期刊文献+
共找到540篇文章
< 1 2 27 >
每页显示 20 50 100
TiO_(2)和ZrO_(2)对金尾矿基微晶玻璃的析晶行为与结构影响
1
作者 祝旭帆 郝晓栋 +2 位作者 周亚辉 李浩 邓磊波 《中国陶瓷》 北大核心 2026年第1期52-61,共10页
中国工业的快速发展对矿产资源的需求逐年增加,导致大量尾矿排放与堆存,带来了资源浪费与环境污染问题。本文以金尾矿为主要原料,TiO_(2)和ZrO_(2)为晶核剂,利用熔融法制得微晶玻璃材料。采用DSC、XRD、SEM、热台显微镜及红外光谱等手段... 中国工业的快速发展对矿产资源的需求逐年增加,导致大量尾矿排放与堆存,带来了资源浪费与环境污染问题。本文以金尾矿为主要原料,TiO_(2)和ZrO_(2)为晶核剂,利用熔融法制得微晶玻璃材料。采用DSC、XRD、SEM、热台显微镜及红外光谱等手段,研究了TiO_(2)/ZrO_(2)对微晶玻璃析晶行为、结构和性能的影响。结果表明,随着TiO_(2)/ZrO_(2)质量比增加,玻璃的析晶活化能呈现下降趋势,范围在235~334 kJ/mol;析晶指数范围为3.1~5.5,以二维/三维整体晶化为主。制得的微晶玻璃主晶相为堇青石,且随着热处理温度升高,伴随有尖晶石、氧化锆和蓝宝石相等次晶相析出。当TiO_(2)和ZrO_(2)的质量比为3.5/2.0时,基础玻璃经1000℃热处理得到的微晶玻璃密度为2.61 g/cm^(3)、硬度为8.09 GPa,利用金尾矿制得的微晶玻璃在建筑材料领域具有潜在的应用前景。 展开更多
关键词 金尾矿 微晶玻璃 TiO_(2) ZrO_(2) 析晶
原文传递
负载骨形态发生蛋白-2的生物活性玻璃水凝胶治疗骨缺损的效果研究
2
作者 田斌 宋嵬 +3 位作者 秦明凯 孙卫国 梁树永 闫旭升 《医学理论与实践》 2026年第1期1-5,共5页
目的:以生物活性玻璃(BG)水凝胶为载体,负载骨形态发生蛋白-2(BMP-2),构建一种高效能、经济的BMP-2/BG复合水凝胶用于骨组织修复,为临床骨缺损治疗提供理论依据。方法:将40只SD大鼠随机分配至4个实验组(A、B、C、D组),每组10只,于右侧... 目的:以生物活性玻璃(BG)水凝胶为载体,负载骨形态发生蛋白-2(BMP-2),构建一种高效能、经济的BMP-2/BG复合水凝胶用于骨组织修复,为临床骨缺损治疗提供理论依据。方法:将40只SD大鼠随机分配至4个实验组(A、B、C、D组),每组10只,于右侧股骨中段建立标准化3mm节段性骨缺损模型。A组骨缺损区域植入BMP-2/BG复合水凝胶材料,B组局部注射BMP-2溶液(浓度2μg/μL),C组单纯填充BG,D组保持空白缺损作为阴性对照。结果:X线检查结果显示,术后4周A组材料已完全降解,骨皮质实现连接,骨缺损得到完全修复;B组材料大部分降解,伴有大量骨痂形成,骨缺损大部分得到修复;C组材料部分降解,出现少量骨密度影和少量骨痂,骨髓腔基本恢复通畅,骨缺损得到部分修复;D组骨折断端呈现光滑硬化并吸收,无新骨质生长,骨髓腔封闭,形成骨不连现象。组织学检查结果表明,术后4周A组材料完全降解,伴随大量骨细胞形成,骨痂完成塑形,骨缺损得以修复;B组材料大部分降解,骨细胞形成明显,骨缺损大部分得到修复;C组材料部分降解,骨细胞有所形成,并出现少许新生骨组织,骨缺损得到部分修复;D组仅见少量骨细胞形成,骨缺损断端有大量纤维组织增生,未见新骨形成,断端呈现骨不连状态。生物力学检测显示,术后2、3、4周A、B、C组与D组比较,抗压强度均显著高于D组(P<0.05)。结论:BMP-2/BG复合水凝胶在修复长骨骨缺损方面具有潜在的临床应用价值,为临床选择骨缺损修复材料提供了理论支撑。 展开更多
关键词 生物活性玻璃 重组人骨形态发生蛋白-2 骨组织工程 骨缺损修复 生物材料
暂未订购
Effects of MgO/SiO_(2) Ratio on Crystallization Properties of MgSiO_(3) and Mg_(2)SiO_(4) Nanocrystals in Aluminosilicate Glasses
3
作者 GENG Kangkang GUO Yunlan LIU Chao 《Journal of Wuhan University of Technology(Materials Science)》 2025年第4期975-983,共9页
Transparent glass-ceramics containing MgSiO_(3)and/or Mg_(2)SiO_(4)nanocrystals were prepared.Effects of MgO/SiO_(2)ratio on crystallization properties of MgSiO_(3)and Mg_(2)SiO_(4)nanocrystals were investigated.When ... Transparent glass-ceramics containing MgSiO_(3)and/or Mg_(2)SiO_(4)nanocrystals were prepared.Effects of MgO/SiO_(2)ratio on crystallization properties of MgSiO_(3)and Mg_(2)SiO_(4)nanocrystals were investigated.When the MgO/SiO_(2)ratio is relatively low,crystallization of MgSiO_(3)is favored,whereas a higher MgO/SiO_(2)ratio tends to promote the crystallization of Mg_(2)SiO_(4).Glass-ceramics are transparent in the visible range due to the small size of the precipitated nanocrystals.Replacing SiO_(2)with MgO results in an increase in Vickers hardness,and the Vickers hardness can be further enhanced through the precipitation of MgSiO_(3)and Mg_(2)SiO_(4)nanocrystals.The findings presented herein are meaningful for the preparation of highly transparent glass-ceramics containing MgSiO_(3)and Mg_(2)SiO_(4)nanocrystals. 展开更多
