To ensure the safe operation of batteries,accurately obtaining key internal state parameters is essential.However,traditional parameter measurement methods either require opening the battery or long-term measurements,...To ensure the safe operation of batteries,accurately obtaining key internal state parameters is essential.However,traditional parameter measurement methods either require opening the battery or long-term measurements,which are impractical.Therefore,the fixed values are commonly used for these parameters in electrochemical models and have significant limitations.To overcome these limitations,this paper proposes a deep neural network(DNN)based data-driven evaluation method to determine model parameters.By coupling an improved one-dimensional isothermal pseudo-twodimensional(P2D)model with DNN,this study identified concentration-dependent parameters through detailed discharge curve analysis.The results show that the data-driven method can effectively obtain the change trend of concentration-dependent parameters through the charge and discharge curve,and the method can be extended to different battery systems in different discharge rates and aging applications.This work is expected to provide new parameter selection insights for data-driven battery prediction and monitoring models.展开更多
The Mn-Ce-Nb-O_x/P84 catalytic filter for removal of particulates and NO simultaneous was prepared by a novel method(foam coating method). The process parameters including the concentrations of PTFE emulsion, particle...The Mn-Ce-Nb-O_x/P84 catalytic filter for removal of particulates and NO simultaneous was prepared by a novel method(foam coating method). The process parameters including the concentrations of PTFE emulsion, particle size of catalyst and calcination temperature for preparation of catalytic filters were analyzed. In addition, the physical properties and performance for removal of NO(NH_3-SCR) and particulates of Mn-Ce-Nb-O_x/P84 catalytic filter prepared under the optimized parameters, were also systematic studied. Results show that the process parameters had significant influences on stability and performance of catalytic filter, The Mn-Ce-Nb-O_x/P84 catalytic filter prepared by foam coating method under the optimized parameters, has satisfactory physical properties and catalytic performance for removal of NO and particulates at 140-220 ℃. The NO removal efficiency of catalytic filter can reach95.3% at 200 ℃ as the catalyst loading amount is 450 g/m^2, Moreover,the dust removal efficiency of MnGe-Nb-O_x/P84 catalytic filter reaches as high as 99.98%, and the PM2.5 removal efficiency also reaches99.98%. The anti-sulfur performance of Mn-Ce-Nb-O_x catalytic filter is also attractive, after injecting150 ppm SO_2, the NO removal efficiency still retains up to 85%. It is indicated that the foam coating method can not only make a bond of high strength between catalyst and filter, but also make the catalytic filter possessing an excellent and stable performance for removal of NO and particulates.展开更多
The effect of Na-excess content in the precursor on the structural and electrochemical performances of sodium nickel manganese oxide(NNMO)prepared by sol-gel and electrospinning methods is investigated in this paper.X...The effect of Na-excess content in the precursor on the structural and electrochemical performances of sodium nickel manganese oxide(NNMO)prepared by sol-gel and electrospinning methods is investigated in this paper.X-ray diffraction results of the prepared NNMO without adding Na-excess content indicate sodium loss,while the mixed phase of P2/O′3-type layered NNMO presented after adding Na-excess content.Compared with the sol-gel method,the secondary phase of NiO is more suppressed by using the electrospinning method,which is further confirmed by field emission scanning electron microscope images.N_(2) adsorption-desorption isotherms show no remarkably difference in specific surface areas between different preparation methods and Na-excess contents.The analysis of X-ray absorption near edge structure indicates that the oxidation states of Ni and Mn are+2 and+4,respectively.For the electrochemical properties,superior electrochemical performance is observed in the NNMO electrode with a low Na-excess content of 5wt%.The highest specific capacitance is 36.07 F·g^(-1)at0.1 A·g^(-1)in the NNMO electrode prepared by using the sol-gel method.By contrast,the NNMO electrode prepared using the electrospinning method with decreased Na-excess content shows excellent cycling stability of 100%after charge-discharge measurements for 300 cycles.Therefore,controlling the Na excess in the precursor together with the preparation method is important for improving the electrochemical performance of Na-based electrode materials in supercapacitors.展开更多
