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Estimation of plasma parameters in the process of micro-scale powder plastic and characteristics of its products 被引量:1
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作者 Lunjiang CHEN Wenbo CHEN +2 位作者 Chuandong LIU Honghui TONG Qing ZHAO 《Plasma Science and Technology》 SCIE EI CAS CSCD 2019年第7期54-59,共6页
The temperature and density of plasma jets were estimated with a Boltzmann plot and Stark broadening of Ar I(696.54 nm) lines by optical emission spectroscopy(OES) in the process of plasma plastic, and the morphology ... The temperature and density of plasma jets were estimated with a Boltzmann plot and Stark broadening of Ar I(696.54 nm) lines by optical emission spectroscopy(OES) in the process of plasma plastic, and the morphology and microstructure of tungsten(W) powders were investigated by scanning electron microscope(SEM) and x-ray Diffraction(XRD), respectively.The results show that the assumption of local thermodynamic equilibrium(LTE) was invalid at the end of the plasma jets, and earlier than this after the injection of tungsten powder. The temperature and electron density of the plasma jets were up to about T?=?6797 K with Qc?=?50 slpm and ne?=?1.05?×?1016 cm-3 with Qs?=?115 slpm at Z?=?60 mm, respectively, and both dropped rapidly with the injected tungsten powders of 20 μm. After the plasma plastic process,the spherical tungsten powders were prepared and there were some satellite particles on the surface of the spherical products. The tungsten powders were both composed of a single equilibrium α-W phase with a body centered cubic(bbc) crystal structure before and after plasma treatment. 展开更多
关键词 plasma temperature ELECTRON density powder plastic OES BOLTZMANN
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Consolidation of AA 7075-2 wt% ZrO2 Composite Powders by Severe Plastic Deformation via ECAP 被引量:2
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作者 S. E. Hernandez-Martinez J. J. Cruz-Rivera +4 位作者 R. Martinez-Sanchez C. G. Garay-Reyes J. A. Mufioz-Bolanos J. M. Cabrera J.L.Hernández-Rivera 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2016年第10期895-901,共7页
The powders of the AA 7075-ZRO2 were mixed by mechanical milling, but it was found that the system presents a few disadvantages when processed by conventional sintering and hot extrusion, since intermetallic phases be... The powders of the AA 7075-ZRO2 were mixed by mechanical milling, but it was found that the system presents a few disadvantages when processed by conventional sintering and hot extrusion, since intermetallic phases between ZrO2 particles and alloying elements were formed. Equal channel angular pressing (ECAP) processing was proposed as an alternative method to consolidate the composite where there is no intermetallic formation. The analysis of the ECAP process showed that the intermediate temperature (220℃) produced a higher consolidation level than conventional sintering and hot extrusion (400 and 500℃, respectively). This fact was supported by relative density analysis. In the case of the sintered and hot-extruded sample, the relative density exhibited a value of 0.95, while ECAP sample showed a value of 0.98. Hardness values show that microstructural refinement obtained during mechanical milling was preserved during ECAP processing even when it was carded out at 220℃. 展开更多
关键词 Metal matrix composites (MMCs) powder consolidation Severe plastic deformation (SPD)
