Corn starch gelatinized by sodium hydroxide was grafted with acrylonitrile(AN)in presence of photoinitiators,benzophenone(BP)or/and benzoin ethyl ether(BE),under UVlight.A composite initiation system containing BP and...Corn starch gelatinized by sodium hydroxide was grafted with acrylonitrile(AN)in presence of photoinitiators,benzophenone(BP)or/and benzoin ethyl ether(BE),under UVlight.A composite initiation system containing BP and BE was proposed to overcome the homopolymerization.By designing the time schedule of addition of both the components,results showed BP and BE form an efficacious composite initiation system,which can not only initiate the graft copolymerization with percent synthetic polymer(%addon)of 32%,but also avoid homopolymerization in the process of grafting with graft efficiency(E%)as high as 92%.展开更多
This review summarizes our achievements in designing new initiation systems for atom transfer radical polymerization (ATRP). First-order kinetics and extension experiments revealed the living nature of these reactions...This review summarizes our achievements in designing new initiation systems for atom transfer radical polymerization (ATRP). First-order kinetics and extension experiments revealed the living nature of these reactions. Tailor- made vinyl polymers with functional end groups were characterized by 1H-NMR and UV-vis spectroscopic analyses. Replacing traditional radical initiators AIBN and BPO, carbon-carbon bond compounds, 1,1,2,2-tetraphenyl-1,2-ethanediol, diethyl 2,3-dicyano-2,3-diphenylsuccinate and diethyl 2,3-dicyano-2,3-di(p-tolyl)succinate, were utilized in reverse ATRP to produce the initiating radical. Sulfur-sulfur bond iniferter, tetraethylthiuram disulfide (TD), in conjunction with CuBr/bpy or NiCl2/PPh3 complex could control the styrene polymerization via redox reaction. Pseudo-halogen transfer reaction was demonstrated to maintain the dormant-active species equilibrium in normal and reverse ATRP with Cu(S2CNEt2), Cu(S2CNEt2)Cl and Fe(S2CNEt2)3 as catalysts. The organic halide initiator and reduced transition metal compound that started the living polymerization were produced in situ from the components of TD/FeCl3/PPh3, TD/CuBr2/bpy and Fe(S2CNEt2)3/FeCl3/PPh3 systems. Accurate control of UV irradiation time favored the radical generation process in photo ATRP with the 2,2-dimethoxy-2-phenylacetophenone/Fe(S2CNEt2)3 initiation system.展开更多
The redox initiation system for polyacrylate sodium of high molecular mass was designed and its effect with varying component dosage on the degree of polymerization was investigated. The results show that the proper t...The redox initiation system for polyacrylate sodium of high molecular mass was designed and its effect with varying component dosage on the degree of polymerization was investigated. The results show that the proper type and amount of inorganic salt, as well as amine initiator, are conductive to the increase of degree of polymerization. The fine ingredient of the initiation system is as follows:the dosages of amine, persulphate and inorganic salt are 0.75%, 0.10% and 1.00% by mass based on acryl acid respectively, the molar ratio of sulphite to the persulphate is 1:1. Under such conditions the degree of polyacrylate can reach 7.43×107 with a acceptable polymerization time for industrial production.展开更多
Using high-resolution observations,mesoscale simulations,and idealized experiments,this study investigates the mechanisms governing an episode of orographic convection initiation(CI)during the North China Heavy Rainfa...Using high-resolution observations,mesoscale simulations,and idealized experiments,this study investigates the mechanisms governing an episode of orographic convection initiation(CI)during the North China Heavy Rainfall Experiment.On 4 August 2024,repeated CI occurred over the eastern slopes of the Taihang Mountains in the late afternoon,subsequently enhancing an upstream downhill convective storm.Wind profiler radar data and dense automatic weather stations reveal that CI was supported by strengthening southeasterly upslope winds.These winds primarily resulted from the migration of the mountain-plain solenoid and the mountainward-propagating outflow from a convective cold pool over the plain,with sensitivity experiments showing the latter contributed roughly 22%of the wind strength.The upslope flows gradually transported unstable air from the plain to the slope,fostering CI.Mesoscale simulations further highlight the key role of orographic waves near the mountain ridge,which generated strong downslope winds.The near-surface convergence between downslope and upslope flows,combined with wave-induced divergence aloft,produced deep ascent over the slope.Removing mountain ridges weakened wave strength and reduced downslope wind speeds by~8 m s^(-1).Without orographic heating in the idealized simulation(i.e.,no mountain-plain solenoid),only strong wave descent occurred below 2??km,inhibiting CI.These findings underscore the critical interplay among plain convection,orographic waves,and the mountain-plain solenoid,offering new insight into the processes controlling orographic CI in North China.展开更多
