The pre-wetting of aggregate surface is a means to improve the interface performance of SBS modified asphalt and aggregate.The effect of pre-wetting technology on the interaction between SBS modified asphalt and aggre...The pre-wetting of aggregate surface is a means to improve the interface performance of SBS modified asphalt and aggregate.The effect of pre-wetting technology on the interaction between SBS modified asphalt and aggregate was analyzed by molecular dynamics simulation.The diffusion coefficient and concentration distribution of SBS modified asphalt on aggregate surface are included.The simulation results show that the diffusion coefficient of the aggregate surface of SBS modified asphalt is increased by 47.6%and 70.5%respectively after 110#asphalt and 130#asphalt are pre-wetted.The concentration distribution of SBS modified asphalt on the aggregate surface after pre-wetting is more uniform.According to the results of interface energy calculation,the interface energy of SBS modified bitumen and aggregate can be increased by about 5%after pre-wetting.According to the results of molecular dynamics simulation,the pre-wetting technology can effectively improve the interface workability of SBS modified bitumen and aggregate,so as to improve the interface performance.展开更多
Metal-carbon dioxide(CO_(2))batteries hold great promise for reducing greenhouse gas emissions and are regarded as one of the most promising energy storage techniques due to their efficiency advantages in CO_(2)recove...Metal-carbon dioxide(CO_(2))batteries hold great promise for reducing greenhouse gas emissions and are regarded as one of the most promising energy storage techniques due to their efficiency advantages in CO_(2)recovery and conversion.Moreover,rechargeable nonaqueous metal-CO_(2)batteries have attracted much attention due to their high theoretical energy density.However,the stability issues of the electrode-electrolyte interfaces of nonaqueous metal-CO_(2)(lithium(Li)/sodium(Na)/potassium(K)-CO_(2))batteries have been troubling its development,and a large number of related research in the field of electrolytes have conducted in recent years.This review retraces the short but rapid research history of nonaqueous metal-CO_(2)batteries with a detailed electrochemical mechanism analysis.Then it focuses on the basic characteristics and design principles of electrolytes,summarizes the latest achievements of various types of electrolytes in a timely manner and deeply analyzes the construction strategies of stable electrode-electrolyte interfaces for metal-CO_(2)batteries.Finally,the key issues related to electrolytes and interface engineering are fully discussed and several potential directions for future research are proposed.This review enriches a comprehensive understanding of electrolytes and interface engineering toward the practical applications of next-generation metal-CO_(2)batteries.展开更多
The scaled suction caisson repre sents an innovative design featuring a bio-inspired sidewall modeled after snake skin,commonly utilized in offshore mooring platforms.In comparison with traditional suction caissons,th...The scaled suction caisson repre sents an innovative design featuring a bio-inspired sidewall modeled after snake skin,commonly utilized in offshore mooring platforms.In comparison with traditional suction caissons,this bio-inspired design demonstrates reduced penetration resistance and enhanced pull-out capacity due to the anisotropic shear behaviors of its sidewall.To investigate the shear behavior of the bio-inspired sidewall under pull-out load,direct shear tests were conducted between the bio-inspired surface and sand.The research demonstrates that the interface shear strength of the bio-inspired surface significantly surpasses that of the smooth surface due to interlocking effects.Additionally,the interface shear strength correlates with the aspect ratio of the bio-inspired surface,shear angle,and particle diameter distribution,with values increasing as the uniformity coefficient Cudecreases,while initially increasing and subsequently decreasing with increases in both aspect ratio and shear angle.The ratio between the interface friction angleδand internal friction angle δ_(s) defines the interface effect factor k.For the bio-inspired surface,the interface effect factor k varies with shear angleβ,ranging from 0.9 to 1.12.The peak value occurs at a shear angleβof 60°,substantially exceeding that of the smooth surface.A method for calculating the relative roughness R_(N) is employed to evaluate the interface roughness of the bio-inspired surface,taking into account scale dimension and particle diameter distribution effects.展开更多
Efficient utilization of electrostatic charges is paramount for numerous applications,from printing to kinetic energy harvesting.However,existing technologies predominantly focus on the static qualities of these charg...Efficient utilization of electrostatic charges is paramount for numerous applications,from printing to kinetic energy harvesting.However,existing technologies predominantly focus on the static qualities of these charges,neglecting their dynamic capabilities as carriers for energy conversion.Herein,we report a paradigm-shifting strategy that orchestrates the swift transit of surface charges,generated through contact electrification,via a freely moving droplet.This technique ingeniously creates a bespoke charged surface which,in tandem with a droplet acting as a transfer medium to the ground,facilitates targeted charge displacement and amplifies electrical energy collection.The spontaneously generated electric field between the charged surface and needle tip,along with the enhanced water ionization under the electric field,proves pivotal in facilitating controlled charge transfer.By coupling the effects of charge self-transfer,contact electrification,and electrostatic induction,a dual-electrode droplet-driven(DD)triboelectric nanogenerator(TENG)is designed to harvest the water-related energy,exhibiting a two-orderof-magnitude improvement in electrical output compared to traditional single-electrode systems.Our strategy establishes a fundamental groundwork for efficient water drop energy acquisition,offering deep insights and substantial utility for future interdisciplinary research and applications in energy science.展开更多
Interface chemical modulation strategies are considered as promising method to prepare electrocatalysts for the urea oxidation reaction(UOR).However,conventional interface catalysts are generally limited by the inhere...Interface chemical modulation strategies are considered as promising method to prepare electrocatalysts for the urea oxidation reaction(UOR).However,conventional interface catalysts are generally limited by the inherent activity and incompatibility of the individual components themselves,and the irregular charge distribution and slow charge transfer ability between interfaces severely limit the activity of UOR.Therefore,we optimized and designed a Ni_(2)P/CoP interface with modulated surface charge distribution and directed charge transfer to promote UOR activity.Density functional theorycalculations first predict a regular charge transfer from CoP to Ni_(2)P,which creates a built-in electric field between Ni_(2)P and CoP interface.Optimization of the adsorption/desorption process of UOR/HER reaction intermediates leads to the improvement of catalytic activity.Electrochemical impedance spectroscopy and ex situ X-ray photoelectron spectroscopy characterization confirm the unique mechanism of facilitated reaction at the Ni_(2)P/CoP interface.Electrochemical tests further validated the prediction with excellent UOR/HER activities of 1.28 V and 19.7 mV vs.RHE,at 10 mA cm^(-2),respectively.Furthermore,Ni_(2)P/CoP achieves industrial-grade current densities(500 mA cm^(−2))at 1.75 V and 1.87 V in the overall urea electrolyzer(UOR||HER)and overall human urine electrolyzer(HUOR||HER),respectively,and demonstrates considerable durability.展开更多
Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding...Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding soil.Previous studies focused on estimating the interface frictional anisotropy mobilized by snakeskin-inspired textured surfaces and sand under monotonic shear loading conditions.However,there is a need to estimate interface frictional anisotropy under repetitive shear loads.In this study,a series of repetitive direct shear(DS)tests are performed with snakeskin-inspired textured surfaces under a constant vertical stress and two shear directions(cranial first half→caudal second half or caudal first half→cranial second half).The results show that(1)mobilized shear stress increases with the number of shearing cycles,(2)cranial shearing(shearing against the scales)consistently produces a higher shear resistance and less contractive behavior than caudal shearing(shearing along the scales),and(3)a higher scale height or smaller scale length of the surface yields a higher interface friction angle across all shearing cycles.Further analysis reveals that the gap between the cranial and caudal shear zones of the interface friction angle as a function of L/H(i.e.the ratio of scale length L to scale height H)continues to decrease as the number of shearing cycles approaches asymptotic values.The directional frictional resistance(DFR)decreases as the number of shearing cycles increases.Furthermore,the discussion covers the impact of initial relative density,vertical stress,and the number of shearing cycles on interface frictional anisotropy.展开更多
The formation of interphase layers,including the cathode-electrolyte interphase(CEI)and solidelectrolyte interphase(SEI),exhibits significant chemical complexity and plays a pivotal role in determining the performance...The formation of interphase layers,including the cathode-electrolyte interphase(CEI)and solidelectrolyte interphase(SEI),exhibits significant chemical complexity and plays a pivotal role in determining the performance of lithium batteries.Despite considerable advances in simulating the bulk phase properties of battery materials,the understanding of interfaces,including crystalline interfaces that represent the simplest case,remains limited.This is primarily due to challenges in performing ground-state searches for interface microstructures and the high computational costs associated with first-principles methods.Herein,we introduce InterOptimus,an automated workflow designed to efficiently search for ground-state heterogeneous interfaces.InterOptimus incorporates a rigorous,symmetry-aware equivalence analysis for lattice matching and termination scanning.Additionally,it introduces stereographic projection as an intuitive and comprehensive framework for visualizing and classifying interface structures.By integrating universal machine learning interatomic potentials(MLIPs),InterOptimus enables rapid predictions of interface energy and stability,significantly reducing the necessary computational cost in density functional theory(DFT)by over 90%.We benchmarked several MLIPs at three critical lithium battery interfaces,Li_(2)S|Ni_(3)S_(2),LiF|NCM,and Li_(3)PS_(4)|Li,and demonstrated that the MLIPs achieve accuracy comparable to DFT in modeling potential energy surfaces and ranking interface stabilities.Thus,InterOptimus facilitates the efficient determination of ground-state heterogeneous interface structures and subsequent studies of structure-property relationships,accelerating the interface engineering of novel battery materials.展开更多
Steel slag(SS)accumulates unavoidably due to its complex and unstable composition,high production volumes,and limited value-added resource utilization.Single or multiple interface modifiers were proposed to enhance th...Steel slag(SS)accumulates unavoidably due to its complex and unstable composition,high production volumes,and limited value-added resource utilization.Single or multiple interface modifiers were proposed to enhance the properties of SS through high-speed dispersion,transforming its inherent hydrophilic and oleophobic characteristics into hydrophily and lipophilicity.The modification effects were innovatively assessed by observing the color changes of modified steel slag solutions following the dissolution-settlement equilibrium constant.This approach avoided human-induced errors and improved estimated accuracy in conformance with conventional methods such as oil absorption value,activation index,sedimentation volume,and lipophilicity.The hydrolysis of 3-aminopropyltriethoxysilane(KH)generated–Si(OH)_(3)structure to form hydrogen or covalent bonds with active substances(OH groups)from SS.Concurrently,SS underwent encapsulation via Si–O–Si structure resulting from the dehydration of–Si(OH)_(3).The stearic acid coupling agent(SA),aluminate coupling agent(AC),and titanate coupling agent(TN)underwent chemical reactions with Ca(OH)_(2),Al(OH)_(3),and CaCO_(3)in SS.The acidic SA primarily created stable chemical bonds and acted as a supplement due to its package,reducing surface activity and hydrophilicity while enhancing lipophilicity.Specifically,the optimal modification effect was obtained at 3 wt.%SA.Consequently,3 wt.%SA was established as the benchmark for multiple modifiers and the most effective combination was 3 wt.%SA and 3 wt.%AC.Compared with a single interface modifier,SA corroded the SS surface to provide numerous active sites for further modification by KH,AC,or TN,resulting in a more densely packed structure.In addition,more organic groups on SS prevent the proximity of other particles from agglomerating to achieve dispersion and a synergistic modification,laying a theoretical foundation of SS in a new pathway for organic composite materials.展开更多
Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spa...Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spacer cations but suffer from vertical phase segregation and buried interface defects.Herein,we introduce dicyanodiamide(DCD)to simultaneously address these dual limitations in GA(MA)_(n)Pb_(n)I_(3n+1)perovskites.The guanidine group in DCD passivates undercoordinated Pb^(2+)and MA^(+)vacancies at the perovskite/TiO_(2)interface,while cyano groups eliminate oxygen vacancies in TiO_(2)via Ti^(4+)-CN coordination,reducing interfacial trap density by 73%with respect to the control sample.In addition,DCD regulates crystallization kinetics,suppressing low-n-phase aggregation and promoting vertical alignment of high-n phases,which benefit for carrier transport.This dual-functional modification enhances charge transport and stabilizes energy-level alignment.The optimized devices achieve a record power conversion efficiency of 21.54%(vs.19.05%control)and retain 94%initial efficiency after 1200 h,outperforming unmodified counterparts(84%retention).Combining defect passivation with phase homogenization,this work establishes a molecular bridge strategy to decouple stability-efficiency trade-offs in low-dimensional perovskites,providing a universal framework for interface engineering in high-performance optoelectronics.展开更多
Cleanliness control of advanced steels is of vital importance for quality control of the products.In order to understand and control the inclusion removal during refining process in molten steel,its motion behaviors a...Cleanliness control of advanced steels is of vital importance for quality control of the products.In order to understand and control the inclusion removal during refining process in molten steel,its motion behaviors at the multiple steel/gas/slag interfaces have attracted the attention much of metallurgical community.The recent development of the agglomeration of non-metallic inclusions at the steel/Ar and steel/slag interfaces has been summarized,and both the experimental as well as theoretical works have been surveyed.In terms of in situ observation of high-temperature interfacial phenomena in the molten steel,researchers utilized high-temperature confocal laser scanning microscopy to observe the movement of more types of inclusions at the interface,i.e.,the investigated inclusion is no longer limited to Al_(2)O_(3)-based inclusions but moves forward to rare earth oxides,MgO-based oxides,etc.In terms of theoretical models,especially the model of inclusions at the steel/slag interface,the recent development has overcome the limitations of the assumptions of Kralchevsky-Paunov model and verified the possible errors caused by the model assumptions by combining the water model and the physical model.Last but not least,the future work in this topic has been suggested,which could be in combination of thermal physical properties of steels and slag,as well as utilize the artificial intelligence-based methodology to implement a comprehensive inclusion motion behaviors during a comprehensive metallurgical process.展开更多
Moisture-enabled electricity generation(MEG)has emerged as a promising sustainable energy harvesting technology,comparable to photovoltaics,thermoelectrics,and triboelectrics[1].MEGs generate electricity by converting...Moisture-enabled electricity generation(MEG)has emerged as a promising sustainable energy harvesting technology,comparable to photovoltaics,thermoelectrics,and triboelectrics[1].MEGs generate electricity by converting the chemical potential of moisture into electric energy through interactions with hygroscopic materials and nanostructured interfaces.Unlike solar or thermal harvesters,MEGs operate continuously by utilizing ubiquitous atmospheric moisture,granting them unique spatial and temporal adaptability.Despite nearly a decade of progress and the exploration of diverse material systems for MEG,the overall output power remains significantly limited due to inherently low charge carrier concentrations and restricted ion diffusion fluxes[2].As a result,standalone MEG devices often deliver low and unstable output,limiting practical applications.To enhance performance and versatility,recent efforts have explored hybridization of MEG with other ambient energy sources such as triboelectric or thermoelectric effects.展开更多
Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is con...Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.展开更多
Silicon stands as a key anode material in lithium-ion battery ascribing to its high energy density.Nevertheless,the poor rate performance and limited cycling life remain unresolved through conventional approaches that...Silicon stands as a key anode material in lithium-ion battery ascribing to its high energy density.Nevertheless,the poor rate performance and limited cycling life remain unresolved through conventional approaches that involve carbon composites or nanostructures,primarily due to the un-controllable effects arising from the substantial formation of a solid electrolyte interphase(SEI)during the cycling.Here,an ultra-thin and homogeneous Ti doping alumina oxide catalytic interface is meticulously applied on the porous Si through a synergistic etching and hydrolysis process.This defect-rich oxide interface promotes a selective adsorption of fluoroethylene carbonate,leading to a catalytic reaction that can be aptly described as“molecular concentration-in situ conversion”.The resultant inorganic-rich SEI layer is electrochemical stable and favors ion-transport,particularly at high-rate cycling and high temperature.The robustly shielded porous Si,with a large surface area,achieves a high initial Coulombic efficiency of 84.7%and delivers exceptional high-rate performance at 25 A g^(−1)(692 mAh g^(−1))and a high Coulombic efficiency of 99.7%over 1000 cycles.The robust SEI constructed through a precious catalytic layer promises significant advantages for the fast development of silicon-based anode in fast-charging batteries.展开更多
The poor reversibility and stability of Zn anodes greatly restrict the practical application of aqueous Zn-ion batteries(AZIBs),resulting from the uncontrollable dendrite growth and H_(2)O-induced side reactions durin...The poor reversibility and stability of Zn anodes greatly restrict the practical application of aqueous Zn-ion batteries(AZIBs),resulting from the uncontrollable dendrite growth and H_(2)O-induced side reactions during cycling.Electrolyte additive modification is considered one of the most effective and simplest methods for solving the aforementioned problems.Herein,the pyridine derivatives(PD)including 2,4-dihydroxypyridine(2,4-DHP),2,3-dihydroxypyridine(2,3-DHP),and 2-hydroxypyrdine(2-DHP),were em-ployed as novel electrolyte additives in ZnSO_(4)electrolyte.Both density functional theory calculation and experimental findings demonstrated that the incorporation of PD additives into the electrolyte effectively modulates the solvation structure of hydrated Zn ions,thereby suppressing side reactions in AZIBs.Ad-ditionally,the adsorption of PD molecules on the zinc anode surface contributed to uniform Zn deposi-tion and dendrite growth inhibition.Consequently,a 2,4-DHP-modified Zn/Zn symmetrical cell achieved an extremely long cyclic stability up to 5650 h at 1 mA cm^(-2).Furthermore,the Zn/NH_(4)V_(4)O_(10)full cell with 2,4-DHP-containing electrolyte exhibited an outstanding initial capacity of 204 mAh g^(-1),with a no-table capacity retention of 79%after 1000 cycles at 5 A g^(-1).Hence,this study expands the selection of electrolyte additives for AZIBs,and the working mechanism of PD additives provides new insights for electrolyte modification enabling highly reversible zinc anode.展开更多
Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interfa...Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interface dynamics influenced by complex topology commonly leads to non-wetting fluid trapping.Particularly,the underlying mechanisms under viscously unfavorable conditions remain unclear.This study employs a direct numerical simulation method to simulate forced imbibition through the reconstructed digital rocks of sandstone.The interface dynamics and fluid–fluid interactions are investigated through transient simulations,while the pore topology metrics are introduced to analyze the impact on steady-state residual fluid distribution obtained by a pseudo-transient scheme.The results show that the cooperative pore-filling process promoted by corner flow is dominant at low capillary numbers.This leads to unstable inlet pressure,mass flow,and interface curvature,which correspond to complicated interface dynamics and higher residual fluid saturation.During forced imbibition,the interface curvature gradually increases,with the pore-filling mechanisms involving the cooperation of main terminal meniscus movement and arc menisci filling.Complex topology with small diameter pores may result in the destabilization of interface curvature.The residual fluid saturation is negatively correlated with porosity and pore throat size,and positively correlated with tortuosity and aspect ratio.A large mean coordination number characterizing global connectivity promotes imbibition.However,high connectivity characterized by the standardized Euler number corresponding to small pores is associated with a high probability of non-wetting fluid trapping.展开更多
In order to solve the problem of poor formability caused by different materials and properties in the process of tailor-welded sheets forming,a forming method was proposed to change the stress state of tailor-welded s...In order to solve the problem of poor formability caused by different materials and properties in the process of tailor-welded sheets forming,a forming method was proposed to change the stress state of tailor-welded sheets by covering the tailor-welded sheets with better plastic properties overlapping sheets.At the same time,the interface friction effect between the overlapping and tailor-welded sheets was utilized to control the stress magnitude and further improve the formability and quality of the tailor-welded sheets.In this work,the bulging process of the tailor-welded overlapping sheets was taken as the research object.Aluminum alloy tailor-welded overlapping sheets bulging specimens were studied by a combination of finite element analysis and experimental verification.The results show that the appropriate use of interface friction between tailor-welded and overlapping sheets can improve the formability of tailor-welded sheets and control the flow of weld seam to improve the forming quality.When increasing the interface friction coefficient on the side of tailor-welded sheets with higher strength and decreasing that on the side of tailor-welded sheets with lower strength,the deformation of the tailor-welded sheets are more uniform,the offset of the weld seam is minimal,the limit bulging height is maximal,and the forming quality is optimal.展开更多
Brain-computer interfaces(BCIs)represent an emerging technology that facilitates direct communication between the brain and external devices.In recent years,numerous review articles have explored various aspects of BC...Brain-computer interfaces(BCIs)represent an emerging technology that facilitates direct communication between the brain and external devices.In recent years,numerous review articles have explored various aspects of BCIs,including their fundamental principles,technical advancements,and applications in specific domains.However,these reviews often focus on signal processing,hardware development,or limited applications such as motor rehabilitation or communication.This paper aims to offer a comprehensive review of recent electroencephalogram(EEG)-based BCI applications in the medical field across 8 critical areas,encompassing rehabilitation,daily communication,epilepsy,cerebral resuscitation,sleep,neurodegenerative diseases,anesthesiology,and emotion recognition.Moreover,the current challenges and future trends of BCIs were also discussed,including personal privacy and ethical concerns,network security vulnerabilities,safety issues,and biocompatibility.展开更多
Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and...Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.展开更多
As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal...As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.展开更多
The microstructure,micro-hardness,and tensile properties of interface between hot isostatic pressing densified low alloy steel and Inconel 690 cladding were investigated during the aging process at 600℃.The results s...The microstructure,micro-hardness,and tensile properties of interface between hot isostatic pressing densified low alloy steel and Inconel 690 cladding were investigated during the aging process at 600℃.The results show that the interface region can be divided into four zones from base metal to deposited metal:carbon-depleted zone(CDZ),partial melting zone(PMZ),planar growth zone(PGZ),and brownish feature zone(BFZ).Dimensions of these zones do not significantly change during aging.However,type I carbides noticeably increase in size in the PMZ,and precipitates clearly occur in the PGZ.The main reason for their growth and occurrence is continuous carbon migration.The highest micro-hardness appears in the PGZ and BFZ regions,which is related to carbon accumulation and precipitates in these regions.Tensile failure occurs on the base metal side due to the high strength mismatch between these two materials.The CDZ,composed of only ferrite,has lower strength and fractures at the boundary between CDZ and base metal.The ultimate tensile strength decreases by only 50 MPa after aging for 1500 h,and the interface region maintains high strength without significant deformation.展开更多
基金Funded by the Research Funds of China University of Mining and Technology(No.102523215)。
文摘The pre-wetting of aggregate surface is a means to improve the interface performance of SBS modified asphalt and aggregate.The effect of pre-wetting technology on the interaction between SBS modified asphalt and aggregate was analyzed by molecular dynamics simulation.The diffusion coefficient and concentration distribution of SBS modified asphalt on aggregate surface are included.The simulation results show that the diffusion coefficient of the aggregate surface of SBS modified asphalt is increased by 47.6%and 70.5%respectively after 110#asphalt and 130#asphalt are pre-wetted.The concentration distribution of SBS modified asphalt on the aggregate surface after pre-wetting is more uniform.According to the results of interface energy calculation,the interface energy of SBS modified bitumen and aggregate can be increased by about 5%after pre-wetting.According to the results of molecular dynamics simulation,the pre-wetting technology can effectively improve the interface workability of SBS modified bitumen and aggregate,so as to improve the interface performance.
