Thermodynamics for chemical vapor synthesis （CVS） of Nb nanopowder in NbCl5-H2-Ar system was investigated by using FactSage software. The validation experiments were conducted to confirm the thermodynamics points. T...Thermodynamics for chemical vapor synthesis （CVS） of Nb nanopowder in NbCl5-H2-Ar system was investigated by using FactSage software. The validation experiments were conducted to confirm the thermodynamics points. The results indicate that under the atmospheric pressure, the reduction approach from NbCl5（g） to Nb（s） is a stage-wise process with the formation of complex sub-chlorides, and is controllable at low hydrogen ratio （mole ratio of n（NbCl5）：n（H2）＆lt;1：180） and low temperature （＆lt;1050 ＆#176;C）. Furthermore, a reasonable amount of inert loading gas is favorable to increase the reduction ratio of NbCl5 and the powder yield. The as-synthesized Nb nanopowder with the homogeneous size of 30-50 nm and the powder yield of 85% （mass fraction） is obtained by the CVS process under n（NbCl5）：n（H2）：n（Ar）=1：120：1 and 950 ＆#176;C with the NbCl5 reduction rate of 96.1%.展开更多
Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized sam...Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized samples were characterized by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS） and photoluminescence （PL）. The effects of Y and Cd ions on the optical properties of the samples were studied. Doping of Y into ZnO evidently increases the intensity of UV emission, or co-doping of Y and Cd enhances the UV emission, narrows the band gap of ZnO and hence red shifts the UV emission at the same time. Therefore, Y and Cd co-doped ZnO nanopowders exhibit an intense violet emission in the room temperature PL spectrum, which could be a potential candidate material for optoelectronic applications.展开更多
La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation te...La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation temperature increases, while the particle size decreases as the Ladoping content goes up. The partial substitution of Sr^（2＋） by La^（3＋） results in the suppression effects on the growth-up of the crystallites and the enhancement of the electron hopping between Fe^（3＋） with different valences, which leads to the improvement in the dielectric loss and magnetic loss.Therefore, both the microwave absorbing abilities and absorbing frequency ranges are tuned by La-doping. The synthesized Sr-hexaferrite nanopowders with doping element content of 0.10 demonstrate the fine broad microwave absorbing properties.展开更多
Effects of metal (Ni, Cu, Al) and composite metal (NiB, NiCu, NiCuB) nanopowders on the thermal decomposition of ammonium perchlorate (AP) and composite solid propellant ammonium perchlorate/hydroxyterminated polybuta...Effects of metal (Ni, Cu, Al) and composite metal (NiB, NiCu, NiCuB) nanopowders on the thermal decomposition of ammonium perchlorate (AP) and composite solid propellant ammonium perchlorate/hydroxyterminated polybutadiene (AP/HTPB) were studied by thermal analysis (DTA). The results show that metal and composite metal nanopowders all have good catalytic effects on the thermal decomposition of AP and AP/HTPB composite solid propellant. The effects of metal nanopowders on the thermal decomposition of AP are less than those of the composite metal nanopowders. The effects of metal and composite metal nanopowders on the thermal decomposition of AP are different from those on the thermal decomposition of the AP/HTPB composite solid propellant.展开更多
In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applicati...In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.展开更多
Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal...Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal phase without any impurities. Scanning electron microscopy and static light scattering technique were used to study morphology and size of prepared nanoparticles. Average diameter of the nanoparticles was about 40 nm. The changes in structural and luminescence properties were observed as a function of the first and second calcination temperature. The optimal conditions for synthesis of nanoparticles were determined as Т1=500℃, t1=1 h; Т2=950 ℃, t2=1.5 h. The effect of different media surrounding the nanoparticles on their luminescence properties and lifetime was investigated and discussed in terms of effective refractive index. It was found that the observed lifetime of YVO4：Eu^3＋ 5 at.% nanophosphor was decreased from 0.64 ms in air（nmed=1） to 0.45 ms in chalcogenide glass As39S61（nmed=2.39）.展开更多