The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechani...The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.展开更多
The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated....The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.展开更多
Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dime...Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dimensional freezing tests is designed using the particle image velocimetry(PIV)method to monitor the frost heave and ice lens formation.The results show that the conventional parameters,such as displacement and velocity,cannot be used to track the ice lens formation,while the strain can be employed to detect the ice lens formation and investigate the freezing change patterns.This study proposes strain as a new criterion for assessing ice lens initiation,applicable across various soil types and freezing conditions(constant freezing and ramped freezing).The strain change in the region where the ice lens forms is the largest during the freezing process.Additionally,strain curves at the top of the soil samples can reveal different freezing patterns and distinguish the first and second frost heave stages.This newly developed technology enables continuous,non-destructive monitoring of ice lens initiation across diverse conditions and soil types,enhancing data visualization and three-dimensional modeling of freezing parameters while improving traditional methods by directly measuring velocity and strain in frost heave investigations.The study is expected to enhance the research of ice lens criterion and provide a new perspective for monitoring the freezing process.展开更多
On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of glob...On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of global governance system to build and how to reform and improve global governance.The GGI is committed to sovereign equality,the international rule of law,multilateralism,the people-centered approach,and real results,offering China's wisdom and solutions for building a more just and equitable global governance system.On the journey ahead,China will hold high the banner of a community with a shared future for humanity and advance the GGI through multiple measures,effectively strengthening and improving global governance.展开更多
Eukaryotic initiation factor 5A2(eIF5A2),as one of the two isoforms in the family,is reported to be a novel oncogenic protein that is involved in multiple aspects of many types of human cancer.Overexpression or gene a...Eukaryotic initiation factor 5A2(eIF5A2),as one of the two isoforms in the family,is reported to be a novel oncogenic protein that is involved in multiple aspects of many types of human cancer.Overexpression or gene amplification of EIF5A2 has been demonstrated in many cancers.Accumulated evidence shows that eIF5A2 initiates tumor formation,enhances cancer cell growth,increases cancer cell metastasis,and promotes treatment resistance through multiple means,including inducing epithelial–mesenchymal transition,cytoskeletal rearrangement,angiogenesis,and metabolic reprogramming.Expression of eIF5A2 in cancer correlates with poor survival,advanced disease stage,as well as metastasis,suggesting that eIF5A2 function is crucial for tumor development and maintenance but not for normal tissue homeostasis.All these studies suggest that eIF5A2 is a useful biomarker in the prediction of cancer prognosis and serves as an anticancer molecular target.This review focuses on the expression,subcellular localization,post-translational modifications,and regulatory networks of eIF5A2,as well as its biochemical functions and evolving clinical applications in cancer,especially in human digestive system neoplasms.展开更多
It is found that acetoacetanilide possesses very high promoting reactivity towards ceric ion in initiating polymerization of vinyl monomer. The kinetics of acrylamide polymerization and the activation energies were st...It is found that acetoacetanilide possesses very high promoting reactivity towards ceric ion in initiating polymerization of vinyl monomer. The kinetics of acrylamide polymerization and the activation energies were studied. The initiation mechanism of ceric/acetoacetanilide is proposed on the basis of experimental results of FT-IR and ESR.展开更多
