Accurately acquiring catalyst size and morphology is essential for supporting catalytic reaction process design and optimal control. We report an intelligent catalyst sizing and morphological classification method bas...Accurately acquiring catalyst size and morphology is essential for supporting catalytic reaction process design and optimal control. We report an intelligent catalyst sizing and morphological classification method based on the Mask-RCNN framework. A dataset of 9880 high-resolution images was captured by using a self-made fiber-optic endoscopic system for 13 kinds of silicoaluminophosphate-34 (SAPO-34) catalyst samples with different coke. Then there were approximately 877881 individual particles extracted from this dataset by our AI-based particle recognition algorithm. To clearly describe the morphology of irregular particles, we proposed a hybrid classification criterion that combines five different parameters, which are deformity, circularity, roundness, aspect ratio, and compactness. Therefore, catalyst morphology can be classified into two categories with four types. The first category includes regular types, such as the spherical, ellipsoidal, and rod-shaped types. And all the irregular types fall into the second category. The experimental results showed that a catalyst particle tends to be larger when its coke deposition increased. Whereas particle morphology remained primarily spherical and ellipsoidal, the ratio of each type varied slightly according to its coke. Our findings illustrate that this is a promising approach to be developing intelligent instruments for catalyst particle sizing and classification.展开更多
SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 pow...SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 powders on several occasions as well. Comparison and evaluation of various particle-sizing techniques have been made.展开更多
Principles of a novel submicron particle sizing technology are first introduced followed by experimental validation. The sizing was accomplished by coupling aerodynamic particle focusing and maximum ion measurement. E...Principles of a novel submicron particle sizing technology are first introduced followed by experimental validation. The sizing was accomplished by coupling aerodynamic particle focusing and maximum ion measurement. Experimental results showed that the prototype could detect particle sizes down to 40 nm in diameter. Comparison between the prototype and a scanning mobility particle sizer using identical polydisperse particles showed that the measurements agreed well for the tested particles.展开更多
In particle sizing by light extinction method, the regularization parameter plays an important role in applying regularization to find the solution to ill-posed inverse problems. We combine the generalized cross-valid...In particle sizing by light extinction method, the regularization parameter plays an important role in applying regularization to find the solution to ill-posed inverse problems. We combine the generalized cross-validation （GCV） and L-curve criteria with the Twomey-NNLS algorithm in parameter optimization. Numerical simulation and experimental validation show that the resistance of the newly developed algorithms to measurement errors can be improved leading to stable inversion results for unimodal particle size distribution.展开更多
Ultrasound spectrometry is one of very few methods that can size particles over the range 10 nm to I mm for optically opaque, undiluted materials. It has in-line, non-invasive capabilities which make it a serious cont...Ultrasound spectrometry is one of very few methods that can size particles over the range 10 nm to I mm for optically opaque, undiluted materials. It has in-line, non-invasive capabilities which make it a serious contender for use in industrial process monitoring, with the potential for 100% inspection. In aqueous systems, it is more sensitive to nanoparticles than to particles in the micrometre range upwards because the scattering power varies as the inverse square of particle diameter, making it suitable for the detec- tion of nanoparticles in concentrated, mixed systems. Future development of ultrasound spectrometers suitable for widespread laboratory and industrial use depends on meeting the challenges of complex data interpretation and the need for considerable know how. In this review we provide a brief account of ultrasound propagation and scattering theory which underlies the ultrasound spectrometer, describe several types of spectrometer and demonstrate its successful use in the characterization of colloidal silica, whole milk and protein solutions.展开更多
This paper discusses two problems in in-line particle sizing when using light fluctuation method. First, by retrieving the ratio of particle concentrations at different time, the intensity of incident light is obtaine...This paper discusses two problems in in-line particle sizing when using light fluctuation method. First, by retrieving the ratio of particle concentrations at different time, the intensity of incident light is obtained. There exists narrow error between the calculated and pre-detected value of the intensity of incident light. Secondly, by combining spectrum analysis with Gregory＇s theory, a multi-sub-size zone model is proposed, with which the relationship between the distribution of turbidity and the particle size distribution （PSD） can be established, and an algorithm developed to determine the distribution of turbidity. Experiments conducted in the laboratory indicate that the measured size distribution of pulverized coal conforms well with the imaging result.展开更多
The combination of laser diffraction with upstream sampling realized a break-through for the in- and on-line particles size analysis in industrial applications. Today, the combination of representative sampling, dry d...The combination of laser diffraction with upstream sampling realized a break-through for the in- and on-line particles size analysis in industrial applications. Today, the combination of representative sampling, dry dispersion, particle size analysis by laser diffraction and integrated feedback of the sample is well accepted in many industrial applications. No more interactions of the user are required, and for standard applications the on-line monitoring of particle sizes became nearly as simple as the monitoring of any other process parameter. The increase of inspection interval from 24-hour operation to months has increased user confidence in this technology, and industries with more demanding measurement requirements are seeking to benefit from this performance. This challenge could not be solved with simple scale-ups or scale-downs. New solutions had to be found for the sampling system, the measuring sensor, the adaptation to the environmental conditions and the processing of fast growing volume of data.展开更多