Polycrystalline Nd3+ and La3+ co-doped yttria nanopowder Nd3+:Y1.90La0.10O3 for transparent ceramics was synthesized by co-precipitation method using oxalate acid as the precipitant and(NH4)2SO4 as the electrical stab...Polycrystalline Nd3+ and La3+ co-doped yttria nanopowder Nd3+:Y1.90La0.10O3 for transparent ceramics was synthesized by co-precipitation method using oxalate acid as the precipitant and(NH4)2SO4 as the electrical stabilizer under ultrasonic radiation.Nanopowders calcined at different temperatures were characterized with thermal gravimetric-differential thermal analysis(TG/DTA),X-ray diffraction(XRD),transmitting electron microscopy(TEM),energy dispersive spectrometry(EDS) and spectral analysis techniques.Th...展开更多
The homogeneously dispersed, less agglomerated YAG nanopowders are synthesized by the citrate-gel method followed by low-temperature self-propagating combustion reaction, using Y2O3, Al(NO3)3?9H2O and citric acid as s...The homogeneously dispersed, less agglomerated YAG nanopowders are synthesized by the citrate-gel method followed by low-temperature self-propagating combustion reaction, using Y2O3, Al(NO3)3?9H2O and citric acid as starting materials. This method effectively solves the problems caused by solid-state reaction at high temperature and the hard ag-glomerates brought by the chemical precipitation method. The powders are characterized by TG-DTA, XRD, FT-IR and TEM respectively. The experiments show that the forming temperature of YAG crystal phase is 850°C and the pseudo-YAG crystalline appears during the calcination and transforms to pure YAG at 1050°C. The powders with sizes less than 50 nm are observed by TEM micrography, which is consistent with the result calculated by Scherrer's formula. The powders consist of single grains.展开更多
Vibrational properties of silicon nanopowders are discussed with reference to Raman spectroscopic measurements. The powders were produced in a low pressure rf plasma from the cluster induced agglomeration of positive ...Vibrational properties of silicon nanopowders are discussed with reference to Raman spectroscopic measurements. The powders were produced in a low pressure rf plasma from the cluster induced agglomeration of positive ions formed during the dissociation of silane. Influence of thermal treatment and the crystallization phenomena of the powder were studied. Raman spectroscopic measurements reveal size quantization effects for the particles as well as the existence of partially ordered regions in the apparently amorphous primary particles. The crystalline and amorphous volume fraction in the material were calculated from the relative spectraI intensities. The results obtained in these experiments are consistent with the observations from recent high resolution transmission electron microscopy studies of these powders展开更多
In this study, the influences of La_(2)O_(3) added on the phase, morphology and reduction process of tungsten oxide prepared by solution combustion synthesis(SCS) were investigated for the first time. And tungsten nan...In this study, the influences of La_(2)O_(3) added on the phase, morphology and reduction process of tungsten oxide prepared by solution combustion synthesis(SCS) were investigated for the first time. And tungsten nanopowders with different La_(2)O_(3) doping amount(0.5~5.0 wt%) were successfully prepared by SCS and followed hydrogen reduction. The results showed that with the increase of La_(2)O_(3) addition,the product synthesized by SCS changed from needle-like W_(18) O_(49) to irregularly granulated H0.53 WO3 and the complete reduction temperature also increased form 700°C to 850°C. The densification behavior of as-prepared W nanopowders revealed that the densification inhibitory effect of La_(2)O_(3) was enhanced as the La_2O_3 addition increased. Nevertheless, due to the optimal size and distribution of La_(2)O_(3) particles,the sample with 2.0 wt% La_(2)O_(3) addition has a smallest grain size of 0.47 μm and a highest microhardness value of 739.3 Hv0.2, which are the best compared with the literature.展开更多