In order to improve the power of initiating explosive warheads, besides exploring new type of high explosive, multipoint initiation technology becomes the research focus. With research on electronic safety and arming ...In order to improve the power of initiating explosive warheads, besides exploring new type of high explosive, multipoint initiation technology becomes the research focus. With research on electronic safety and arming devices （ESADs）, pulse power devices and slapper detonators, a hardware control circuit was designed for multipoint initiation control system based on complex programmable logic device （ CPLD ）. In addition, a real-time monitoring interface based on virtual instru- ments technology was designed by the prevailing software of Laboratory Virtual Instrument Engineer- ing Workbench （LabVIEW）. It provides users a real-time status of the hardware circuit system. Mo- reover, a series of experiments were done on the software and hardware platform. The results show that the signals transmission, collection, analysis and display can be realized reliably through a serial port line. It is verified that using a serial bus controller for multiple initiators is reasonable. Successful design of the platform will play an important foundation for the theory and engineering of the fu- ture weapon system. Surely, it will become one of the development directions for intelligent initia- tion system.展开更多
Single-component epoxy cement system is an interesting material used in construction engineering, and it is different from traditional two-component epoxy-cement system. We studied the interaction mechanism of single-...Single-component epoxy cement system is an interesting material used in construction engineering, and it is different from traditional two-component epoxy-cement system. We studied the interaction mechanism of single-component epoxy-cement system only in the range of macro mechanical performances, and used the cement and single-component epoxy directly to investigate the interaction between the both. Solidstate 13 C NMR, FT-IR, Raman spectroscopy and XRD were employed to trace the change of the system. Results showed that the epoxide rings in cementitious environment had been opened by cement ingredients. It was true that single-component epoxy could be used as reactive additive in cementitious system.展开更多
Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fa...Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.展开更多
Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can...Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can respond immediately to the threat.Therefore,when an animal detects a threat through its visual system,it must quickly direct its gaze and attention toward the source of danger,assess the threat level,and take appropriate action.展开更多
Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of ...Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of the Meso-Tethys Shiquanhe-Jiali ophiolite sub-belt(SJO sub-belt)within BangongNujiang Suture Zone(BNSZ),central xizang,are disputed for the complex rock composition and ages.In this paper,we present geochronology,geochemistry and field observations on the Shiquanhe ophiolite,providing a representative ophiolite example in the western end of SJO.Based on investigation of the petrogenesis and tectonic setting of different rock types,combined with the U-Pb dating,we propose a twostage subduction model for explaining the tectonic evolution of SJO as well as the wither away of a backarc basin.Geochemical and geochronological data indicate that the ca.183 Ma LAN(north of Lameila)gabbros formed in the forearc setting and represent the early-stage subduction of the Bangong MesoTethys.This subduction induced the back-arc spreading recorded in the ca.170 Ma gabbros and lower pillow basalts of PL-SDN(Pagelizanong-Shiquanhe Dam Nan)ophiolitic fragments in the Shiquanhe ophiolite.The basaltic lavas overlying the lower basalts,represented by the ca.168–164 Ma diabasic and boninite dikes have forearc characteristics,and they represent the back-arc basin subduction initiation at a late stage.This work thus recovered the multiple tectonic evolution of SJO sub-belt and emphasise the importance of the back-arc basin subduction in the evolution of ancient oceans.展开更多
0 INTRODUCTION Initial subduction involves the complex process of oceanic lithosphere first inserting beneath oceanic or continental lithosphere(Chen et al.,2024;Yang et al.,2022;Stern and Gerya,2018).The modern Izu-B...0 INTRODUCTION Initial subduction involves the complex process of oceanic lithosphere first inserting beneath oceanic or continental lithosphere(Chen et al.,2024;Yang et al.,2022;Stern and Gerya,2018).The modern Izu-Bonin-Mariana(IBM)initial subduction system suggests that identifying the earliest ophiolites,arc igneous and metamorphic complexes(e.g.,blueschist,eclogites)can reconstruct ancient initial subduction systems(Yao et al.,2021;Ishizuka et al.,2011).However,knowledge of ancient subduction initiation is often limited due to poor exposures of rocks formed during the earliest stages of subduction(Chen et al.,2024;Cawood et al.,2009).展开更多
In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated i...In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.展开更多
