The mixing injection of natural gas and pulverized coal into the blast furnaces shows a promising technological approach in the context of global carbon reduction initiatives.Carrier gas and coal pass through the air ...The mixing injection of natural gas and pulverized coal into the blast furnaces shows a promising technological approach in the context of global carbon reduction initiatives.Carrier gas and coal pass through the air inlet of coal lance,and the characteristics of carrier gas affect the flow in the air inlet and the combustion efficiency of coal,so it is very important to study the change of carrier gas charac-teristics in the lower part of blast furnace.By means of numerical simulation,the influence of carrier gas characteristics(injection rate,composition,and temperature)on the mixed combustion of natural gas(NG)and pulverized coal in the tuyere raceway of Russian blast furnace was analyzed.When N_(2) is used as carrier gas,the injection rate of carrier gas is reduced from 4000 to 2000 m3/h,the average tuy-ere temperature is increased(1947.42 to 1963.30 K),the mole fractions of CO and H_(2) are increased,and the burnout rate of pulverized coal is decreased.Increasing the carrier gas temperature is helpful to improve the burnout of pulverized coal.For every 20 K increase of carrier gas temperature,the average temperature in the raceway increases by 20.6 K,which promotes the release and combustion of volat-iles,but the increase of carrier gas temperature from 373 to 393 K only leads to 1.16%burnout change.Considering the transportation characteristics of pulverized coal,it is suggested that the carrier gas temperature should be kept at about 373 K to obtain the best perform-ance.It is worth noting that when air is used as carrier gas,the burnout rate of pulverized coal is increased by 2.69%compared with N_(2).展开更多
Molecular dynamics simulations were employed to establish a more realistic model of nanoscale boiling phase transitions.We examined the effects of different configurations of nanoscale sinusoidal protrusions and surfa...Molecular dynamics simulations were employed to establish a more realistic model of nanoscale boiling phase transitions.We examined the effects of different configurations of nanoscale sinusoidal protrusions and surface wettability on the phase transition behavior of systems containing insoluble gases under continuous heat flux input.To enhance the clarity and comparability of the results,a quantitative evaluation method was introduced.The findings reveal that,under identical wettability conditions,increasing the number of sinusoidal protrusions accelerates the onset of phase transition.In contrast,for a fixed number of protrusions,higher surface wettability delays the initiation of the phase change.By incorporating regression analysis to quantify the phase transition process and compare influencing factors,it was observed that although high wettability generally inhibits phase transition,the synergistic interaction between surface structure and wettability ultimately facilitates the phase transition process.展开更多
Industry and energy continue to require piston engines(PICE)at a high level worldwide.Therefore,science and technology must urgently work on improving the PICE working cycle.Improving the quality of the intake process...Industry and energy continue to require piston engines(PICE)at a high level worldwide.Therefore,science and technology must urgently work on improving the PICE working cycle.Improving the quality of the intake process of theworking fluid into the cylinder is one of the most effective ways to improve the operational performance of PICE.The purpose of the study was to assess the impact of various cylinder head(CylH)designs on the gas-dynamic and heat-exchange qualities of air flows within an engine model’s intake system.Three different CylH designs were studied:the basic configuration and upgraded cylinder heads with a square valve and a square valve port.These designs are innovative.Laboratory conditions were used to conduct the studies for stationary air flow.The experiments covered the range of Reynolds numbers from 8500 to 96,000.The intake system’s gas dynamics and heat transfer were determined using the thermal anemometry method,which was based on constant-temperature hot-wire anemometers.It has been established that the use of upgraded CylHs causes an increase in the turbulence number of flow by an average of 13.5%.Additionally,itwas found that the increase in the turbulence number of flowin the cylinder is about 19%when installing new CylH designs.It was shown that therewas an increase in the heat transfer coefficient in the intake pipe by 10%–40%when installing modernized CylH designs in the intake system.The article focused on the problems of increasing the turbulence level and intensifying the heat transfer of stationary air flow in the intake system,specifically in PICEs.The study’s findings are novel in the areas of applied gas dynamics and PICEs.展开更多