关键词 glass-CERAMIC MgSiO_(3) Mg_(2)SiO_(4) glass structure vickers hardness
原文传递
Energy transfer study on dense and transparent Eu^(3+)/Tb^(3+)-coactivated TeO_(2)-Gd_(2)O_(3)-WO_(3)-ZnO glass scintillators
4
作者 Miaochun Wu Meidong Yu +7 位作者 Xi Cheng Guifang Zhang Jiandi Liu Zuofu Hu Yufeng Wen Jiuzhi Cui Zhuohao Xiao Xin-Yuan Sun 《Journal of Rare Earths》 2025年第7期1364-1372,共9页
Tb^(3+)-,Eu^(3+)-activated and Eu^(3+)/Tb^(3+)-coactivated TeO_(2)-Gd_(2)O_(3)-WO_(3)-ZnO(TGWZ)glasses with the density of about 6.60 g/cm^(3)were successfully synthesized by a melt-quenching method.These glass scinti... Tb^(3+)-,Eu^(3+)-activated and Eu^(3+)/Tb^(3+)-coactivated TeO_(2)-Gd_(2)O_(3)-WO_(3)-ZnO(TGWZ)glasses with the density of about 6.60 g/cm^(3)were successfully synthesized by a melt-quenching method.These glass scintillato rs show a line transmittance coefficient in excess of 80%in the strongest green-emitting regions of Tb^(3+)ions.The optimal concentration of incorporated Tb^(3+)and Eu^(3+)ions and the corresponding interaction mechanism are determined in both Tb^(3+)and Eu^(3+)-activated TGWZ glasses.Compared with that of Tb^(3+)-activated TGWZ glasses,the luminous intensity of the Eu^(3+)/Tb^(3+)-coactivated TGWZ glasses is enhanced by 7.6 times,which can be attributed to the effective energy transfer(ET)from Tb^(3+)to Eu^(3+)ions.By investigating the concentration-dependent optical properties of these glasses including transmittance,photoluminescence(excitation and emission spectra),photoluminescence decay,the mechanism of ET in Eu^(3+)/Tb^(3+)-coactivated TGWZ glass scintillators is obtained.Also,the potential scintillation properties of the TGWZ glass scintillators are discussed by X-excited luminescence(XEL)sp ectra and the corresponding X-ray dose response tailored by various current intensity within 0-240μA(which corresponds to 0-40000 mGy). 展开更多
关键词 Rare earths TeO_(2)-Gd_(2)O_(3)-WO_(3)-ZnO glass scintillator Photoluminescence Energy transfer X-excited luminescence Dose response
原文传递
HCL Net: Deep Learning for Accurate Classification of Honeycombing Lung and Ground Glass Opacity in CT Images
5
作者 Hairul Aysa Abdul Halim Sithiq Liyana Shuib +1 位作者 Muneer Ahmad Chermaine Deepa Antony 《Computers, Materials & Continua》 2026年第1期999-1023,共25页