In this work,the effect of high angle grain boundaries(HAGBs),including prior austenite grain boundaries(PAGB),packet grain boundaries(PGB)and block grain boundaries(BGB),on the priority of pitting and microcrack init...In this work,the effect of high angle grain boundaries(HAGBs),including prior austenite grain boundaries(PAGB),packet grain boundaries(PGB)and block grain boundaries(BGB),on the priority of pitting and microcrack initiation for 10Cr13Co13Mo5Ni3W1VE ultra-high strength stainless steel(UHSS)has been clarified.PAGB had the highest carbide distribution coefficient and was the main location where pitting preferentially initiated for the UHSS in 3.5 wt.%NaCl solution without strain.It was shown that nanocarbides were the key factor of pitting initiation for the UHSS without strain.However,BGB was the key factor of pitting/microcrack initiation for the UHSS with strain,which was attributed to the high-density dislocations accumulated at BGB and then enhanced the local electrochemical activity of the UHSS surface.The change of the key factor for the pitting initiation in the UHSS was the result of the synergy between strain and corrosion environment.This study provides guidance for designing advanced UHSS with high service stability and safety.展开更多
Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic a...Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic and whole-rock geochemical data,we report the first discovery of a latest Cambrian–Early Ordovician forearc-arc rock sequence in the Eastern Alps.This sequence includes granitic gneisses,amphibolites,and amphibole plagiogneisses from the ophiolitic Speik Complex and Gleinalpe Complex.These rocks exhibit geochemical affinities with typical oceanic plagiogranites,forearc basalts(FABs),and island arc basalts,respectively.The latest Cambrian plagiogranitic protoliths(491±2 Ma)are shearing-type plagiogranites that were formed in the tectonic setting of forearc spreading.The latest Cambrian FABs(496–489 Ma)have similar geochemical compositions and positiveεHf(t)values(+2.5 to+14.9)to the depleted mid-ocean ridge basalts.However,they show depletion in high field strength elements(HFSEs;e.g.,Nb,Ta,and Zr)and have relatively low Ti/V ratios.These features suggest that they were derived from a depleted mantle source modified by subducting slab-released components in a forearc environment.The Early Ordovician basaltic protoliths(476–472 Ma)of amphibole plagiogneisses show enrichment in large ion lithophile elements and depletion in HFSEs(e.g.Nb,Ta,Zr,and Hf),implying a mature island arc environment.These metaigneous rocks,along with the coeval boninite-like high-Mg amphibolites near the study area,form a typical rock sequence resembling that of the Izu–Bonin–Mariana(IBM)arc system.The Speik and Gleinalpe complexes document a complete magmatic evolution from subduction initiation to mature arc development within the West Proto-Tethys Ocean.Integrating our new data with published work,we reconstruct the late Ediacaran–early Paleozoic tectonic evolution of the northern Gondwana.During the late Ediacaran–early Cambrian,the rollback of the West Proto-Tethys oceanic plate triggered the separation of the Wechsel-Silvretta-Gleinalpe continental arc from the northern Gondwana.This process led to the formation of the Speik back-arc oceanic basin,a southwestern branch of the West Proto-Tethys Ocean.In the latest Cambrian–Early Ordovician,subduction initiation occurred in the Speik Ocean,which subsequently developed into an intra-oceanic arc system.During the Early Devonian,the Speik Ocean closed and the Wechsel-Silvretta-Gleinalpe continental arc reattached to the Gondwana,as evidenced by the metamorphic event at ca.400 Ma.展开更多
The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China S...The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China Sea opened,a continental margin likely existed,meaning that Luzon was directly adjacent to the continental margin rather than the oceanic basin.This would make subduction initiation more challenging.Here,we propose a new model suggesting that during the formation of the South China Sea,extensive mafic magmatic underplating occurred along its continental margin.The high-density magmatic additions may have increased the overall density of the continental margin,potentially exceeding that of Luzon,thereby enabling subduction to proceed.展开更多
文摘Corn starch gelatinized by sodium hydroxide was grafted with acrylonitrile(AN)in presence of photoinitiators,benzophenone(BP)or/and benzoin ethyl ether(BE),under UVlight.A composite initiation system containing BP and BE was proposed to overcome the homopolymerization.By designing the time schedule of addition of both the components,results showed BP and BE form an efficacious composite initiation system,which can not only initiate the graft copolymerization with percent synthetic polymer(%addon)of 32%,but also avoid homopolymerization in the process of grafting with graft efficiency(E%)as high as 92%.