In this study,an artificial intelligence-based machine vision system was developed for in-line particle size analysis during the pellet layering process.Drug-layered pellets were produced by coating microcrystalline c...In this study,an artificial intelligence-based machine vision system was developed for in-line particle size analysis during the pellet layering process.Drug-layered pellets were produced by coating microcrystalline cellulose cores with an ibuprofen-containing layering liquid until the target drug content was achieved.Drug content increases with pellet size;therefore,particle size monitoring can ensure product safety and quality.The direct imaging system,consisting of a rigid endoscope,a light source,and a high-speed camera,provides real-time information about pellet size and layer uniformity,enabling timely intervention in the case of out-of-spec products.A convolutional neural network-based instance segmentation algorithm was employed to detect particles in focus,ensuring that pellet size could be accurately determined despite the dense flow of the particles.After training the model,the performance of the developed system was assessed by analysing the particle size distribution of pellet cores with variable sizes within the 250 e850 mm size range.The endoscopic system was tested in-line at a larger scale during the drug layering of inert pellet cores.The particle size data acquired in real time with the endoscopic imaging system corresponded with the reference methods,demonstrating the feasibility of the proposed machine vision-based method as a process analytical technology tool for in-line process monitoring.展开更多
The aluminum hydroxide adjuvant possesses a poorly crystalline boehmite (PCB) structure, the stability of which is significantly affected by storage conditions. In the present study, we conducted a comprehensive inves...The aluminum hydroxide adjuvant possesses a poorly crystalline boehmite (PCB) structure, the stability of which is significantly affected by storage conditions. In the present study, we conducted a comprehensive investigation into the structural and quality alterations of aluminum hydroxide adjuvants under varying temperature conditions over time. Three batches of the adjuvant were stored at 2–8℃, 18–25℃, and 37℃, respectively, for 6 months. Key parameters, including X-ray diffraction patterns, pH, isoelectric point (pI), adsorption capacity, and average particle size, were analyzed to assess the impact of storage temperatures. X-ray diffraction analysis confirmed the PCB structure of the aluminum hydroxide adjuvant. Notably, after 1 month of storage at 37℃, new diffraction peaks emerged at 18.2 °2θ, with their intensity increasing progressively over time. Concurrently, the largest decreases in pI and pH were observed, measuring 0.78 and 1.33, respectively. In contrast, adjuvants stored at 2–8℃ for 6 months exhibited only faint diffraction peaks at 18.2 °2θ, indicating minor structural changes. Under these conditions, the reductions in pI and pH were comparatively smaller, at 0.43 and 0.80, respectively. The average particle size of the adjuvants remained within 110–140 nm across all storage conditions. Additionally, the aluminum hydroxide adjuvant consistently demonstrated a high protein adsorption capacity, approximately 8 mg BSA/mg Al^(3+), with no statistically significant differences in adsorption rates observed among the different temperature conditions (P > 0.05). These findings highlighted the remarkable adsorption efficiency of nanoparticle aluminum hydroxide adjuvants throughout storage, reinforcing their potential as superior vaccine adsorbents. However, elevated storage temperatures were shown to accelerate structural aging, promoting the formation of highly crystalline phases such as gibbsite or bayerite, which could compromise the stability and quality of the adjuvant.展开更多
The particle size distribution plays a crucial role in the transportation and deposition of eroded sediments.Gaining insights into the related sorting mechanism can significantly enhance our understanding of such proc...The particle size distribution plays a crucial role in the transportation and deposition of eroded sediments.Gaining insights into the related sorting mechanism can significantly enhance our understanding of such processes.In this study,sand-covered slopes were examined.A controlled indoor rainfall simulation was conducted on loess slopes with a 12°incline and a rainfall intensity of 1.5 mm/min.These slopes were then covered with sand layers of varying thicknesses—0.5,1.0,and 1.5 cm—to observe their effects.The findings have revealed that as the thickness of the sand cover increases,the content of sediment particles smaller than 0.054 mm decreases.In contrast,the content of particles larger than 0.054 mm increases after the sixth minute of runoff.The eroded sediment was predominantly composed of silt.During the inter-rill erosion stage,runoff primarily transported particles larger than 0.054 mm.However,in the subsequent rill erosion and combined rill and inter-rill erosion stages,the runoff predominantly carried finer particles,smaller than 0.054 mm.Moreover,the presence of the sand layer significantly influenced the size and form of the eroded sediment particles.Initially,during the first 10 min of runoff,the eroded particles were predominantly larger than 0.054 mm.After this period,however,the particle size shifted,with the majority of particles being smaller than 0.054 mm.This study highlights the intricate relationship between sediment sorting,the thickness of sand covers,and the dynamics of sediment transport under rainfall-induced erosion.展开更多
Brake wear particle(BWP)emissions are considered one of the dominant sources of particulate matter pollution in urban environments.BWP emissions have increased significantly under high-temperature conditions,emerging ...Brake wear particle(BWP)emissions are considered one of the dominant sources of particulate matter pollution in urban environments.BWP emissions have increased significantly under high-temperature conditions,emerging as a focal point of research interest.This study investigates the effect of brake temperatures on BWP emissions.The brake pad materials undergo violent decomposition and oxidation reactions and generate large amounts of incompletely oxidized organic products at temperatures above 475℃.These organic products cause particles below 200 nm to proliferate,and nanoparticles below 40 nm account for the largest contribution of total BWPs.When the friction surface temperature exceeds 475℃,the high-concentration BWPs below 200 nm will agglomerate into larger particles.High temperatures also cause the brake pad surface to delaminate and fragment into particles above 2.5μm.In addition,when the initial brake speed is above 160 km/h,or the brake pressure is above 7 bar,there is a sharp increase in particles below 200 nm.The results suggest that a significant number of nanoparticles below 40 nm are inferred to be generated as the flash temperature of the friction surface reaches the violent reaction temperature.This study provides guidelines for designing low-emission brake pads,as improving the high-temperature resistance of brake pad material components possibly reduces BWP generation.展开更多
