At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systema...At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.展开更多
We present the approaches to implementing the k-√k L turbulence model within the framework of the high-order discontinuous Galerkin(DG)method.We use the DG discretization to solve the full Reynolds-averaged Navier-St...We present the approaches to implementing the k-√k L turbulence model within the framework of the high-order discontinuous Galerkin(DG)method.We use the DG discretization to solve the full Reynolds-averaged Navier-Stokes equations.In order to enhance the robustness of approaches,some effective techniques are designed.The HWENO(Hermite weighted essentially non-oscillatory)limiting strategy is adopted for stabilizing the turbulence model variable k.Modifications have been made to the model equation itself by using the auxiliary variable that is always positive.The 2nd-order derivatives of velocities required in computing the von Karman length scale are evaluated in a way to maintain the compactness of DG methods.Numerical results demonstrate that the approaches have achieved the desirable accuracy for both steady and unsteady turbulent simulations.展开更多
基金supported by the National Natural Science Foundation of China(Project No.42307555).
文摘At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.
基金supported by the National Natural Science Foundation of China(Grant Nos.92252201 and 11721202)the Fundamental Research Funds for the Central Universities.
文摘We present the approaches to implementing the k-√k L turbulence model within the framework of the high-order discontinuous Galerkin(DG)method.We use the DG discretization to solve the full Reynolds-averaged Navier-Stokes equations.In order to enhance the robustness of approaches,some effective techniques are designed.The HWENO(Hermite weighted essentially non-oscillatory)limiting strategy is adopted for stabilizing the turbulence model variable k.Modifications have been made to the model equation itself by using the auxiliary variable that is always positive.The 2nd-order derivatives of velocities required in computing the von Karman length scale are evaluated in a way to maintain the compactness of DG methods.Numerical results demonstrate that the approaches have achieved the desirable accuracy for both steady and unsteady turbulent simulations.