A model for modified-atmosphere packaging （MAP） systems containing fruits and vegetables was developed.The computer simulation was performed to predict the gas mass concentrations inside the packages and was success...A model for modified-atmosphere packaging （MAP） systems containing fruits and vegetables was developed.The computer simulation was performed to predict the gas mass concentrations inside the packages and was successfully verified by experiments with yellow peaches at 5,15 and 25 ℃ using two types of packaging films.A Michaelis-Menten type respiration model with noncompetitive inhibition mechanism due to CO2 was adopted while the respiration rates were measured with an improved permeable system method suitable for either steady or unsteady state.The applicability of the model in the design of MAP systems was demonstrated with a calculation to evaluate film specification and equilibrium concentrations of O2 and CO2 in the package containing yellow peaches.展开更多
In this paper molecular dynamics simulations are performed to study the accumulation behaviour of N2 and H2 at water/graphite interface under ambient temperature and pressure. It finds that both N2 and H2 molecules ca...In this paper molecular dynamics simulations are performed to study the accumulation behaviour of N2 and H2 at water/graphite interface under ambient temperature and pressure. It finds that both N2 and H2 molecules can accumulate at the interface and form one of two states according to the ratio of gas molecules number to square of graphite surface from our simulation results： gas films （pancake-like） for a larger ratio and nanobubbles for a smaller ratio. In addition, we discuss the stabilities of nanobubbles at different environment temperatures. Surprisingly, it is found that the density of both kinds of gas states can be greatly increased, even comparable with that of the liquid N2 and liquid H2. The present results are expected to be helpful for the understanding of the stable existence of gas film （pancake-like） and nanobubbles.展开更多
Based on the study of the relationship between structure and feedback of China’s natural gas demand system, this paper establishes a system dynamics model. In order to simulate the total demand and consumption struct...Based on the study of the relationship between structure and feedback of China’s natural gas demand system, this paper establishes a system dynamics model. In order to simulate the total demand and consumption structure of natural gas in China, we set up seven scenarios by changing some of the parameters of the model. The results showed that the total demand of natural gas would increase steadily year by year and reach in the range from 3600 to 4500 billion cubic meters in 2035. Furthermore, in terms of consumption structure, urban gas consumption would still be the largest term, followed by the gas consumption as industrial fuel, gas power generation and natural gas chemical industry. In addition, compared with the population growth, economic development still plays a dominant role in the natural gas demand growth, the impact of urbanization on urban gas consumption is significant, and the promotion of natural gas utilization technology can effectively reduce the total consumption of natural gas.展开更多
In this paper, we study the vanishing viscosity limit for non-isentropic gas dy- namics with interacting shocks. Given any entropy solution of non-isentropic gas dynamics which consists of two different families of sh...In this paper, we study the vanishing viscosity limit for non-isentropic gas dy- namics with interacting shocks. Given any entropy solution of non-isentropic gas dynamics which consists of two different families of shocks interacting at some positive time, we show that such solution is the vanishing viscosity limit of a family of smooth global solutions for a viscous system of conservation law. We remark that, after the interacting time, not only shocks but also contact discontinuity are generated.展开更多
Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization proces...Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.展开更多
In this article, we study the global L^∞ entropy solutions for the Cauchy problem of system of isentropic gas dynamics in a divergent nozzle with a friction. Especially when the adiabatic exponent γ=3, we apply for ...In this article, we study the global L^∞ entropy solutions for the Cauchy problem of system of isentropic gas dynamics in a divergent nozzle with a friction. Especially when the adiabatic exponent γ=3, we apply for the maximum principle to obtain the L^∞ estimates w(ρ^δ,ε, u^δ,ε)≤ B(t) and z(ρ^δ,ε, u^δ,ε)≤ B(t) for the viscosity solutions (ρ^δ,ε, u^δ,ε), where B(t) is a nonnegative bounded function for any finite time t. This work, in the special case γ≥ 3, extends the previous works, which provided the global entropy solutions for the same Cauchy problem with the restriction w(ρ^δ,ε, u^δ,ε)≤ 0 or z(ρ^δ,ε, u^δ,ε)≤ 0.展开更多
A compactness frame of the Lax-Friedrichs scheme for the equations of gas dynamics is obtained by using some embedding theorems and an analysis of the difference scheme and the weak entropy.