基金supports from the Beijing Laboratory of New Energy Storage Technology, North China Electric Power Universitythe Program of the National Energy Storage Industry-Education Platformthe Interdisciplinary Innovation Program of North China Electric Power University (No. XM2212315)
文摘Metal-carbon dioxide(CO_(2))batteries hold great promise for reducing greenhouse gas emissions and are regarded as one of the most promising energy storage techniques due to their efficiency advantages in CO_(2)recovery and conversion.Moreover,rechargeable nonaqueous metal-CO_(2)batteries have attracted much attention due to their high theoretical energy density.However,the stability issues of the electrode-electrolyte interfaces of nonaqueous metal-CO_(2)(lithium(Li)/sodium(Na)/potassium(K)-CO_(2))batteries have been troubling its development,and a large number of related research in the field of electrolytes have conducted in recent years.This review retraces the short but rapid research history of nonaqueous metal-CO_(2)batteries with a detailed electrochemical mechanism analysis.Then it focuses on the basic characteristics and design principles of electrolytes,summarizes the latest achievements of various types of electrolytes in a timely manner and deeply analyzes the construction strategies of stable electrode-electrolyte interfaces for metal-CO_(2)batteries.Finally,the key issues related to electrolytes and interface engineering are fully discussed and several potential directions for future research are proposed.This review enriches a comprehensive understanding of electrolytes and interface engineering toward the practical applications of next-generation metal-CO_(2)batteries.
基金supported by the National Natural Science Foundation of China(Grant Nos.52371301 and 52471289)。
文摘The scaled suction caisson repre sents an innovative design featuring a bio-inspired sidewall modeled after snake skin,commonly utilized in offshore mooring platforms.In comparison with traditional suction caissons,this bio-inspired design demonstrates reduced penetration resistance and enhanced pull-out capacity due to the anisotropic shear behaviors of its sidewall.To investigate the shear behavior of the bio-inspired sidewall under pull-out load,direct shear tests were conducted between the bio-inspired surface and sand.The research demonstrates that the interface shear strength of the bio-inspired surface significantly surpasses that of the smooth surface due to interlocking effects.Additionally,the interface shear strength correlates with the aspect ratio of the bio-inspired surface,shear angle,and particle diameter distribution,with values increasing as the uniformity coefficient Cudecreases,while initially increasing and subsequently decreasing with increases in both aspect ratio and shear angle.The ratio between the interface friction angleδand internal friction angle δ_(s) defines the interface effect factor k.For the bio-inspired surface,the interface effect factor k varies with shear angleβ,ranging from 0.9 to 1.12.The peak value occurs at a shear angleβof 60°,substantially exceeding that of the smooth surface.A method for calculating the relative roughness R_(N) is employed to evaluate the interface roughness of the bio-inspired surface,taking into account scale dimension and particle diameter distribution effects.
基金supported by the Natural Science Foundation of Zhejiang Province(LZ22C130001)the National Natural Science Foundation of China(32171887,and 52002028,and 52192610)+1 种基金the National Key Research and Development Project from Minister of Science&Technology(2021YFA0202704)Beijing Municipal Science&Technology Commission(Z171100002017017).
文摘Efficient utilization of electrostatic charges is paramount for numerous applications,from printing to kinetic energy harvesting.However,existing technologies predominantly focus on the static qualities of these charges,neglecting their dynamic capabilities as carriers for energy conversion.Herein,we report a paradigm-shifting strategy that orchestrates the swift transit of surface charges,generated through contact electrification,via a freely moving droplet.This technique ingeniously creates a bespoke charged surface which,in tandem with a droplet acting as a transfer medium to the ground,facilitates targeted charge displacement and amplifies electrical energy collection.The spontaneously generated electric field between the charged surface and needle tip,along with the enhanced water ionization under the electric field,proves pivotal in facilitating controlled charge transfer.By coupling the effects of charge self-transfer,contact electrification,and electrostatic induction,a dual-electrode droplet-driven(DD)triboelectric nanogenerator(TENG)is designed to harvest the water-related energy,exhibiting a two-orderof-magnitude improvement in electrical output compared to traditional single-electrode systems.Our strategy establishes a fundamental groundwork for efficient water drop energy acquisition,offering deep insights and substantial utility for future interdisciplinary research and applications in energy science.
文摘Interface chemical modulation strategies are considered as promising method to prepare electrocatalysts for the urea oxidation reaction(UOR).However,conventional interface catalysts are generally limited by the inherent activity and incompatibility of the individual components themselves,and the irregular charge distribution and slow charge transfer ability between interfaces severely limit the activity of UOR.Therefore,we optimized and designed a Ni_(2)P/CoP interface with modulated surface charge distribution and directed charge transfer to promote UOR activity.Density functional theorycalculations first predict a regular charge transfer from CoP to Ni_(2)P,which creates a built-in electric field between Ni_(2)P and CoP interface.Optimization of the adsorption/desorption process of UOR/HER reaction intermediates leads to the improvement of catalytic activity.Electrochemical impedance spectroscopy and ex situ X-ray photoelectron spectroscopy characterization confirm the unique mechanism of facilitated reaction at the Ni_(2)P/CoP interface.Electrochemical tests further validated the prediction with excellent UOR/HER activities of 1.28 V and 19.7 mV vs.RHE,at 10 mA cm^(-2),respectively.Furthermore,Ni_(2)P/CoP achieves industrial-grade current densities(500 mA cm^(−2))at 1.75 V and 1.87 V in the overall urea electrolyzer(UOR||HER)and overall human urine electrolyzer(HUOR||HER),respectively,and demonstrates considerable durability.
基金the funding supported from the National Research Foundation of Korea(NRF)grant funded by the Korea Government MSIT(No.2021R1C1C1006003).
文摘Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding soil.Previous studies focused on estimating the interface frictional anisotropy mobilized by snakeskin-inspired textured surfaces and sand under monotonic shear loading conditions.However,there is a need to estimate interface frictional anisotropy under repetitive shear loads.In this study,a series of repetitive direct shear(DS)tests are performed with snakeskin-inspired textured surfaces under a constant vertical stress and two shear directions(cranial first half→caudal second half or caudal first half→cranial second half).The results show that(1)mobilized shear stress increases with the number of shearing cycles,(2)cranial shearing(shearing against the scales)consistently produces a higher shear resistance and less contractive behavior than caudal shearing(shearing along the scales),and(3)a higher scale height or smaller scale length of the surface yields a higher interface friction angle across all shearing cycles.Further analysis reveals that the gap between the cranial and caudal shear zones of the interface friction angle as a function of L/H(i.e.the ratio of scale length L to scale height H)continues to decrease as the number of shearing cycles approaches asymptotic values.The directional frictional resistance(DFR)decreases as the number of shearing cycles increases.Furthermore,the discussion covers the impact of initial relative density,vertical stress,and the number of shearing cycles on interface frictional anisotropy.
