A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffrac...A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic space group P2 1 /c with a=11.218（3）,b=9.355（3）,c=13.449（4）,β=108.722（4）°,V=1336.8（6）3,Z=2,Dc=2.008 g/cm 3,μ（MoKα）=7.024 mm-1,F（000）=806,S=0.999,the final R=0.0342 and wR=0.0641for2611observed reflections （I〉2σ（I））.The central copper（Ⅱ） is four-coordinate and bonds to two nitrogen and two oxygen atoms from two Schiff base ligands.The complex is linked into a two-dimensional supramolecular structure by weak intermolecular interactions.In addition,DNA-binding properties of the metal complex were investigated using spectrometric titrations and viscosity measurements.The results show that the complex binds with calf-thymus DNA（CT-DNA）,presumably via a partial intercalative mode.The intrinsic binding constant of the Cu（Ⅱ） complex with DNA is 7.335×10 3 M-1.展开更多
The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. ...The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. A satisfactory description of the liquid phase in the Fe C-Si system has been obtained. The C Mn Si system was assessed treating the liquid phase as a substitutional solution. Phase equilibria in the C- Mn-Si system, especially those involving the liquid phase, can be well described. Based on the extrapolation of the experimental data in the quaternary system, the Fe Mn Si system has been modified to agree well with experimental data at high temperatures. The comparison between the calculated and measured phase transformation tempera tures confirms the reliability of the present quaternary database. Additionally, the solidification process of Fe-0. 16C-1. 5Mn-1. 5Si （wt. %） alloy was simulated by using the thermodynamic database developed.展开更多
Cold thermal energy storage is an active method for reducing the peak electrical demand and electricity consumption of air con-ditioners.This paper investigates two different cases:partial operating mode-load levellin...Cold thermal energy storage is an active method for reducing the peak electrical demand and electricity consumption of air con-ditioners.This paper investigates two different cases:partial operating mode-load levelling(POM-LL)and demand-limiting mode(DLM).4E(energy,exergy,economic,environment)analyses along with a multi-objective optimization process based on a genetic algorithm is applied to determine optimal design values.Exergy efficiency,total annual cost and payback-period time are considered as objective functions in this study.The results have shown that POM and DLM decreased the electricity consumption by 10.36%and 11.29%,respectively,resulting in raising the annual costs by 11.08%and 11.42%.Also,their annual payback periods were 4.36 and 4.18 years each.In addition,using off-peak hours instead of on-peak hours for electricity consumption and reducing electricity consump-tion are the two main ways of decreasing CO_(2) emissions during electricity generation.Therefore,the CO_(2) emissions through POM and DLM are 13.31%and 13.72%less than those of conventional systems,respectively.展开更多
文摘A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic space group P2 1 /c with a=11.218（3）,b=9.355（3）,c=13.449（4）,β=108.722（4）°,V=1336.8（6）3,Z=2,Dc=2.008 g/cm 3,μ（MoKα）=7.024 mm-1,F（000）=806,S=0.999,the final R=0.0342 and wR=0.0641for2611observed reflections （I〉2σ（I））.The central copper（Ⅱ） is four-coordinate and bonds to two nitrogen and two oxygen atoms from two Schiff base ligands.The complex is linked into a two-dimensional supramolecular structure by weak intermolecular interactions.In addition,DNA-binding properties of the metal complex were investigated using spectrometric titrations and viscosity measurements.The results show that the complex binds with calf-thymus DNA（CT-DNA）,presumably via a partial intercalative mode.The intrinsic binding constant of the Cu（Ⅱ） complex with DNA is 7.335×10 3 M-1.
基金the financial support from the Chinese National Key Project of Science and Technology (Grant No. 2012ZX06004-012)the support from the Chinese Scholarship Council (CSC)the support from the Shanghai Municipal Science and Technology Commission (Grant No. 15DZ2260300,15DZ2260301)
文摘The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. A satisfactory description of the liquid phase in the Fe C-Si system has been obtained. The C Mn Si system was assessed treating the liquid phase as a substitutional solution. Phase equilibria in the C- Mn-Si system, especially those involving the liquid phase, can be well described. Based on the extrapolation of the experimental data in the quaternary system, the Fe Mn Si system has been modified to agree well with experimental data at high temperatures. The comparison between the calculated and measured phase transformation tempera tures confirms the reliability of the present quaternary database. Additionally, the solidification process of Fe-0. 16C-1. 5Mn-1. 5Si （wt. %） alloy was simulated by using the thermodynamic database developed.
文摘Cold thermal energy storage is an active method for reducing the peak electrical demand and electricity consumption of air con-ditioners.This paper investigates two different cases:partial operating mode-load levelling(POM-LL)and demand-limiting mode(DLM).4E(energy,exergy,economic,environment)analyses along with a multi-objective optimization process based on a genetic algorithm is applied to determine optimal design values.Exergy efficiency,total annual cost and payback-period time are considered as objective functions in this study.The results have shown that POM and DLM decreased the electricity consumption by 10.36%and 11.29%,respectively,resulting in raising the annual costs by 11.08%and 11.42%.Also,their annual payback periods were 4.36 and 4.18 years each.In addition,using off-peak hours instead of on-peak hours for electricity consumption and reducing electricity consump-tion are the two main ways of decreasing CO_(2) emissions during electricity generation.Therefore,the CO_(2) emissions through POM and DLM are 13.31%and 13.72%less than those of conventional systems,respectively.