（Ag ＋ Fe）-doped ZnO nanopowders have been synthesized using combustion method. Ag doping level was kept as 2 at.%, and Fe doping level was varied from 3 to 6 at,%, and the structural, optical, surface morphological...（Ag ＋ Fe）-doped ZnO nanopowders have been synthesized using combustion method. Ag doping level was kept as 2 at.%, and Fe doping level was varied from 3 to 6 at,%, and the structural, optical, surface morphological, and antibacterial properties have been investigated. The structural studies show that ZnO/（Ag 4-Fe） nanopowders have hexagonal wurtzite structure with a preferential orientation along the （101） plane. The FE-SEM images indicate that there is a gradual decrease in the grain size with the increase in the doping level of Fe, and the TEM images are correlated well with FE-SEM images. The XPS profile clearly confirms the presence of expected elemental composition. Photolumi- nescence studies reveal the presence of extrinsic defects in the material. Antibacterial activity of Ag- and Fe-doped ZnO nanopowders against Vibrio parahaemolyticus, Vibrio Cholerae, and Staphylococcus aureus bacteria was also investigated.展开更多
The nano composite powder of rare earth-doped CuO were prepared by the stearic gel method and characterized by means of X-ray (XRD) and transmission electron microscopy (TEM) and scanning electron microscope (SEM) and...The nano composite powder of rare earth-doped CuO were prepared by the stearic gel method and characterized by means of X-ray (XRD) and transmission electron microscopy (TEM) and scanning electron microscope (SEM) and IR. Microscopic investigation of the nanopowder was measured by AFM. The result shows that the grain sizes are in the order of nanometers, approximately 10, 12, 22, 32 and 40 nm for the nanopowder deposited at 600, 650, 700, 750 and 800 ℃. The grains grow up with the increase of sintering temperature. There are some agglomeration and selfassemble phenomenon in the particles. IR result indicates that the vibration kurtosis was changed with the different sintering temperature.展开更多
The application of induction plasma technology developed for the synthesis of nano- metric powders is summarized. A brief description of the scientific basis for the induction plasma processes is given, followed by th...The application of induction plasma technology developed for the synthesis of nano- metric powders is summarized. A brief description of the scientific basis for the induction plasma processes is given, followed by the presentation of an induction plasma system developed by Tekna, together with various examples of the nanopowders synthesized using its facilities. The advantages of the induction plasma process over alternative techniques and its adaptability into industrial- scale operation is particularly illustrated. Some specific issues related to the nanopowder synthesis process are also discussed.展开更多
This paper presents an overview of nanopowders preparation using low-temperature plasma (LTP). LTP with its unique processing capabilities provides an attractive and chemically unspecific route for powder synthesis. N...This paper presents an overview of nanopowders preparation using low-temperature plasma (LTP). LTP with its unique processing capabilities provides an attractive and chemically unspecific route for powder synthesis. Nanopowders such as oxides, nitrides, carbides, catalysts and other nanopowders have been successfully synthesized in LTP reactors based on high intensity arcs, plasma jets and radio-frequency (r. f.) inductively coupled discharges.展开更多
In this paper we describe a route to produce crystalline Mg（OH）2 nanopowders from serpentinite ore distributed in the Halilovskiy array （Russia, Orenburg region）. An efficient extraction route consisting of treatm...In this paper we describe a route to produce crystalline Mg（OH）2 nanopowders from serpentinite ore distributed in the Halilovskiy array （Russia, Orenburg region）. An efficient extraction route consisting of treatment on serpentinite in 40% HNO3 at 80 ℃followed by NH4OH titration for Mg（OH）2 precipitation was demonstrated. In this study, crystalline Mg（OH）2 nanopowders have been synthesized by solvothermal reaction method using （Mg（NO3）2·6H2O） which were obtained from serpentinite, NH4OH as a precipitator, and hydroxyethylated nonylphenol as surface-active substance. Microstructure and phase composition of samples were investigated employing scanning electron microscopy （SEM） and transmission electron microscopy （TEM）, X-ray phase analysis （XRD）, and inductively coupled plasma optical emission spectroscopy （ICP-OES）. XRD reveals that Mg（OH）2 nanopowder with high purity has the brucite structure. It was found that crystalline Mg（OH）2 nanopowders exclusively consist of lamellar-like structures and the sizes of Mg（OH）2 are 30-265 nm length or width.展开更多