An incubation study was conducted in laboratory to determine the effect of lime (L) as CaCO3 and phosphorus (P) as TSP on soil pH and available soil P in an acid soil. Four rates of L equivalent to 0, 1, 2 and 3 ton C...An incubation study was conducted in laboratory to determine the effect of lime (L) as CaCO3 and phosphorus (P) as TSP on soil pH and available soil P in an acid soil. Four rates of L equivalent to 0, 1, 2 and 3 ton CaCO3 ha-1 and four rates of P equivalent to 0, 25, 50 and 75 mg P kg-1 were applied in combinations as treatments. The soil was incubated at field capacity for 8 weeks (wk) after which they were extracted using NaHCO3 (Olsen), Mehlich-3, Kelowna and Bray & Kurtz-1 extractants and soil pH was determined. Lime significantly (P < 0.001) increased soil pH. Phosphorus decreased it, though not significantly. Both L and P had significant effects (P < 0.001) on P availability irrespective of extractants used. Two ton CaCO3 plus 75 mg P kg-1 gave the highest available phosphorus. Mehlich-3 method extracted the largest amount of P (14.54 - 67.35 mg·kg-1) while Olsen extracted the smallest amount (3.25 - 32.77 mg·kg-1). The mean extractable P in soils was found to be in the order of Olsen 2 = 0.87 to 0.95).展开更多
The lowest order Pl-nonconforming triangular finite element method （FEM） for elliptic and parabolic interface problems is investigated. Under some reasonable regularity assumptions on the exact solutions, the optima...The lowest order Pl-nonconforming triangular finite element method （FEM） for elliptic and parabolic interface problems is investigated. Under some reasonable regularity assumptions on the exact solutions, the optimal order error estimates are obtained in the broken energy norm. Finally, some numerical results are provided to verify the theoretical analysis.展开更多
TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface w...TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface water, we herein examined the preparation of a P25-TiO2 composite film on a cement substrate via a sol–gel method. In this case, Rhodamine B（Rh B）was employed as the target organic pollutant. The self-generated TiO2 film and the P25-TiO2 composite film were characterized by X-ray diffraction（XRD）, N2 adsorption/desorption measurements, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, and diffuse reflectance spectroscopy（DRS）. The photodegradation efficiencies of the two films were studied by Rh B removal in water under UV（ultraviolet） irradiation. Over 4 day exposure, the P25-TiO2 composite film exhibited higher photocatalytic performance than the self-generated TiO2 film. The photodegradation rate indicated that the efficiency of the P25-TiO2 composite film was enhanced by the addition of the rutile phase Degussa P25 powder. As such, cooperation between the anatase TiO2 and rutile P25 nanoparticles was beneficial for separation of the photo-induced electrons and holes. In addition, the influence of P25 doping on the P25-TiO2 composite films was evaluated. We found that up to a certain saturation point, increased doping enhanced the photodegradation ability of the composite film. Thus, we herein demonstrated that the doping of P25 powders is a simple but effective strategy to prepare a P25-TiO2 composite film on a cement substrate, and the resulting film exhibits excellent removal efficiency in the degradation of organic pollutants.展开更多
The effect of Al-substitution on the electrochemical performances of Li3V2(PO4)3 cathode materials was studied.Samples with stoichiometric proportion of Li3AlxV2-x(PO4)3(x=0,0.05,0.10)were prepared by adding Al(NO3)3 ...The effect of Al-substitution on the electrochemical performances of Li3V2(PO4)3 cathode materials was studied.Samples with stoichiometric proportion of Li3AlxV2-x(PO4)3(x=0,0.05,0.10)were prepared by adding Al(NO3)3 in the raw materials of Li3V2(PO4)3.The XRD analysis shows that the Al-substituted Li3V2(PO4)3 has the same monoclinic structure as the un-substituted Li3V2(PO4)3.The SEM images show that Al-substituted Li3V2(PO4)3 has regular and uniform particles.The electrochemical measurements show that Al-substitution can improve the rate capability of cathode materials.The Li3Al0.05V1.95(PO4)3 sample shows the best high-rate performance.The discharge capacity at 1C rate is 119 mA·h/g with 30th capacity retention rate about 92.97%.The electrode reaction reversibility and electronic conductivity are enhanced,and the charge transfer resistance decreases through Al-substitution.The improved electrochemical performances of Al-substituted Li3V2(PO4)3 cathode materials offer some favorable properties for their commercial application.展开更多
This paper deals with the Alienor method to tackle multiobjective nonlinear optimization problems. In this approach, the multiple criteria of the optimization problem are aggregated into a single one using weighted su...This paper deals with the Alienor method to tackle multiobjective nonlinear optimization problems. In this approach, the multiple criteria of the optimization problem are aggregated into a single one using weighted sums. Then, the resulting single objective nonlinear optimization problem is solved using the Alienor method associated with the Optimization Preserving Operators technique which has proved to be suitable for (nonlinear) optimization problems with a large number of variables (see [1]). The proposed approach is evaluated through test problems. The results show that the approach provides good approximations of the Pareto front while requiring small computational time, even for large instances.展开更多