Honeycombing Lung(HCL)is a chronic lung condition marked by advanced fibrosis,resulting in enlarged air spaces with thick fibrotic walls,which are visible on Computed Tomography(CT)scans.Differentiating between normal... Honeycombing Lung(HCL)is a chronic lung condition marked by advanced fibrosis,resulting in enlarged air spaces with thick fibrotic walls,which are visible on Computed Tomography(CT)scans.Differentiating between normal lung tissue,honeycombing lungs,and Ground Glass Opacity(GGO)in CT images is often challenging for radiologists and may lead to misinterpretations.Although earlier studies have proposed models to detect and classify HCL,many faced limitations such as high computational demands,lower accuracy,and difficulty distinguishing between HCL and GGO.CT images are highly effective for lung classification due to their high resolution,3D visualization,and sensitivity to tissue density variations.This study introduces Honeycombing Lungs Network(HCL Net),a novel classification algorithm inspired by ResNet50V2 and enhanced to overcome the shortcomings of previous approaches.HCL Net incorporates additional residual blocks,refined preprocessing techniques,and selective parameter tuning to improve classification performance.The dataset,sourced from the University Malaya Medical Centre(UMMC)and verified by expert radiologists,consists of CT images of normal,honeycombing,and GGO lungs.Experimental evaluations across five assessments demonstrated that HCL Net achieved an outstanding classification accuracy of approximately 99.97%.It also recorded strong performance in other metrics,achieving 93%precision,100%sensitivity,89%specificity,and an AUC-ROC score of 97%.Comparative analysis with baseline feature engineering methods confirmed the superior efficacy of HCL Net.The model significantly reduces misclassification,particularly between honeycombing and GGO lungs,enhancing diagnostic precision and reliability in lung image analysis. 展开更多
关键词 Deep learning honeycombing lung ground glass opacity Resnet50v2 multiclass classification
在线阅读 下载PDF
微量Fe_(2)O_(3)对无碱玻璃性能影响研究
6
作者 柏晓强 邢文忠 +2 位作者 沈林 章林 黄鑫雨 《玻璃》 2026年第2期31-35,共5页
针对玻璃纤维生产时所用高岭土与叶腊石原料中Fe_(2)O_(3)成分波动,研究Fe_(2)O_(3)对玻璃纤维用无碱玻璃性能的影响,包括玻璃的黏度与析晶、高温电阻率、玻璃热膨胀与热稳定性能、玻璃折射率与颜色。以0.5%质量含量的Fe_(2)O_(3)替代Si... 针对玻璃纤维生产时所用高岭土与叶腊石原料中Fe_(2)O_(3)成分波动,研究Fe_(2)O_(3)对玻璃纤维用无碱玻璃性能的影响,包括玻璃的黏度与析晶、高温电阻率、玻璃热膨胀与热稳定性能、玻璃折射率与颜色。以0.5%质量含量的Fe_(2)O_(3)替代SiO2,结果表明:(1)玻璃液成形温度Tlgη=3降低10℃,成形范围ΔT基本一致;(2)1500℃时高温电阻率ρ1500℃降低1.8Ω·cm;(3)热膨胀系数α、转变温度Tg与膨胀软化点Td接近,热稳定性相当;(4)玻璃折射率n略微提高,亮度L大幅降低,绿值a、黄值b大幅增加,颜色差异明显。因此在特定应用领域,玻璃纤维中依旧需控制Fe_(2)O_(3)等着色成分,以避免纤维累积而造成色差。 展开更多
关键词 Fe_(2)O_(3) 无碱玻璃 黏度 高温电阻率 热稳定性 颜色
在线阅读 下载PDF
Al(PO_(3))_(3)-Ba(PO_(3))_(2)对Tm^(3+)掺杂氟磷酸盐玻璃1.8μm荧光的影响
7
作者 王毅 岳玉 +1 位作者 于海斌 高俊杰 《山东建筑大学学报》 2026年第1期104-110,共7页
