Nanoscale powder of SiO2/Al2O3/TiO2 composite was prepared by sol-gel method. Microstructure and morphology of the obtained samples were characterized by infrared （IR）, X-ray diffraction （XRD） analysis and transmi...Nanoscale powder of SiO2/Al2O3/TiO2 composite was prepared by sol-gel method. Microstructure and morphology of the obtained samples were characterized by infrared （IR）, X-ray diffraction （XRD） analysis and transmission electron microscopy （TEM）. It is proved that infrared absorbing peaks of the samples are in waveband range of 1300-400 cm^-1, and the peak shape changes with their component. Mechanism of the infrared peak＇s positions and shapes which changes with the size and morphology of the prepared nano-particles has been tentatively discussed.展开更多
In the practical application,a wide-angle absorption with simple structure is still crucial property of metamaterial absorbers(MAs).A single-band infrared MA is introduced to analyze the angle insensitive mechanism.Nu...In the practical application,a wide-angle absorption with simple structure is still crucial property of metamaterial absorbers(MAs).A single-band infrared MA is introduced to analyze the angle insensitive mechanism.Numerical simulation reveals that a perfect absorption peak with 99.9%(7.55μm)is achieved at normal incidence,as well as the absorptivity is respectively 69.7%(7.46μm)and 93.5%(7.46μm)for transverse electric(TE)and transverse magnetic(TM)modes at 70°incidence.By changing substrate thickness,the absorption ratio at 70°is increased to 91%(7.46μm)for TE mode.Our design can also keep the good absorption stability for the geometric parameters.The E z-field distributions for different incident angles are given to investigate the physical mechanism.The designed MA can realize good wide-angle tolerance.This MA owns great applications,including infrared spectroscopy,solar harvester and plasmonic sensors.展开更多
We fabricate a three-layer metamaterial of metal patterns/dielectric/metal films. The optical properties associated with Fano resonance of the metamaterials are investigated experimentally and theoretically. The resul...We fabricate a three-layer metamaterial of metal patterns/dielectric/metal films. The optical properties associated with Fano resonance of the metamaterials are investigated experimentally and theoretically. The results indicate that the introduction of Fano resonance due to symmetry breaking leads to a much wider absorption range. Furthermore, the amplitude and phase of reflection can be modulated effectively by adjusting various free parameters using the proposed structure.展开更多
With continuous enhancement of gas-turbine inlet temperature and rapid increase of radiant heat transfer,thermal barrier coating(TBC)materials with a combination of low thermal conductivity and good high-temperature t...With continuous enhancement of gas-turbine inlet temperature and rapid increase of radiant heat transfer,thermal barrier coating(TBC)materials with a combination of low thermal conductivity and good high-temperature thermal radiation shielding performance play vital roles in ensuring the durability of metallic blades.However,yttria-stabilized zirconia(YSZ),as the state-of-the-art TBC and current industry standard,is unable to meet such demands since it is almost translucent to high-temperature thermal radiation.Besides,poor corrosion resistance of YSZ to molten calcia-magnesia-alumina-silicates(CMAS)also impedes its application in sand,dust,or volcanic ash laden environments.In order to improve the hightemperature thermal radiation shielding performance and CMAS resistance of YSZ and further reduce its thermal conductivity,two medium-entropy(ME)oxide ceramics,ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),were designed and prepared by pressureless sintering of binary powder compacts in this work.ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)presents cubic structure but a trace amount of secondary phase,while ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)displays a combination of tetragonal phase(81.6 wt.%)and cubic phase(18.4 wt.%).Both ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)possess better high-temperature thermal radiation shielding performance than YSZ.Especially,the high-temperature thermal radiation shielding performance of ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)is superior to that of ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)due to its narrower band gap and correspondingly higher infrared absorbance(above 0.7)at the waveband of 1 to 5μm.The two ME oxides also display significantly lower thermal conductivity than YSZ and close thermal expansion coefficients(TECs)to YSZ and Ni-based superalloys.In addition,the two ME oxides possess excellent CMAS resistance.After attack by molten CMAS at 1250℃for 4 h,merely~2μm thick penetration layer has been formed and the structure below the penetration layer is still intact.These results demonstrate that ME(Me,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)(Me=Y and Ta),especially ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),are promising thermal barrier materials for high-temperature thermal radiation shielding and CMAS blocking.展开更多