基金supported by the National Natural Science Foundation of China(92470110)the Special Funds for the Development of Strategic Emerging Industries in Shenzhen(XMHT20240108008)the Shenzhen Stable Support Program for Higher Education Institutions(WDZC20231126215806001)。
文摘The formation of interphase layers,including the cathode-electrolyte interphase(CEI)and solidelectrolyte interphase(SEI),exhibits significant chemical complexity and plays a pivotal role in determining the performance of lithium batteries.Despite considerable advances in simulating the bulk phase properties of battery materials,the understanding of interfaces,including crystalline interfaces that represent the simplest case,remains limited.This is primarily due to challenges in performing ground-state searches for interface microstructures and the high computational costs associated with first-principles methods.Herein,we introduce InterOptimus,an automated workflow designed to efficiently search for ground-state heterogeneous interfaces.InterOptimus incorporates a rigorous,symmetry-aware equivalence analysis for lattice matching and termination scanning.Additionally,it introduces stereographic projection as an intuitive and comprehensive framework for visualizing and classifying interface structures.By integrating universal machine learning interatomic potentials(MLIPs),InterOptimus enables rapid predictions of interface energy and stability,significantly reducing the necessary computational cost in density functional theory(DFT)by over 90%.We benchmarked several MLIPs at three critical lithium battery interfaces,Li_(2)S|Ni_(3)S_(2),LiF|NCM,and Li_(3)PS_(4)|Li,and demonstrated that the MLIPs achieve accuracy comparable to DFT in modeling potential energy surfaces and ranking interface stabilities.Thus,InterOptimus facilitates the efficient determination of ground-state heterogeneous interface structures and subsequent studies of structure-property relationships,accelerating the interface engineering of novel battery materials.
基金supported by the National Natural Science Foundation of China(U23A20605)Anhui Graduate Innovation and Entrepreneurship Practice Project(2022cxcysj090)+2 种基金China Baowu Low Carbon Metallurgy Innovation Foundation(BWLCF202202)the University Synergy Innovation Program of Anhui Province(GXXT-2020-072)the Outstanding Youth Fund of Anhui Province(2208085J19).
文摘Steel slag(SS)accumulates unavoidably due to its complex and unstable composition,high production volumes,and limited value-added resource utilization.Single or multiple interface modifiers were proposed to enhance the properties of SS through high-speed dispersion,transforming its inherent hydrophilic and oleophobic characteristics into hydrophily and lipophilicity.The modification effects were innovatively assessed by observing the color changes of modified steel slag solutions following the dissolution-settlement equilibrium constant.This approach avoided human-induced errors and improved estimated accuracy in conformance with conventional methods such as oil absorption value,activation index,sedimentation volume,and lipophilicity.The hydrolysis of 3-aminopropyltriethoxysilane(KH)generated–Si(OH)_(3)structure to form hydrogen or covalent bonds with active substances(OH groups)from SS.Concurrently,SS underwent encapsulation via Si–O–Si structure resulting from the dehydration of–Si(OH)_(3).The stearic acid coupling agent(SA),aluminate coupling agent(AC),and titanate coupling agent(TN)underwent chemical reactions with Ca(OH)_(2),Al(OH)_(3),and CaCO_(3)in SS.The acidic SA primarily created stable chemical bonds and acted as a supplement due to its package,reducing surface activity and hydrophilicity while enhancing lipophilicity.Specifically,the optimal modification effect was obtained at 3 wt.%SA.Consequently,3 wt.%SA was established as the benchmark for multiple modifiers and the most effective combination was 3 wt.%SA and 3 wt.%AC.Compared with a single interface modifier,SA corroded the SS surface to provide numerous active sites for further modification by KH,AC,or TN,resulting in a more densely packed structure.In addition,more organic groups on SS prevent the proximity of other particles from agglomerating to achieve dispersion and a synergistic modification,laying a theoretical foundation of SS in a new pathway for organic composite materials.
基金support from the National Key R&D Program of China(Grant No.2023YFE0111500)the National Natural Science Foundation of China(Grant No.52321006,T2394480,T2394484,22109143,22479131)+8 种基金Beijing National Laboratory for Molecular Sciences(BNLMS-CXXM-202005)the China Postdoctoral Innovative Talent Support Program(Grant No.BX2021271)the China Postdoctoral Science Foundation(2022M712851)the Opening Project of State Key Laboratory of Advanced Technology for Float Glass(Grant No.2022KF04)Graduate Education Reform Project of Henan Province(Grant No.2023SJGLX136Y)Key R&D Special Program of Henan Province(Grant No.241111242000)Program for Science and Technology Innovation Talents in Universities of Henan Province(Grant No.25HASTIT005)Training Plan for Young Backbone Teachers of Zhengzhou University(Grant No.2023ZDGGJS017)the Joint Research Project of Puyang Shengtong Juyuan New Materials Co.,Ltd.(Grant No.20230128A).
文摘Organic-inorganic hybrid perovskite solar cells achieve remarkable efficiencies(>26%)yet face stability challenges.Quasi-2D alternating-cation-interlayer perovskites offer enhanced stability through hydrophobic spacer cations but suffer from vertical phase segregation and buried interface defects.Herein,we introduce dicyanodiamide(DCD)to simultaneously address these dual limitations in GA(MA)_(n)Pb_(n)I_(3n+1)perovskites.The guanidine group in DCD passivates undercoordinated Pb^(2+)and MA^(+)vacancies at the perovskite/TiO_(2)interface,while cyano groups eliminate oxygen vacancies in TiO_(2)via Ti^(4+)-CN coordination,reducing interfacial trap density by 73%with respect to the control sample.In addition,DCD regulates crystallization kinetics,suppressing low-n-phase aggregation and promoting vertical alignment of high-n phases,which benefit for carrier transport.This dual-functional modification enhances charge transport and stabilizes energy-level alignment.The optimized devices achieve a record power conversion efficiency of 21.54%(vs.19.05%control)and retain 94%initial efficiency after 1200 h,outperforming unmodified counterparts(84%retention).Combining defect passivation with phase homogenization,this work establishes a molecular bridge strategy to decouple stability-efficiency trade-offs in low-dimensional perovskites,providing a universal framework for interface engineering in high-performance optoelectronics.