1.8μm波段的中红外激光在医学手术、环境监测和军事通信等领域具有应用前景,开发性能优异的1.8μm波段激光增益材料具有现实意义。文章利用高温熔融法制备了掺Tm^(3+)的Al(PO_(3))_(3)-Ba(PO_(3))_(2)体系氟磷酸盐玻璃样品,研究样品的... 1.8μm波段的中红外激光在医学手术、环境监测和军事通信等领域具有应用前景,开发性能优异的1.8μm波段激光增益材料具有现实意义。文章利用高温熔融法制备了掺Tm^(3+)的Al(PO_(3))_(3)-Ba(PO_(3))_(2)体系氟磷酸盐玻璃样品,研究样品的热稳定性、发光特性以及Judd-Ofelt参数。结果表明:Tm^(3+)在1.8μm发光中起到关键作用,表现出强烈的中红外发光特性;Al(PO_(3))_(3)含量的增加有利于增强玻璃网络的连接性,从而进一步改善玻璃的热稳定性和发光效率;掺Tm^(3+)的氟磷酸盐玻璃具有优异的荧光特性和热学性能,是一种优异的1.8μm波段中红外激光材料。 展开更多
关键词 Al(PO_(3))_(3)-Ba(PO_(3))_(2)系统 氟磷酸盐玻璃 1.8μm荧光 中红外荧光特性
在线阅读 下载PDF
Effect of Fe_2O_3 on non-isothermal crystallization of CaO-MgO-Al_2O_3-SiO_2 glass 被引量:6
8
作者 郁青春 燕春培 +3 位作者 邓勇 冯月斌 刘大春 杨斌 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第7期2279-2284,共6页
The crystallization behavior and kinetics of CaO-MgO-Al2O3 SiO2(CMAS) glass with the Fe2O3 content ranging from zero to 5%were investigated by differential scanning calorimetry(DSC).The structure and phase analyse... The crystallization behavior and kinetics of CaO-MgO-Al2O3 SiO2(CMAS) glass with the Fe2O3 content ranging from zero to 5%were investigated by differential scanning calorimetry(DSC).The structure and phase analyses were made by Fourier transform infrared spectroscopy(FT-IR) and X-ray diffraction(XRD).The experiment results show that the endothermic peak temperature about 760℃ is associated with transition and the exothermic peak temperature about 1000℃ is associated with crystallization.The crystallization peak temperature decreases with increasing the Fe203 content.The crystallization mechanism is changed from two-dimensional crystallization to one-dimensional growth,and the intensity of diopside peaks becomes stronger gradually.There is a saltation for the crystallization temperature with the addition of 0.5%Fe2O3 due to the decomposition of Fe2O3.Si-O-Si,O-Si-O and T-O-T(T=Si,Fe,Al) linkages are observed in Fe2O3-CaO-MgO-Al2O3-SiO2 glass. 展开更多
关键词 CaO-MgO-Al2O3-SiO2 glass FE2O3 DIOPSIDE CRYSTALLIZATION kinetics
在线阅读 下载PDF
锐钛矿结构TiO_2/glass膜光催化作用的研究.紫外灯照射下水中苯酚的光催化降解 被引量:3
9
作者 吴月顺 张延昌 +3 位作者 许青 王娅娟 郑清华 买光昕 《化学世界》 CAS CSCD 北大核心 2002年第6期289-289.,共1页
以溶胶 -凝胶法制得锐钛矿型结构的 Ti O2 /glass膜。在紫外灯照射下研究了膜对水中苯酚的光催化降解作用 ,研究证明 ,灯距控温反应器 1 0 cm时的液外照射 ,可使苯酚降解率达 70 %以上 ;在 H2 O2 存在下效果更佳 ;
关键词 锐肽矿结构 光催化降解 溶胶-凝胶法 TiO2/glass 苯酚 紫外光 污水处理
在线阅读 下载PDF
TiO_2-SO_4^(2-)/Glass光催化降解甲基橙溶液的方法 被引量:2
10
作者 赵谦 姜廷顺 《环境科学与技术》 CAS CSCD 2003年第4期56-58,共3页
研究以平玻璃和毛玻璃为载体,用Sol gel法制备附载型TiO2/Glass光催化剂,并用H2SO4溶液浸泡制得TiO2 SO2-4/Glass光催化剂。考察了光催化剂对甲基橙溶液的光催化性能。结果表明:平玻璃附载TiO2的光催化活性低于毛玻璃附载TiO2的光催化... 研究以平玻璃和毛玻璃为载体,用Sol gel法制备附载型TiO2/Glass光催化剂,并用H2SO4溶液浸泡制得TiO2 SO2-4/Glass光催化剂。考察了光催化剂对甲基橙溶液的光催化性能。结果表明:平玻璃附载TiO2的光催化活性低于毛玻璃附载TiO2的光催化活性。且毛玻璃附载TiO2经连续6次使用后光催化活性基本不变。毛玻璃附载TiO2经H2SO4溶液处理后光催化活性明显升高。 展开更多
关键词 TiO2-SO4^2-/glass 光催化氧化 甲基橙
在线阅读 下载PDF
K_(2) O-PbO-SiO_(2)系古玻璃的复仿制及组成对玻璃结构和性能的影响研究
11
