To enhance boron doping efficiency and reduce metal impurities in diamonds,selecting an appropriate metal solvent is essential for producing p-type diamonds using the high-pressure high-temperature(HPHT)method.This pa...To enhance boron doping efficiency and reduce metal impurities in diamonds,selecting an appropriate metal solvent is essential for producing p-type diamonds using the high-pressure high-temperature(HPHT)method.This paper presents a detailed study of the properties and characteristics of boron-doped diamond(BDD)single crystals grown using FeNi and FeCo solvents through the HPHT method.The results indicate that,with the same TiB_(2)addition ratio,BDD crystals grown using FeCo solvent have a higher concentration of uncompensated boron ions,resulting in improved boron doping efficiency.Additionally,by growing BDD in the same synthesis environment(FeCo-3 wt%TiB_(2))using(111)and(100)seed crystals as growth surfaces,it was found that the boron content in the crystal grown from the(100)seed crystal was higher than that in the crystal grown from the(111)seed crystal.Additionally,the crystals grown with the FeCo solvent contained fewer metal elements(Fe and Co)compared to those produced with the FeNi solvent(Fe and Ni),which supported the growth of high-quality BDD single crystals.This indicated that the choice of growth planes significantly influences the incorporation of boron in diamonds.Our findings hold significant research value for the development of high-quality p-type diamond semiconductors using the HPHT method.展开更多
With the increasing demand for new technologies in HPHT (high pressure high temperature) wells, more and more attention has been paid to the system of technical qualifications. Most established norms, standards and re...With the increasing demand for new technologies in HPHT (high pressure high temperature) wells, more and more attention has been paid to the system of technical qualifications. Most established norms, standards and recommended practices are written in prescribed formats, setting out methods, procedures and acceptance criteria for product design, manufacture and testing. However, established norms, standards or recommended practices may not adequately cover new technologies or applications. The technical qualification system is established in this paper, which can identify the potential failure modes and some activities in order to control the uncertainties and increase confidence of using new technology. A risk-based technical qualification system is used to assess non-traditional operations. It includes following seven main steps: system breakdown, technology assessment and classification, technical novelty, failure model and risk analysis, risk-based qualification planning and participation level development. The core of technical qualification system is to understand the ways and causes of system failure, and to carry out corresponding activities to provide evidence that the system will not fail. Through the technical identification process, the detailed equipment/operation specifications and identification requirements have been formulated. Different levels of participation are assigned for each eligibility activity, depending on the hazard and risk. It is proved that the application of the technical qualification principle in the systematic evaluation and control of the risks of new technologies or new applications is successful. In HPHT wells in particular, operators can move from a reactive approach to a proactive approach.展开更多
Drilling in any environment is challenging as it poses a challenge to drill reservoir targets without losses and minimum casing strings and is even challenging in HPHT (high pressure high temperature) environment. Sei...Drilling in any environment is challenging as it poses a challenge to drill reservoir targets without losses and minimum casing strings and is even challenging in HPHT (high pressure high temperature) environment. Seismic is the fundamental for pre-drill prognosis and completion design. The target depth prognosis is achieved through depth transformation by using seismic velocities or available velocity logs in the nearby field or block and often has varying degree of uncertainty in target depths depending upon the suitable of the velocity function used. The velocity function used could be affected due to available seismic bandwidth or structure. These uncertainties in target depths often lead to increased well costs as a result of wellbore stability issues & undesired casing strings. Most common issue faced by drillers is the target confirmation & distance to these targets ahead of bit. Vertical seismic profile (VSP) look-ahead at intermediate depths is one of the approaches to mitigate these uncertainties and drill wells safely. VSP help confirm the presence of drilling targets & also predict the depth to top of these targets. Additionally, the predicted interval velocity is used to predict the pre-pressure for next section drilling. In South China Sea, oil & gas operators face a significant risk while drilling over-pressured formations. It is therefore imperative to know the depth to top of these high pressured formations to avoid drilling directly into it and risking the