基金the National Natural Science Foundation of China(Grant No.52074179)for the financial supportNational Key Research and Development Program of China(2024YFB3713705)is also acknowledged.
文摘Cleanliness control of advanced steels is of vital importance for quality control of the products.In order to understand and control the inclusion removal during refining process in molten steel,its motion behaviors at the multiple steel/gas/slag interfaces have attracted the attention much of metallurgical community.The recent development of the agglomeration of non-metallic inclusions at the steel/Ar and steel/slag interfaces has been summarized,and both the experimental as well as theoretical works have been surveyed.In terms of in situ observation of high-temperature interfacial phenomena in the molten steel,researchers utilized high-temperature confocal laser scanning microscopy to observe the movement of more types of inclusions at the interface,i.e.,the investigated inclusion is no longer limited to Al_(2)O_(3)-based inclusions but moves forward to rare earth oxides,MgO-based oxides,etc.In terms of theoretical models,especially the model of inclusions at the steel/slag interface,the recent development has overcome the limitations of the assumptions of Kralchevsky-Paunov model and verified the possible errors caused by the model assumptions by combining the water model and the physical model.Last but not least,the future work in this topic has been suggested,which could be in combination of thermal physical properties of steels and slag,as well as utilize the artificial intelligence-based methodology to implement a comprehensive inclusion motion behaviors during a comprehensive metallurgical process.
基金the financial support of the National Natural Science Foundation of China(No.22205165).
文摘Moisture-enabled electricity generation(MEG)has emerged as a promising sustainable energy harvesting technology,comparable to photovoltaics,thermoelectrics,and triboelectrics[1].MEGs generate electricity by converting the chemical potential of moisture into electric energy through interactions with hygroscopic materials and nanostructured interfaces.Unlike solar or thermal harvesters,MEGs operate continuously by utilizing ubiquitous atmospheric moisture,granting them unique spatial and temporal adaptability.Despite nearly a decade of progress and the exploration of diverse material systems for MEG,the overall output power remains significantly limited due to inherently low charge carrier concentrations and restricted ion diffusion fluxes[2].As a result,standalone MEG devices often deliver low and unstable output,limiting practical applications.To enhance performance and versatility,recent efforts have explored hybridization of MEG with other ambient energy sources such as triboelectric or thermoelectric effects.
基金financially supported by the National Natural Science Foundation of China(No.52377026 and No.52301192)Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)+4 种基金Postdoctoral Fellowship Program of CPSF under Grant Number(No.GZB20240327)Shandong Postdoctoral Science Foundation(No.SDCXZG-202400275)Qingdao Postdoctoral Application Research Project(No.QDBSH20240102023)China Postdoctoral Science Foundation(No.2024M751563)the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites).
文摘Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.
基金the National Key R&D Plan of the Ministry of Science and Technology of China(2022YFE0122400)National Natural Science Foundation of China(52002238,22102207)+1 种基金Science and Technology Commission of Shanghai Municipality(22ZR1423800,21ZR1465200,23ZR1423600)Shanghai Municipal Education Commission and the NSRF via the Program Management Unit for Human Resources&Institutional Development,Research and Innovation(B49G680115).
文摘Silicon stands as a key anode material in lithium-ion battery ascribing to its high energy density.Nevertheless,the poor rate performance and limited cycling life remain unresolved through conventional approaches that involve carbon composites or nanostructures,primarily due to the un-controllable effects arising from the substantial formation of a solid electrolyte interphase(SEI)during the cycling.Here,an ultra-thin and homogeneous Ti doping alumina oxide catalytic interface is meticulously applied on the porous Si through a synergistic etching and hydrolysis process.This defect-rich oxide interface promotes a selective adsorption of fluoroethylene carbonate,leading to a catalytic reaction that can be aptly described as“molecular concentration-in situ conversion”.The resultant inorganic-rich SEI layer is electrochemical stable and favors ion-transport,particularly at high-rate cycling and high temperature.The robustly shielded porous Si,with a large surface area,achieves a high initial Coulombic efficiency of 84.7%and delivers exceptional high-rate performance at 25 A g^(−1)(692 mAh g^(−1))and a high Coulombic efficiency of 99.7%over 1000 cycles.The robust SEI constructed through a precious catalytic layer promises significant advantages for the fast development of silicon-based anode in fast-charging batteries.
基金supported by the Key Science and Technol-ogy Program of Henan Province(No.232102241020)the Ph.D.Research Startup Foundation of Henan University of Science and Technology(No.400613480015)+1 种基金the Postdoctoral Research Startup Foundation of Henan University of Science and Technology(No.400613554001)the Natural Science Foundation of Henan Province(242300420021).
文摘The poor reversibility and stability of Zn anodes greatly restrict the practical application of aqueous Zn-ion batteries(AZIBs),resulting from the uncontrollable dendrite growth and H_(2)O-induced side reactions during cycling.Electrolyte additive modification is considered one of the most effective and simplest methods for solving the aforementioned problems.Herein,the pyridine derivatives(PD)including 2,4-dihydroxypyridine(2,4-DHP),2,3-dihydroxypyridine(2,3-DHP),and 2-hydroxypyrdine(2-DHP),were em-ployed as novel electrolyte additives in ZnSO_(4)electrolyte.Both density functional theory calculation and experimental findings demonstrated that the incorporation of PD additives into the electrolyte effectively modulates the solvation structure of hydrated Zn ions,thereby suppressing side reactions in AZIBs.Ad-ditionally,the adsorption of PD molecules on the zinc anode surface contributed to uniform Zn deposi-tion and dendrite growth inhibition.Consequently,a 2,4-DHP-modified Zn/Zn symmetrical cell achieved an extremely long cyclic stability up to 5650 h at 1 mA cm^(-2).Furthermore,the Zn/NH_(4)V_(4)O_(10)full cell with 2,4-DHP-containing electrolyte exhibited an outstanding initial capacity of 204 mAh g^(-1),with a no-table capacity retention of 79%after 1000 cycles at 5 A g^(-1).Hence,this study expands the selection of electrolyte additives for AZIBs,and the working mechanism of PD additives provides new insights for electrolyte modification enabling highly reversible zinc anode.