Genotoxicity in wastewater and reclaimed water now is gaining increased attention because of genotoxins＇ potential damage to the ecosystem and human health. The effect of ozonation on genotoxicity in reclaimed water ...Genotoxicity in wastewater and reclaimed water now is gaining increased attention because of genotoxins＇ potential damage to the ecosystem and human health. The effect of ozonation on genotoxicity in reclaimed water was investigated. It was found that ozonation decreased the genotoxicy dramatically in three tertiary treatment plants. In the further batch ozonation experiment in laboratory, secondary effluent sample used exhibited the genotoxicity of （41.1 ± 4.1） μg 4NQO/L. Ozonation with a dose of 10 mg O3/L completely removed the genotoxicity in secondary effluent. However, after ozonation, the dissolved organic carbonvalue of the sample didn＇t change much but the specific ultraviolet absorbance （SUVA） value dropped sharply. With the help of Fourier transform infrared spectroscopy, ozonation was found to change chemical aliphatic carbon and C-O of the dissolved arganic matter, which might be the reason of the significant decreases of SUVA and genotoxicity.展开更多
The significance of research of water system is demonstrated by the experiments and statistical data. Some physical and chemical properties of water system affected by various factors in the nature are given. It also ...The significance of research of water system is demonstrated by the experiments and statistical data. Some physical and chemical properties of water system affected by various factors in the nature are given. It also points out that further research of the effect on extremely complicated water system caused by electricity, magnetic field, sound and light now becomes an important research subject.展开更多
We numerically demonstrate a novel ultra-broadband polarization-independent metamaterial perfect absorber in the visible and near-infrared region involving the phase-change material Ge_2Sb_2Te_5(GST).The novel perfect...We numerically demonstrate a novel ultra-broadband polarization-independent metamaterial perfect absorber in the visible and near-infrared region involving the phase-change material Ge_2Sb_2Te_5(GST).The novel perfect absorber scheme consists of an array of high-index strong-absorbance GST square resonators separated from a continuous Au substrate by a low-index lossless dielectric layer(silica)and a high-index GST planar cavity.Three absorption peaks with the maximal absorbance up to 99.94% are achieved,owing to the excitation of plasmon-like dipolar or quadrupole resonances from the high-index GST resonators and cavity resonances generated by the GST planar cavity.The intensities and positions of the absorption peaks show strong dependence on structural parameters.A heat transfer model is used to investigate the temporal variation of temperature within the GST region.The results show that the temperature of amorphous GST can reach up to 433 K of the phase transition temperature from room temperature in just 0.37 ns with a relatively low incident light intensity of 1.11×10~8W∕m^2,due to the enhanced ultra-broadband light absorbance through strong plasmon resonances and cavity resonance in the absorber.The study suggests a feasible means to lower the power requirements for photonic devices based on a thermal phase change via engineering ultra-broadband light absorbers.展开更多
In this work,an optical transparent infrared high absorption metamaterial absorber is proposed based on indium tin oxide(ITO)substrate.Due to the fact that ITO holds high reflectivity property in infrared region while...In this work,an optical transparent infrared high absorption metamaterial absorber is proposed based on indium tin oxide(ITO)substrate.Due to the fact that ITO holds high reflectivity property in infrared region while transparent in optical region,ITO can be used in the application of Surface Plasmon Polaritons.In this design,three kinds of infrared metamaterial absorbers were proposed.All of them can achieve high absorption at 10.6μm while remaining transparent in visible region.LC equivalent circuit model was served as design foundation.The infrared absorption efficiency was numerically calculated and the mechanism analysis is given in the paper.The simulation results show that all three structures can achieve high absorption efficiency at 10.6μm under TE/TM polarization.The absorption remains high when the incident angle is less than 70°.Experimental results exhibit good accordance with simulation.展开更多