作者 赵婷 翟佳豪 +1 位作者 朱建锋 秦毅 《材料导报》 北大核心 2025年第24期52-58,共7页
以碳酸钾(K_(2)CO_(3))、四氧化三铅(Pb_(3)O 4)以及二氧化硅(SiO_(2))为主体原料,氧化铜(CuO)作为着色剂,氟化钙(CaF_(2))作为助熔剂,设计了不同m(SiO_(2))/m(CaO+CaF_(2))比值的玻璃成分。采用熔融-浇注成型法成功实现了K_(2)O-PbO-Si... 以碳酸钾(K_(2)CO_(3))、四氧化三铅(Pb_(3)O 4)以及二氧化硅(SiO_(2))为主体原料,氧化铜(CuO)作为着色剂,氟化钙(CaF_(2))作为助熔剂,设计了不同m(SiO_(2))/m(CaO+CaF_(2))比值的玻璃成分。采用熔融-浇注成型法成功实现了K_(2)O-PbO-SiO_(2)系古代玻璃的复仿制。在此基础上,研究了m(SiO_(2))/m(CaO+CaF_(2))比值保持不变时,CaF_(2)含量对该体系古代玻璃物相组成、网络结构、微观形貌、色度及显微硬度的影响规律;阐明了CaF_(2)在古代玻璃中的作用机制。结果表明,当m(SiO_(2))/m(CaO+CaF_(2))比值为4.252时,复仿制玻璃最接近古代玻璃。在控制比值为4.252不变的基础上,当CaF_(2)含量小于6%(质量分数)时,CaF_(2)充当助熔剂,玻璃呈透明状,且颜色为深蓝色;当CaF_(2)含量大于6%时,Si-O键被破坏,玻璃体系的化学稳定性下降,成核位点增多,析出细小的CaF_(2)晶体,玻璃透光率下降,此时玻璃偏绿色;其硬度随CaF_(2)含量的增加略有降低,从5.0 GPa降低至4.25 GPa。结合优良遮光性、外观颜色及合适的硬度要求,CaF_(2)含量为6%时效果最佳。这对于K_(2)O-PbO-SiO_(2)系古玻璃的科学认知及后续的保护修复具有重要的理论和实践意义。 展开更多
关键词 K_(2)O-PbO-SiO_(2) 复仿制 氟化钙(CaF_(2)) 古代玻璃 文物保护
在线阅读 下载PDF
用HF/H_(2)SO_(4) 混合酸从废弃微晶玻璃中提取锂
12
作者 陈成 严群 +3 位作者 唐学昆 刘子帅 周贺鹏 李恩昊 《湿法冶金》 北大核心 2025年第3期316-326,共11页
针对火法回收固废中锂存在的能耗高、效率低、回收困难且易造成二次污染等问题,研究了以HF/H_(2)SO_(4) 混合酸为浸出剂,对废弃锂铝硅系(Li_(2)O-Al_(2)O_(3) -SiO_(2),LAS)微晶玻璃样品中的锂进行强化浸出。考察了液固体积质量比、硫... 针对火法回收固废中锂存在的能耗高、效率低、回收困难且易造成二次污染等问题,研究了以HF/H_(2)SO_(4) 混合酸为浸出剂,对废弃锂铝硅系(Li_(2)O-Al_(2)O_(3) -SiO_(2),LAS)微晶玻璃样品中的锂进行强化浸出。考察了液固体积质量比、硫酸质量浓度、浸出温度、浸出时间、搅拌速度、原料粒径等因素对锂浸出率的影响,以及液固体积质量比、浸出温度对铝、硅浸出率的影响,并探讨了锂浸出动力学。结果表明:在m(样品)∶V(HF)∶V(H_(2)SO_(4) )=1∶2.5∶2、粒径为-0.074 mm、硫酸质量浓度900 g/L、浸出温度60℃、浸出时间120 min、搅拌速度200 r/min最佳条件下,锂浸出率接近99%,与其他影响因素相比,HF与样品的液固体积质量比和浸出温度对锂浸出率影响较大;相较而言,HF与样品的液固体积质量比和浸出温度对铝浸出的影响比硅大;锂浸出符合未反应核收缩模型,反应表观活化能E_(a)=39.53 kJ/mol,锂浸出率受化学反应-内扩散混合控制。研究结果可为废弃LAS微晶玻璃中有价元素回收再利用提供理论指导。 展开更多
关键词 废弃微晶玻璃 HF H_(2)SO_(4) 提取 动力学
在线阅读 下载PDF
Regeneration of the deactivated TiO_2-ZrO_2-CeO_2 /ATS catalyst for NH_3-SCR of NO_x in glass furnace 被引量:10
13
作者 杨波 沈岳松 +1 位作者 沈树宝 祝社民 《Journal of Rare Earths》 SCIE EI CAS CSCD 2013年第2期130-136,共7页
Larger amounts of alkalis, alkali earth metals and sulfides in flue gas from glass furnace were easier to deactivate selective catalytic reduction (SCR) catalyst compared to the flue gases from other stationary sour... Larger amounts of alkalis, alkali earth metals and sulfides in flue gas from glass furnace were easier to deactivate selective catalytic reduction (SCR) catalyst compared to the flue gases from other stationary sources. Catalyst regeneration has been an emerging research topic for flue gas denitrification in glass furnace. Regeneration of the deactivated TiO2-ZrO2-CeO2 /Al2TiO 5 -TiO2-SiO2 (ATS) complex phase ceramics catalysts used for NH3 -SCR of NO x in glass furnace was studied in this work. Effects of regeneration methods, including washing with different aqueous solutions and sulfuric acid, thermal regeneration, thermal reduction