文摘This review summarizes our achievements in designing new initiation systems for atom transfer radical polymerization (ATRP). First-order kinetics and extension experiments revealed the living nature of these reactions. Tailor- made vinyl polymers with functional end groups were characterized by 1H-NMR and UV-vis spectroscopic analyses. Replacing traditional radical initiators AIBN and BPO, carbon-carbon bond compounds, 1,1,2,2-tetraphenyl-1,2-ethanediol, diethyl 2,3-dicyano-2,3-diphenylsuccinate and diethyl 2,3-dicyano-2,3-di(p-tolyl)succinate, were utilized in reverse ATRP to produce the initiating radical. Sulfur-sulfur bond iniferter, tetraethylthiuram disulfide (TD), in conjunction with CuBr/bpy or NiCl2/PPh3 complex could control the styrene polymerization via redox reaction. Pseudo-halogen transfer reaction was demonstrated to maintain the dormant-active species equilibrium in normal and reverse ATRP with Cu(S2CNEt2), Cu(S2CNEt2)Cl and Fe(S2CNEt2)3 as catalysts. The organic halide initiator and reduced transition metal compound that started the living polymerization were produced in situ from the components of TD/FeCl3/PPh3, TD/CuBr2/bpy and Fe(S2CNEt2)3/FeCl3/PPh3 systems. Accurate control of UV irradiation time favored the radical generation process in photo ATRP with the 2,2-dimethoxy-2-phenylacetophenone/Fe(S2CNEt2)3 initiation system.
基金Project(G199906490 2) supported by the National Key Fundamental Research and Development Program of China
文摘The redox initiation system for polyacrylate sodium of high molecular mass was designed and its effect with varying component dosage on the degree of polymerization was investigated. The results show that the proper type and amount of inorganic salt, as well as amine initiator, are conductive to the increase of degree of polymerization. The fine ingredient of the initiation system is as follows:the dosages of amine, persulphate and inorganic salt are 0.75%, 0.10% and 1.00% by mass based on acryl acid respectively, the molar ratio of sulphite to the persulphate is 1:1. Under such conditions the degree of polyacrylate can reach 7.43×107 with a acceptable polymerization time for industrial production.
基金supported by the National Key Research and Development Program of China(Grant No.2024YFC3013003)the National Natural Science Foundation of China(Grant Nos.424B2033 and 42475002)+3 种基金projects supported by the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(Grant Nos.SML2024SP035,SML2024SP012,311024001)the Guangdong Project of Basic and Applied Basic Research(Grant Nos.2024A1515510005 and2025A1515011974)the Key Innovation Team of the China Meteorological Administration(Grant No.CMA2023ZD08)the State Key Laboratory of Severe Weather Meteorological Science and Technology(Grant No.2025QZA10)。
文摘Using high-resolution observations,mesoscale simulations,and idealized experiments,this study investigates the mechanisms governing an episode of orographic convection initiation(CI)during the North China Heavy Rainfall Experiment.On 4 August 2024,repeated CI occurred over the eastern slopes of the Taihang Mountains in the late afternoon,subsequently enhancing an upstream downhill convective storm.Wind profiler radar data and dense automatic weather stations reveal that CI was supported by strengthening southeasterly upslope winds.These winds primarily resulted from the migration of the mountain-plain solenoid and the mountainward-propagating outflow from a convective cold pool over the plain,with sensitivity experiments showing the latter contributed roughly 22%of the wind strength.The upslope flows gradually transported unstable air from the plain to the slope,fostering CI.Mesoscale simulations further highlight the key role of orographic waves near the mountain ridge,which generated strong downslope winds.The near-surface convergence between downslope and upslope flows,combined with wave-induced divergence aloft,produced deep ascent over the slope.Removing mountain ridges weakened wave strength and reduced downslope wind speeds by~8 m s^(-1).Without orographic heating in the idealized simulation(i.e.,no mountain-plain solenoid),only strong wave descent occurred below 2??km,inhibiting CI.These findings underscore the critical interplay among plain convection,orographic waves,and the mountain-plain solenoid,offering new insight into the processes controlling orographic CI in North China.
基金financially supported by the National Nature Science Foundation of China(Nos.52379110 and 42207222)the Key Technologies for Accurate Diagnosis and Intelligent Prevention and Control of Slope Hazards in Open Pit Mines,181 Major R&D projects of Metallurgical Corporation of China Ltd。
文摘The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.