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Plastic Deformation of Powders Aggregates Sprayed on a Hard Ball Under Impact of Another Hard Ball
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作者 刘祖岩 王永前 +1 位作者 梁国宪 王尔德 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1997年第2期118-121,共4页
A simple gravity drop experiment was run to investigate plastic deformation of powder aggregrate sprayed on a hard ball under impact of another free falling hard ball and measure coefficient of restitution and plastic... A simple gravity drop experiment was run to investigate plastic deformation of powder aggregrate sprayed on a hard ball under impact of another free falling hard ball and measure coefficient of restitution and plastic strain of powder aggregate. Experimental results show that coefficient of restitution and plastic strain of powder aggregate increase as the velocity of ball increases and initial height (h 0) of powder aggregate has great effects on plastic deformation of powder aggregate. At a higher initial height (h 0), much of kinetic energy is dissipated is interparticle frictional work and coefficient of restitution is very small. Plastic strain of powder aggregate first increases as h 0 increases until a maximum value and then decreases as h 0 increases. 展开更多
关键词 plastic DEFORMATION powder aggregate IMPACT DEFORMATION
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Influence of the Partial Substitution of Bitumen by a Mixture of Sulphur and Tyre and Plastic Bottle Powders on the Behaviour of Bituminous Concrete
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作者 Parfait Isidore Mbenkoue Mbida Déodonne Kunwufine +1 位作者 Charles Bwemba Michel Mbessa 《Journal of Minerals and Materials Characterization and Engineering》 2023年第6期213-223,共11页
This article deals with the influence of the partial substitution of bitumen by a mixture of sulphur and tyre and plastic bottle powders on the characterization of asphalt concrete. The approach adopted was to subject... This article deals with the influence of the partial substitution of bitumen by a mixture of sulphur and tyre and plastic bottle powders on the characterization of asphalt concrete. The approach adopted was to subject a control asphalt concrete to level 2 formulation tests as well as those modified at 10%, 20%, 30% and 40% by substituting bitumen with a mixture of tyre powder, plastic bottle powder and sulphur at 40%, 28% and 32% respectively. The results of the PCG, Duriez and rutting tests carried out on the control and modified bituminous concretes (manufactured using the wet process) revealed three (03) major findings, in particular with regard to workability, resistance to simple compression and rutting. The experimental results show an increasing trend in the essential parameters. At 40% substitution, there was a 22.73% increase in compactness, reflecting a significant improvement in the material’s workability. With regard to simple compressive strength, the increase is 34.02% at 40% substitution, highlighting the limitation of crack formation and propagation under heavy precipitation. With regard to rutting, the 16% drop in susceptibility at 40% substitution reflects a significant improvement in the behaviour of the material under dynamic mechanical stresses in heavy precipitation. The improvement in these behaviours results from the insertion of the plastic bottle powder into the interstices of the granular skeleton, thus reducing its cellular structure, and also from the interactions between the sulphur with the tyre powder and the sulphur with the plastic bottle powder, i.e. cross-linking or vulcanisation. 展开更多