Dear Editor,I am Dr.Jia X from the Department of Ophthalmology,Second Xiangya Hospital,Central South University,Changsha,China.I write to present a rare case report of 9p deletion syndrome with congenital infantile gl...Dear Editor,I am Dr.Jia X from the Department of Ophthalmology,Second Xiangya Hospital,Central South University,Changsha,China.I write to present a rare case report of 9p deletion syndrome with congenital infantile glaucoma in an infant,accompanying with an effective method of both diagnosis and treatment.展开更多
Based on the Mohr-Coulomb failure principle and Rankine's theory, the laterally loaded pile ultimate resistance formulas of sand and soft clay proposed by Reese and Matlock respectively are discussed in this paper...Based on the Mohr-Coulomb failure principle and Rankine's theory, the laterally loaded pile ultimate resistance formulas of sand and soft clay proposed by Reese and Matlock respectively are discussed in this paper. The authors put forward the modified ultimate resistance formulas on the basis of which the ultimate resistance formula is developed for horizontally loaded pile in multi-layer soil in consideration of the effect of the overburden soil pressure on the calculation of soil layer. It is significant to the correct application of the ultimate resistance formulas in API and ZCS Rules into offshore engineering.展开更多
Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane （OCM） were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the be...Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane （OCM） were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the best catalytic performance among all samples. In addition, the effects of different addition sequences of Na, W, Mn, Zr, S and P on the catalytic performance were studied. The absence of Na before the addition of Mn and Zr in the catalysts preparation depressed the formation of the active phases of Mn2O3 and ZrO2 and decreased the activities of the catalysts significantly.展开更多
基金supported by National Natural Science Foundation of China(22478239)Science and Technology Commission of Shanghai Municipality(19DZ2271100)National Natural Science Foundation of China(22208208)。
文摘To ensure the safe operation of batteries,accurately obtaining key internal state parameters is essential.However,traditional parameter measurement methods either require opening the battery or long-term measurements,which are impractical.Therefore,the fixed values are commonly used for these parameters in electrochemical models and have significant limitations.To overcome these limitations,this paper proposes a deep neural network(DNN)based data-driven evaluation method to determine model parameters.By coupling an improved one-dimensional isothermal pseudo-twodimensional(P2D)model with DNN,this study identified concentration-dependent parameters through detailed discharge curve analysis.The results show that the data-driven method can effectively obtain the change trend of concentration-dependent parameters through the charge and discharge curve,and the method can be extended to different battery systems in different discharge rates and aging applications.This work is expected to provide new parameter selection insights for data-driven battery prediction and monitoring models.
基金Project supported by the National Natural Science Foundation of China(21501097,21272118,21577065)the Natural Science Foundation of Jiangsu Province(BK20170954)+2 种基金the Startup Foundation for Introducing Talent of NUIST(2017r073)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China,China(18KJB430019)University Science Research Project of Jiangsu Province(18KJB430019)
文摘The Mn-Ce-Nb-O_x/P84 catalytic filter for removal of particulates and NO simultaneous was prepared by a novel method(foam coating method). The process parameters including the concentrations of PTFE emulsion, particle size of catalyst and calcination temperature for preparation of catalytic filters were analyzed. In addition, the physical properties and performance for removal of NO(NH_3-SCR) and particulates of Mn-Ce-Nb-O_x/P84 catalytic filter prepared under the optimized parameters, were also systematic studied. Results show that the process parameters had significant influences on stability and performance of catalytic filter, The Mn-Ce-Nb-O_x/P84 catalytic filter prepared by foam coating method under the optimized parameters, has satisfactory physical properties and catalytic performance for removal of NO and particulates at 140-220 ℃. The NO removal efficiency of catalytic filter can reach95.3% at 200 ℃ as the catalyst loading amount is 450 g/m^2, Moreover,the dust removal efficiency of MnGe-Nb-O_x/P84 catalytic filter reaches as high as 99.98%, and the PM2.5 removal efficiency also reaches99.98%. The anti-sulfur performance of Mn-Ce-Nb-O_x catalytic filter is also attractive, after injecting150 ppm SO_2, the NO removal efficiency still retains up to 85%. It is indicated that the foam coating method can not only make a bond of high strength between catalyst and filter, but also make the catalytic filter possessing an excellent and stable performance for removal of NO and particulates.