In this paper,Runge-Kutta Discontinuous Galerkin（RKDG） finite element method is presented to solve the onedimensional inviscid compressible gas dynamic equations in a Lagrangian coordinate.The equations are discreti...In this paper,Runge-Kutta Discontinuous Galerkin（RKDG） finite element method is presented to solve the onedimensional inviscid compressible gas dynamic equations in a Lagrangian coordinate.The equations are discretized by the DG method in space and the temporal discretization is accomplished by the total variation diminishing Runge-Kutta method.A limiter based on the characteristic field decomposition is applied to maintain stability and non-oscillatory property of the RKDG method.For multi-medium fluid simulation,the two cells adjacent to the interface are treated differently from other cells.At first,a linear Riemann solver is applied to calculate the numerical ？ux at the interface.Numerical examples show that there is some oscillation in the vicinity of the interface.Then a nonlinear Riemann solver based on the characteristic formulation of the equation and the discontinuity relations is adopted to calculate the numerical ？ux at the interface,which suppresses the oscillation successfully.Several single-medium and multi-medium fluid examples are given to demonstrate the reliability and efficiency of the algorithm.展开更多
This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and tec...This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and technical gaps between experiments and classical theories.The experimental data are scarce at these conditions which are also out of assumptions for classical predictive correlations,such as the Dranchuk&Abou-Kassem(DAK)equation of state(EOS).Force fields of natural gas components were carefully chosen from literatures and the simulation results are validated with experimental data.The largest relative error is 2.67%for pure hydrocarbons,2.99%for C1/C3 mixture,7.85%for C1/C4 mixture,and 8.47%for pure H2S.These satisfactory predictions demonstrate that the MD simulation approach is reliable to predict natural-and acid-gases thermodynamic properties.The validated model is further used to generate data for the study of the EOS with pressure up to 276 MPa and temperature up to 573 K.Our results also reveal that the Dranchuk&Abou-Kassem(DAK)EOS is capable of predicting natural gas compressibility to a satisfactory accuracy at x HPHT conditions,which extends the confidence range of the DAK EOS.展开更多
The precision of dynamic reserve calculations in gas reservoirs is crucial for the rational and efficient development of oil and gas fields and the formulation of gas well production plans.The Shaximiao gas reservoir ...The precision of dynamic reserve calculations in gas reservoirs is crucial for the rational and efficient development of oil and gas fields and the formulation of gas well production plans.The Shaximiao gas reservoir in the ZT block of northwestern Sichuan is densely packed and highly heterogeneous,featuring complex gas-water distribution,substantial variations in test production among gas wells,and a rapid decline rate.To precisely determine the dynamic reserves of these tight water-bearing gas wells,this study focuses on the water-tight gas reservoirs in the ZT block of northwestern Sichuan,conducting core X-ray diffraction,constant-rate mercury injection,and reservoir rock stress sensitivity experiments.Utilizing the experimental findings,the porosity and permeability of the rock samples under effective stress conditions are adjusted via binary linear regression.These adjusted parameters are then incorporated into the water-sealed gas material balance method,thereby establishing a novel approach for calculating dynamic reserves in water-tight gas reservoirs under stress sensitivity conditions.The results show that:(1)the rock porosity ranges from 6.08%to 10.22%,permeability ranges from 0.035 mD to 0.547 mD,clay mineral content ranges from 6.58%to 19.14%,pore radius distribution ranges from 90μm to 180μm,throat radius distribution ranges from 0.61μm to 3.41μm,with significant differences in throat distribution,indicating poor reservoir fluid flow capacity and strong tightness;(2)after aging experiments,rock samples exhibit plastic deformation,with porosity and permeability unable to fully recover after pressure relief.The stress sensitivity curve of rock samples shows a two-stage characteristic,with moderate to strong stress sensitivity;(3)porosity stress sensitivity is mainly influenced by pore radius and mineral composition-larger pore radius and higher clay content lead to stronger stress sensitivity,with porosity loss rates ranging from 8.26%to 23.69%.Permeability stress sensitivity is mainly influenced by throat radius and mineral composition-smaller throat radius and higher clay content result in stronger stress sensitivity,with permeability loss rates ranging from 47.91%to 62.03%;(4)a comparative analysis between the traditional dynamic reserve calculation method for gas wells and the new method considering stress sensitivity shows a relative error between 0.90%and 2.41%,with the new method demonstrating better accuracy.This study combines physical experimental results with an effective stress model of reservoir rocks to develop a new method for calculating dynamic reserves of water-bearing tight gas reservoirs under effective stress conditions,providing experimental data and example calculation results to support subsequent dynamic evaluation of gas reservoirs and the establishment of rational well allocation plans.展开更多
To address the issues of single warning indicators,fixed thresholds,and insufficient adaptability in coal and gas outburst early warning models,this study proposes a dynamic early warning model for gas outbursts based...To address the issues of single warning indicators,fixed thresholds,and insufficient adaptability in coal and gas outburst early warning models,this study proposes a dynamic early warning model for gas outbursts based on adaptive fractal dimension characterization.By analyzing the nonlinear characteristics of gas concentration data,an adaptive window fractal analysis method is introduced.Combined with boxcounting dimension and variation of box dimension metrics,a cross-scale dynamic warning model for disaster prevention is established.The implementation involves three key phases:First,wavelet denoising and interpolation methods are employed for raw data preprocessing,followed by validation of fractal characteristics.Second,an adaptive window cross-scale fractal dimension method is proposed to calculate the box-counting dimension of gas concentration,enabling effective capture of multi-scale complex features.Finally,dynamic threshold partitioning is achieved through membership functions and the 3σprinciple,establishing a graded classification standard for the mine gas disaster(MGD)index.Validated through engineering applications at Shoushan#1 Coal Mine in Henan Province,the results demonstrate that the adaptive window fractal dimension curve exhibits significantly enhanced fluctuation characteristics compared to fixed window methods,with local feature detection capability improved and warning accuracy reaching 86.9%.The research reveals that this model effectively resolves the limitations of traditional methods in capturing local features and dependency on subjective thresholds through multiindicator fusion and threshold optimization,providing both theoretical foundation and practical tool for coal mine gas outburst early warning.展开更多
