This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS beh...This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS behaviors was synthesized using a seed-mediated growth method and the dimensions of the Au NTOH was easily tuned.In addition,the influence of size on the SERS performance of their monolayers was systematically investigated,and the Au NTOH with the size of 61 nm possessed the best SERS performance.Importantly,a hydrophilic-substrateassisted interfacial self-assembled monolayer transfer technique was proposed to transfer Au NTOH onto PDMS films,resulting in forming flexible and transparent Au NTOH@PDMS substrates.Furthermore,the excellent signal homoge⁃neity of this substrate was demonstrated and the sensitivity was verified by a measurement of crystal violet(CV)as low as 1×10^(-8) mol/L.As a result,this SERS sensor is progressing for applying in the identification of trace contaminants in broad fields.展开更多
Herein,the surface of Moso bamboo was hydrophobically modified by combining O_(2)/N_(2)plasma treatments with polydimethylsiloxane(PDMS)solution treatment as the hydrophobic solution.The effects of plasma treatment pr...Herein,the surface of Moso bamboo was hydrophobically modified by combining O_(2)/N_(2)plasma treatments with polydimethylsiloxane(PDMS)solution treatment as the hydrophobic solution.The effects of plasma treatment process(power and time),PDMS solution concentration,and maceration time on the hydrophobic performance of bamboo specimens were studied,and the optimal treatment conditions for improving the hydrophobicity were determined.Scanning electron microscopy(SEM),fourier transform infrared(FTIR),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS)were used to analyze the surface morphology,chemical structure,and functional groups in the specimens before and after the plasma and PDMS solution treatments under optimal conditions.Response surface analysis was also performed to determine the optimal treatment conditions.Results show that the hydrophobic performance of the Moso bamboo surface is effectively improved and the surface energy is reduced after the coordinated treatment.The optimal conditions for improving the hydrophobic performance of Moso bamboo surface are a treatment power of 800 W,treatment time of 15 s,O_(2)flow rate of 1.5 L/min,PDMS solution concentration of 5%,and maceration time of 60 min for O_(2)plasma treatment and a treatment power of 1000 W,treatment time of 15 s,N_(2)flow rate of 1.5 L/min,PDMS solution concentration of 5%,and maceration time of 60 min for N_(2)plasma treatment.After treatment,silicone oil particles and plasma etching traces are observed on the bamboo surface.Moreover,Si-O bonds in the PDMS solution are grafted to the bamboo surface via covalent bonds,thereby increasing the contact angle and decreasing the surface energy to achieve the hydrophobic effect.展开更多
文章以新工科背景下工程认证的新要求为依据,以课程建设为契机,重点研究PDMS三维设计管理系统在环境工程专业《工程制图与CAD》教学中的应用。文章着重围绕提升环境工程专业学生的工程设计能力展开,目的是让学生更快掌握国际先进的工程...文章以新工科背景下工程认证的新要求为依据,以课程建设为契机,重点研究PDMS三维设计管理系统在环境工程专业《工程制图与CAD》教学中的应用。文章着重围绕提升环境工程专业学生的工程设计能力展开,目的是让学生更快掌握国际先进的工程设计理念和设计工具。该项目致力于解决环境类《工程制图与CAD》课程重理论轻实践的问题,通过让学生掌握PDMS软件的使用,使学生不但具备二维平面设计能力,更具备国际先进的数字化三维设计能力。Based on the new requirements of engineering certification under the background of new engineering, this paper focuses on the application of PDMS 3D design management system in the teaching of “Engineering Drawing and CAD” for environmental engineering majors. This paper focuses on improving the engineering design ability of students majoring in environmental engineering, with the aim of enabling students to master international advanced engineering design concepts and design tools faster. This project is committed to solving the problem that the environmental course “Engineering Drawing and CAD” focuses on theory rather than practice. By allowing students to master the use of PDMS software, students will not only have the ability of two-dimensional graphic design, but also have the international advanced digital three-dimensional design ability.展开更多
This paper presents a method for fabricating a low-cost,highly reproducible miniature optical fiber Fabry-Perot(FP)sensor based on a polydimethylsiloxane(PDMS)end-cap structure.The FP cavity end-cap is formed by the o...This paper presents a method for fabricating a low-cost,highly reproducible miniature optical fiber Fabry-Perot(FP)sensor based on a polydimethylsiloxane(PDMS)end-cap structure.The FP cavity end-cap is formed by the optical fiber end-face and a PDMS droplet deposited onto it.The PDMS deposition is achieved by immersing the fiber end into pre-cured PDMS at a fixed speed,a process requiring careful control of PDMS viscosity and surface tension.By leveraging PDMS’s excellent thermal expansion coefficient,Poisson’s ratio,and other parameters,this method achieves high reproducibility via viscosity-optimized pre-curing,enhanced sensitivity for temperature measurements,and significant cost reduction versus commercial counterparts.Fiber FP sensors are increasingly widely used in biomedical and precision detection fields owing to their significant advantages,including small size,light weight,high sensitivity,and immunity to electromagnetic interference.In the fabrication of fiber FP sensors,using polymer materials is an effective technical approach.These polymers can be applied as coatings on the optical fiber end-face or as interlayer materials embedded between fibers to form the FP cavity structure,which not only significantly improves the overall sensor performance,but also enhances its sensitivity to changes in temperature,pressure,and refractive index.In the final part of this study,we successfully validated the exceptional performance of the PDMS end-cap based fiber FP sensor in detecting different temperatures conditions.Experimental results demonstrate a temperature sensitivity of 0.752 nm/℃for sensors with a 60-μm PDMS end-cap,further confirming the sensor’s reliability and efficiency in practical applications.展开更多
基金The National Natural Science Foundation of China(12274055)the Fundamental Research Funds for the Central Universities(04442024072)the Training Program of Innovation and Entrepreneurship for Undergraduates in Dalian Minzu University(202312026063)。
文摘This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS behaviors was synthesized using a seed-mediated growth method and the dimensions of the Au NTOH was easily tuned.In addition,the influence of size on the SERS performance of their monolayers was systematically investigated,and the Au NTOH with the size of 61 nm possessed the best SERS performance.Importantly,a hydrophilic-substrateassisted interfacial self-assembled monolayer transfer technique was proposed to transfer Au NTOH onto PDMS films,resulting in forming flexible and transparent Au NTOH@PDMS substrates.Furthermore,the excellent signal homoge⁃neity of this substrate was demonstrated and the sensitivity was verified by a measurement of crystal violet(CV)as low as 1×10^(-8) mol/L.As a result,this SERS sensor is progressing for applying in the identification of trace contaminants in broad fields.