regeneration, and thermal regeneration with SO2 , on catalytic performance were comparatively investigated. In comparison of catalytic activities between the catalysts before and after regeneration, results showed that washing was the most effective regeneration method, and the sulfuric acid concentration of the washing solution was an important factor. Washing time directly affected catalyst regeneration efficiency and catalyst life. The regenerated TiO2-ZrO2 -CeO2 /ATS catalyst regained more than 90% NO conversion after being washed with 10 wt.% H2SO4 for 30 min. 展开更多
关键词 deactivated TiO 2 -ZrO 2 -CeO 2 /ATS regeneration method catalytic performance glass furnace rare earths
原文传递
玻璃纤维复合材料结构对CO_(2)管道外部止裂性能的影响
14
作者 陈兵 付子言 +2 位作者 徐梦林 王香增 齐文娇 《油气储运》 北大核心 2025年第1期26-36,共11页
【目的】碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)是目前中国实现“双碳”战略目标的关键技术,CO_(2)管输则是实现规模化CCUS的重要环节。CO_(2)管道本身存在各类缺陷,受CO_(2)特殊的减压特性及管道内压的影响... 【目的】碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)是目前中国实现“双碳”战略目标的关键技术,CO_(2)管输则是实现规模化CCUS的重要环节。CO_(2)管道本身存在各类缺陷,受CO_(2)特殊的减压特性及管道内压的影响,管道缺陷发展成初始裂纹并产生延性扩展的风险大大增加,严重威胁管道运输安全。【方法】为使CO_(2)管道实现有效止裂,采用有限元软件ANSYS建立玻璃纤维复合材料外部止裂结构模型,基于EPRI(Electric Power Research Institute)的J积分理论公式与应力分布理论计算公式对所建模型进行可靠性验证,分析外部止裂结构铺设角度、铺设厚度、铺设长度、管道径厚比以及裂纹尺寸等因素对其止裂性能的影响,最后结合延长油田400×10^(4) t/a超临界CO_(2)输送方案的L21管道对外部止裂结构模型进行评估。【结果】玻璃纤维复合材料外部止裂结构可以有效转移并承担管道所受应力,降低管道发生延性断裂的风险;止裂结构铺设厚度、铺设长度、管道径厚比及裂纹尺寸均与止裂性能正相关,而铺设角度则存在最优值。止裂结构的止裂性能由各影响因素共同决定,其中铺设厚度的影响最大,而铺设角度的影响最小。止裂结构的最佳性能尺寸为:铺设厚度与管道壁厚相等、铺设长度为0.8倍管道外径、铺设角度为60°。【结论】铺设厚度为12 mm、长度为326 mm的外部止裂结构可有效阻止L21管道的延性断裂,研究结果可为外部止裂结构的设计提供理论基础与参考范例。 展开更多
关键词 CCUS 止裂结构 CO_(2)管道 玻璃纤维 止裂性能
原文传递
Preparation and Spectra Properties of BaO-Al_2O_3-P_2O_5-Sm_2O_3 System Protection Glasses 被引量:10
15
作者 张其土 孟献丰 +2 位作者 王丽熙 陆春华 许仲梓 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第z2期207-210,共4页
The forming-regions of phosphate glasses doped with high Sm2O3 contents were studied by two step melting method. The relationship between absorption spectrum and rare earth contents was also discussed. The spectra of ... The forming-regions of phosphate glasses doped with high Sm2O3 contents were studied by two step melting method. The relationship between absorption spectrum and rare earth contents was also discussed. The spectra of BASP glasses were measured by spectrophotometer. The results show that the forming regions will shrink with the increase of Al2O3 and it is difficult to form glass when [PO4]/[AlO4] < 2. The forming regions tend to be a closed elliptical, and the intensity of characteristic absorption peak increases gradually with the increase of Sm2O3, the absorption lines broadens non-uniformly and there is approximate linear relation between optical density at the 1064 nm wavelength and Sm2O3 content. 展开更多