基金supported by the National Natural Science Foundation of China(No.52090041).
文摘The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.
基金supported by the National Natural Science Foundation of China(Grant No.52178376)National Key R&D Program of China(Grant No.2022YFB2603301)Science and Technology Research and Development Program of China Railway Group Limited(Grant No.2022-ZD-13).
文摘Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dimensional freezing tests is designed using the particle image velocimetry(PIV)method to monitor the frost heave and ice lens formation.The results show that the conventional parameters,such as displacement and velocity,cannot be used to track the ice lens formation,while the strain can be employed to detect the ice lens formation and investigate the freezing change patterns.This study proposes strain as a new criterion for assessing ice lens initiation,applicable across various soil types and freezing conditions(constant freezing and ramped freezing).The strain change in the region where the ice lens forms is the largest during the freezing process.Additionally,strain curves at the top of the soil samples can reveal different freezing patterns and distinguish the first and second frost heave stages.This newly developed technology enables continuous,non-destructive monitoring of ice lens initiation across diverse conditions and soil types,enhancing data visualization and three-dimensional modeling of freezing parameters while improving traditional methods by directly measuring velocity and strain in frost heave investigations.The study is expected to enhance the research of ice lens criterion and provide a new perspective for monitoring the freezing process.
文摘On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of global governance system to build and how to reform and improve global governance.The GGI is committed to sovereign equality,the international rule of law,multilateralism,the people-centered approach,and real results,offering China's wisdom and solutions for building a more just and equitable global governance system.On the journey ahead,China will hold high the banner of a community with a shared future for humanity and advance the GGI through multiple measures,effectively strengthening and improving global governance.
基金Supported by Natural Science Foundation of Hubei Province,No.2016CFB596Wuhan City Medical Research Project,Nos.WX15B14and WX17Q39Hubei Province Scientific Research Project,No.WJ2015MB137
文摘Eukaryotic initiation factor 5A2(eIF5A2),as one of the two isoforms in the family,is reported to be a novel oncogenic protein that is involved in multiple aspects of many types of human cancer.Overexpression or gene amplification of EIF5A2 has been demonstrated in many cancers.Accumulated evidence shows that eIF5A2 initiates tumor formation,enhances cancer cell growth,increases cancer cell metastasis,and promotes treatment resistance through multiple means,including inducing epithelial–mesenchymal transition,cytoskeletal rearrangement,angiogenesis,and metabolic reprogramming.Expression of eIF5A2 in cancer correlates with poor survival,advanced disease stage,as well as metastasis,suggesting that eIF5A2 function is crucial for tumor development and maintenance but not for normal tissue homeostasis.All these studies suggest that eIF5A2 is a useful biomarker in the prediction of cancer prognosis and serves as an anticancer molecular target.This review focuses on the expression,subcellular localization,post-translational modifications,and regulatory networks of eIF5A2,as well as its biochemical functions and evolving clinical applications in cancer,especially in human digestive system neoplasms.
文摘It is found that acetoacetanilide possesses very high promoting reactivity towards ceric ion in initiating polymerization of vinyl monomer. The kinetics of acrylamide polymerization and the activation energies were studied. The initiation mechanism of ceric/acetoacetanilide is proposed on the basis of experimental results of FT-IR and ESR.
文摘In order to improve the power of initiating explosive warheads, besides exploring new type of high explosive, multipoint initiation technology becomes the research focus. With research on electronic safety and arming devices （ESADs）, pulse power devices and slapper detonators, a hardware control circuit was designed for multipoint initiation control system based on complex programmable logic device （ CPLD ）. In addition, a real-time monitoring interface based on virtual instru- ments technology was designed by the prevailing software of Laboratory Virtual Instrument Engineer- ing Workbench （LabVIEW）. It provides users a real-time status of the hardware circuit system. Mo- reover, a series of experiments were done on the software and hardware platform. The results show that the signals transmission, collection, analysis and display can be realized reliably through a serial port line. It is verified that using a serial bus controller for multiple initiators is reasonable. Successful design of the platform will play an important foundation for the theory and engineering of the fu- ture weapon system. Surely, it will become one of the development directions for intelligent initia- tion system.