High-steep waste dumps in open-pit mines frequently demonstrate complex particle-size distributions and fractal characteristics along their slopes,which have a significant impact on slope stability.This study takes th...High-steep waste dumps in open-pit mines frequently demonstrate complex particle-size distributions and fractal characteristics along their slopes,which have a significant impact on slope stability.This study takes the Dasuji South waste dump in Inner Mongolia as a case to quantify the fractal dimensions of soil-rock mixtures at various slope heights,and to clarify how these fractal properties govern shear strength and deformation behavior under overlying stress,thereby affecting the overall stability of the waste dump slope.Field sampling and laboratory tests were conducted to determine the particle-size composition and fractal dimensions while direct shear tests were conducted and revealed that lower fractal dimensions indicating coarser particle assemblages significantly enhance shear resistance.Complementary PFC_(2)D discrete element simulations demonstrate that slopes composed of lower-fractaldimension materials deform less and contain localized deformation zones,whereas higher-fractal-dimension slopes experience more extensive displacement and a heightened risk of landslides.These findings refine our understanding of the relationship between fractal grain-size distribution and slope stability,providing a robust theoretical basis for improved stability assessment and optimized support strategies in deep open-pit mining waste dumps,and ultimately aiding in more effective disaster prevention within geotechnical engineering.展开更多
Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stabili...Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stability and dynamical behaviour under external loading and environmental changes.This paper investigates the effect of particle size distribution and normal pressure on the mechanical response of a ballast bed.Grading curves of ballast layers with different sizes are illustrated to discuss their strength behaviour under various strains to deduce the significant effect on the direct shear performance of the ballast layer.Direct shear tests with different Particle Size Distribution(PSD)were reproduced using the Discrete Element Method(DEM).It is noticed that when the number of small-sized ballast increases,the shear strength and the friction angle increase to varying degrees under different normal pressures,with an average increase of 27%and 8%,respectively.When the number of large-sized ballast decreases,the shear strength and the friction angle decrease to varying degrees under different normal pressures,with an average decrease of 6%and 3%,respectively.展开更多
The increased risk of chronic diseases has led to increasing importance of coarse foods in daily life,but the inclusion of new ingredients has a great degree of influence on the structural characteristics and sensory ...The increased risk of chronic diseases has led to increasing importance of coarse foods in daily life,but the inclusion of new ingredients has a great degree of influence on the structural characteristics and sensory qualities of the food.The effects of five different particle size variations on the physicochemical characteristics,dough,and steamed bread structure of Flaxseed-based milk coproduct(FMC)were investigated.As the particle size decreases,the structure of the dough becomes denser due to an increase in water retention capacity and dissolution capacity,weakening the competition for dough moisture and allowing for an increase in air-holding capacity.The reduction in particle size increased the specific volume of the steamed bread,a decrease in the spread ratio,and an optimization of hardness and elasticity,as well as an increase in consumer acceptance of the FMC steamed bread.However,it is not the smaller the particle size,the higher the quality of steamed bread,appropriate reduction of particle size can improve the quality of steamed bread.In addition,the addition of FMC reduces fat digestion.Therefore,the present study proposes a method to change the particle size of FMC to optimize the quality of the steamed bread and to reduce fat digestibility by adding FMC.展开更多
This work used 5CrMnMo steel and titanium carbide(TiC)powders to fabricate particulate metal matrix composites(PMMCS).The composites’microstructure,hardness,and impact toughness were compared with four different tita...This work used 5CrMnMo steel and titanium carbide(TiC)powders to fabricate particulate metal matrix composites(PMMCS).The composites’microstructure,hardness,and impact toughness were compared with four different titanium carbide ceramic particle sizes.The phase composition and microstructure of composites were studied.Vickers hardness and Charpy impact tests were employed to analyze composites’hardness and impact ductility,respectively.The results showed that the four groups of composites are mainly composed of martensite,trace residual austenite,and titanium carbide(undissolved TiC and primary TiC particles).With the growth of the ceramic particle dimension in the composite layer,the number of primary titanium carbide ceramics gradually decreased.When the initial ceramic particle size was small,it tended to generate dendritic primary TiC,and when the particle size was large,it tended to generate polygons and ellipsoids.Furthermore,with the growth of titanium carbide ceramic particle dimension in the composites,the hardness of the composites decreased but the impact toughness of the composites rose first and then descended.When the ceramic particle size was 50-75μm,the composite had the highest hardness,and the impact energy of the composites was the highest,which is 8 J.This was because there were more undissolved titanium carbide ceramics in the composite,and there was a thicker matrix metal between the ceramic particles.展开更多