The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.T...The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.The dynamic sealing capacity of a caprock-fault system is a critical constraint for safe operation,and is a key factor in determining the maximum operating pressure(MOP).This study proposed an efficient semi-analytical method for calculating changes in the in situ stress within the caprock.Next,the parameters of dynamic pore pressure,in situ stresses,and deformations obtained from reservoir simulations and geomechanical modeling were used for inputs for the analytical solution.Based on the calculated results,an experimental scheme for the coupled cyclic stress-permeability testing of caprock was designed.The stability analysis indicated that the caprock was not prone to fatigue shear failure under the current injection and production strategy,supported by the experimental results.The experimental results further reveal that the sealing capacity of caprock plugs may remain stable.This phenomenon is attributed to cyclic stress causing pore connectivity and microcrack initiation in certain plugs,while leading to pore compaction in others.A comparison between the dynamic pore pressure and the minimum principal stress suggests that the risk of tensile failure is extremely low.Furthermore,although the faults remain stable under the current injection and production strategies,the continuous increase in injection pressure may lead to an increased tendency for fault slip and dilation,which can cause fault slip ultimately.The MOPs corresponding to each failure mode were calculated.The minimum value of approximately 36.5 MPa at capillary sealing failure indicated that the gas breakthrough in the caprock occurred earlier than rock failure.Therefore,this minimumvalue can be used as the MOP for the target UGS.展开更多
Organic semiconductor materials have demonstrated extensive potential in the field of gas sensors due to the advantages including designable chemical structure,tunable physical and chemical properties.Through density ...Organic semiconductor materials have demonstrated extensive potential in the field of gas sensors due to the advantages including designable chemical structure,tunable physical and chemical properties.Through density functional theory(DFT)calculations,researchers can investigate gas sensing mechanisms,optimize,and predict the electronic structures and response characteristics of these materials,and thereby identify candidate materials with promising gas sensing applications for targeted design.This review concentrates on three primary applications of DFT technology in the realm of organic semiconductor-based gas sensors:(1)Investigating the sensing mechanisms by analyzing the interactions between gas molecules and sensing materials through DFT,(2)simulating the dynamic responses of gas molecules,which involves the behavior on the sensing interface using DFT combined with other computational methods to explore adsorption and diffusion processes,and(3)exploring and designing sensitive materials by employing DFT for screening and predicting chemical structures,thereby developing new sensing materials with exceptional performance.Furthermore,this review examines current research outcomes and anticipates the extensive application prospects of DFT technology in the domain of organic semiconductor-based gas sensors.These efforts are expected to provide valuable insights for further indepth exploration of DFT applications in sensor technology,thereby fostering significant advancements and innovations in the field.展开更多
In nonisentropic gas dynamics, with general equations of state, strong cornpressive shocks satisfying the Liu E-condition may violate the Second Law of thermodynamics.
We investigate the vacuum in nonisentropic gas dynamics in one space vari- able, with the most general equation of states allowed by thermodynamics. We recall physical constraints on the equations of state and give ex...We investigate the vacuum in nonisentropic gas dynamics in one space vari- able, with the most general equation of states allowed by thermodynamics. We recall physical constraints on the equations of state and give explicit and easily checkable conditions under which vacuums occur in the solution of the Riemann problem. We then present a class of models for which the Riemann problem admits unique global solutions without vacuums.展开更多
Evolution and interaction of plane waves of the multidimensional zero-pressure gas dynamics system leads to the study of the corresponding one dimensional system.In this paper,we study the initial value problem for on...Evolution and interaction of plane waves of the multidimensional zero-pressure gas dynamics system leads to the study of the corresponding one dimensional system.In this paper,we study the initial value problem for one dimensional zero-pressure gas dynamics system.Here the first equation is the Burgers equation and the second one is the continuity equation.We consider the solution with initial data in the space of bounded Borel measures.First we prove a general existence result in the algebra of generalized functions of Colombeau.Then we study in detail special solutions withδ-measures as initial data.We study interaction of waves originating from initial data concentrated on two point sources and interaction with classical shock/rarefaction waves.This gives an understanding of plane-wave interactions in the multidimensional case.We use the vanishing viscosity method in our analysis as this gives the physical solution.展开更多
基金financially supported by the National Key R&D Program of China(No.2022YFE0208100)the Major Science and Technology Project of Xinjiang Uygur Autonomous Region,China(No.2022A01003)+1 种基金the Key Research and Development Plan of Anhui Province,China(No.202210700037)the National Natural Science Foundation of China(No.52274316).
