Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. ...Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. The maximum external quantum efficiency （EQE） is 685% for the device with 2% ICBA doping ratio, which is much higher than that of OPDs with P3HT：ICBA （1：1） as the active layer. The PM phenomenon is attributed to the hole tunneling injection assisted by trapped electron in ICBA near A1 cathode, which can be demonstrated from the EQE spectra and transient photocurrent curves of OPDs with different ICBA doping ratios.展开更多
基金supported by the National Training Program of Innovation and Entrepreneurship for Undergraduates,Fundamental Research Funds for the Central Universities(Grant No.2014JBZ017)National Natural Science Foundation of China(Grant No.613770029)Beijing Natural Science Foundation(Grant No.2122050)
文摘Here, we report a trap-assisted photomultiplication （PM） phenomenon in solution-processed organic photodetectors （OPDs） using poly（3-hexylthiophene） （P3HT）： indene-C60 bisadduct （ICBA） as the active layer. The maximum external quantum efficiency （EQE） is 685% for the device with 2% ICBA doping ratio, which is much higher than that of OPDs with P3HT：ICBA （1：1） as the active layer. The PM phenomenon is attributed to the hole tunneling injection assisted by trapped electron in ICBA near A1 cathode, which can be demonstrated from the EQE spectra and transient photocurrent curves of OPDs with different ICBA doping ratios.