The high stress levels in tall tailings dams can lead to particle crushing.Understanding the compressibility and breakage characteristics of tailings particles will contribute to the advancement to the design and cons...The high stress levels in tall tailings dams can lead to particle crushing.Understanding the compressibility and breakage characteristics of tailings particles will contribute to the advancement to the design and construction processes of high-rise tailings dams,as well as the accurate evaluation of the stability of tailings storage facilities(TSFs).This paper presents the results of a series of detailed one-dimensional oedometer compression tests conducted to investigate the compression behavior and particle breakage of iron ore tailings(IOTs)collected from two typical TSFs,with different initial particle size distributions and a wide range of initial specific volumes,under effective vertical stresses of up to 4.8 MPa.The results show that the compression paths of the IOTs were slowly convergent,and this nontransitional mode of compression behavior experienced a significant amount of particle breakage.The relative breakage(Br)was used to quantify the amount of breakage and the input specific work(W)was adopted to evaluate the factors influencing Br.The initial breakage stress of the IOTs was less than 0.2 MPa.For the finer tailings,Br increased with increasing vertical stresses until it reached a threshold,after which Br tended to remain constant.However,coarser IOTs continued to experience crushing even at 4.8 MPa.The particle breakage in the coarser IOTs is much more significant than it in the finer IOTs overall.It was also observed that the tailings grains within the loose specimens broke more easily than those within the dense specimens.Additionally,three types of particle crushing modes were identified for IOTs under one-dimensional compression,namely,abrasion,chipping,and splitting.展开更多
The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emi...The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emissions or through new particle formation events.However,their variations during the lockdown period are under investigation.This study focuses on Luohe,a city on the southern edge of the North China Plain,analyzing the changes in PNC and its sources before,during,and after the COVID-19 lockdown.From March 25^(th)to May 31^(st),2022,real-time PNC measurements were conducted using a Scanning Mobility Particle Sizer for particle size.Results showed an 11.2%decrease in PNC during the lockdown compared to pre-lockdown and a 3.6%decrease compared to post-lockdown,indicating reduced local emissions and weakened regional transportation during the lockdown.Positive Matrix Factorization analysis identified six sources contributing to the total PNC,including photochemical nucleation,aged photochemical nucleation,gasoline vehicle emissions,diesel vehicle emissions,coal and biomass combustion,and secondary aerosols.The significant changes in source emissions indicate a substantially reduced traffic volume after the implementation of lockdown measures(2644.8#/cm^(3),2202.2#/cm^(3),2792.7#/cm^(3)).Concurrently,photochemical nucleation(310.1#/cm^(3),306.3#/cm^(3),393.1#/cm^(3))and photochemical nucleation aging(592.8#/cm^(3),744.1#/cm^(3),810.7#/cm^(3))exhibited increasing trends,while coal/biomass combustion(1656.6#/cm^(3),1586.2#/cm^(3),980.0#/cm^(3))and secondary sources(999.4#/cm^(3),791.1#/cm^(3),804.1#/cm^(3))showed decreasing trends.In summary,the contributions of traffic emissions to PNC highlight the potential for targeted traffic management strategies to improve urban air quality.展开更多
To clarify the effect of SnO2 particle size on the arc erosion behavior of AgSnO2 contact material, Ag?4%SnO2 (mass fraction) contact materials with different sizes of SnO2 particles were fabricated by powder metallur...To clarify the effect of SnO2 particle size on the arc erosion behavior of AgSnO2 contact material, Ag?4%SnO2 (mass fraction) contact materials with different sizes of SnO2 particles were fabricated by powder metallurgy. The microstructure of Ag?4%SnO2 contact materials was characterized, and the relative density, hardness and electrical conductivity were measured. The arc erosion of Ag?4%SnO2 contact materials was tested, the arc duration and mass loss before and after arc erosion were determined, the surface morphologies and compositions of Ag?4%SnO2 contact materials after arc erosion were characterized, and the arc erosion mechanism of AgSnO2 contact materials was discussed. The results show that fine SnO2 particle is beneficial for the improvement of the relative density and hardness, but decreases the electrical conductivity. With the decrease of SnO2 particle size, Ag?4%SnO2contact material presents shorter arc duration, less mass loss, larger erosion area and shallower arc erosion pits.展开更多
Effects of size distribution (particle size and content of fine fraction (<10μm)) on scheelite flotation were studied using flotation tests and theoretical calculations. The results show that particle size influen...Effects of size distribution (particle size and content of fine fraction (<10μm)) on scheelite flotation were studied using flotation tests and theoretical calculations. The results show that particle size influences the scheelite recovery and the performance of combined reagents. The scheelite recovery is lowered by adding fine particles (<10μm) into the pulp containing coarse particles. Extended DLVO (EDLVO) theory confirms that the fine fractions (<10μm) could interface with the coarse fractions. The interaction energy and fluid forces are relative to the particle size, which might explain why the fine fractions influence the scheelite flotation. The highest recovery of scheelite using combined reagents as collector and optimum ratio of combined reagents were determined by scheelite particle size and reagent performance. However, the optimum adding order was only determined by reagent performance, which has nothing to do with particle size.展开更多
By using the probe data of two sorties airplane in the middle and southern parts of Hebei Province in 2007 spring,the characteristics of atmospheric aerosol particles concentration and size distribution in the area in...By using the probe data of two sorties airplane in the middle and southern parts of Hebei Province in 2007 spring,the characteristics of atmospheric aerosol particles concentration and size distribution in the area in the cloudy day situation were analyzed.The results showed that the overall trend of aerosol particles concentration in the weather systems which included the south branch trough and North China low vortex was the decrease as the height increased.However,if the cirrostratus was in the high altitude,it increased as the height increased.In the bottom of inversion layer,there existed the obvious accumulation of aerosol and cloud droplet.Affected by the complex weather systems,the aerosol particle size distribution presented the multi-peak type for the disturbance of updraft or turbulence.展开更多
基金supported by the National Natural Science Foundation of China(22308348)the Natural Science Foundation of Liaoning Province of China(2024-MSBA-65)+1 种基金the Qin Chuangyuan Project for Introducing High-Level Innovative and Entrepreneurial Talents(QCYRCXM-2023-024)the Energy Revolution S&T Program of Yulin Innovation Institute of Clean Energy(E201041206).