文摘The mixing injection of natural gas and pulverized coal into the blast furnaces shows a promising technological approach in the context of global carbon reduction initiatives.Carrier gas and coal pass through the air inlet of coal lance,and the characteristics of carrier gas affect the flow in the air inlet and the combustion efficiency of coal,so it is very important to study the change of carrier gas charac-teristics in the lower part of blast furnace.By means of numerical simulation,the influence of carrier gas characteristics(injection rate,composition,and temperature)on the mixed combustion of natural gas(NG)and pulverized coal in the tuyere raceway of Russian blast furnace was analyzed.When N_(2) is used as carrier gas,the injection rate of carrier gas is reduced from 4000 to 2000 m3/h,the average tuy-ere temperature is increased(1947.42 to 1963.30 K),the mole fractions of CO and H_(2) are increased,and the burnout rate of pulverized coal is decreased.Increasing the carrier gas temperature is helpful to improve the burnout of pulverized coal.For every 20 K increase of carrier gas temperature,the average temperature in the raceway increases by 20.6 K,which promotes the release and combustion of volat-iles,but the increase of carrier gas temperature from 373 to 393 K only leads to 1.16%burnout change.Considering the transportation characteristics of pulverized coal,it is suggested that the carrier gas temperature should be kept at about 373 K to obtain the best perform-ance.It is worth noting that when air is used as carrier gas,the burnout rate of pulverized coal is increased by 2.69%compared with N_(2).
基金supported by the National Natural Science Foundation of China(Grant No.52176077).
文摘Molecular dynamics simulations were employed to establish a more realistic model of nanoscale boiling phase transitions.We examined the effects of different configurations of nanoscale sinusoidal protrusions and surface wettability on the phase transition behavior of systems containing insoluble gases under continuous heat flux input.To enhance the clarity and comparability of the results,a quantitative evaluation method was introduced.The findings reveal that,under identical wettability conditions,increasing the number of sinusoidal protrusions accelerates the onset of phase transition.In contrast,for a fixed number of protrusions,higher surface wettability delays the initiation of the phase change.By incorporating regression analysis to quantify the phase transition process and compare influencing factors,it was observed that although high wettability generally inhibits phase transition,the synergistic interaction between surface structure and wettability ultimately facilitates the phase transition process.
文摘Industry and energy continue to require piston engines(PICE)at a high level worldwide.Therefore,science and technology must urgently work on improving the PICE working cycle.Improving the quality of the intake process of theworking fluid into the cylinder is one of the most effective ways to improve the operational performance of PICE.The purpose of the study was to assess the impact of various cylinder head(CylH)designs on the gas-dynamic and heat-exchange qualities of air flows within an engine model’s intake system.Three different CylH designs were studied:the basic configuration and upgraded cylinder heads with a square valve and a square valve port.These designs are innovative.Laboratory conditions were used to conduct the studies for stationary air flow.The experiments covered the range of Reynolds numbers from 8500 to 96,000.The intake system’s gas dynamics and heat transfer were determined using the thermal anemometry method,which was based on constant-temperature hot-wire anemometers.It has been established that the use of upgraded CylHs causes an increase in the turbulence number of flow by an average of 13.5%.Additionally,itwas found that the increase in the turbulence number of flowin the cylinder is about 19%when installing new CylH designs.It was shown that therewas an increase in the heat transfer coefficient in the intake pipe by 10%–40%when installing modernized CylH designs in the intake system.The article focused on the problems of increasing the turbulence level and intensifying the heat transfer of stationary air flow in the intake system,specifically in PICEs.The study’s findings are novel in the areas of applied gas dynamics and PICEs.
基金The Start-up Research Fund for Teachers withDoctor s Degree by Shanghai University of Science and Technology (No.X530)the Key Subject Foundation of Shanghai Education Committee(PeriodⅣ).
文摘A model for modified-atmosphere packaging （MAP） systems containing fruits and vegetables was developed.The computer simulation was performed to predict the gas mass concentrations inside the packages and was successfully verified by experiments with yellow peaches at 5,15 and 25 ℃ using two types of packaging films.A Michaelis-Menten type respiration model with noncompetitive inhibition mechanism due to CO2 was adopted while the respiration rates were measured with an improved permeable system method suitable for either steady or unsteady state.The applicability of the model in the design of MAP systems was demonstrated with a calculation to evaluate film specification and equilibrium concentrations of O2 and CO2 in the package containing yellow peaches.