基金Funded by the National Natural Science Foundation of China(No.51578290)
文摘Single-component epoxy cement system is an interesting material used in construction engineering, and it is different from traditional two-component epoxy-cement system. We studied the interaction mechanism of single-component epoxy-cement system only in the range of macro mechanical performances, and used the cement and single-component epoxy directly to investigate the interaction between the both. Solidstate 13 C NMR, FT-IR, Raman spectroscopy and XRD were employed to trace the change of the system. Results showed that the epoxide rings in cementitious environment had been opened by cement ingredients. It was true that single-component epoxy could be used as reactive additive in cementitious system.
基金supported by the National Natural Science Foundation of China(Nos.52074231,52274396 and 52001258)the Chongqing Natural Science Foundation(No.cstc2020jcyj-msxmX1056).
文摘Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.
基金supported by the National Natural Science Foundation of China(32471055 and 82171090)Shanghai Municipal Science and Technology Major Project(2018SHZDZX01)ZJLab,Shanghai Center for Brain Science and Brain-Inspired Technology,the Lingang Laboratory(LG-QS-202203-12).
文摘Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can respond immediately to the threat.Therefore,when an animal detects a threat through its visual system,it must quickly direct its gaze and attention toward the source of danger,assess the threat level,and take appropriate action.
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(Grant Nos.2024A1515010439,2025A1515010724)National Nature Science Foundation of China(Grant Nos.41972049,41472054,42072229,41977231)+4 种基金Young Innovative Talent Project of Department of Education of Guangdong Province(Natural ScienceGrant No.2022KQNCX184)Natural Research Project of Guangdong Polytechnic of Industry&Commerce(Grant No.2022-ZKT-01)China State Scholarship Fund of visiting scholar(Grant No.20170638507)High-level Talent Special Support Program of Guangdong Polytechnic of Industry&Commerce(Grant No.2023-gc-03).
文摘Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of the Meso-Tethys Shiquanhe-Jiali ophiolite sub-belt(SJO sub-belt)within BangongNujiang Suture Zone(BNSZ),central xizang,are disputed for the complex rock composition and ages.In this paper,we present geochronology,geochemistry and field observations on the Shiquanhe ophiolite,providing a representative ophiolite example in the western end of SJO.Based on investigation of the petrogenesis and tectonic setting of different rock types,combined with the U-Pb dating,we propose a twostage subduction model for explaining the tectonic evolution of SJO as well as the wither away of a backarc basin.Geochemical and geochronological data indicate that the ca.183 Ma LAN(north of Lameila)gabbros formed in the forearc setting and represent the early-stage subduction of the Bangong MesoTethys.This subduction induced the back-arc spreading recorded in the ca.170 Ma gabbros and lower pillow basalts of PL-SDN(Pagelizanong-Shiquanhe Dam Nan)ophiolitic fragments in the Shiquanhe ophiolite.The basaltic lavas overlying the lower basalts,represented by the ca.168–164 Ma diabasic and boninite dikes have forearc characteristics,and they represent the back-arc basin subduction initiation at a late stage.This work thus recovered the multiple tectonic evolution of SJO sub-belt and emphasise the importance of the back-arc basin subduction in the evolution of ancient oceans.
基金supported by the special fund of the State Key Laboratory of Deep Earth and Mineral Exploration(No.KFDM2025203)the Natural Science Foundation of Liaoning Province(No.2025-MS-037)+2 种基金the National Natural Science Foundation of China(No.41972234)support provided by the China Scholarship Council(No.202306080045)the Geological Society Research Grants-Mike Coward Fund.
文摘0 INTRODUCTION Initial subduction involves the complex process of oceanic lithosphere first inserting beneath oceanic or continental lithosphere(Chen et al.,2024;Yang et al.,2022;Stern and Gerya,2018).The modern Izu-Bonin-Mariana(IBM)initial subduction system suggests that identifying the earliest ophiolites,arc igneous and metamorphic complexes(e.g.,blueschist,eclogites)can reconstruct ancient initial subduction systems(Yao et al.,2021;Ishizuka et al.,2011).However,knowledge of ancient subduction initiation is often limited due to poor exposures of rocks formed during the earliest stages of subduction(Chen et al.,2024;Cawood et al.,2009).