well. It is also important to know the pore-pressure and mud weight for the next section to be drilled for safe drilling & with minimum casing strings [1] [2] [3]. It is more difficult to get this information in the HPHT environment due to the lack of high temperature tools [4]. Schlumberger’s proprietary QVSI*—High pressure, high temperature VSI* (Versatile Seismic Imager) has been successfully used to predict the target depth for casing landing and pore-pressure prediction in HPHT environment. QVSI is the latest generation of VSI* Versatile Seismic Imager tools developed by Schlumberger to acquire high quality tri-axial borehole seismic data in extreme environment wells. The QVSI* tool uses the Q-Technology* singlesensor hardware and software and advanced wireline telemetry for fast digital seismic data transmission from borehole to surface. QVSI is a high-temperature, high-pressure array tool design that focuses on tri-axial vector fidelity and efficient data acquisition, extending the limits in a 4-tool configuration to 500°F (260℃) and 30 kpsi (207 MPa). In this paper, a case study is presented for Well-XX for CNOOC from South China Sea. The well-xx is located in Yanyan Sag, Qiongdongnan Basin and the downhole temperature was 204℃. The main target layer is Lingshui III sandstone, which is controlled by Northwest fault. It is a gas well and critical for the client to land the casing at right depth and know the drilling parameters for the next section ahead. QVSI* predicted the target depth within ±2 m for decision on casing point. The predicted pore pressure was within ±0.1 ppg.展开更多
Investigations of crystal habit, micro-topographic imaging, micro-composition and micro-structural analysis of HPHT synthetic diamonds from the Fe-C(H) system indicate that most of them have an oc-tahedral habit. The ...Investigations of crystal habit, micro-topographic imaging, micro-composition and micro-structural analysis of HPHT synthetic diamonds from the Fe-C(H) system indicate that most of them have an oc-tahedral habit. The crystals grow mainly layer-to-layer from center to periphery. HPHT synthetic dia-mond is smaller in size than natural diamond because it only goes through nucleation and growth in the early stage. In the middle and late stages, due to the coalescence of diamond grains related to dif-ferences of surface energy, the growth of HPHT synthetic diamond is limited. The active energy (E) of transforming single nitrogen into a nitrogen-pair is lowered and the time of transforming single nitro-gen into a nitrogen-pair is shortened because of the existence of hydrogen. Therefore, aggregate ni-trogen (A-centers) may exist in synthetic diamond from HPHT and explosive detonation processes. It needs further discussion on a worldwide view that the time of natural diamond formation extracted from nitrogen aggregation is some hundred million years. Consideration of the way in which surface energy influences the growth of diamond can help to understand some of the remaining issues (e.g. growth mechanism, etc.) in the HPHT synthetic process and effectively explain the formation of natural diamond in terms of HPHT thermodynamic theory. Especially, it is important to pay more attention to the influence of hydrogen on surface energy in that hydrogen may be a "bridge" for explaining the formation of HPHT synthetic and natural diamond.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.12274373 and 12274372)the Natural Science Foundation of Henan Province(Grant Nos.242300421155 and 252300421475)+2 种基金the Key Research Projects of Higher Education Institutions in Henan Province(Grant No.25A140008)the Natural Science Foundation of Chongqing,China(Grant Nos.CSTB2023NSCQ-LZX0100 and CSTB2023NSCQ-MSX0362)Central Plains Science and Technology Innovation Youth Top Notch Talents,and Independent Innovation Project for Graduate Students of Zhengzhou University(Grant No.20250450).
文摘To enhance boron doping efficiency and reduce metal impurities in diamonds,selecting an appropriate metal solvent is essential for producing p-type diamonds using the high-pressure high-temperature(HPHT)method.This paper presents a detailed study of the properties and characteristics of boron-doped diamond(BDD)single crystals grown using FeNi and FeCo solvents through the HPHT method.The results indicate that,with the same TiB_(2)addition ratio,BDD crystals grown using FeCo solvent have a higher concentration of uncompensated boron ions,resulting in improved boron doping efficiency.Additionally,by growing BDD in the same synthesis environment(FeCo-3 wt%TiB_(2))using(111)and(100)seed crystals as growth surfaces,it was found that the boron content in the crystal grown from the(100)seed crystal was higher than that in the crystal grown from the(111)seed crystal.Additionally,the crystals grown with the FeCo solvent contained fewer metal elements(Fe and Co)compared to those produced with the FeNi solvent(Fe and Ni),which supported the growth of high-quality BDD single crystals.This indicated that the choice of growth planes significantly influences the incorporation of boron in diamonds.Our findings hold significant research value for the development of high-quality p-type diamond semiconductors using the HPHT method.