基金supported in part by National Natural Science Foundation of China (Grant Nos 10474109 and 10674146)supported is part by the Shanghai Supercomputer Center of China
文摘In this paper molecular dynamics simulations are performed to study the accumulation behaviour of N2 and H2 at water/graphite interface under ambient temperature and pressure. It finds that both N2 and H2 molecules can accumulate at the interface and form one of two states according to the ratio of gas molecules number to square of graphite surface from our simulation results： gas films （pancake-like） for a larger ratio and nanobubbles for a smaller ratio. In addition, we discuss the stabilities of nanobubbles at different environment temperatures. Surprisingly, it is found that the density of both kinds of gas states can be greatly increased, even comparable with that of the liquid N2 and liquid H2. The present results are expected to be helpful for the understanding of the stable existence of gas film （pancake-like） and nanobubbles.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 71273021 and 7167030506)
文摘Based on the study of the relationship between structure and feedback of China’s natural gas demand system, this paper establishes a system dynamics model. In order to simulate the total demand and consumption structure of natural gas in China, we set up seven scenarios by changing some of the parameters of the model. The results showed that the total demand of natural gas would increase steadily year by year and reach in the range from 3600 to 4500 billion cubic meters in 2035. Furthermore, in terms of consumption structure, urban gas consumption would still be the largest term, followed by the gas consumption as industrial fuel, gas power generation and natural gas chemical industry. In addition, compared with the population growth, economic development still plays a dominant role in the natural gas demand growth, the impact of urbanization on urban gas consumption is significant, and the promotion of natural gas utilization technology can effectively reduce the total consumption of natural gas.
基金Xiaoding Shi was supported by National Natural Sciences Foundation of China(11471321)Yan Yong was supported by National Natural Sciences Foundation of China(11201301)
文摘In this paper, we study the vanishing viscosity limit for non-isentropic gas dy- namics with interacting shocks. Given any entropy solution of non-isentropic gas dynamics which consists of two different families of shocks interacting at some positive time, we show that such solution is the vanishing viscosity limit of a family of smooth global solutions for a viscous system of conservation law. We remark that, after the interacting time, not only shocks but also contact discontinuity are generated.
基金supported by National Natural Science Foundation of China(62104082)Guangdong Basic and Applied Basic Research Foundation(2022A1515010746,2022A1515011228,and 2022B1515120006)the Science and Technology Program of Guangzhou(202201010458).
文摘Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.
基金supported by the Zhejiang Natural Science Foundation of China(LQ13A010022)supported by the Qianjiang professorship of Zhejiang Province of Chinathe National Natural Science Foundation of China(11271105)
文摘In this article, we study the global L^∞ entropy solutions for the Cauchy problem of system of isentropic gas dynamics in a divergent nozzle with a friction. Especially when the adiabatic exponent γ=3, we apply for the maximum principle to obtain the L^∞ estimates w(ρ^δ,ε, u^δ,ε)≤ B(t) and z(ρ^δ,ε, u^δ,ε)≤ B(t) for the viscosity solutions (ρ^δ,ε, u^δ,ε), where B(t) is a nonnegative bounded function for any finite time t. This work, in the special case γ≥ 3, extends the previous works, which provided the global entropy solutions for the same Cauchy problem with the restriction w(ρ^δ,ε, u^δ,ε)≤ 0 or z(ρ^δ,ε, u^δ,ε)≤ 0.
文摘A compactness frame of the Lax-Friedrichs scheme for the equations of gas dynamics is obtained by using some embedding theorems and an analysis of the difference scheme and the weak entropy.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11261035,11171038,and 10771019)the Science Reaearch Foundation of Institute of Higher Education of Inner Mongolia Autonomous Region,China (Grant No. NJZZ12198)the Natural Science Foundation of Inner Mongolia Autonomous Region,China (Grant No. 2012MS0102)
文摘In this paper,Runge-Kutta Discontinuous Galerkin（RKDG） finite element method is presented to solve the onedimensional inviscid compressible gas dynamic equations in a Lagrangian coordinate.The equations are discretized by the DG method in space and the temporal discretization is accomplished by the total variation diminishing Runge-Kutta method.A limiter based on the characteristic field decomposition is applied to maintain stability and non-oscillatory property of the RKDG method.For multi-medium fluid simulation,the two cells adjacent to the interface are treated differently from other cells.At first,a linear Riemann solver is applied to calculate the numerical ？ux at the interface.Numerical examples show that there is some oscillation in the vicinity of the interface.Then a nonlinear Riemann solver based on the characteristic formulation of the equation and the discontinuity relations is adopted to calculate the numerical ？ux at the interface,which suppresses the oscillation successfully.Several single-medium and multi-medium fluid examples are given to demonstrate the reliability and efficiency of the algorithm.
