The sodium silicate, ferric chloride, ferrous sulfate, sodium chlorate and other common inorganic materials were used to synthesize two new poly silicate iron coagulants： Polysilicate Ferric Chloride （PFSiC） and Po...The sodium silicate, ferric chloride, ferrous sulfate, sodium chlorate and other common inorganic materials were used to synthesize two new poly silicate iron coagulants： Polysilicate Ferric Chloride （PFSiC） and Polymeric Ferric Silicate Sulfate （PFSiS）. Their coagulation effect on micro-polluted water was compared with the poly ferric choride （PFC） saled in the market. The results showed that turbidity, organic matter, total phosphorus, total nitrogen removal rate ofPFSiC, PFSiS coagulant were better than PFC on micro-polluted water treatment at the same dosage. The coagulation effect of PFSiC was the best. The surface morphology of three coagulants was observed by scanning electron microscopy （SEM）, and the coagulation mechanism was discussed preliminarily.展开更多
A new process for preparing poly(phenylene sulfide amide, PPSA), which is by reaction of sulfur instead of sodium sulfide as S source with dichlorobenzamide (DCBA) and alkali in polar orga...A new process for preparing poly(phenylene sulfide amide, PPSA), which is by reaction of sulfur instead of sodium sulfide as S source with dichlorobenzamide (DCBA) and alkali in polar organic solvent at the atmospheric pressure (called sulfur solution route), is reported in the present paper. The influences of polymerization time, molar ratio of precursors, catalyst and solvent upon the polymer were investigated. To seek the best parameters of polymerization, orthogonal design was employed in the experiments. The results indicate that the molar ratio of precursors is the most significant effect on both of viscosity and yield of the polymer. The suitable parameters for preparing the related polymer are presented. The polymer was characterized by IRspectrum, 1HNMRspectrum and Raman spectrum, etc.展开更多
A new blend of poly(2-hydroxyethyl methacrylate) (PHEMA) with poly (ethylene glycol) (PEG) was prepared. The results from solid-state NMR indicate that the PHEMA/PEG(88:12, w/w) blend is miscible on a molecular level.
A solid phase crystallizing method has been developed to grow a Si crystal at tem-peratures as low as 550 ℃. Using this method, a high-quality thin-film polycrystalline silicon (Poly-Si) was obtained. The largest gra...A solid phase crystallizing method has been developed to grow a Si crystal at tem-peratures as low as 550 ℃. Using this method, a high-quality thin-film polycrystalline silicon (Poly-Si) was obtained. The largest grain size, examined with X-ray diffraction spectroscopy and scanning electron microscopy images of recrystallized samples, is approximately 1 /μm for substrate temperature at 300 ℃ and annealed at 550℃ for 3 hours.展开更多
Lactide was synthesized using lactic acid and stannous octoate as raw material and catalyst, respectively. Poly(lactic acid)-poly(ethylene glycol) (PLA-PEG) was prepared by lactide and poly (ethylene glycol) (PEG) via...Lactide was synthesized using lactic acid and stannous octoate as raw material and catalyst, respectively. Poly(lactic acid)-poly(ethylene glycol) (PLA-PEG) was prepared by lactide and poly (ethylene glycol) (PEG) via ring-opening polymerization. The most appropriate technological conditions of synthesis of lactide were researched in the paper. The copolymers were measured by Infrared spectroscopy (IR) and <sup>1</sup>H nuclear magnetic resonance (<sup>1</sup>H NMR). The results proved that the lactide and PLA-PEG were synthesized successfully. Hydrophilic performance of the copolymer was measured by a water contact angle tester after prepared into a flat membrane. The water contact angle changed from 81.5? to 71.6?, which proved that the hydrophily of PLA-PEG was better than PLA.展开更多
This work demonstrated that mesoporous TiO= （meso-TiO2） with con- trollable mesoporous and crystalline structures can be facilely prepared by using poly （ethylene glycol） （PEG） as structure-directing （SD） agen...This work demonstrated that mesoporous TiO= （meso-TiO2） with con- trollable mesoporous and crystalline structures can be facilely prepared by using poly （ethylene glycol） （PEG） as structure-directing （SD） agent and peroxotitanic acid （PTA） as precursor. Meso-TiO2 with high specific surface area （157 m2.g-1）, pore volume （0.45 cm3.g-1） and large mesopore size of 13.9 nm can be obtained after calcination at 450℃. Such meso-TiO2 also shows relatively high thermal stability. BET surface area still reaches 114 m2-g-1 after calcination at 550℃. In the synthesis and calcination process, PEG that plays multiple and important roles in delivering thermally stable and tunable mesoporous and crystalline structures shows to be a suitable low-cost SD agent for the controllable preparation of nanocrystalline meso-TiO2. The photocataiytic activity tests show that both high surface area and bi-crystallinity of obtained meso-TiO2 are important in enhancing the performance in photo-decomposing Rhodamine B in water.展开更多
文摘The sodium silicate, ferric chloride, ferrous sulfate, sodium chlorate and other common inorganic materials were used to synthesize two new poly silicate iron coagulants： Polysilicate Ferric Chloride （PFSiC） and Polymeric Ferric Silicate Sulfate （PFSiS）. Their coagulation effect on micro-polluted water was compared with the poly ferric choride （PFC） saled in the market. The results showed that turbidity, organic matter, total phosphorus, total nitrogen removal rate ofPFSiC, PFSiS coagulant were better than PFC on micro-polluted water treatment at the same dosage. The coagulation effect of PFSiC was the best. The surface morphology of three coagulants was observed by scanning electron microscopy （SEM）, and the coagulation mechanism was discussed preliminarily.