文摘Accurately acquiring catalyst size and morphology is essential for supporting catalytic reaction process design and optimal control. We report an intelligent catalyst sizing and morphological classification method based on the Mask-RCNN framework. A dataset of 9880 high-resolution images was captured by using a self-made fiber-optic endoscopic system for 13 kinds of silicoaluminophosphate-34 (SAPO-34) catalyst samples with different coke. Then there were approximately 877881 individual particles extracted from this dataset by our AI-based particle recognition algorithm. To clearly describe the morphology of irregular particles, we proposed a hybrid classification criterion that combines five different parameters, which are deformity, circularity, roundness, aspect ratio, and compactness. Therefore, catalyst morphology can be classified into two categories with four types. The first category includes regular types, such as the spherical, ellipsoidal, and rod-shaped types. And all the irregular types fall into the second category. The experimental results showed that a catalyst particle tends to be larger when its coke deposition increased. Whereas particle morphology remained primarily spherical and ellipsoidal, the ratio of each type varied slightly according to its coke. Our findings illustrate that this is a promising approach to be developing intelligent instruments for catalyst particle sizing and classification.
基金This Subject was Partly Supported by the Scientific Reasearch Foundation for Returned Overseas Scholars from the State Education Department of China for RJZ(1997-436)
文摘SEM,TEM, gas absorption, X-ray Sedi-graph and laser particle sizing have been employed to analyse particle size distribution and powder agglomeration for Alcoa A16 and for Sumitomo AKS-53B and SKP-53 alpha - Al2O3 powders on several occasions as well. Comparison and evaluation of various particle-sizing techniques have been made.
基金the financial support from Natural Science and Engineering Research Council(NSERC)Canada Foundation for Innovation(CFI)
文摘Principles of a novel submicron particle sizing technology are first introduced followed by experimental validation. The sizing was accomplished by coupling aerodynamic particle focusing and maximum ion measurement. Experimental results showed that the prototype could detect particle sizes down to 40 nm in diameter. Comparison between the prototype and a scanning mobility particle sizer using identical polydisperse particles showed that the measurements agreed well for the tested particles.
基金The present work is supported by National Science Foundation of China （NSFC 50376041）the National High Technology Development 863 Program （2006AA03Z349）the ShuGuang project of Shanghai Educational Development Foundation （04SG49）, which are gratefully acknowledged.
文摘In particle sizing by light extinction method, the regularization parameter plays an important role in applying regularization to find the solution to ill-posed inverse problems. We combine the generalized cross-validation （GCV） and L-curve criteria with the Twomey-NNLS algorithm in parameter optimization. Numerical simulation and experimental validation show that the resistance of the newly developed algorithms to measurement errors can be improved leading to stable inversion results for unimodal particle size distribution.
文摘Ultrasound spectrometry is one of very few methods that can size particles over the range 10 nm to I mm for optically opaque, undiluted materials. It has in-line, non-invasive capabilities which make it a serious contender for use in industrial process monitoring, with the potential for 100% inspection. In aqueous systems, it is more sensitive to nanoparticles than to particles in the micrometre range upwards because the scattering power varies as the inverse square of particle diameter, making it suitable for the detec- tion of nanoparticles in concentrated, mixed systems. Future development of ultrasound spectrometers suitable for widespread laboratory and industrial use depends on meeting the challenges of complex data interpretation and the need for considerable know how. In this review we provide a brief account of ultrasound propagation and scattering theory which underlies the ultrasound spectrometer, describe several types of spectrometer and demonstrate its successful use in the characterization of colloidal silica, whole milk and protein solutions.
文摘This paper discusses two problems in in-line particle sizing when using light fluctuation method. First, by retrieving the ratio of particle concentrations at different time, the intensity of incident light is obtained. There exists narrow error between the calculated and pre-detected value of the intensity of incident light. Secondly, by combining spectrum analysis with Gregory＇s theory, a multi-sub-size zone model is proposed, with which the relationship between the distribution of turbidity and the particle size distribution （PSD） can be established, and an algorithm developed to determine the distribution of turbidity. Experiments conducted in the laboratory indicate that the measured size distribution of pulverized coal conforms well with the imaging result.
文摘The combination of laser diffraction with upstream sampling realized a break-through for the in- and on-line particles size analysis in industrial applications. Today, the combination of representative sampling, dry dispersion, particle size analysis by laser diffraction and integrated feedback of the sample is well accepted in many industrial applications. No more interactions of the user are required, and for standard applications the on-line monitoring of particle sizes became nearly as simple as the monitoring of any other process parameter. The increase of inspection interval from 24-hour operation to months has increased user confidence in this technology, and industries with more demanding measurement requirements are seeking to benefit from this performance. This challenge could not be solved with simple scale-ups or scale-downs. New solutions had to be found for the sampling system, the measuring sensor, the adaptation to the environmental conditions and the processing of fast growing volume of data.
基金Project no.RRF-2.3.1-21-2022-00015 has been implemented with the support provided by the European Unionsupported by the Agency for Credits and Study Grants coordinated by the Romanian Ministry of National Education from the source of the research grant established through the Government Decision no.118/2023+1 种基金supported by the EKÖP-24-3-BME-103 New National Excellence Program of the Ministry for Culture and Innovation from the source of the National,Research,Development and Innovation Fundsupported by the Doctoral Excellence Fellowship Programme(DCEP)is funded by the National Research Development and Innovation Fund of the Ministry of Culture and Innovation and the Budapest University of Technology and Economics,under a grant agreement with the National Research,Development and Innovation Office.