Colloidal quantum dot(CQD)shows great potential for application in infrared solar cells due to the simple synthesis techniques,tunable infrared absorption spectrum,and high stability and solution-processability.Thanks...Colloidal quantum dot(CQD)shows great potential for application in infrared solar cells due to the simple synthesis techniques,tunable infrared absorption spectrum,and high stability and solution-processability.Thanks to significant efforts made on the surface chemistry of CQDs,device structure optimization,and device physics of CQD solar cells(CQDSCs),remarkable breakthroughs are achieved to boost the infrared photovoltaic performance and stability of CQDSCs.In particular,the CQDSC with a high power conversion efficiency of~14%and good stability is reported,which is very promising for infrared-absorbing solar cells.In this review,we highlight the unique optoelectronic properties of CQDs for the development of infrared-absorbing solar cells.Meanwhile,the latest advances in finely controlling surface properties of CQDs are comprehensively summarized and discussed.Moreover,the device operation of CQDSCs is discussed in-depth to highlight the impact of the device structure optimization of CQDSCs on their photovoltaic performance,and the emerging novel types of CQDSCs,such as semitransparent,flexible,and lightweight CQDSCs,are also demonstrated.The device stability of CQDSCs is also highlighted from the viewpoint of practical applications.Finally,the conclusions and possible challenges and opportunities are presented to promote the development steps of the CQDSCs with higher infrared photovoltaic performance and robust stability.展开更多
This paper introduces a low-cost infrared absorbing structure for an uncooled infrared detector in a standard 0.5 m CMOS technology and post-CMOS process. The infrared absorbing structure can be created by etching the...This paper introduces a low-cost infrared absorbing structure for an uncooled infrared detector in a standard 0.5 m CMOS technology and post-CMOS process. The infrared absorbing structure can be created by etching the surface sacrificial layer after the CMOS fabrication, without any additional lithography and deposition procedures. An uncooled infrared microbolometer is fabricated with the proposed infrared absorbing structure.The microbolometer has a size of 6565 m2and a fill factor of 37.8%. The thermal conductance of the microbolometer is calculated as 1.3310 5W/K from the measured response to different heating currents. The fabricated microbolometer is irradiated by an infrared laser, which is modulated by a mechanical chopper in a frequency range of 10–800 Hz. Measurements show that the thermal time constant is 0.995 ms and the thermal mass is 1.3210 8J/K. The responsivity of the microbolometer is about 3.03104V/W at 10 Hz and the calculated detectivity is 1.4108cm Hz1=2/W.展开更多
基金the Science Foundation of Yunnan Province under grant No.2001E0003Z.
文摘Nanoscale powder of SiO2/Al2O3/TiO2 composite was prepared by sol-gel method. Microstructure and morphology of the obtained samples were characterized by infrared （IR）, X-ray diffraction （XRD） analysis and transmission electron microscopy （TEM）. It is proved that infrared absorbing peaks of the samples are in waveband range of 1300-400 cm^-1, and the peak shape changes with their component. Mechanism of the infrared peak＇s positions and shapes which changes with the size and morphology of the prepared nano-particles has been tentatively discussed.
文摘In the practical application,a wide-angle absorption with simple structure is still crucial property of metamaterial absorbers(MAs).A single-band infrared MA is introduced to analyze the angle insensitive mechanism.Numerical simulation reveals that a perfect absorption peak with 99.9%(7.55μm)is achieved at normal incidence,as well as the absorptivity is respectively 69.7%(7.46μm)and 93.5%(7.46μm)for transverse electric(TE)and transverse magnetic(TM)modes at 70°incidence.By changing substrate thickness,the absorption ratio at 70°is increased to 91%(7.46μm)for TE mode.Our design can also keep the good absorption stability for the geometric parameters.The E z-field distributions for different incident angles are given to investigate the physical mechanism.The designed MA can realize good wide-angle tolerance.This MA owns great applications,including infrared spectroscopy,solar harvester and plasmonic sensors.
基金Supported by the National Natural Science Foundation of China under Grant No 11304002the Natural Science Foundation of Education Bureau of Anhui Province under Grant No KJ2013A136the Natural Science Foundation of Anhui Province under Grant No 1208085MA07
文摘We fabricate a three-layer metamaterial of metal patterns/dielectric/metal films. The optical properties associated with Fano resonance of the metamaterials are investigated experimentally and theoretically. The results indicate that the introduction of Fano resonance due to symmetry breaking leads to a much wider absorption range. Furthermore, the amplitude and phase of reflection can be modulated effectively by adjusting various free parameters using the proposed structure.
