[Objective] The aim was to study the adsorption property of adsorbent Ni-TiO2-SiO2 synthesized by using rice husks as silicon source and template to gentian violet.[Method] The renewable dye adsorbent Ni-TiO2-SiO2 was...[Objective] The aim was to study the adsorption property of adsorbent Ni-TiO2-SiO2 synthesized by using rice husks as silicon source and template to gentian violet.[Method] The renewable dye adsorbent Ni-TiO2-SiO2 was synthesized by using rice husks as raw material,and the adsorption property of Ni-TiO2-SiO2 to gentian violet was studied.[Result] The adsorption rate of Ni-TiO2-SiO2 to gentian violet reached about 90% after 1 h.In 100 ml gentian violet solution with concentration of 25 mg/L and pH=8,Ni-TiO2-SiO2 with dosage of 0.07 g had the best adsorption effect.More importantly,Ni-TiO2-SiO2 as adsorbent could be used repeatedly,and couldn’t lead to secondary pollution due to leaking.[Conclusion] The study could provide references for practical engineering application.展开更多
The crystallization behavior and kinetics of CaO-MgO-Al2O3 SiO2（CMAS） glass with the Fe2O3 content ranging from zero to 5%were investigated by differential scanning calorimetry（DSC）.The structure and phase analyse...The crystallization behavior and kinetics of CaO-MgO-Al2O3 SiO2（CMAS） glass with the Fe2O3 content ranging from zero to 5%were investigated by differential scanning calorimetry（DSC）.The structure and phase analyses were made by Fourier transform infrared spectroscopy（FT-IR） and X-ray diffraction（XRD）.The experiment results show that the endothermic peak temperature about 760℃ is associated with transition and the exothermic peak temperature about 1000℃ is associated with crystallization.The crystallization peak temperature decreases with increasing the Fe203 content.The crystallization mechanism is changed from two-dimensional crystallization to one-dimensional growth,and the intensity of diopside peaks becomes stronger gradually.There is a saltation for the crystallization temperature with the addition of 0.5%Fe2O3 due to the decomposition of Fe2O3.Si-O-Si,O-Si-O and T-O-T（T=Si,Fe,Al） linkages are observed in Fe2O3-CaO-MgO-Al2O3-SiO2 glass.展开更多
A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acid...A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased.展开更多
基金Supported by Research Funds of Educational Commission of Yunnan Province(09Y0392)Scientific Research Funds of Qujing Normal University(2009QN032)+1 种基金Teaching Reform Project of Qujing Normal University about " Key Course of Analytical Chemistry" and " Excellent Course of Instrumental Analysis"Scientific Funds of Baoshan University(11B004K)
文摘[Objective] The aim was to study the adsorption property of adsorbent Ni-TiO2-SiO2 synthesized by using rice husks as silicon source and template to gentian violet.[Method] The renewable dye adsorbent Ni-TiO2-SiO2 was synthesized by using rice husks as raw material,and the adsorption property of Ni-TiO2-SiO2 to gentian violet was studied.[Result] The adsorption rate of Ni-TiO2-SiO2 to gentian violet reached about 90% after 1 h.In 100 ml gentian violet solution with concentration of 25 mg/L and pH=8,Ni-TiO2-SiO2 with dosage of 0.07 g had the best adsorption effect.More importantly,Ni-TiO2-SiO2 as adsorbent could be used repeatedly,and couldn’t lead to secondary pollution due to leaking.[Conclusion] The study could provide references for practical engineering application.
基金Projects(51264023,51364020,U1202271)supported by the National Natural Science Foundation of ChinaProject(IRT1250)supported by the Program for Innovative Research Team in University of Ministry of Education of ChinaProject(2014HA003)supported by the Science and Technology Leading Talent of Yunnan Province,China
文摘The crystallization behavior and kinetics of CaO-MgO-Al2O3 SiO2（CMAS） glass with the Fe2O3 content ranging from zero to 5%were investigated by differential scanning calorimetry（DSC）.The structure and phase analyses were made by Fourier transform infrared spectroscopy（FT-IR） and X-ray diffraction（XRD）.The experiment results show that the endothermic peak temperature about 760℃ is associated with transition and the exothermic peak temperature about 1000℃ is associated with crystallization.The crystallization peak temperature decreases with increasing the Fe203 content.The crystallization mechanism is changed from two-dimensional crystallization to one-dimensional growth,and the intensity of diopside peaks becomes stronger gradually.There is a saltation for the crystallization temperature with the addition of 0.5%Fe2O3 due to the decomposition of Fe2O3.Si-O-Si,O-Si-O and T-O-T（T=Si,Fe,Al） linkages are observed in Fe2O3-CaO-MgO-Al2O3-SiO2 glass.
文摘A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased.