The Mn-doped Ce02 nanopowders with high catalysis activity were successfully fabricated through a simple hydrolyzed-oxidized approach. Firstly, the alloy Ce37Mnl 8C45 was prepared in vacuum induction melting furnace. ...The Mn-doped Ce02 nanopowders with high catalysis activity were successfully fabricated through a simple hydrolyzed-oxidized approach. Firstly, the alloy Ce37Mnl 8C45 was prepared in vacuum induction melting furnace. Subsequently, Mn-doped CeO2 nanopowders with 142 m2/g of specific surface area were obtained through a simple hydrolyzed-oxidized procedure of the alloy Those nanopowders were heat treated at different temperatures. The obtained materials were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, high-resolution transmission electron microscopy （HRTEM） and energy dispersive spectroscopy （EDS）. And the catalytic activity on vinyl chloride （VC） emission combustion was investigated. The results showed that those nanopowders after hydrolyzed-oxidized from Ce37Mn18C45 mainly consisted of CeO2 and Mn304. Manganese element increased the thermal stability of CeO2 nanopowders. The Mn-doped CeO2 nanopowders had three morphologies. Small particles were Mn-doped CeO2, square particles were Mn304 and the rods were Mn304 and Mn203. The Mn-doped CeO2 nanopowders had good vinyl chloride （VC） emission catalytic performance.展开更多
A series of KY3F10 nanophosphors doped with Gd3＋, Ce3＋ and Eu3＋ ions were obtained with the use of a co-precipitation method. The resulting products were white precipitates, consisting of spherical particles with d...A series of KY3F10 nanophosphors doped with Gd3＋, Ce3＋ and Eu3＋ ions were obtained with the use of a co-precipitation method. The resulting products were white precipitates, consisting of spherical particles with diameter about 150-200 nm, which was confirmed using transmission electron microscopy （TEM） technique. Powder X-ray diffraction （XRD） and energy dispersive X-ray analysis （EDX） measurements confirmed appropriate structures of the nanoparticles obtained. Spectroscopic properties of the prod- ucts were examined on the basis of the measured excitation/emission spectra and luminescence decay curves. The synthesized sam- ples showed orange-red luminescence, characteristic for Eu3＋ ions. The reaction process was performed in required alkaline pH ad- justed with the use of ethylenediaminetetraacetic acid （EDTA） and potassium hydroxide. The samples containing large amounts of Gd3＋ dooant ions exhibited a tendencv to form nroducts with different momhologies.展开更多
Study was made on the effect of surface modification on the behaviors of cerium oxide nanopowders.A surfactant-sodium dodecyl sulfate（C12H25SO4Na）was used to modify the surface of CeO2 powder particles.The unmodifie...Study was made on the effect of surface modification on the behaviors of cerium oxide nanopowders.A surfactant-sodium dodecyl sulfate（C12H25SO4Na）was used to modify the surface of CeO2 powder particles.The unmodified and modified CeO2 powders were characterized by using a powder comprehensive characteristic tester,laser particle size analyzer,specific surface area tester,X-ray diffraction tester,and a scanning electron microscope.The testing and analysis results showed that C12H25SO4Na surface modification might increase the flowability and dispersity,and decrease the specific surface area and agglomeration of CeO2 powders.The mechanism of the surface modification of CeO2 powder particles was also discussed.展开更多
Pure Ni nanopowders were successfully prepared by the method of anodic arc disch arged plasma with homemade experimental apparatus. The particle size, mircostruc ture and morphology of the particles by this process we...Pure Ni nanopowders were successfully prepared by the method of anodic arc disch arged plasma with homemade experimental apparatus. The particle size, mircostruc ture and morphology of the particles by this process were characterized via X-ra y powder diffraction (XRD), transmission electron microscopy (TEM) and the corre sponding selected area electron diffraction (SAED); The specific surface area an d pore parameters were investigated by multi-point full analysis of nitrogen ads orption-desorption isotherms at 77K by Brunauer- Emmett-Teller (BET) surface are a analyzer; The chemical composition were determined by X-ray energy dispersive spectrometry (XEDS) equipped in SEM and element analyze instrument. The experime nt results indicate that the samples by this method with high purity,the crystal structure of the particles is as same as the bulk material, is fcc structure, w ith average particle sizes about 47nm, ranging from 20 to 70nm, and distributed uniformly in spherical chain shapes, the specific surface areavis 14.23m2/g, po re volume of pore is 0.09cm3/g and average pore diameter is 23nm.展开更多