文摘A new process for preparing poly(phenylene sulfide amide, PPSA), which is by reaction of sulfur instead of sodium sulfide as S source with dichlorobenzamide (DCBA) and alkali in polar organic solvent at the atmospheric pressure (called sulfur solution route), is reported in the present paper. The influences of polymerization time, molar ratio of precursors, catalyst and solvent upon the polymer were investigated. To seek the best parameters of polymerization, orthogonal design was employed in the experiments. The results indicate that the molar ratio of precursors is the most significant effect on both of viscosity and yield of the polymer. The suitable parameters for preparing the related polymer are presented. The polymer was characterized by IRspectrum, 1HNMRspectrum and Raman spectrum, etc.
文摘A new blend of poly(2-hydroxyethyl methacrylate) (PHEMA) with poly (ethylene glycol) (PEG) was prepared. The results from solid-state NMR indicate that the PHEMA/PEG(88:12, w/w) blend is miscible on a molecular level.
基金This work was supported by the Guangdong Provincial Natural Science Foundation of China No.990781.
文摘A solid phase crystallizing method has been developed to grow a Si crystal at tem-peratures as low as 550 ℃. Using this method, a high-quality thin-film polycrystalline silicon (Poly-Si) was obtained. The largest grain size, examined with X-ray diffraction spectroscopy and scanning electron microscopy images of recrystallized samples, is approximately 1 /μm for substrate temperature at 300 ℃ and annealed at 550℃ for 3 hours.
文摘Lactide was synthesized using lactic acid and stannous octoate as raw material and catalyst, respectively. Poly(lactic acid)-poly(ethylene glycol) (PLA-PEG) was prepared by lactide and poly (ethylene glycol) (PEG) via ring-opening polymerization. The most appropriate technological conditions of synthesis of lactide were researched in the paper. The copolymers were measured by Infrared spectroscopy (IR) and <sup>1</sup>H nuclear magnetic resonance (<sup>1</sup>H NMR). The results proved that the lactide and PLA-PEG were synthesized successfully. Hydrophilic performance of the copolymer was measured by a water contact angle tester after prepared into a flat membrane. The water contact angle changed from 81.5? to 71.6?, which proved that the hydrophily of PLA-PEG was better than PLA.
文摘This work demonstrated that mesoporous TiO= （meso-TiO2） with con- trollable mesoporous and crystalline structures can be facilely prepared by using poly （ethylene glycol） （PEG） as structure-directing （SD） agent and peroxotitanic acid （PTA） as precursor. Meso-TiO2 with high specific surface area （157 m2.g-1）, pore volume （0.45 cm3.g-1） and large mesopore size of 13.9 nm can be obtained after calcination at 450℃. Such meso-TiO2 also shows relatively high thermal stability. BET surface area still reaches 114 m2-g-1 after calcination at 550℃. In the synthesis and calcination process, PEG that plays multiple and important roles in delivering thermally stable and tunable mesoporous and crystalline structures shows to be a suitable low-cost SD agent for the controllable preparation of nanocrystalline meso-TiO2. The photocataiytic activity tests show that both high surface area and bi-crystallinity of obtained meso-TiO2 are important in enhancing the performance in photo-decomposing Rhodamine B in water.