基金partial financial support from Ballard Petroleum Holdings and Yangtze Universitythe Schooner Supercomputing from the University of Oklahomathe startup support from the University of Oklahoma。
文摘This work applied molecular dynamics(MD)simulation to calculate densities of natural gas mixtures at extremely high pressure(>138 MPa)and high temperature(>200℃)conditions(x HPHT)to bridge the knowledge and technical gaps between experiments and classical theories.The experimental data are scarce at these conditions which are also out of assumptions for classical predictive correlations,such as the Dranchuk&Abou-Kassem(DAK)equation of state(EOS).Force fields of natural gas components were carefully chosen from literatures and the simulation results are validated with experimental data.The largest relative error is 2.67%for pure hydrocarbons,2.99%for C1/C3 mixture,7.85%for C1/C4 mixture,and 8.47%for pure H2S.These satisfactory predictions demonstrate that the MD simulation approach is reliable to predict natural-and acid-gases thermodynamic properties.The validated model is further used to generate data for the study of the EOS with pressure up to 276 MPa and temperature up to 573 K.Our results also reveal that the Dranchuk&Abou-Kassem(DAK)EOS is capable of predicting natural gas compressibility to a satisfactory accuracy at x HPHT conditions,which extends the confidence range of the DAK EOS.
基金supported by CNPC Southwest Oil and Gas Field Branch's 2023 Scientific Research Program Project(20230303-14).
文摘The precision of dynamic reserve calculations in gas reservoirs is crucial for the rational and efficient development of oil and gas fields and the formulation of gas well production plans.The Shaximiao gas reservoir in the ZT block of northwestern Sichuan is densely packed and highly heterogeneous,featuring complex gas-water distribution,substantial variations in test production among gas wells,and a rapid decline rate.To precisely determine the dynamic reserves of these tight water-bearing gas wells,this study focuses on the water-tight gas reservoirs in the ZT block of northwestern Sichuan,conducting core X-ray diffraction,constant-rate mercury injection,and reservoir rock stress sensitivity experiments.Utilizing the experimental findings,the porosity and permeability of the rock samples under effective stress conditions are adjusted via binary linear regression.These adjusted parameters are then incorporated into the water-sealed gas material balance method,thereby establishing a novel approach for calculating dynamic reserves in water-tight gas reservoirs under stress sensitivity conditions.The results show that:(1)the rock porosity ranges from 6.08%to 10.22%,permeability ranges from 0.035 mD to 0.547 mD,clay mineral content ranges from 6.58%to 19.14%,pore radius distribution ranges from 90μm to 180μm,throat radius distribution ranges from 0.61μm to 3.41μm,with significant differences in throat distribution,indicating poor reservoir fluid flow capacity and strong tightness;(2)after aging experiments,rock samples exhibit plastic deformation,with porosity and permeability unable to fully recover after pressure relief.The stress sensitivity curve of rock samples shows a two-stage characteristic,with moderate to strong stress sensitivity;(3)porosity stress sensitivity is mainly influenced by pore radius and mineral composition-larger pore radius and higher clay content lead to stronger stress sensitivity,with porosity loss rates ranging from 8.26%to 23.69%.Permeability stress sensitivity is mainly influenced by throat radius and mineral composition-smaller throat radius and higher clay content result in stronger stress sensitivity,with permeability loss rates ranging from 47.91%to 62.03%;(4)a comparative analysis between the traditional dynamic reserve calculation method for gas wells and the new method considering stress sensitivity shows a relative error between 0.90%and 2.41%,with the new method demonstrating better accuracy.This study combines physical experimental results with an effective stress model of reservoir rocks to develop a new method for calculating dynamic reserves of water-bearing tight gas reservoirs under effective stress conditions,providing experimental data and example calculation results to support subsequent dynamic evaluation of gas reservoirs and the establishment of rational well allocation plans.
基金funded by the National Key Research and Development ProgramFund for Young Scientists(No.2021YFC2900400)+5 种基金the National Natural Science Foundation of China(No.52304123)Fundamental Research Funds for the Central Universities(No.2024CDJXY025)Sichuan-Chongqing Science and Technology Innovation Cooperation Program Project(No.CSTB2024TIAD-CYKJCXX0016)Postdoctoral Research Foundation of China(No.2023M730412)Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(No.GZB20230914)Chongqing Outstanding Youth Science Foundation Program(No.CSTB2023NSCQ-JQX0027)。
文摘To address the issues of single warning indicators,fixed thresholds,and insufficient adaptability in coal and gas outburst early warning models,this study proposes a dynamic early warning model for gas outbursts based on adaptive fractal dimension characterization.By analyzing the nonlinear characteristics of gas concentration data,an adaptive window fractal analysis method is introduced.Combined with boxcounting dimension and variation of box dimension metrics,a cross-scale dynamic warning model for disaster prevention is established.The implementation involves three key phases:First,wavelet denoising and interpolation methods are employed for raw data preprocessing,followed by validation of fractal characteristics.Second,an adaptive window cross-scale fractal dimension method is proposed to calculate the box-counting dimension of gas concentration,enabling effective capture of multi-scale complex features.Finally,dynamic threshold partitioning is achieved through membership functions and the 3σprinciple,establishing a graded classification standard for the mine gas disaster(MGD)index.Validated through engineering applications at Shoushan#1 Coal Mine in Henan Province,the results demonstrate that the adaptive window fractal dimension curve exhibits significantly enhanced fluctuation characteristics compared to fixed window methods,with local feature detection capability improved and warning accuracy reaching 86.9%.The research reveals that this model effectively resolves the limitations of traditional methods in capturing local features and dependency on subjective thresholds through multiindicator fusion and threshold optimization,providing both theoretical foundation and practical tool for coal mine gas outburst early warning.