yb3＋/Dy3＋ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results...yb3＋/Dy3＋ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results show that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663 nm, corresponding to 4C9/2→ 6H13/2, 4C9/2→ 6Hll/2, 4115/2 → 6H13/2, and 4F9/2 →6Hll/2 transitions of Dy3＋, respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion emissions. The energy transition between Yb3＋ and Dy3＋ is discussed.展开更多
基金Project(51102015)supported by the National Natural Science Foundation of China
文摘Thermodynamics for chemical vapor synthesis （CVS） of Nb nanopowder in NbCl5-H2-Ar system was investigated by using FactSage software. The validation experiments were conducted to confirm the thermodynamics points. The results indicate that under the atmospheric pressure, the reduction approach from NbCl5（g） to Nb（s） is a stage-wise process with the formation of complex sub-chlorides, and is controllable at low hydrogen ratio （mole ratio of n（NbCl5）：n（H2）＆lt;1：180） and low temperature （＆lt;1050 ＆#176;C）. Furthermore, a reasonable amount of inert loading gas is favorable to increase the reduction ratio of NbCl5 and the powder yield. The as-synthesized Nb nanopowder with the homogeneous size of 30-50 nm and the powder yield of 85% （mass fraction） is obtained by the CVS process under n（NbCl5）：n（H2）：n（Ar）=1：120：1 and 950 ＆#176;C with the NbCl5 reduction rate of 96.1%.
基金Project(2010CB631001) supported by the National Basic Research Program of ChinaProject(20121098) supported by the Foundation from of Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Ministry of Education,ChinaProject supported by Graduate Innovation Fund of Jilin University,China
文摘Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized samples were characterized by X-ray diffraction （XRD）, X-ray photoelectron spectroscopy （XPS） and photoluminescence （PL）. The effects of Y and Cd ions on the optical properties of the samples were studied. Doping of Y into ZnO evidently increases the intensity of UV emission, or co-doping of Y and Cd enhances the UV emission, narrows the band gap of ZnO and hence red shifts the UV emission at the same time. Therefore, Y and Cd co-doped ZnO nanopowders exhibit an intense violet emission in the room temperature PL spectrum, which could be a potential candidate material for optoelectronic applications.
基金financially supported by the National Natural Science Foundation of China(No.51103125)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(Chemistry)+2 种基金the Natural Science Foundation of Yangzhou(No.YZ2014043)the Science Innovative Foundation of Yangzhou University(No.2014CXJ017)the Graduate Student Innovation foundation of Yangzhou University(No.CXLX 1413)
文摘La-doped Sr-hexaferrite（Sr（1-x）LaxFe（12）O（19））（x=0.05,0.10,0.15,0.20） nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation temperature increases, while the particle size decreases as the Ladoping content goes up. The partial substitution of Sr^（2＋） by La^（3＋） results in the suppression effects on the growth-up of the crystallites and the enhancement of the electron hopping between Fe^（3＋） with different valences, which leads to the improvement in the dielectric loss and magnetic loss.Therefore, both the microwave absorbing abilities and absorbing frequency ranges are tuned by La-doping. The synthesized Sr-hexaferrite nanopowders with doping element content of 0.10 demonstrate the fine broad microwave absorbing properties.
文摘Effects of metal (Ni, Cu, Al) and composite metal (NiB, NiCu, NiCuB) nanopowders on the thermal decomposition of ammonium perchlorate (AP) and composite solid propellant ammonium perchlorate/hydroxyterminated polybutadiene (AP/HTPB) were studied by thermal analysis (DTA). The results show that metal and composite metal nanopowders all have good catalytic effects on the thermal decomposition of AP and AP/HTPB composite solid propellant. The effects of metal nanopowders on the thermal decomposition of AP are less than those of the composite metal nanopowders. The effects of metal and composite metal nanopowders on the thermal decomposition of AP are different from those on the thermal decomposition of the AP/HTPB composite solid propellant.
基金Project(2017YFB0305601) supported by the National Key R&D Program of ChinaProjects(51874368,51274246) supported by the National Natural Science Foundation of China
文摘In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.