关键词 laser protection glass SM2O3 phosphate glass glass forming-region optical density rare earths
在线阅读 下载PDF
Structure of Bi_2O_3-ZnO-B_2O_3 system low-melting sealing glass 被引量:7
16
作者 何峰 程金树 +1 位作者 邓大伟 王俊 《Journal of Central South University》 SCIE EI CAS 2010年第2期257-262,共6页
Bi2O3-ZnO-B2O3 system glass is a kind of lead-free low melting sealing glasses. The structure of Bi2O3-ZnO-B2O3 system low-melting sealing glass was investigated by DSC, FT-IR, XRD and SEM. The results show that with ... Bi2O3-ZnO-B2O3 system glass is a kind of lead-free low melting sealing glasses. The structure of Bi2O3-ZnO-B2O3 system low-melting sealing glass was investigated by DSC, FT-IR, XRD and SEM. The results show that with the increase of B2O3 content, the transition temperature Tg and softening temperature Tf of Bi2O3-ZnO-B2O3 system low-melting sealing glasses increase, which leads to the liquid phase precipitation temperature increasing and promotes the structure stability in the glass. With increasing the heat treatment temperature, a large number of liquid phases appear in samples and the sinter efficiency of the samples increases. The FT-IR spectra of the glasses show the presence of some bands that are assigned to vibrations of Bi--O bond from [BO3] pyramidal and [BiO6] octahedral units and B--O from [BO3] and [BO4] units. With the decrease of B203 content, the crystallization tendency of the glass increases. In glass samples Bl and B〉 crystallization starts at 460 ℃ and 540 ℃, respectively. Both of them precipitate Bi24B2O39 phases. 展开更多
关键词 Bi2O3-ZnO-B2O3 system glass low-melting sealing glass transition temperature softening temperature
在线阅读 下载PDF
THE STRUCTURE AND PROPERTIES OF Li_2O-Al_2O_3-SiO_2LOW EXPANSION GLASS CERAMICS CONTAINING B_2O_3 被引量:8
17
作者 XIAO Jing LI Hong CHENG Jinshu Wuhan University of Technology Wuhan University of Metallurgy 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 1999年第1期41-45,共5页
Through measuring the coefficient of linear expansion, the structure and properties of the Li2O-Al2O3-SiO2 low expansion glass ceramics containing B2O3 are studied by JR and XRD. It is shoutn that the IR method is eff... Through measuring the coefficient of linear expansion, the structure and properties of the Li2O-Al2O3-SiO2 low expansion glass ceramics containing B2O3 are studied by JR and XRD. It is shoutn that the IR method is efficient in the study of the glass-ceramics structure. There is a " Boron abnormality" in the system which has an important influence on the properties of the glass-ceramics. 展开更多
关键词 boron abnormality Li2O-Al2O3-SiO2 system glass ceramics