基金supported by the National Natural Science Foundation of China(Grant No.42072166)Natural Science Foundation of Heilongjiang Province of China(Grant No.LH2020D004)Key R&D Program of Heilongjiang Province of China(Grant No.JD2023SJ26)。
文摘The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.The dynamic sealing capacity of a caprock-fault system is a critical constraint for safe operation,and is a key factor in determining the maximum operating pressure(MOP).This study proposed an efficient semi-analytical method for calculating changes in the in situ stress within the caprock.Next,the parameters of dynamic pore pressure,in situ stresses,and deformations obtained from reservoir simulations and geomechanical modeling were used for inputs for the analytical solution.Based on the calculated results,an experimental scheme for the coupled cyclic stress-permeability testing of caprock was designed.The stability analysis indicated that the caprock was not prone to fatigue shear failure under the current injection and production strategy,supported by the experimental results.The experimental results further reveal that the sealing capacity of caprock plugs may remain stable.This phenomenon is attributed to cyclic stress causing pore connectivity and microcrack initiation in certain plugs,while leading to pore compaction in others.A comparison between the dynamic pore pressure and the minimum principal stress suggests that the risk of tensile failure is extremely low.Furthermore,although the faults remain stable under the current injection and production strategies,the continuous increase in injection pressure may lead to an increased tendency for fault slip and dilation,which can cause fault slip ultimately.The MOPs corresponding to each failure mode were calculated.The minimum value of approximately 36.5 MPa at capillary sealing failure indicated that the gas breakthrough in the caprock occurred earlier than rock failure.Therefore,this minimumvalue can be used as the MOP for the target UGS.
基金supported by National Natural Science Foundation of China(Nos.92263109 and 61904188)the Shanghai Rising-Star Program(No.22QA1410400)。
文摘Organic semiconductor materials have demonstrated extensive potential in the field of gas sensors due to the advantages including designable chemical structure,tunable physical and chemical properties.Through density functional theory(DFT)calculations,researchers can investigate gas sensing mechanisms,optimize,and predict the electronic structures and response characteristics of these materials,and thereby identify candidate materials with promising gas sensing applications for targeted design.This review concentrates on three primary applications of DFT technology in the realm of organic semiconductor-based gas sensors:(1)Investigating the sensing mechanisms by analyzing the interactions between gas molecules and sensing materials through DFT,(2)simulating the dynamic responses of gas molecules,which involves the behavior on the sensing interface using DFT combined with other computational methods to explore adsorption and diffusion processes,and(3)exploring and designing sensitive materials by employing DFT for screening and predicting chemical structures,thereby developing new sensing materials with exceptional performance.Furthermore,this review examines current research outcomes and anticipates the extensive application prospects of DFT technology in the domain of organic semiconductor-based gas sensors.These efforts are expected to provide valuable insights for further indepth exploration of DFT applications in sensor technology,thereby fostering significant advancements and innovations in the field.
文摘In nonisentropic gas dynamics, with general equations of state, strong cornpressive shocks satisfying the Liu E-condition may violate the Second Law of thermodynamics.
基金supported in part by NSF Applied Mathematics Grant Number DMS-0908190
文摘We investigate the vacuum in nonisentropic gas dynamics in one space vari- able, with the most general equation of states allowed by thermodynamics. We recall physical constraints on the equations of state and give explicit and easily checkable conditions under which vacuums occur in the solution of the Riemann problem. We then present a class of models for which the Riemann problem admits unique global solutions without vacuums.
基金supported by the TIFR-CAM Doctoral Fellowshipthe NISER Postdoctoral Fellowship (through the project “Basic research in physics and multidisciplinary sciences” with identification # RIN4001) during the preparation of this papersupported by the Raja Ramanna Fellowship
文摘Evolution and interaction of plane waves of the multidimensional zero-pressure gas dynamics system leads to the study of the corresponding one dimensional system.In this paper,we study the initial value problem for one dimensional zero-pressure gas dynamics system.Here the first equation is the Burgers equation and the second one is the continuity equation.We consider the solution with initial data in the space of bounded Borel measures.First we prove a general existence result in the algebra of generalized functions of Colombeau.Then we study in detail special solutions withδ-measures as initial data.We study interaction of waves originating from initial data concentrated on two point sources and interaction with classical shock/rarefaction waves.This gives an understanding of plane-wave interactions in the multidimensional case.We use the vanishing viscosity method in our analysis as this gives the physical solution.