关键词 Bituminous Concrete Tyre powder plastic Bottle powder SULPHUR
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On Numerical Modelling of Industrial Powder Compaction Processes for Large Deformation of Endochronic Plasticity at Finite Strains
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作者 A R Khoei A Bakhshiani M Mofid 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期95-96,共2页
Compaction processes are one the most important par ts of powder forming technology. The main applications are focused on pieces for a utomotive, aeronautic, electric and electronic industries. The main goals of the c... Compaction processes are one the most important par ts of powder forming technology. The main applications are focused on pieces for a utomotive, aeronautic, electric and electronic industries. The main goals of the compaction processes are to obtain a compact with the geometrical requirements, without cracks, and with a uniform distribution of density. Design of such proc esses consist, essentially, in determine the sequence and relative displacements of die and punches in order to achieve such goals. A.B. Khoei presented a gener al framework for the finite element simulation of powder forming processes based on the following aspects; a large displacement formulation, centred on a total and updated Lagrangian formulation; an adaptive finite element strategy based on error estimates and automatic remeshing techniques; a cap model based on a hard ening rule in modelling of the highly non-linear behaviour of material; and the use of an efficient contact algorithm in the context of an interface element fo rmulation. In these references, the non-linear behaviour of powder was adequately desc ribed by the cap plasticity model. However, it suffers from a serious deficiency when the stress-point reaches a yield surface. In the flow theory of plasticit y, the transition from an elastic state to an elasto-plastic state appears more or less abruptly. For powder material it is very difficult to define the locati on of yield surface, because there is no distinct transition from elastic to ela stic-plastic behaviour. Results of experimental test on some hard met al powder show that the plastic effects were begun immediately upon loading. In such mater ials the domain of the yield surface would collapse to a point, so making the di rection of plastic increment indeterminate, because all directions are normal to a point. Thus, the classical plasticity theory cannot deal with such materials and an advanced constitutive theory is necessary. In the present paper, the constitutive equations of powder materials will be discussed via an endochronic theory of plasticity. This theory provides a unifi ed point of view to describe the elastic-plastic behaviour of material since it places no requirement for a yield surface and a ’loading function’ to disting uish between loading an unloading. Endochronic theory of plasticity has been app lied to a number of metallic materials, concrete and sand, but to the knowledge of authors, no numerical scheme of the model has been applied to powder material . In the present paper, a new approach is developed