基金financially supported by (i) Suranaree University of Technology,(ii) Thailand Science Research and Innovation,and (iii) National Science,Research and Innovation Fund(project codes 90464 and 160363)。
文摘The effect of Na-excess content in the precursor on the structural and electrochemical performances of sodium nickel manganese oxide(NNMO)prepared by sol-gel and electrospinning methods is investigated in this paper.X-ray diffraction results of the prepared NNMO without adding Na-excess content indicate sodium loss,while the mixed phase of P2/O′3-type layered NNMO presented after adding Na-excess content.Compared with the sol-gel method,the secondary phase of NiO is more suppressed by using the electrospinning method,which is further confirmed by field emission scanning electron microscope images.N_(2) adsorption-desorption isotherms show no remarkably difference in specific surface areas between different preparation methods and Na-excess contents.The analysis of X-ray absorption near edge structure indicates that the oxidation states of Ni and Mn are+2 and+4,respectively.For the electrochemical properties,superior electrochemical performance is observed in the NNMO electrode with a low Na-excess content of 5wt%.The highest specific capacitance is 36.07 F·g^(-1)at0.1 A·g^(-1)in the NNMO electrode prepared by using the sol-gel method.By contrast,the NNMO electrode prepared using the electrospinning method with decreased Na-excess content shows excellent cycling stability of 100%after charge-discharge measurements for 300 cycles.Therefore,controlling the Na excess in the precursor together with the preparation method is important for improving the electrochemical performance of Na-based electrode materials in supercapacitors.
文摘An incubation study was conducted in laboratory to determine the effect of lime (L) as CaCO3 and phosphorus (P) as TSP on soil pH and available soil P in an acid soil. Four rates of L equivalent to 0, 1, 2 and 3 ton CaCO3 ha-1 and four rates of P equivalent to 0, 25, 50 and 75 mg P kg-1 were applied in combinations as treatments. The soil was incubated at field capacity for 8 weeks (wk) after which they were extracted using NaHCO3 (Olsen), Mehlich-3, Kelowna and Bray & Kurtz-1 extractants and soil pH was determined. Lime significantly (P < 0.001) increased soil pH. Phosphorus decreased it, though not significantly. Both L and P had significant effects (P < 0.001) on P availability irrespective of extractants used. Two ton CaCO3 plus 75 mg P kg-1 gave the highest available phosphorus. Mehlich-3 method extracted the largest amount of P (14.54 - 67.35 mg·kg-1) while Olsen extracted the smallest amount (3.25 - 32.77 mg·kg-1). The mean extractable P in soils was found to be in the order of Olsen 2 = 0.87 to 0.95).
基金Project supported by the National Natural Science Foundation of China(No.11271340)
文摘The lowest order Pl-nonconforming triangular finite element method （FEM） for elliptic and parabolic interface problems is investigated. Under some reasonable regularity assumptions on the exact solutions, the optimal order error estimates are obtained in the broken energy norm. Finally, some numerical results are provided to verify the theoretical analysis.