文摘In this study,an artificial intelligence-based machine vision system was developed for in-line particle size analysis during the pellet layering process.Drug-layered pellets were produced by coating microcrystalline cellulose cores with an ibuprofen-containing layering liquid until the target drug content was achieved.Drug content increases with pellet size;therefore,particle size monitoring can ensure product safety and quality.The direct imaging system,consisting of a rigid endoscope,a light source,and a high-speed camera,provides real-time information about pellet size and layer uniformity,enabling timely intervention in the case of out-of-spec products.A convolutional neural network-based instance segmentation algorithm was employed to detect particles in focus,ensuring that pellet size could be accurately determined despite the dense flow of the particles.After training the model,the performance of the developed system was assessed by analysing the particle size distribution of pellet cores with variable sizes within the 250 e850 mm size range.The endoscopic system was tested in-line at a larger scale during the drug layering of inert pellet cores.The particle size data acquired in real time with the endoscopic imaging system corresponded with the reference methods,demonstrating the feasibility of the proposed machine vision-based method as a process analytical technology tool for in-line process monitoring.
文摘The aluminum hydroxide adjuvant possesses a poorly crystalline boehmite (PCB) structure, the stability of which is significantly affected by storage conditions. In the present study, we conducted a comprehensive investigation into the structural and quality alterations of aluminum hydroxide adjuvants under varying temperature conditions over time. Three batches of the adjuvant were stored at 2–8℃, 18–25℃, and 37℃, respectively, for 6 months. Key parameters, including X-ray diffraction patterns, pH, isoelectric point (pI), adsorption capacity, and average particle size, were analyzed to assess the impact of storage temperatures. X-ray diffraction analysis confirmed the PCB structure of the aluminum hydroxide adjuvant. Notably, after 1 month of storage at 37℃, new diffraction peaks emerged at 18.2 °2θ, with their intensity increasing progressively over time. Concurrently, the largest decreases in pI and pH were observed, measuring 0.78 and 1.33, respectively. In contrast, adjuvants stored at 2–8℃ for 6 months exhibited only faint diffraction peaks at 18.2 °2θ, indicating minor structural changes. Under these conditions, the reductions in pI and pH were comparatively smaller, at 0.43 and 0.80, respectively. The average particle size of the adjuvants remained within 110–140 nm across all storage conditions. Additionally, the aluminum hydroxide adjuvant consistently demonstrated a high protein adsorption capacity, approximately 8 mg BSA/mg Al^(3+), with no statistically significant differences in adsorption rates observed among the different temperature conditions (P > 0.05). These findings highlighted the remarkable adsorption efficiency of nanoparticle aluminum hydroxide adjuvants throughout storage, reinforcing their potential as superior vaccine adsorbents. However, elevated storage temperatures were shown to accelerate structural aging, promoting the formation of highly crystalline phases such as gibbsite or bayerite, which could compromise the stability and quality of the adjuvant.
基金research was funded bymultiple sources,including the Guangxi Natural Science Foundation of Youth Fund(2020GXNSFBA159004)the National Natural Science Foundation Project of China(51779204)the Guilin University of Technology High-Level Talent Research Startup Project(GUTQDJJ2018069).
文摘The particle size distribution plays a crucial role in the transportation and deposition of eroded sediments.Gaining insights into the related sorting mechanism can significantly enhance our understanding of such processes.In this study,sand-covered slopes were examined.A controlled indoor rainfall simulation was conducted on loess slopes with a 12°incline and a rainfall intensity of 1.5 mm/min.These slopes were then covered with sand layers of varying thicknesses—0.5,1.0,and 1.5 cm—to observe their effects.The findings have revealed that as the thickness of the sand cover increases,the content of sediment particles smaller than 0.054 mm decreases.In contrast,the content of particles larger than 0.054 mm increases after the sixth minute of runoff.The eroded sediment was predominantly composed of silt.During the inter-rill erosion stage,runoff primarily transported particles larger than 0.054 mm.However,in the subsequent rill erosion and combined rill and inter-rill erosion stages,the runoff predominantly carried finer particles,smaller than 0.054 mm.Moreover,the presence of the sand layer significantly influenced the size and form of the eroded sediment particles.Initially,during the first 10 min of runoff,the eroded particles were predominantly larger than 0.054 mm.After this period,however,the particle size shifted,with the majority of particles being smaller than 0.054 mm.This study highlights the intricate relationship between sediment sorting,the thickness of sand covers,and the dynamics of sediment transport under rainfall-induced erosion.
基金supported by the National Natural Science Foundation of China(Nos.52172337 and 52272342)the Postdoctoral Fellowship Program(Grade B)of China Postdoctoral Science Foundation(No.GZB20240352)the Shuimu Tsinghua Scholar Program of Tsinghua University(No.2023SM230)。
文摘Brake wear particle(BWP)emissions are considered one of the dominant sources of particulate matter pollution in urban environments.BWP emissions have increased significantly under high-temperature conditions,emerging as a focal point of research interest.This study investigates the effect of brake temperatures on BWP emissions.The brake pad materials undergo violent decomposition and oxidation reactions and generate large amounts of incompletely oxidized organic products at temperatures above 475℃.These organic products cause particles below 200 nm to proliferate,and nanoparticles below 40 nm account for the largest contribution of total BWPs.When the friction surface temperature exceeds 475℃,the high-concentration BWPs below 200 nm will agglomerate into larger particles.High temperatures also cause the brake pad surface to delaminate and fragment into particles above 2.5μm.In addition,when the initial brake speed is above 160 km/h,or the brake pressure is above 7 bar,there is a sharp increase in particles below 200 nm.The results suggest that a significant number of nanoparticles below 40 nm are inferred to be generated as the flash temperature of the friction surface reaches the violent reaction temperature.This study provides guidelines for designing low-emission brake pads,as improving the high-temperature resistance of brake pad material components possibly reduces BWP generation.