based on an endochronic rate independent, density-dependent plasticity model for describing the isothermal deformation behavior of metal powder at low homologous temperature. Although the concept of yield surface has not been explicitly assumed in endochronic theory, it is shown that the cone-cap plasticity yield surface (Fig.1), which is the m ost commonly used plasticity models for describing the behavior of powder materi al can be easily derived as a special case of the proposed endochronic theory. Fig.1 Trace of cone-cap yield function on the meridian pl ane for different relative density As large deformation is observed in powder compaction process, a hypoelastic-pl astic formulation is developed in the context of finite deformation plasticity. Constitutive equations are stated in unrotated frame of reference that greatly s implifies endochronic constitutive relation in finite plasticity. Constitutive e quations of the endochronic theory and their numerical integration are establish ed and procedures for determining material parameters of the model are demonstra ted. Finally, the numerical schemes are examined for efficiency in the model ling of a tip shaped component, as shown in Fig.2. Fig.2 A shaped tip component. a) Geometry, boundary conditio n and finite element mesh; b) density distribution at final stage of 展开更多
关键词 In On Numerical Modelling of Industrial powder Compaction Processes for Large Deformation of Endochronic plasticity at Finite Strains
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Analysis on plastic properties of reactive powder concrete continuous beams reinforced with GFRP bars
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作者 卢姗姗 郑文忠 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2010年第4期471-475,共5页
To study the plastic properties of reactive powder concrete continuous beams reinforced with GFRP bars,the calculation programs for moment redistribution coefficients are prepared by using nonlinear analysis methods s... To study the plastic properties of reactive powder concrete continuous beams reinforced with GFRP bars,the calculation programs for moment redistribution coefficients are prepared by using nonlinear analysis methods such as moment-curvature,conjugate beam method and so on. By comparing the test results of existed FRP bars reinforced concrete continuous beams with simulation results,the accuracy of the calculation program is verified. Then 18 simulated GFRP bars reinforced reactive powder concrete continuous beams are selected whose change parameters are reinforcement ratio of mid-span and middle support. Through the nonlinear analysis of simulated beams,moment redistribution coefficients under mid-span concentrated loads,one-third point loads and uniformly distributed loads are obtained respectively. Thus the formula of moment redistribution coefficients is obtained by fitting moment redistribution coefficients and factors. The results show that the reactive powder concrete continuous beams reinforced with GFRP bars have good plastic properties. 展开更多
关键词 GFRP bars reactive powder concrete ( RPC) continuous beam plastic properties
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基于碳纤维增强PPS的工业锁控高防腐工艺
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作者 丁凡 毛建华 +1 位作者 胡伟力 姚春良 《金属功能材料》 2026年第1期116-124,共9页
