The rapid development of nanotechnology has significantly revolutionized wearable electronics and expanded their functionality.Through introducing innovative solutions for energy harvesting and autonomous sensing,this...The rapid development of nanotechnology has significantly revolutionized wearable electronics and expanded their functionality.Through introducing innovative solutions for energy harvesting and autonomous sensing,this research presents a cost-effective strategy to enhance the performance of triboelectric nanogenerators(TENGs).The TENG was fabricated from polyvinylidene fluoride(PVDF)and N,N'-poly(methyl methacrylate)(PMMA)blend with a porous structure via a novel optimized quenching method.The developed approach results in a highβ-phase content(85.7%)PVDF/3wt.%PMMA porous blend,known for its superior piezoelectric properties.PVDF/3wt.%PMMA modified porous TENG demonstrates remarkable electrical output,with a dielectric constant of 40 and an open-circuit voltage of approximately 600 V.The porous matrix notably increases durability,enduring over 36000 operational cycles without performance degradation.Moreover,practical applications were explored in this research,including powering LEDs and pacemakers with a maximum power output of 750mWm^(-2).Also,TENG served as a self-powered tactile sensor for robotic applications in various temperature conditions.The work highlights the potential of the PVDF/PMMA porous blend to utilize the next-generation self-powered sensors and power small electronic devices.展开更多
为提高锂离子电池聚偏氟乙烯(PVDF)基聚合物隔膜对电解液体系的亲和性和导电性,引入聚甲基丙烯酸甲酯(PMMA)与聚偏氟乙烯(PVDF)进行共混,并添加有机增塑剂聚乙二醇PEG-400对PVDF基聚合物隔膜进行改性研究。采用先干法后湿法的相转化方...为提高锂离子电池聚偏氟乙烯(PVDF)基聚合物隔膜对电解液体系的亲和性和导电性,引入聚甲基丙烯酸甲酯(PMMA)与聚偏氟乙烯(PVDF)进行共混,并添加有机增塑剂聚乙二醇PEG-400对PVDF基聚合物隔膜进行改性研究。采用先干法后湿法的相转化方法制备PVDF/PMMA/PEG型聚合物隔膜。通过对制备的聚合物隔膜的孔隙率、吸液率、微观形貌和电化学性能的分析研究,确定制膜的最佳工艺条件为聚合物占溶剂质量百分比为8%,PVDF∶PMMA=7∶3,增塑剂含量为30%,非溶剂含量为3%,反应温度为45℃,在此最佳工艺条件下制备的PVDF/PMMA/PEG隔膜的离子电导率可达2.848 m S/cm,对电解液体系的亲和性和导电性得到显著提高。展开更多
文摘采用机械共混法制备了Si O2改性的CPVC/PVDF/PMMA复合材料,考察了Si O2用量、PVB、PVC、丁腈粉、DBP对材料成膜性能、吸墨性能、柔软性和韧性的影响.结果表明:1当Si O2的质量浓度为4.5%时,CPVC的成膜性和吸墨性能最佳;2当DBP、丁腈粉的质量分数分别为3.0%和3.4%时,膜的柔韧性最佳;3最佳的制备工艺是将PMMA、CPVC、PVDF和丁腈粉溶于DMAC和DBP的混合溶液中,再恒温4 h.
基金supported by the research projects AP14869428 from the Ministry of Science and Higher Education of the Republic of Kazakhstan20122022FD4135 from Nazarbayev University.
文摘The rapid development of nanotechnology has significantly revolutionized wearable electronics and expanded their functionality.Through introducing innovative solutions for energy harvesting and autonomous sensing,this research presents a cost-effective strategy to enhance the performance of triboelectric nanogenerators(TENGs).The TENG was fabricated from polyvinylidene fluoride(PVDF)and N,N'-poly(methyl methacrylate)(PMMA)blend with a porous structure via a novel optimized quenching method.The developed approach results in a highβ-phase content(85.7%)PVDF/3wt.%PMMA porous blend,known for its superior piezoelectric properties.PVDF/3wt.%PMMA modified porous TENG demonstrates remarkable electrical output,with a dielectric constant of 40 and an open-circuit voltage of approximately 600 V.The porous matrix notably increases durability,enduring over 36000 operational cycles without performance degradation.Moreover,practical applications were explored in this research,including powering LEDs and pacemakers with a maximum power output of 750mWm^(-2).Also,TENG served as a self-powered tactile sensor for robotic applications in various temperature conditions.The work highlights the potential of the PVDF/PMMA porous blend to utilize the next-generation self-powered sensors and power small electronic devices.
文摘为提高锂离子电池聚偏氟乙烯(PVDF)基聚合物隔膜对电解液体系的亲和性和导电性,引入聚甲基丙烯酸甲酯(PMMA)与聚偏氟乙烯(PVDF)进行共混,并添加有机增塑剂聚乙二醇PEG-400对PVDF基聚合物隔膜进行改性研究。采用先干法后湿法的相转化方法制备PVDF/PMMA/PEG型聚合物隔膜。通过对制备的聚合物隔膜的孔隙率、吸液率、微观形貌和电化学性能的分析研究,确定制膜的最佳工艺条件为聚合物占溶剂质量百分比为8%,PVDF∶PMMA=7∶3,增塑剂含量为30%,非溶剂含量为3%,反应温度为45℃,在此最佳工艺条件下制备的PVDF/PMMA/PEG隔膜的离子电导率可达2.848 m S/cm,对电解液体系的亲和性和导电性得到显著提高。