基金supported by the National Key Research and Development Program of China(2024YFC2909500)State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(SDGZ2505)National Natural Science Foundation of China(42377148)。
文摘High-steep waste dumps in open-pit mines frequently demonstrate complex particle-size distributions and fractal characteristics along their slopes,which have a significant impact on slope stability.This study takes the Dasuji South waste dump in Inner Mongolia as a case to quantify the fractal dimensions of soil-rock mixtures at various slope heights,and to clarify how these fractal properties govern shear strength and deformation behavior under overlying stress,thereby affecting the overall stability of the waste dump slope.Field sampling and laboratory tests were conducted to determine the particle-size composition and fractal dimensions while direct shear tests were conducted and revealed that lower fractal dimensions indicating coarser particle assemblages significantly enhance shear resistance.Complementary PFC_(2)D discrete element simulations demonstrate that slopes composed of lower-fractaldimension materials deform less and contain localized deformation zones,whereas higher-fractal-dimension slopes experience more extensive displacement and a heightened risk of landslides.These findings refine our understanding of the relationship between fractal grain-size distribution and slope stability,providing a robust theoretical basis for improved stability assessment and optimized support strategies in deep open-pit mining waste dumps,and ultimately aiding in more effective disaster prevention within geotechnical engineering.
基金"PSPC Régions n°2"("Projets Structurants des Pôles de Compétitivitéen région")funded by Conseil Régional Hauts-de-France and BPI.
文摘Developing the railway transport sector is a challenging scientific,economic and social research topic starting with ensuring human security.The main topic that should be developed in that sense is the ballast stability and dynamical behaviour under external loading and environmental changes.This paper investigates the effect of particle size distribution and normal pressure on the mechanical response of a ballast bed.Grading curves of ballast layers with different sizes are illustrated to discuss their strength behaviour under various strains to deduce the significant effect on the direct shear performance of the ballast layer.Direct shear tests with different Particle Size Distribution(PSD)were reproduced using the Discrete Element Method(DEM).It is noticed that when the number of small-sized ballast increases,the shear strength and the friction angle increase to varying degrees under different normal pressures,with an average increase of 27%and 8%,respectively.When the number of large-sized ballast decreases,the shear strength and the friction angle decrease to varying degrees under different normal pressures,with an average decrease of 6%and 3%,respectively.
基金support of the National Key Research and Development Program of China(2023YFD2100403)the Agricultural Science and Technology Innovation Program of Chinese Academy of Agricultural Sciences(CAAS-ASTIP-2021-OCRI)+3 种基金the Earmarked Fund for CARS-14the Innovation Group Project of Hubei Province(2023AFA042)the Key Research Projects of Hubei Province(2020BBA045)the Knowledge Innovation Program of Wuhan-Basic Research(3562).
文摘The increased risk of chronic diseases has led to increasing importance of coarse foods in daily life,but the inclusion of new ingredients has a great degree of influence on the structural characteristics and sensory qualities of the food.The effects of five different particle size variations on the physicochemical characteristics,dough,and steamed bread structure of Flaxseed-based milk coproduct(FMC)were investigated.As the particle size decreases,the structure of the dough becomes denser due to an increase in water retention capacity and dissolution capacity,weakening the competition for dough moisture and allowing for an increase in air-holding capacity.The reduction in particle size increased the specific volume of the steamed bread,a decrease in the spread ratio,and an optimization of hardness and elasticity,as well as an increase in consumer acceptance of the FMC steamed bread.However,it is not the smaller the particle size,the higher the quality of steamed bread,appropriate reduction of particle size can improve the quality of steamed bread.In addition,the addition of FMC reduces fat digestion.Therefore,the present study proposes a method to change the particle size of FMC to optimize the quality of the steamed bread and to reduce fat digestibility by adding FMC.
基金supported by the Equipment Pre-research and Sharing Technology(41423030503)provided funding for this workThe Equipment Pre-research and Sharing Technology(41423030503)funded this work.
文摘This work used 5CrMnMo steel and titanium carbide(TiC)powders to fabricate particulate metal matrix composites(PMMCS).The composites’microstructure,hardness,and impact toughness were compared with four different titanium carbide ceramic particle sizes.The phase composition and microstructure of composites were studied.Vickers hardness and Charpy impact tests were employed to analyze composites’hardness and impact ductility,respectively.The results showed that the four groups of composites are mainly composed of martensite,trace residual austenite,and titanium carbide(undissolved TiC and primary TiC particles).With the growth of the ceramic particle dimension in the composite layer,the number of primary titanium carbide ceramics gradually decreased.When the initial ceramic particle size was small,it tended to generate dendritic primary TiC,and when the particle size was large,it tended to generate polygons and ellipsoids.Furthermore,with the growth of titanium carbide ceramic particle dimension in the composites,the hardness of the composites decreased but the impact toughness of the composites rose first and then descended.When the ceramic particle size was 50-75μm,the composite had the highest hardness,and the impact energy of the composites was the highest,which is 8 J.This was because there were more undissolved titanium carbide ceramics in the composite,and there was a thicker matrix metal between the ceramic particles.
基金supported by the National Natural Science Foundation of China(Grant Nos.41630640,41790445)the National Key Research and Development Program of China(Grant No.2022YFC3003205).