为了满足户外储能柜对工业锁闭系统的高防腐要求,对主锁及传动负载部件的结构、材料和表面处理工艺进行了优化设计。基于摩擦接触面隔离设计以及金属表面处理工艺优化原则,针对锁体执行部件的运动摩擦结构,采用了包塑工艺,并用碳纤维增... 为了满足户外储能柜对工业锁闭系统的高防腐要求,对主锁及传动负载部件的结构、材料和表面处理工艺进行了优化设计。基于摩擦接触面隔离设计以及金属表面处理工艺优化原则,针对锁体执行部件的运动摩擦结构,采用了包塑工艺,并用碳纤维增强聚苯硫醚(Cf-PPS)替代锌合金,以形成塑料-金属配副,从而取代传统的金属-金属配副。这一改进显著提升了部件的耐磨性和耐腐蚀性能。在外观方面,锁体采用电泳涂层与氟碳塑粉喷涂相结合,传动部件选用316L不锈钢并经过钝化处理。通过工艺分析,并进行了机械性能测试和中性盐雾测试,结果显示锁闭机构有效开关次数达到了20 000次,所有零部件在交变盐雾环境下耐受时间超过2 300 h。这些措施显著提高了工业锁闭系统的可靠性与稳定性,同时增强了工业锁在户外高温、高湿及高腐蚀环境中的生存能力。 展开更多
关键词 高防腐 Cf-PPS 氟碳塑粉 316L不锈钢钝化
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NUMERICAL SIMULATION OF EXTRUSION OF COMPOSITE POWDERS PREPARED BY HIGH ENERGY MILLING 被引量:2
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作者 X.Q.Li W.P.Chen +3 位作者 W.Xia Q.L.Zhu Y.Y.Li E.D.Wang 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2004年第1期51-54,共4页
Based on the characteristic of high energy milling and the micromechanics of composite material, a plastic constitutive equation is implemented for milled composite powders. To check the equation, the extrusion of Ti/... Based on the characteristic of high energy milling and the micromechanics of composite material, a plastic constitutive equation is implemented for milled composite powders. To check the equation, the extrusion of Ti/Al composite powders prepared by high energy milling was simulated. It was from the numerical analysis that the predicted extrusion pressure mounted up with milling time and extrusion ratio increasing, which was perfect agreement with experimental results. 展开更多
关键词 high energy milling composite powder plastic constitutive equation EXTRUSION numerical simulation
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A Constitutive Model for Uni-axial Compaction of Non-adhesive CornStalk Powder
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作者 ZhaoDong SunYanling 《Forestry Studies in China》 CAS 2004年第2期46-49,共4页
In order to study mechanical behaviors of corn stalk powder during the compaction, the yield criterion for corn stalk powder is proposed with a plasticity theory. From the stress-strain curves of uni-axial compaction ... In order to study mechanical behaviors of corn stalk powder during the compaction, the yield criterion for corn stalk powder is proposed with a plasticity theory. From the stress-strain curves of uni-axial compaction test for corn stalk powder, the constitutive model, in which the equations are modified by experiments on corn stalk powder, is adopted to describe plastic behaviors of powder, and is discussed based on the incremental theory and deformation theory. The numerical results agree well with the experimental ones. 展开更多
关键词 constitutive model corn stalk powder plastic deformation
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Workability Studies in Forming of Sintered Fe-0.35CPowder Metallurgy Preform During Cold Upsetting
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作者 S Narayan A Rajeshkannan 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2011年第12期71-78,共8页
An experimental investigation on the workability behaviour of sintered Fe-0.35C steel preforms under cold upsetting,have been studied in order to understand the influence of aspect ratio and lubrication condition on t... An experimental investigation on the workability behaviour of sintered Fe-0.35C steel preforms under cold upsetting,have been studied in order to understand the influence of aspect ratio and lubrication condition on the workability process.The above mentioned powder metallurgy sintered preform with constant initial theoretical density of 