基金financially supported by the National Natural Science Foundation of China(No.U21A2050)support of the Chinese Scholarship Council(No.202006290165).
文摘In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.
文摘In this work,the effect of high angle grain boundaries(HAGBs),including prior austenite grain boundaries(PAGB),packet grain boundaries(PGB)and block grain boundaries(BGB),on the priority of pitting and microcrack initiation for 10Cr13Co13Mo5Ni3W1VE ultra-high strength stainless steel(UHSS)has been clarified.PAGB had the highest carbide distribution coefficient and was the main location where pitting preferentially initiated for the UHSS in 3.5 wt.%NaCl solution without strain.It was shown that nanocarbides were the key factor of pitting initiation for the UHSS without strain.However,BGB was the key factor of pitting/microcrack initiation for the UHSS with strain,which was attributed to the high-density dislocations accumulated at BGB and then enhanced the local electrochemical activity of the UHSS surface.The change of the key factor for the pitting initiation in the UHSS was the result of the synergy between strain and corrosion environment.This study provides guidance for designing advanced UHSS with high service stability and safety.
基金supported by the National Natural Science Foundation of China(Grant Nos.42272244 and 91755212)Taishan Scholars(Grant No.ts20190918).
文摘Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic and whole-rock geochemical data,we report the first discovery of a latest Cambrian–Early Ordovician forearc-arc rock sequence in the Eastern Alps.This sequence includes granitic gneisses,amphibolites,and amphibole plagiogneisses from the ophiolitic Speik Complex and Gleinalpe Complex.These rocks exhibit geochemical affinities with typical oceanic plagiogranites,forearc basalts(FABs),and island arc basalts,respectively.The latest Cambrian plagiogranitic protoliths(491±2 Ma)are shearing-type plagiogranites that were formed in the tectonic setting of forearc spreading.The latest Cambrian FABs(496–489 Ma)have similar geochemical compositions and positiveεHf(t)values(+2.5 to+14.9)to the depleted mid-ocean ridge basalts.However,they show depletion in high field strength elements(HFSEs;e.g.,Nb,Ta,and Zr)and have relatively low Ti/V ratios.These features suggest that they were derived from a depleted mantle source modified by subducting slab-released components in a forearc environment.The Early Ordovician basaltic protoliths(476–472 Ma)of amphibole plagiogneisses show enrichment in large ion lithophile elements and depletion in HFSEs(e.g.Nb,Ta,Zr,and Hf),implying a mature island arc environment.These metaigneous rocks,along with the coeval boninite-like high-Mg amphibolites near the study area,form a typical rock sequence resembling that of the Izu–Bonin–Mariana(IBM)arc system.The Speik and Gleinalpe complexes document a complete magmatic evolution from subduction initiation to mature arc development within the West Proto-Tethys Ocean.Integrating our new data with published work,we reconstruct the late Ediacaran–early Paleozoic tectonic evolution of the northern Gondwana.During the late Ediacaran–early Cambrian,the rollback of the West Proto-Tethys oceanic plate triggered the separation of the Wechsel-Silvretta-Gleinalpe continental arc from the northern Gondwana.This process led to the formation of the Speik back-arc oceanic basin,a southwestern branch of the West Proto-Tethys Ocean.In the latest Cambrian–Early Ordovician,subduction initiation occurred in the Speik Ocean,which subsequently developed into an intra-oceanic arc system.During the Early Devonian,the Speik Ocean closed and the Wechsel-Silvretta-Gleinalpe continental arc reattached to the Gondwana,as evidenced by the metamorphic event at ca.400 Ma.
基金support from the National Natural Science Foundation of China (Grant No. 42276049)。
文摘The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China Sea opened,a continental margin likely existed,meaning that Luzon was directly adjacent to the continental margin rather than the oceanic basin.This would make subduction initiation more challenging.Here,we propose a new model suggesting that during the formation of the South China Sea,extensive mafic magmatic underplating occurred along its continental margin.The high-density magmatic additions may have increased the overall density of the continental margin,potentially exceeding that of Luzon,thereby enabling subduction to proceed.