文摘With the increasing demand for new technologies in HPHT (high pressure high temperature) wells, more and more attention has been paid to the system of technical qualifications. Most established norms, standards and recommended practices are written in prescribed formats, setting out methods, procedures and acceptance criteria for product design, manufacture and testing. However, established norms, standards or recommended practices may not adequately cover new technologies or applications. The technical qualification system is established in this paper, which can identify the potential failure modes and some activities in order to control the uncertainties and increase confidence of using new technology. A risk-based technical qualification system is used to assess non-traditional operations. It includes following seven main steps: system breakdown, technology assessment and classification, technical novelty, failure model and risk analysis, risk-based qualification planning and participation level development. The core of technical qualification system is to understand the ways and causes of system failure, and to carry out corresponding activities to provide evidence that the system will not fail. Through the technical identification process, the detailed equipment/operation specifications and identification requirements have been formulated. Different levels of participation are assigned for each eligibility activity, depending on the hazard and risk. It is proved that the application of the technical qualification principle in the systematic evaluation and control of the risks of new technologies or new applications is successful. In HPHT wells in particular, operators can move from a reactive approach to a proactive approach.
文摘Drilling in any environment is challenging as it poses a challenge to drill reservoir targets without losses and minimum casing strings and is even challenging in HPHT (high pressure high temperature) environment. Seismic is the fundamental for pre-drill prognosis and completion design. The target depth prognosis is achieved through depth transformation by using seismic velocities or available velocity logs in the nearby field or block and often has varying degree of uncertainty in target depths depending upon the suitable of the velocity function used. The velocity function used could be affected due to available seismic bandwidth or structure. These uncertainties in target depths often lead to increased well costs as a result of wellbore stability issues & undesired casing strings. Most common issue faced by drillers is the target confirmation & distance to these targets ahead of bit. Vertical seismic profile (VSP) look-ahead at intermediate depths is one of the approaches to mitigate these uncertainties and drill wells safely. VSP help confirm the presence of drilling targets & also predict the depth to top of these targets. Additionally, the predicted interval velocity is used to predict the pre-pressure for next section drilling. In South China Sea, oil & gas operators face a significant risk while drilling over-pressured formations. It is therefore imperative to know the depth to top of these high pressured formations to avoid drilling directly into it and risking the well. It is also important to know the pore-pressure and mud weight for the next section to be drilled for safe drilling & with minimum casing strings [1] [2] [3]. It is more difficult to get this information in the HPHT environment due to the lack of high temperature tools [4]. Schlumberger’s proprietary QVSI*—High pressure, high temperature VSI* (Versatile Seismic Imager) has been successfully used to predict the target depth for casing landing and pore-pressure prediction in HPHT environment. QVSI is the latest generation of VSI* Versatile Seismic Imager tools developed by Schlumberger to acquire high quality tri-axial borehole seismic data in extreme environment wells. The QVSI* tool uses the Q-Technology* singlesensor hardware and software and advanced wireline telemetry for fast digital seismic data transmission from borehole to surface. QVSI is a high-temperature, high-pressure array tool design that focuses on tri-axial vector fidelity and efficient data acquisition, extending the limits in a 4-tool configuration to 500°F (260℃) and 30 kpsi (207 MPa). In this paper, a case study is presented for Well-XX for CNOOC from South China Sea. The well-xx is located in Yanyan Sag, Qiongdongnan Basin and the downhole temperature was 204℃. The main target layer is Lingshui III sandstone, which is controlled by Northwest fault. It is a gas well and critical for the client to land the casing at right depth and know the drilling parameters for the next section ahead. QVSI* predicted the target depth within ±2 m for decision on casing point. The predicted pore pressure was within ±0.1 ppg.
基金the National Natural Science Foundation of China (Grant No. 40502007)
文摘Investigations of crystal habit, micro-topographic imaging, micro-composition and micro-structural analysis of HPHT synthetic diamonds from the Fe-C(H) system indicate that most of them have an oc-tahedral habit. The crystals grow mainly layer-to-layer from center to periphery. HPHT synthetic dia-mond is smaller in size than natural diamond because it only goes through nucleation and growth in the early stage. In the middle and late stages, due to the coalescence of diamond grains related to dif-ferences of surface energy, the growth of HPHT synthetic diamond is limited. The active energy (E) of transforming single nitrogen into a nitrogen-pair is lowered and the time of transforming single nitro-gen into a nitrogen-pair is shortened because of the existence of hydrogen. Therefore, aggregate ni-trogen (A-centers) may exist in synthetic diamond from HPHT and explosive detonation processes. It needs further discussion on a worldwide view that the time of natural diamond formation extracted from nitrogen aggregation is some hundred million years. Consideration of the way in which surface energy influences the growth of diamond can help to understand some of the remaining issues (e.g. growth mechanism, etc.) in the HPHT synthetic process and effectively explain the formation of natural diamond in terms of HPHT thermodynamic theory. Especially, it is important to pay more attention to the influence of hydrogen on surface energy in that hydrogen may be a "bridge" for explaining the formation of HPHT synthetic and natural diamond.