基金financially supported by the National Natural Science Foundation of China(No.51772275 and No.51972089)Distinguished Young Foundation of Henan Province(No.202300410355)。
文摘With continuous enhancement of gas-turbine inlet temperature and rapid increase of radiant heat transfer,thermal barrier coating(TBC)materials with a combination of low thermal conductivity and good high-temperature thermal radiation shielding performance play vital roles in ensuring the durability of metallic blades.However,yttria-stabilized zirconia(YSZ),as the state-of-the-art TBC and current industry standard,is unable to meet such demands since it is almost translucent to high-temperature thermal radiation.Besides,poor corrosion resistance of YSZ to molten calcia-magnesia-alumina-silicates(CMAS)also impedes its application in sand,dust,or volcanic ash laden environments.In order to improve the hightemperature thermal radiation shielding performance and CMAS resistance of YSZ and further reduce its thermal conductivity,two medium-entropy(ME)oxide ceramics,ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),were designed and prepared by pressureless sintering of binary powder compacts in this work.ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)presents cubic structure but a trace amount of secondary phase,while ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)displays a combination of tetragonal phase(81.6 wt.%)and cubic phase(18.4 wt.%).Both ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)possess better high-temperature thermal radiation shielding performance than YSZ.Especially,the high-temperature thermal radiation shielding performance of ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)is superior to that of ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)due to its narrower band gap and correspondingly higher infrared absorbance(above 0.7)at the waveband of 1 to 5μm.The two ME oxides also display significantly lower thermal conductivity than YSZ and close thermal expansion coefficients(TECs)to YSZ and Ni-based superalloys.In addition,the two ME oxides possess excellent CMAS resistance.After attack by molten CMAS at 1250℃for 4 h,merely~2μm thick penetration layer has been formed and the structure below the penetration layer is still intact.These results demonstrate that ME(Me,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)(Me=Y and Ta),especially ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),are promising thermal barrier materials for high-temperature thermal radiation shielding and CMAS blocking.
基金supported by the National Natural Science Foundation of China (No. 51138006)the National HighTech Research and Development Program (863) of China (No. SS2013AA061805)+1 种基金the Ministry of Environmental Protection of China (No. 201109015)the Collaborative Innovation Center for Regional Environmental Quality
文摘Genotoxicity in wastewater and reclaimed water now is gaining increased attention because of genotoxins＇ potential damage to the ecosystem and human health. The effect of ozonation on genotoxicity in reclaimed water was investigated. It was found that ozonation decreased the genotoxicy dramatically in three tertiary treatment plants. In the further batch ozonation experiment in laboratory, secondary effluent sample used exhibited the genotoxicity of （41.1 ± 4.1） μg 4NQO/L. Ozonation with a dose of 10 mg O3/L completely removed the genotoxicity in secondary effluent. However, after ozonation, the dissolved organic carbonvalue of the sample didn＇t change much but the specific ultraviolet absorbance （SUVA） value dropped sharply. With the help of Fourier transform infrared spectroscopy, ozonation was found to change chemical aliphatic carbon and C-O of the dissolved arganic matter, which might be the reason of the significant decreases of SUVA and genotoxicity.
文摘The significance of research of water system is demonstrated by the experiments and statistical data. Some physical and chemical properties of water system affected by various factors in the nature are given. It also points out that further research of the effect on extremely complicated water system caused by electricity, magnetic field, sound and light now becomes an important research subject.