文摘The high stress levels in tall tailings dams can lead to particle crushing.Understanding the compressibility and breakage characteristics of tailings particles will contribute to the advancement to the design and construction processes of high-rise tailings dams,as well as the accurate evaluation of the stability of tailings storage facilities(TSFs).This paper presents the results of a series of detailed one-dimensional oedometer compression tests conducted to investigate the compression behavior and particle breakage of iron ore tailings(IOTs)collected from two typical TSFs,with different initial particle size distributions and a wide range of initial specific volumes,under effective vertical stresses of up to 4.8 MPa.The results show that the compression paths of the IOTs were slowly convergent,and this nontransitional mode of compression behavior experienced a significant amount of particle breakage.The relative breakage(Br)was used to quantify the amount of breakage and the input specific work(W)was adopted to evaluate the factors influencing Br.The initial breakage stress of the IOTs was less than 0.2 MPa.For the finer tailings,Br increased with increasing vertical stresses until it reached a threshold,after which Br tended to remain constant.However,coarser IOTs continued to experience crushing even at 4.8 MPa.The particle breakage in the coarser IOTs is much more significant than it in the finer IOTs overall.It was also observed that the tailings grains within the loose specimens broke more easily than those within the dense specimens.Additionally,three types of particle crushing modes were identified for IOTs under one-dimensional compression,namely,abrasion,chipping,and splitting.
基金supported by the National Research Program for Key Issues in Air Pollution Control in China(No.DQGG202137)the National Natural Science Foundation of China(No.42277429)。
文摘The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emissions or through new particle formation events.However,their variations during the lockdown period are under investigation.This study focuses on Luohe,a city on the southern edge of the North China Plain,analyzing the changes in PNC and its sources before,during,and after the COVID-19 lockdown.From March 25^(th)to May 31^(st),2022,real-time PNC measurements were conducted using a Scanning Mobility Particle Sizer for particle size.Results showed an 11.2%decrease in PNC during the lockdown compared to pre-lockdown and a 3.6%decrease compared to post-lockdown,indicating reduced local emissions and weakened regional transportation during the lockdown.Positive Matrix Factorization analysis identified six sources contributing to the total PNC,including photochemical nucleation,aged photochemical nucleation,gasoline vehicle emissions,diesel vehicle emissions,coal and biomass combustion,and secondary aerosols.The significant changes in source emissions indicate a substantially reduced traffic volume after the implementation of lockdown measures(2644.8#/cm^(3),2202.2#/cm^(3),2792.7#/cm^(3)).Concurrently,photochemical nucleation(310.1#/cm^(3),306.3#/cm^(3),393.1#/cm^(3))and photochemical nucleation aging(592.8#/cm^(3),744.1#/cm^(3),810.7#/cm^(3))exhibited increasing trends,while coal/biomass combustion(1656.6#/cm^(3),1586.2#/cm^(3),980.0#/cm^(3))and secondary sources(999.4#/cm^(3),791.1#/cm^(3),804.1#/cm^(3))showed decreasing trends.In summary,the contributions of traffic emissions to PNC highlight the potential for targeted traffic management strategies to improve urban air quality.
基金Project(51274163)supported by the National Natural Science Foundation of ChinaProject(13JS076)supported by the Key Laboratory Research Program of Shaanxi Province,China+1 种基金Project(2012KCT-25)supported by the Pivot Innovation Team of Shaanxi Electrical Materials and Infiltration Technique,ChinaProject(2011HBSZS009)supported by the Special Foundation of Key Disciplines,China
文摘To clarify the effect of SnO2 particle size on the arc erosion behavior of AgSnO2 contact material, Ag?4%SnO2 (mass fraction) contact materials with different sizes of SnO2 particles were fabricated by powder metallurgy. The microstructure of Ag?4%SnO2 contact materials was characterized, and the relative density, hardness and electrical conductivity were measured. The arc erosion of Ag?4%SnO2 contact materials was tested, the arc duration and mass loss before and after arc erosion were determined, the surface morphologies and compositions of Ag?4%SnO2 contact materials after arc erosion were characterized, and the arc erosion mechanism of AgSnO2 contact materials was discussed. The results show that fine SnO2 particle is beneficial for the improvement of the relative density and hardness, but decreases the electrical conductivity. With the decrease of SnO2 particle size, Ag?4%SnO2contact material presents shorter arc duration, less mass loss, larger erosion area and shallower arc erosion pits.
基金Project(51074037)supported by the National Natural Science Foundation of China
文摘Effects of size distribution (particle size and content of fine fraction (<10μm)) on scheelite flotation were studied using flotation tests and theoretical calculations. The results show that particle size influences the scheelite recovery and the performance of combined reagents. The scheelite recovery is lowered by adding fine particles (<10μm) into the pulp containing coarse particles. Extended DLVO (EDLVO) theory confirms that the fine fractions (<10μm) could interface with the coarse fractions. The interaction energy and fluid forces are relative to the particle size, which might explain why the fine fractions influence the scheelite flotation. The highest recovery of scheelite using combined reagents as collector and optimum ratio of combined reagents were determined by scheelite particle size and reagent performance. However, the optimum adding order was only determined by reagent performance, which has nothing to do with particle size.
基金Supported by The Project of Key and Open Laboratory for Cloud Fog Physics Environment of China Meteorological Administration(2009Z0034)The Special Project of Public Welfare Industry(Mete-orology) Science Research of Science and Technology Ministry(GY-HY200806001)Research and Development Projects of Weather Modification Office in Hebei Province:Aircraft Observations Under Fog and Haze Conditions in Hebei Province(10ky04)
文摘By using the probe data of two sorties airplane in the middle and southern parts of Hebei Province in 2007 spring,the characteristics of atmospheric aerosol particles concentration and size distribution in the area in the cloudy day situation were analyzed.The results showed that the overall trend of aerosol particles concentration in the weather systems which included the south branch trough and North China low vortex was the decrease as the height increased.However,if the cirrostratus was in the high altitude,it increased as the height increased.In the bottom of inversion layer,there existed the obvious accumulation of aerosol and cloud droplet.Affected by the complex weather systems,the aerosol particle size distribution presented the multi-peak type for the disturbance of updraft or turbulence.