文摘Nanocrystalline yttrium vanadate doped with europium ions powders were synthesized via sol-gel method based on decomposition of metal-polymer complex. X-ray diffraction analysis showed that samples had pure tetragonal phase without any impurities. Scanning electron microscopy and static light scattering technique were used to study morphology and size of prepared nanoparticles. Average diameter of the nanoparticles was about 40 nm. The changes in structural and luminescence properties were observed as a function of the first and second calcination temperature. The optimal conditions for synthesis of nanoparticles were determined as Т1=500℃, t1=1 h; Т2=950 ℃, t2=1.5 h. The effect of different media surrounding the nanoparticles on their luminescence properties and lifetime was investigated and discussed in terms of effective refractive index. It was found that the observed lifetime of YVO4：Eu^3＋ 5 at.% nanophosphor was decreased from 0.64 ms in air（nmed=1） to 0.45 ms in chalcogenide glass As39S61（nmed=2.39）.
基金supported by the Science and Technology Development Program of Jilin Province (20080511)
文摘Polycrystalline Nd3+ and La3+ co-doped yttria nanopowder Nd3+:Y1.90La0.10O3 for transparent ceramics was synthesized by co-precipitation method using oxalate acid as the precipitant and(NH4)2SO4 as the electrical stabilizer under ultrasonic radiation.Nanopowders calcined at different temperatures were characterized with thermal gravimetric-differential thermal analysis(TG/DTA),X-ray diffraction(XRD),transmitting electron microscopy(TEM),energy dispersive spectrometry(EDS) and spectral analysis techniques.Th...
基金This work is financially supported by the Excellent Teachers Fund by the Ministry of Education of China (No. KB200226).
文摘The homogeneously dispersed, less agglomerated YAG nanopowders are synthesized by the citrate-gel method followed by low-temperature self-propagating combustion reaction, using Y2O3, Al(NO3)3?9H2O and citric acid as starting materials. This method effectively solves the problems caused by solid-state reaction at high temperature and the hard ag-glomerates brought by the chemical precipitation method. The powders are characterized by TG-DTA, XRD, FT-IR and TEM respectively. The experiments show that the forming temperature of YAG crystal phase is 850°C and the pseudo-YAG crystalline appears during the calcination and transforms to pure YAG at 1050°C. The powders with sizes less than 50 nm are observed by TEM micrography, which is consistent with the result calculated by Scherrer's formula. The powders consist of single grains.
文摘Vibrational properties of silicon nanopowders are discussed with reference to Raman spectroscopic measurements. The powders were produced in a low pressure rf plasma from the cluster induced agglomeration of positive ions formed during the dissociation of silane. Influence of thermal treatment and the crystallization phenomena of the powder were studied. Raman spectroscopic measurements reveal size quantization effects for the particles as well as the existence of partially ordered regions in the apparently amorphous primary particles. The crystalline and amorphous volume fraction in the material were calculated from the relative spectraI intensities. The results obtained in these experiments are consistent with the observations from recent high resolution transmission electron microscopy studies of these powders
基金financially supported by the National Key R&D Program of China (2017YFB0306000 and 2017YFB0305600)the National Natural Science Foundation Program of China (51574031,51604239,51604240 and 51674095)+2 种基金the Natural Science Foundation Program of Beijing (2162027)the General Project of the Education Department of Hunan Province (15C1308)the Fundamental Research Funds for the Central Universities(JZ2017HGBZ0920)。
文摘In this study, the influences of La_(2)O_(3) added on the phase, morphology and reduction process of tungsten oxide prepared by solution combustion synthesis(SCS) were investigated for the first time. And tungsten nanopowders with different La_(2)O_(3) doping amount(0.5~5.0 wt%) were successfully prepared by SCS and followed hydrogen reduction. The results showed that with the increase of La_(2)O_(3) addition,the product synthesized by SCS changed from needle-like W_(18) O_(49) to irregularly granulated H0.53 WO3 and the complete reduction temperature also increased form 700°C to 850°C. The densification behavior of as-prepared W nanopowders revealed that the densification inhibitory effect of La_(2)O_(3) was enhanced as the La_2O_3 addition increased. Nevertheless, due to the optimal size and distribution of La_(2)O_(3) particles,the sample with 2.0 wt% La_(2)O_(3) addition has a smallest grain size of 0.47 μm and a highest microhardness value of 739.3 Hv0.2, which are the best compared with the literature.