84% of different aspect ratios,namely,0.4 and 0.6 respectively were prepared using a suitable die-set assembly on a 1 MN capacity hydraulic press and sintered for 90 min at 1200 ℃.Each sintered preform was cold upset under nil/no and graphite frictional constraint,respectively.Under the condition of triaxial stress densification state,axial stress,hoop stress,hydrostatic stress,effective stress and formability stress index against axial strain relationship was established and presented in this work.Further more,attained density was considered to establish formability stress index and various stress ratio parameters behaviour. 展开更多
关键词 powder metallurgy failure analysis plastic behaviour WORKABILITY
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盾粉/石塑复合材料的制备与力学性能 被引量:1
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作者 任晓健 王倩 +3 位作者 赵令 杜晓燕 张浩 龙红明 《复合材料学报》 北大核心 2025年第8期4716-4725,共10页
针对滑石粉成本高、工艺复杂和钢渣产量大但利用率低的问题,采用超细立磨技术结合功能助剂,成功将钢渣加工为中位径(d50)分别为6.445μm、5.775μm和5.098μm的盾粉。通过熔融共混与热压冷压相结合的工艺实现用盾粉替代滑石粉制备盾粉/... 针对滑石粉成本高、工艺复杂和钢渣产量大但利用率低的问题,采用超细立磨技术结合功能助剂,成功将钢渣加工为中位径(d50)分别为6.445μm、5.775μm和5.098μm的盾粉。通过熔融共混与热压冷压相结合的工艺实现用盾粉替代滑石粉制备盾粉/石塑复合材料。对其进行拉伸强度、弯曲强度和冲击强度测试,并通过XRD、SEM、FTIR和DSC进行表征分析。结果表明,盾粉的加入显著提升了石塑复合材料的力学性能。尤其是在6.445μm、5.775μm和5.098μm盾粉替代滑石粉比例为50%时,与纯滑石粉/石塑复合材料相比,拉伸强度分别提高12.3%、33.2%和27.4%,弯曲强度分别提高11.7%、26.0%和17.6%,冲击强度分别提高33.3%、52.9%和32.8%。由于5.775μm盾粉因其粒径分布宽度最小(2.177),在石塑复合材料中分散性良好,显著提升了界面相容性,因此在提升石塑复合材料力学性能方面表现最为突出。此外,5.775μm盾粉有效提高了熔融焓和结晶焓,分别为45.16 J·g^(-1)和42.31 J·g^(-1),这有助于石塑复合材料形成更均匀的晶体结构,并促进成核和晶体生长,从而进一步提升了其力学性能。 展开更多
关键词 钢渣 石塑 力学性能 固废利用 滑石粉
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Effects of Stone Cutting Powder (Al-Khamkha) on the Properties of Self-Compacting Concrete
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作者 Manal O. Suliman Hesham Alsharie +1 位作者 Yasser I. O. Yahia Talal Masoud 《World Journal of Engineering and Technology》 2017年第4期613-625,共13页
Most of the construction materials research now concerns on investigation of construction materials that is locally produced at a rate and cost compatible with the pace of construction. The present paper is concerned ... Most of the construction materials research now concerns on investigation of construction materials that is locally produced at a rate and cost compatible with the pace of construction. The present paper is concerned with investigation of fresh and hardened properties of self-compacting concrete (SCC) produced from local available materials in JORDAN. The produced SCC contains the local stone cut waste powder which is called Al-KHAMKHA in JORDAN with different replacement of (0%, 10%, and 25%) of fine silica aggregate;?the study also investigatesthe effects of SP33 super?plasticizer which is used by different doses (1%, 1.5% and 2%) for cement. The slump flow and the compressive strength of SCC were studied and the experimental results indicate the possibility of using Al-KHAMKHA in the production of SCC as the results showed that the compressive strength of the SCC with 10 % replacement by al-khamkha together with 1% SP33?super plasticizer was higher compared to pure SCC without al-khamkha;?the results also showed that as al-khamkha content increased the slump flow decreased. 展开更多
关键词 Al-Khamkh COMPRESSIVE Strength Self COMPACTING Concrete STONE powder SP33 Super plasticIZER
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汽车内饰材料聚己二酸/对苯二甲酸丁二酯的改性研究