在线阅读 下载PDF
锐钛矿结构TiO_2/glass膜光催化作用的研究Ⅱ——氘灯照射下亚甲基兰光催化分解 被引量:2
18
作者 陶秀峻 许 青 张瑞华 《泰安师专学报》 2001年第6期61-64,共4页
采用Sol-gel法制备了TiO2/glass薄膜,以氘灯作为光源,对微酸性溶液中的亚甲基兰进行光催化降解的实验研究.对溶液酸度、光源照射距离、照射时间等几个方面作用了初步探索.由光催化性能测试结果可知:TiO2薄膜能对亚甲基兰进行有效的光催... 采用Sol-gel法制备了TiO2/glass薄膜,以氘灯作为光源,对微酸性溶液中的亚甲基兰进行光催化降解的实验研究.对溶液酸度、光源照射距离、照射时间等几个方面作用了初步探索.由光催化性能测试结果可知:TiO2薄膜能对亚甲基兰进行有效的光催化降解. 展开更多
关键词 锐钛矿结构 TiO2/glass 氘灯 亚甲基兰 光催化分解
在线阅读 下载PDF
The Oxidation State of Sulfur Detected in Na_2O-CaO-SiO_2 Float Glass by X-ray Absorption Near Edge Structure Spectra 被引量:6
19
作者 孟政 JIANG Hong +3 位作者 HUANG Yourong LI Changjiu WANG Jinzhen CUI Zhu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第1期79-81,共3页
The oxidation state of sulfur is detected in Na20-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure (XANES) spectra at the sulfur K edge. The measured spectra show the only presence ... The oxidation state of sulfur is detected in Na20-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure (XANES) spectra at the sulfur K edge. The measured spectra show the only presence of S^6+ in the Na20-CaO-SiO2 float glass and the oxidation state of sulfur do not change with the increase of glass depth. It is also found that, after the melt has gone through the molten tin bath, the S^6+ is the dominant species, but S^2- is also present on both surfaces. It is not certain whether cation bonds to S^2- or not, because there are many cations dissolved in the melted tin which makes the spectrum complicated. 展开更多
关键词 XANES sulfur K-edge Na20-CaO-SiO2 float glass oxidation state sulfur speciation
原文传递
Optical properties of Eu^(2+)-doped strontium borate glasses containing F~– and Li^+ ions 被引量:1
20
作者 黄彦林 张基完 +1 位作者 王锡钢 姜传芳 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第4期490-494,共5页
In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence ... In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence (XEL), and luminescence decay curve of the as-prepared glasses were investigated at room temperature. The as-prepared glasses had two kinds of Eu ions, i.e., Eu^2+ and Eu^2+. Compared with the reported results of strontium borate glasses, Eu^2+ luminescence was enhanced in the studied strontium borate glasses coprepared with F^- and Li^+ ions. The coexisting of Li^+ or F^- in the borate glasses could create more negative defect Vsr″ and stabilize Eu^2+ ions, which might act as donor of electrons; For the F^- doping, the new center of B(O, F)4 (or BO3F) and BO2F2 units could be considered to be the distorted (BO4), which were needed as a rigid framework to stabilize the divalent rare earth ions. 展开更多
关键词 Eu^2 noncrystalline materials glassES LUMINESCENCE rare earths
在线阅读 下载PDF
上一页 1 2 27 下一页 到第
使用帮助 返回顶部