基金the financial assistance from the director of collegiate education,Govt.of Tamil Nadu,Chennai
文摘（Ag ＋ Fe）-doped ZnO nanopowders have been synthesized using combustion method. Ag doping level was kept as 2 at.%, and Fe doping level was varied from 3 to 6 at,%, and the structural, optical, surface morphological, and antibacterial properties have been investigated. The structural studies show that ZnO/（Ag 4-Fe） nanopowders have hexagonal wurtzite structure with a preferential orientation along the （101） plane. The FE-SEM images indicate that there is a gradual decrease in the grain size with the increase in the doping level of Fe, and the TEM images are correlated well with FE-SEM images. The XPS profile clearly confirms the presence of expected elemental composition. Photolumi- nescence studies reveal the presence of extrinsic defects in the material. Antibacterial activity of Ag- and Fe-doped ZnO nanopowders against Vibrio parahaemolyticus, Vibrio Cholerae, and Staphylococcus aureus bacteria was also investigated.
文摘The nano composite powder of rare earth-doped CuO were prepared by the stearic gel method and characterized by means of X-ray (XRD) and transmission electron microscopy (TEM) and scanning electron microscope (SEM) and IR. Microscopic investigation of the nanopowder was measured by AFM. The result shows that the grain sizes are in the order of nanometers, approximately 10, 12, 22, 32 and 40 nm for the nanopowder deposited at 600, 650, 700, 750 and 800 ℃. The grains grow up with the increase of sintering temperature. There are some agglomeration and selfassemble phenomenon in the particles. IR result indicates that the vibration kurtosis was changed with the different sintering temperature.
文摘The application of induction plasma technology developed for the synthesis of nano- metric powders is summarized. A brief description of the scientific basis for the induction plasma processes is given, followed by the presentation of an induction plasma system developed by Tekna, together with various examples of the nanopowders synthesized using its facilities. The advantages of the induction plasma process over alternative techniques and its adaptability into industrial- scale operation is particularly illustrated. Some specific issues related to the nanopowder synthesis process are also discussed.
文摘This paper presents an overview of nanopowders preparation using low-temperature plasma (LTP). LTP with its unique processing capabilities provides an attractive and chemically unspecific route for powder synthesis. Nanopowders such as oxides, nitrides, carbides, catalysts and other nanopowders have been successfully synthesized in LTP reactors based on high intensity arcs, plasma jets and radio-frequency (r. f.) inductively coupled discharges.
基金the state on behalf of the Ministry of Education and Science of the Russian Federation of the Agreement (No. 14.577.21.0111 (22 September 2014))The unique identifier of the applied research (No. RFMEFI57714X0111)
文摘In this paper we describe a route to produce crystalline Mg（OH）2 nanopowders from serpentinite ore distributed in the Halilovskiy array （Russia, Orenburg region）. An efficient extraction route consisting of treatment on serpentinite in 40% HNO3 at 80 ℃followed by NH4OH titration for Mg（OH）2 precipitation was demonstrated. In this study, crystalline Mg（OH）2 nanopowders have been synthesized by solvothermal reaction method using （Mg（NO3）2·6H2O） which were obtained from serpentinite, NH4OH as a precipitator, and hydroxyethylated nonylphenol as surface-active substance. Microstructure and phase composition of samples were investigated employing scanning electron microscopy （SEM） and transmission electron microscopy （TEM）, X-ray phase analysis （XRD）, and inductively coupled plasma optical emission spectroscopy （ICP-OES）. XRD reveals that Mg（OH）2 nanopowder with high purity has the brucite structure. It was found that crystalline Mg（OH）2 nanopowders exclusively consist of lamellar-like structures and the sizes of Mg（OH）2 are 30-265 nm length or width.
