carbon blacks showed that the maximum strain of the rubber with modified PCB was improved greatly. The mechanical testing results confirmed the conclusion obtained by nuclear magnetic resonance (NMR). PCB modified by the demineralization and NDZ-105 titanate coupling agent could be used to replace the commercial semi-reinforcing carbon black.
文摘Carbon filaments with diameter from several to hundreds deposition of methane without catalyst. The morphology micrometers were synthesized by chemical vapor microstructure and mechanical properties of the carbon filament were investigated by scanning electronic microscopy, optical microscopy, X-ray diffraction and mechanical testing. The results show that the carbon filament is inverted cone shape and grows up along the gas flow direction. The stem of it is formed of annular carbon layers arranged in a tree ring structure while the head is made up of concentrical layers. The tensile strength of the carbon filament is increased after graphitization for the restructuring and growing large of graphene. The growth mechanism of carbon filament was proposed according to the results of two series of experiments with different deposition time and intermittent deposition cycles.
基金financial supports from the National Natural Science Foundation of China(51174152)National Basic Research Program of China(973 Program)(2012CB722702)
文摘Ni-doped phenol resin was prepared with 1∶100 mass ratio of Ni（ NO_3）_2·6H_2O to thermosetting phenol resin to optimize the structure and properties of pyrolytic carbon derived from phenol resin and increase its carbon yield. The specimens were cured at 200 ℃ and carbonized under different atmospheres（ carbon-embedded atmosphere and Ar atmosphere） and at different temperatures（ 600,800,1000 and 1200 ℃） for3 h,respectively. The carbon yield was measured. Thermal decomposition characteristics of Ni-doped phenol resin,and the oxidation resistance,phase composition and microstructure of pyrolytic carbon were characterized by differential scanning calorimetry,X-ray diffraction,energy dispersive spectroscopy, scanning electron microscopy and transmission electron microscopy. The results show that the carbon yield of Ni-doped phenol resin carbonized at800 or 1 000 ℃ is increased significantly,compared with that without any dopants. The graphitization degree of pyrolytic carbon structure derived from Ni-doped phenol resin increases with the increase of carbonization temperature. The massive multi-wall carbon nanotubes of 50-100 nm in diameter and of micrometre scale in length are generated at 1000 ℃. Compared with the carbonembedded atmosphere,carbon nanotubes can be more easily generated in Ar atmosphere,resulting in higher carbon yield and degree of crystallinity of the pyrolyticcarbon derived from Ni-doped phenol resin. The oxidation resistance of the pyrolytic carbon derived from Ni-doped phenol resin at 1200 ℃ is improved significantly and its highest oxidation temperature is increased by about 84℃,compared with that from Ni free phenol resin.
基金Supported by National Key Technologies R&D Program of China(No.2006BAC02A12)
文摘The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as the representative of small organics. The effects of phenol on adsorption equilibrium, kinetics and thermodynamics were studied systematically. The results indicate that APTC is a potential adsorbent for MG. The presence of phenol decreases the adsorption capacity of APTC for MG, but improves the rate of adsorption, while the adsorption characteristics, such as equilibrium, kinetics and thermodynamics are not affected by phenol. The adsorption equilibrium data follow Langmuir isotherm and the kinetic data are well described by the pseudo-second-order kinetic model. The adsorption process follows intra-particle diffusion model and the adsorption rate is determined by more than one process. Thermodynamic study shows that the adsorption is an endothermic and spontaneous physisorption process.
基金financially supported by Jinan Science and Technology Research Grant(No.201401274)Jining 511 Recruitment Program of Global Experts(No.2012N130),P.R.China.
文摘A novel silicon-carbon composite with a 3D pore-nest structure denoted as Si@SiO_(x)/CNTs@C was prepared and studied.The results showed that agglomeration of nano-silicon particles is effectively inhibited by the addition of a surfactant;meanwhile,surfactant pyrolytic carbon(SPC)and a relatively dense SiO_(x) mechanical binding layer on the surface of Si magnificently restrain the volume expansion during the lithiation process and are conducive to the formation of a stable SEI film.In addition,a 3D electron pathway was constituted by CNTs,graphite and SPC on the surface of Si to enhance the conductivity.The results showed that the capacity of the Si@SiO_(x)/CNTs@C composite anode can be maintained at above 1740 mA h g^(-1) at a current density of 0.42 A g^(-1) after 700 cycles without capacity loss compared to the initial charge capacity,which indicated the excellent cycle performance of the composite material.Furthermore,a rule of thumb has been perceived by means of CV,cell charging/discharging measurements and their differential capacity analyses,which is characteristic of an electrode made of silicon as an active material.The finding contributes to the in-depth comprehension and general elucidation of the degradation mechanism of Si-based anode materials.