基金supported by the National Science Funds for Creative Research Groups of China (No. 51421006)the National Major Projects of Water Pollution Control and Management Technology (No. 2017ZX07204003)+2 种基金the National Key Plan for Research and Development of China (2016YFC0502203)the Key Program of National Natural Science Foundation of China (No. 91647206)the Qing Lan Project of Jiangsu Province, and PAPD
文摘TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface water, we herein examined the preparation of a P25-TiO2 composite film on a cement substrate via a sol–gel method. In this case, Rhodamine B（Rh B）was employed as the target organic pollutant. The self-generated TiO2 film and the P25-TiO2 composite film were characterized by X-ray diffraction（XRD）, N2 adsorption/desorption measurements, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, and diffuse reflectance spectroscopy（DRS）. The photodegradation efficiencies of the two films were studied by Rh B removal in water under UV（ultraviolet） irradiation. Over 4 day exposure, the P25-TiO2 composite film exhibited higher photocatalytic performance than the self-generated TiO2 film. The photodegradation rate indicated that the efficiency of the P25-TiO2 composite film was enhanced by the addition of the rutile phase Degussa P25 powder. As such, cooperation between the anatase TiO2 and rutile P25 nanoparticles was beneficial for separation of the photo-induced electrons and holes. In addition, the influence of P25 doping on the P25-TiO2 composite films was evaluated. We found that up to a certain saturation point, increased doping enhanced the photodegradation ability of the composite film. Thus, we herein demonstrated that the doping of P25 powders is a simple but effective strategy to prepare a P25-TiO2 composite film on a cement substrate, and the resulting film exhibits excellent removal efficiency in the degradation of organic pollutants.
基金Project(GuiJiaoRen[2007]71)supported by the Research Funds of the Guangxi Key Laboratory of Environmental Engineering,Protection and Assessment Program to Sponsor Teams for Innovation in the Construction of Talent Highlands in Guangxi Institutions of Higher Learning,China
文摘The effect of Al-substitution on the electrochemical performances of Li3V2(PO4)3 cathode materials was studied.Samples with stoichiometric proportion of Li3AlxV2-x(PO4)3(x=0,0.05,0.10)were prepared by adding Al(NO3)3 in the raw materials of Li3V2(PO4)3.The XRD analysis shows that the Al-substituted Li3V2(PO4)3 has the same monoclinic structure as the un-substituted Li3V2(PO4)3.The SEM images show that Al-substituted Li3V2(PO4)3 has regular and uniform particles.The electrochemical measurements show that Al-substitution can improve the rate capability of cathode materials.The Li3Al0.05V1.95(PO4)3 sample shows the best high-rate performance.The discharge capacity at 1C rate is 119 mA·h/g with 30th capacity retention rate about 92.97%.The electrode reaction reversibility and electronic conductivity are enhanced,and the charge transfer resistance decreases through Al-substitution.The improved electrochemical performances of Al-substituted Li3V2(PO4)3 cathode materials offer some favorable properties for their commercial application.
文摘This paper deals with the Alienor method to tackle multiobjective nonlinear optimization problems. In this approach, the multiple criteria of the optimization problem are aggregated into a single one using weighted sums. Then, the resulting single objective nonlinear optimization problem is solved using the Alienor method associated with the Optimization Preserving Operators technique which has proved to be suitable for (nonlinear) optimization problems with a large number of variables (see [1]). The proposed approach is evaluated through test problems. The results show that the approach provides good approximations of the Pareto front while requiring small computational time, even for large instances.
基金Supported by the Natural Science Foundation of China(No.81370913)
文摘Dear Editor,I am Dr.Jia X from the Department of Ophthalmology,Second Xiangya Hospital,Central South University,Changsha,China.I write to present a rare case report of 9p deletion syndrome with congenital infantile glaucoma in an infant,accompanying with an effective method of both diagnosis and treatment.
文摘Based on the Mohr-Coulomb failure principle and Rankine's theory, the laterally loaded pile ultimate resistance formulas of sand and soft clay proposed by Reese and Matlock respectively are discussed in this paper. The authors put forward the modified ultimate resistance formulas on the basis of which the ultimate resistance formula is developed for horizontally loaded pile in multi-layer soil in consideration of the effect of the overburden soil pressure on the calculation of soil layer. It is significant to the correct application of the ultimate resistance formulas in API and ZCS Rules into offshore engineering.
基金supported by the financial support from National Natural Science Foundation of China (20676116)
文摘Na-W-Mn-Zr-S-P/SiO2 catalysts for oxidative coupling of methane （OCM） were prepared by incipient wetness impregnation, sol-gel and mixture slurry methods. The catalyst prepared by mixture slurry method showed the best catalytic performance among all samples. In addition, the effects of different addition sequences of Na, W, Mn, Zr, S and P on the catalytic performance were studied. The absence of Na before the addition of Mn and Zr in the catalysts preparation depressed the formation of the active phases of Mn2O3 and ZrO2 and decreased the activities of the catalysts significantly.