基金Zhejiang Provincial Cooperative Forestry Science and Technology Project(No.2023SY05)Zhejiang Provincial Science and Technology Project(No.2024F1065-2).
文摘Herein,the surface of Moso bamboo was hydrophobically modified by combining O_(2)/N_(2)plasma treatments with polydimethylsiloxane(PDMS)solution treatment as the hydrophobic solution.The effects of plasma treatment process(power and time),PDMS solution concentration,and maceration time on the hydrophobic performance of bamboo specimens were studied,and the optimal treatment conditions for improving the hydrophobicity were determined.Scanning electron microscopy(SEM),fourier transform infrared(FTIR),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS)were used to analyze the surface morphology,chemical structure,and functional groups in the specimens before and after the plasma and PDMS solution treatments under optimal conditions.Response surface analysis was also performed to determine the optimal treatment conditions.Results show that the hydrophobic performance of the Moso bamboo surface is effectively improved and the surface energy is reduced after the coordinated treatment.The optimal conditions for improving the hydrophobic performance of Moso bamboo surface are a treatment power of 800 W,treatment time of 15 s,O_(2)flow rate of 1.5 L/min,PDMS solution concentration of 5%,and maceration time of 60 min for O_(2)plasma treatment and a treatment power of 1000 W,treatment time of 15 s,N_(2)flow rate of 1.5 L/min,PDMS solution concentration of 5%,and maceration time of 60 min for N_(2)plasma treatment.After treatment,silicone oil particles and plasma etching traces are observed on the bamboo surface.Moreover,Si-O bonds in the PDMS solution are grafted to the bamboo surface via covalent bonds,thereby increasing the contact angle and decreasing the surface energy to achieve the hydrophobic effect.
文摘文章以新工科背景下工程认证的新要求为依据,以课程建设为契机,重点研究PDMS三维设计管理系统在环境工程专业《工程制图与CAD》教学中的应用。文章着重围绕提升环境工程专业学生的工程设计能力展开,目的是让学生更快掌握国际先进的工程设计理念和设计工具。该项目致力于解决环境类《工程制图与CAD》课程重理论轻实践的问题,通过让学生掌握PDMS软件的使用,使学生不但具备二维平面设计能力,更具备国际先进的数字化三维设计能力。Based on the new requirements of engineering certification under the background of new engineering, this paper focuses on the application of PDMS 3D design management system in the teaching of “Engineering Drawing and CAD” for environmental engineering majors. This paper focuses on improving the engineering design ability of students majoring in environmental engineering, with the aim of enabling students to master international advanced engineering design concepts and design tools faster. This project is committed to solving the problem that the environmental course “Engineering Drawing and CAD” focuses on theory rather than practice. By allowing students to master the use of PDMS software, students will not only have the ability of two-dimensional graphic design, but also have the international advanced digital three-dimensional design ability.
文摘This paper presents a method for fabricating a low-cost,highly reproducible miniature optical fiber Fabry-Perot(FP)sensor based on a polydimethylsiloxane(PDMS)end-cap structure.The FP cavity end-cap is formed by the optical fiber end-face and a PDMS droplet deposited onto it.The PDMS deposition is achieved by immersing the fiber end into pre-cured PDMS at a fixed speed,a process requiring careful control of PDMS viscosity and surface tension.By leveraging PDMS’s excellent thermal expansion coefficient,Poisson’s ratio,and other parameters,this method achieves high reproducibility via viscosity-optimized pre-curing,enhanced sensitivity for temperature measurements,and significant cost reduction versus commercial counterparts.Fiber FP sensors are increasingly widely used in biomedical and precision detection fields owing to their significant advantages,including small size,light weight,high sensitivity,and immunity to electromagnetic interference.In the fabrication of fiber FP sensors,using polymer materials is an effective technical approach.These polymers can be applied as coatings on the optical fiber end-face or as interlayer materials embedded between fibers to form the FP cavity structure,which not only significantly improves the overall sensor performance,but also enhances its sensitivity to changes in temperature,pressure,and refractive index.In the final part of this study,we successfully validated the exceptional performance of the PDMS end-cap based fiber FP sensor in detecting different temperatures conditions.Experimental results demonstrate a temperature sensitivity of 0.752 nm/℃for sensors with a 60-μm PDMS end-cap,further confirming the sensor’s reliability and efficiency in practical applications.