基金Project supported by Shanghai Leading Academic Discipline Project (S30107)
文摘The Mn-doped Ce02 nanopowders with high catalysis activity were successfully fabricated through a simple hydrolyzed-oxidized approach. Firstly, the alloy Ce37Mnl 8C45 was prepared in vacuum induction melting furnace. Subsequently, Mn-doped CeO2 nanopowders with 142 m2/g of specific surface area were obtained through a simple hydrolyzed-oxidized procedure of the alloy Those nanopowders were heat treated at different temperatures. The obtained materials were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, high-resolution transmission electron microscopy （HRTEM） and energy dispersive spectroscopy （EDS）. And the catalytic activity on vinyl chloride （VC） emission combustion was investigated. The results showed that those nanopowders after hydrolyzed-oxidized from Ce37Mn18C45 mainly consisted of CeO2 and Mn304. Manganese element increased the thermal stability of CeO2 nanopowders. The Mn-doped CeO2 nanopowders had three morphologies. Small particles were Mn-doped CeO2, square particles were Mn304 and the rods were Mn304 and Mn203. The Mn-doped CeO2 nanopowders had good vinyl chloride （VC） emission catalytic performance.
基金Project supported by the Polish National Science Centre(2015/17/N/ST5/01947)
文摘A series of KY3F10 nanophosphors doped with Gd3＋, Ce3＋ and Eu3＋ ions were obtained with the use of a co-precipitation method. The resulting products were white precipitates, consisting of spherical particles with diameter about 150-200 nm, which was confirmed using transmission electron microscopy （TEM） technique. Powder X-ray diffraction （XRD） and energy dispersive X-ray analysis （EDX） measurements confirmed appropriate structures of the nanoparticles obtained. Spectroscopic properties of the prod- ucts were examined on the basis of the measured excitation/emission spectra and luminescence decay curves. The synthesized sam- ples showed orange-red luminescence, characteristic for Eu3＋ ions. The reaction process was performed in required alkaline pH ad- justed with the use of ethylenediaminetetraacetic acid （EDTA） and potassium hydroxide. The samples containing large amounts of Gd3＋ dooant ions exhibited a tendencv to form nroducts with different momhologies.
基金Project supported by the National Key Basic Research Program(NKBRP20047CCA03900)National Natural Science Foundation of China(2056601)
文摘Study was made on the effect of surface modification on the behaviors of cerium oxide nanopowders.A surfactant-sodium dodecyl sulfate（C12H25SO4Na）was used to modify the surface of CeO2 powder particles.The unmodified and modified CeO2 powders were characterized by using a powder comprehensive characteristic tester,laser particle size analyzer,specific surface area tester,X-ray diffraction tester,and a scanning electron microscope.The testing and analysis results showed that C12H25SO4Na surface modification might increase the flowability and dispersity,and decrease the specific surface area and agglomeration of CeO2 powders.The mechanism of the surface modification of CeO2 powder particles was also discussed.
基金This work was supported by the Natural Science Foundation of Gansu Province,China(No.3ZS042-B25-017).
文摘Pure Ni nanopowders were successfully prepared by the method of anodic arc disch arged plasma with homemade experimental apparatus. The particle size, mircostruc ture and morphology of the particles by this process were characterized via X-ra y powder diffraction (XRD), transmission electron microscopy (TEM) and the corre sponding selected area electron diffraction (SAED); The specific surface area an d pore parameters were investigated by multi-point full analysis of nitrogen ads orption-desorption isotherms at 77K by Brunauer- Emmett-Teller (BET) surface are a analyzer; The chemical composition were determined by X-ray energy dispersive spectrometry (XEDS) equipped in SEM and element analyze instrument. The experime nt results indicate that the samples by this method with high purity,the crystal structure of the particles is as same as the bulk material, is fcc structure, w ith average particle sizes about 47nm, ranging from 20 to 70nm, and distributed uniformly in spherical chain shapes, the specific surface areavis 14.23m2/g, po re volume of pore is 0.09cm3/g and average pore diameter is 23nm.
基金Project supported by the National Natural Science Foundation of China （Grant No. 11004092） and the Scientific Research Fund of Education Department of Liaoning Province, China （Grant No. 2009A417）.
文摘yb3＋/Dy3＋ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results show that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663 nm, corresponding to 4C9/2→ 6H13/2, 4C9/2→ 6Hll/2, 4115/2 → 6H13/2, and 4F9/2 →6Hll/2 transitions of Dy3＋, respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion emissions. The energy transition between Yb3＋ and Dy3＋ is discussed.