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作者 马莹 李海兵 《塑料科技》 北大核心 2025年第10期118-122,共5页
以去壳亚麻籽粉(DeFM)与聚己二酸/对苯二甲酸丁二酯(PBAT)为原料制备复合材料。首先对DeFM进行脱油处理,获得脱油去壳亚麻籽粉(DeFM-O);随后采用二氧化钛(TiO_(2))对DeFM-O进行表面改性,制得TiO_(2)改性的DeFM-O(DeFM-OM)。制备不同添... 以去壳亚麻籽粉(DeFM)与聚己二酸/对苯二甲酸丁二酯(PBAT)为原料制备复合材料。首先对DeFM进行脱油处理,获得脱油去壳亚麻籽粉(DeFM-O);随后采用二氧化钛(TiO_(2))对DeFM-O进行表面改性,制得TiO_(2)改性的DeFM-O(DeFM-OM)。制备不同添加比例的PBAT-DeFM-O复合材料和PBAT-DeFM-OM复合材料,并对其性能进行系统表征与分析。结果表明:脱油处理降低了材料的力学性能,TiO_(2)改性可改善分散性;添加质量分数为5%的DeFM-OM时,复合材料保持最优力学性能,断裂伸长率为501.9%,拉伸强度为10.6 MPa。衰减全反射傅里叶变换红外光谱(ATR-FTIR)及X射线衍射(XRD)结果证实无新物质生成,特征峰变化源于峰叠加,PBAT主导结构;脱油处理降低了结晶度,TiO_(2)改性后结晶度无显著变化。DeFM-OM显著加速了PBAT的降解,PBATDeFM-O的6 h降解率达85.69%;TiO_(2)改性复合材料降解速率略微降低,但仍显著高于纯PBAT。研究结果为轻量化可降解汽车材料的开发提供参考。 展开更多
关键词 可降解塑料 聚己二酸/对苯二甲酸丁二酯 亚麻籽粉
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Chemical characterization of smoke from the production process of wood-plastic composites
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作者 Wang Shi-fa Zhang Ai-jun 《Forestry Studies in China》 CAS 2007年第1期57-62,共6页
The chemical composition of unpleasant smell, emitted from the production process of wood-plastic composites using Manchurian ash sawdust (Fraxinus mandschurica Rupr.) and polypropylene powder as the raw material, w... The chemical composition of unpleasant smell, emitted from the production process of wood-plastic composites using Manchurian ash sawdust (Fraxinus mandschurica Rupr.) and polypropylene powder as the raw material, was investigated. Wood sawdust and polypropylene powder were subjected to heat treatment to 290℃ during 8 min (the conditions were similar to those employed on an industrial scale). The emitted compounds were collected and analyzed by gas chromatography-mass spectrometry (GC-MS). The analytical results showed that the unpleasant smell was emitted from the pyrogenation of wood sawdust rather than from the polypropylene powder. Nine types of compounds (hydrocarbons, ethers, phenols, aldehydes, ketones, alcohols, acids and their derivatives, furan and its derivatives, and nitrogen-containing compounds) were collected in the gas phase during heating. Among those 126 components detected by GC-MS, 112 compounds were identified. 展开更多
关键词 wood-plastic composite unpleasant smell pyrogenation Manchurian ash sawdust polypropylene powder
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装配式局部活性粉末混凝土梁柱节点恢复力模型 被引量:1
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作者 于建兵 徐志强 +2 位作者 夏煜锋 管东芝 郭正兴 《湖南大学学报(自然科学版)》 北大核心 2025年第1期49-60,共12页
为了验证所提出的装配式局部活性粉末混凝土框架梁柱节点的抗震性能,对4个足尺节点进行了低周反复荷载试验,在试验的基础之上,针对节点的连接特点,提出了强度和变形计算方法,构建了平顶的三折线骨架曲线理论模型.通过理论计算得到试验... 为了验证所提出的装配式局部活性粉末混凝土框架梁柱节点的抗震性能,对4个足尺节点进行了低周反复荷载试验,在试验的基础之上,针对节点的连接特点,提出了强度和变形计算方法,构建了平顶的三折线骨架曲线理论模型.通过理论计算得到试验滞回曲线各阶段曲线刚度值,并拟合得到试件在低周往复荷载作用下各级加载、卸载刚度与加载位移角的关系,进而根据滞回规则建立恢复力模型.计算结果表明:通过理论计算所建立的三折线骨架曲线和滞回曲线与试验结果均吻合较好,能够较好地反映该类连接节点在各阶段的受力特点,为弹塑性分析和抗震设计提供理论依据. 展开更多
关键词 装配式混凝土框架 活性粉末混凝土 梁柱节点 恢复力模型 弹塑性分析
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盾粉化学成分对木塑复合材料力学性能影响的熵权-灰色关联度综合分析 被引量:1
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作者 张浩 夏玉蓉 +4 位作者 费海林 陈良军 任晓健 程峥明 赵令 《塑料工业》 北大核心 2025年第2期118-126,共9页