基金973 Program of China(2013CB632704)National Natural Science Foundation of China(NSFC)(11374357,11434017)
文摘We numerically demonstrate a novel ultra-broadband polarization-independent metamaterial perfect absorber in the visible and near-infrared region involving the phase-change material Ge_2Sb_2Te_5(GST).The novel perfect absorber scheme consists of an array of high-index strong-absorbance GST square resonators separated from a continuous Au substrate by a low-index lossless dielectric layer(silica)and a high-index GST planar cavity.Three absorption peaks with the maximal absorbance up to 99.94% are achieved,owing to the excitation of plasmon-like dipolar or quadrupole resonances from the high-index GST resonators and cavity resonances generated by the GST planar cavity.The intensities and positions of the absorption peaks show strong dependence on structural parameters.A heat transfer model is used to investigate the temporal variation of temperature within the GST region.The results show that the temperature of amorphous GST can reach up to 433 K of the phase transition temperature from room temperature in just 0.37 ns with a relatively low incident light intensity of 1.11×10~8W∕m^2,due to the enhanced ultra-broadband light absorbance through strong plasmon resonances and cavity resonance in the absorber.The study suggests a feasible means to lower the power requirements for photonic devices based on a thermal phase change via engineering ultra-broadband light absorbers.
基金the support from National Science Foundation of China under Grant Nos.61501497,61331005 and 61671467the special foundation of New-star Plan of Science and technology,No.2015KJXX-47.
文摘In this work,an optical transparent infrared high absorption metamaterial absorber is proposed based on indium tin oxide(ITO)substrate.Due to the fact that ITO holds high reflectivity property in infrared region while transparent in optical region,ITO can be used in the application of Surface Plasmon Polaritons.In this design,three kinds of infrared metamaterial absorbers were proposed.All of them can achieve high absorption at 10.6μm while remaining transparent in visible region.LC equivalent circuit model was served as design foundation.The infrared absorption efficiency was numerically calculated and the mechanism analysis is given in the paper.The simulation results show that all three structures can achieve high absorption efficiency at 10.6μm under TE/TM polarization.The absorption remains high when the incident angle is less than 70°.Experimental results exhibit good accordance with simulation.
基金the National Key Research and Development Program of China(No.2022YFB3807200)the National Natural Science Foundation of China(Nos.52372169 and 51872014)the Recruitment Program of Global Experts,and the“111”project(No.B17002).
文摘Colloidal quantum dot(CQD)shows great potential for application in infrared solar cells due to the simple synthesis techniques,tunable infrared absorption spectrum,and high stability and solution-processability.Thanks to significant efforts made on the surface chemistry of CQDs,device structure optimization,and device physics of CQD solar cells(CQDSCs),remarkable breakthroughs are achieved to boost the infrared photovoltaic performance and stability of CQDSCs.In particular,the CQDSC with a high power conversion efficiency of~14%and good stability is reported,which is very promising for infrared-absorbing solar cells.In this review,we highlight the unique optoelectronic properties of CQDs for the development of infrared-absorbing solar cells.Meanwhile,the latest advances in finely controlling surface properties of CQDs are comprehensively summarized and discussed.Moreover,the device operation of CQDSCs is discussed in-depth to highlight the impact of the device structure optimization of CQDSCs on their photovoltaic performance,and the emerging novel types of CQDSCs,such as semitransparent,flexible,and lightweight CQDSCs,are also demonstrated.The device stability of CQDSCs is also highlighted from the viewpoint of practical applications.Finally,the conclusions and possible challenges and opportunities are presented to promote the development steps of the CQDSCs with higher infrared photovoltaic performance and robust stability.
基金Project supported by the National Natural Science Foundation of China(Nos.60806038,61131004,61274076)the National HighTechnology Research and Development Program of China(Nos.2006AA040102,2006AA040106)
文摘This paper introduces a low-cost infrared absorbing structure for an uncooled infrared detector in a standard 0.5 m CMOS technology and post-CMOS process. The infrared absorbing structure can be created by etching the surface sacrificial layer after the CMOS fabrication, without any additional lithography and deposition procedures. An uncooled infrared microbolometer is fabricated with the proposed infrared absorbing structure.The microbolometer has a size of 6565 m2and a fill factor of 37.8%. The thermal conductance of the microbolometer is calculated as 1.3310 5W/K from the measured response to different heating currents. The fabricated microbolometer is irradiated by an infrared laser, which is modulated by a mechanical chopper in a frequency range of 10–800 Hz. Measurements show that the thermal time constant is 0.995 ms and the thermal mass is 1.3210 8J/K. The responsivity of the microbolometer is about 3.03104V/W at 10 Hz and the calculated detectivity is 1.4108cm Hz1=2/W.