基金supported by the National Natural Science Foundation of China(Grant Nos.42172159 and 42302143)the Postdoctora Fellowship Program of the China Postdoctoral Science Foundation(CPSF)(Grant No.GZB20230864).
文摘Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interface dynamics influenced by complex topology commonly leads to non-wetting fluid trapping.Particularly,the underlying mechanisms under viscously unfavorable conditions remain unclear.This study employs a direct numerical simulation method to simulate forced imbibition through the reconstructed digital rocks of sandstone.The interface dynamics and fluid–fluid interactions are investigated through transient simulations,while the pore topology metrics are introduced to analyze the impact on steady-state residual fluid distribution obtained by a pseudo-transient scheme.The results show that the cooperative pore-filling process promoted by corner flow is dominant at low capillary numbers.This leads to unstable inlet pressure,mass flow,and interface curvature,which correspond to complicated interface dynamics and higher residual fluid saturation.During forced imbibition,the interface curvature gradually increases,with the pore-filling mechanisms involving the cooperation of main terminal meniscus movement and arc menisci filling.Complex topology with small diameter pores may result in the destabilization of interface curvature.The residual fluid saturation is negatively correlated with porosity and pore throat size,and positively correlated with tortuosity and aspect ratio.A large mean coordination number characterizing global connectivity promotes imbibition.However,high connectivity characterized by the standardized Euler number corresponding to small pores is associated with a high probability of non-wetting fluid trapping.
基金Funded by the National Natural Science Foundation of China(Nos.52075347,51575364)and the Natural Science Foundation of Liaoning Provincial(No.2022-MS-295)。
文摘In order to solve the problem of poor formability caused by different materials and properties in the process of tailor-welded sheets forming,a forming method was proposed to change the stress state of tailor-welded sheets by covering the tailor-welded sheets with better plastic properties overlapping sheets.At the same time,the interface friction effect between the overlapping and tailor-welded sheets was utilized to control the stress magnitude and further improve the formability and quality of the tailor-welded sheets.In this work,the bulging process of the tailor-welded overlapping sheets was taken as the research object.Aluminum alloy tailor-welded overlapping sheets bulging specimens were studied by a combination of finite element analysis and experimental verification.The results show that the appropriate use of interface friction between tailor-welded and overlapping sheets can improve the formability of tailor-welded sheets and control the flow of weld seam to improve the forming quality.When increasing the interface friction coefficient on the side of tailor-welded sheets with higher strength and decreasing that on the side of tailor-welded sheets with lower strength,the deformation of the tailor-welded sheets are more uniform,the offset of the weld seam is minimal,the limit bulging height is maximal,and the forming quality is optimal.
基金supported by the National Key R&D Program of China(2021YFF1200602)the National Science Fund for Excellent Overseas Scholars(0401260011)+3 种基金the National Defense Science and Technology Innovation Fund of Chinese Academy of Sciences(c02022088)the Tianjin Science and Technology Program(20JCZDJC00810)the National Natural Science Foundation of China(82202798)the Shanghai Sailing Program(22YF1404200).
文摘Brain-computer interfaces(BCIs)represent an emerging technology that facilitates direct communication between the brain and external devices.In recent years,numerous review articles have explored various aspects of BCIs,including their fundamental principles,technical advancements,and applications in specific domains.However,these reviews often focus on signal processing,hardware development,or limited applications such as motor rehabilitation or communication.This paper aims to offer a comprehensive review of recent electroencephalogram(EEG)-based BCI applications in the medical field across 8 critical areas,encompassing rehabilitation,daily communication,epilepsy,cerebral resuscitation,sleep,neurodegenerative diseases,anesthesiology,and emotion recognition.Moreover,the current challenges and future trends of BCIs were also discussed,including personal privacy and ethical concerns,network security vulnerabilities,safety issues,and biocompatibility.
基金National Natural Science Foundation of China(32201491)Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University,Arar,KSA for funding this research work through the project number“NBU-FPEJ-2024-1101-02”.
文摘Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.
基金financially supported by the National Key R&D Program of China(No.2022YFE0121300)the National Natural Science Foundation of China(No.52374376)the Introduction Plan for High-end Foreign Experts(No.G2023105001L)。
文摘As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.
基金Major Scientific and Technological Project of Gansu(22ZD6GA008)Excellent Doctorate Project of Gansu(23JRRA806)National Natural Science Foundation of China(52175325,51961024,52071170)。
文摘The microstructure,micro-hardness,and tensile properties of interface between hot isostatic pressing densified low alloy steel and Inconel 690 cladding were investigated during the aging process at 600℃.The results show that the interface region can be divided into four zones from base metal to deposited metal:carbon-depleted zone(CDZ),partial melting zone(PMZ),planar growth zone(PGZ),and brownish feature zone(BFZ).Dimensions of these zones do not significantly change during aging.However,type I carbides noticeably increase in size in the PMZ,and precipitates clearly occur in the PGZ.The main reason for their growth and occurrence is continuous carbon migration.The highest micro-hardness appears in the PGZ and BFZ regions,which is related to carbon accumulation and precipitates in these regions.Tensile failure occurs on the base metal side due to the high strength mismatch between these two materials.The CDZ,composed of only ferrite,has lower strength and fractures at the boundary between CDZ and base metal.The ultimate tensile strength decreases by only 50 MPa after aging for 1500 h,and the interface region maintains high strength without significant deformation.