以前期研究成果盾粉为研究对象,采用熔融共混与热压相结合的工艺,将不同化学成分的盾粉替代50%滑石粉与聚乙烯复合制备盾粉/木塑复合材料。利用X射线射仪(XRD),傅里叶红外光谱仪(FTIR),扫描电子显微镜(SEM)进行表征分析,同时使用熵权-... 以前期研究成果盾粉为研究对象,采用熔融共混与热压相结合的工艺,将不同化学成分的盾粉替代50%滑石粉与聚乙烯复合制备盾粉/木塑复合材料。利用X射线射仪(XRD),傅里叶红外光谱仪(FTIR),扫描电子显微镜(SEM)进行表征分析,同时使用熵权-灰色关联分析法分析盾粉化学成分对盾粉/木塑复合材料力学性能的影响。研究结果表明,具有多孔结构的盾粉,其比表面积大,吸附性好,使其被马来酸酐接枝聚乙烯(MAPE)包裹,马来酸酐基团能够与盾粉表面的—OH发生酯化反应,生成稳定的化学键,增强了界面相容性。盾粉化学成分对盾粉/木塑复合材料拉伸强度的综合关联度排序为CaO(氧化钙)>Fe_(x)O_(y)(铁氧化合物)>MnO(氧化锰)>P_(2)O_(5)(五氧化二磷)>SiO_(2)(二氧化硅)>MgO(氧化镁)>Al_(2)O_(3)(三氧化二铝)>SO_(3)(三氧化硫);盾粉化学成分对盾粉/木塑复合材料弯曲强度的综合关联度排序为CaO>Fe_(x)O_(y)>MnO>P_(2)O_(5)>SiO_(2)>MgO>Al_(2)O_(3)>SO_(3);盾粉化学成分对盾粉/木塑复合材料冲击强度的综合关联度排序为CaO>Fe_(x)O_(y)>P_(2)O_(5)>MnO>SiO_(2)>Al_(2)O_(3)>MgO>SO_(3)。说明盾粉中CaO,Fe_(x)O_(y)是提高盾粉/木塑复合材料力学性能的主要成分,而SO_(3)则对性能提高起负面影响。为盾粉的配方设计提供了明确的优化方向,即提高CaO和Fe_(x)O_(y)含量,并减少SO_(3)含量,以提升木塑复合材料的整体力学性能。 展开更多
关键词 盾粉 木塑复合材料 力学性能 熵权 灰色关联分析
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基于变异系数-灰色关联法的盾粉细度对盾粉基石木塑板力学性能影响研究 被引量:1
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作者 张浩 费海林 +4 位作者 夏玉蓉 陈良军 任晓健 李志刚 赵令 《林产工业》 北大核心 2025年第8期8-15,共8页
基于钢渣为原料制备盾粉的技术,以不同细度盾粉为研究对象制备盾粉基石木塑板,测试其相关性能,并且利用数学方法进行分析。结果表明:盾粉细度增加可显著提升拉伸、弯曲和冲击强度,降低吸水膨胀率。800目以上盾粉与滑石粉复合能提高石木... 基于钢渣为原料制备盾粉的技术,以不同细度盾粉为研究对象制备盾粉基石木塑板,测试其相关性能,并且利用数学方法进行分析。结果表明:盾粉细度增加可显著提升拉伸、弯曲和冲击强度,降低吸水膨胀率。800目以上盾粉与滑石粉复合能提高石木塑板密实度,1 000目盾粉的粒径分布宽度(H)最小,分散性最佳,力学性能提升显著。变异系数-灰色关联分析显示,粒径分布宽度对性能影响权重最高(H>d_(10)>d_(50)>d_(90)),随着细度增大,盾粉粒径减小且分布更均匀,使盾粉接触面积增大。 展开更多
关键词 盾粉 石木塑板 冻融 变异系数 灰色关联分析
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酶催化改性竹粉/聚乳酸复合材料的制备及性能研究 被引量:1
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作者 唐维 《塑料科技》 北大核心 2025年第4期135-139,共5页
以木聚糖酶为催化酶对竹粉进行改性,以酶催化改性竹粉为增强填料、以聚乳酸(PLA)为基材制备酶催化改性竹粉/PLA复合材料。通过电子扫描显微镜(SEM)、傅里叶变换红外光谱(FTIR)、热重分析(TG)和万能试验机分析酶催化改性竹粉/PLA复合材... 以木聚糖酶为催化酶对竹粉进行改性,以酶催化改性竹粉为增强填料、以聚乳酸(PLA)为基材制备酶催化改性竹粉/PLA复合材料。通过电子扫描显微镜(SEM)、傅里叶变换红外光谱(FTIR)、热重分析(TG)和万能试验机分析酶催化改性竹粉/PLA复合材料的性能。SEM、FTIR和TG结果表明,随着木聚糖酶质量浓度的增加,竹粉中的竹纤维表面变得更为粗糙,表面羟基数量变少,更容易与PLA结合,这有利于增强竹粉/PLA复合材料的热稳定性。力学测试结果表明,相比未进行酶催化改性的竹粉/PLA复合材料,酶催化改性竹粉/PLA复合材料的力学性能明显提升。当木聚糖酶质量浓度为3 mg/L时,酶催化改性竹粉/PLA复合材料的拉伸强度、压缩强度、弯曲强度和冲击强度分别达到42、2631、68 MPa和0.83 kJ/m^(2)。 展开更多
关键词 酶催化 聚乳酸 竹粉 复合材料 塑料
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HP/HDPE发泡复合材料的制备及其性能研究
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作者 曹磊 常德鹏 +2 位作者 吕晓阳 刘天 张显权 《化工新型材料》 北大核心 2025年第11期110-115,共6页
通过熔融共混、模压发泡将汉麻杆芯粉(HP)与高密度聚乙烯(HDPE)复合,制备了HP/HDPE发泡复合材料,通过扫描电子显微镜、X射线衍射仪、热重分析仪、差示扫描量热仪、万能力学试验机、简支梁冲击试验机、旋转流变仪等对发泡复合材料的微观... 通过熔融共混、模压发泡将汉麻杆芯粉(HP)与高密度聚乙烯(HDPE)复合,制备了HP/HDPE发泡复合材料,通过扫描电子显微镜、X射线衍射仪、热重分析仪、差示扫描量热仪、万能力学试验机、简支梁冲击试验机、旋转流变仪等对发泡复合材料的微观形貌、结晶性能、热性能、力学性能及流变性能进行了表征和测试。结果表明:发泡复合材料的复数黏度和弹性模量随HP含量的增加先降低后升高,弯曲强度和压缩强度随HP含量增加先上升后下降,HP质量分数为20%时弯曲强度和压缩强度分别提升了21.3%和73.1%;HP质量分数为20%的发泡复合材料其泡孔密度比纯HDPE泡孔密度提升了36.8%;HP对HDPE的结晶影响较小,随着HP含量的增加HDPE结晶度逐渐提高。 展开更多
关键词 汉麻杆芯粉 高密度聚乙烯 发泡 木塑复合材料
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低水灰比水泥基材料早期塑性收缩研究 被引量:3
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作者 王佃超 鲁正 +2 位作者 王远航 谭淇航 朱黎明 《建筑科学与工程学报》 北大核心 2025年第1期131-138,共8页
为研究混凝土早期塑性收缩发展机制,探究不同的减缩抑制剂对混凝土收缩及裂缝发展的控制效果,分析水泥净浆的裂缝发展状态及主应变变化规律,分别选用再生混凝土微粉、碳化再生混凝土微粉、氧化镁基膨胀剂、聚乙烯纤维作为掺入材料,按照... 为研究混凝土早期塑性收缩发展机制,探究不同的减缩抑制剂对混凝土收缩及裂缝发展的控制效果,分析水泥净浆的裂缝发展状态及主应变变化规律,分别选用再生混凝土微粉、碳化再生混凝土微粉、氧化镁基膨胀剂、聚乙烯纤维作为掺入材料,按照相应配合比拌合水泥净浆;通过二维非接触数字图像方法(2D-DIC)研究了不同净浆的收缩裂缝发展历程,定量评价了不同工况下试件中线位置最大主应变的变化趋势;最后通过扫描电镜对不同掺料作用下的裂缝开展状态进行评估。结果表明:不同材料对混凝土早期塑性收缩的裂缝发展影响不同;掺入再生混凝土微粉与碳化再生混凝土微粉均能有效抑制水泥净浆的早期塑性收缩,碳化后的再生混凝土微粉较普通再生混凝土微粉能够进一步提升水泥净浆的收缩控制效果,裂缝出现时间延迟了10 min;加入聚乙烯纤维可有效提高塑性开裂的发展时间并减少裂缝的开展宽度;随着浇筑时间的增加,最大主应变逐渐增大,在4.5 h后达到0.03380;不同掺加剂对主应变的发展趋势影响各不相同,掺入碳化再生混凝土微粉工况下最大主应变在4.5 h时为0.02795,能够使塑性最大主应变降低17.30%;无掺加剂的水泥净浆中裂缝往往呈现主裂缝贯通、其余裂缝分散分布的特征;掺入碳化再生混凝土微粉的情况下,裂缝之间的连接性增强,表明碳化再生混凝土微粉的掺入有效降低了水泥基材料的早期塑性开裂程度。 展开更多
关键词 塑性收缩 数字图像 水泥净浆 碳化再生混凝土微粉 裂缝分布 最大主应变
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