Quantum digital signature(QDS)can guarantee the information-theoretical security of a signature with the fundamental laws of quantum physics.However,most current QDS protocols do not take source security into account,...Quantum digital signature(QDS)can guarantee the information-theoretical security of a signature with the fundamental laws of quantum physics.However,most current QDS protocols do not take source security into account,leading to an overestimation of the signature rate.In this paper,we propose to utilize Hong–Ou–Mandel interference to characterize the upper bound of the source imperfections,and further to quantify information leakage from potential side-channels.Additionally,we combine decoy-state methods and finite-size analysis in analyzing the signature rate.Simulation results demonstrate the performance and feasibility of our approach.Our current work can improve the practical security of QDS systems,thereby promoting their further networked applications.展开更多
Current studies on carbon nanotube (CNT) size effects predominantly employ Eringen’s differential nonlocal model, which is widely recognized as ill-suited for bounded domains. This paper investigates the free vibrati...Current studies on carbon nanotube (CNT) size effects predominantly employ Eringen’s differential nonlocal model, which is widely recognized as ill-suited for bounded domains. This paper investigates the free vibration of multi-walled CNTs (MWCNTs) with mathematically well-posed two-phase strain-driven and stress-driven nonlocal integral models incorporating the bi-Helmholtz kernel. The van der Waals (vdW) forces coupling MWCNT layers are similarly modeled as size-dependent via the bi-Helmholtz two-phase nonlocal integral framework. Critically, conventional pure strain-driven or stress-driven formulations become over-constrained when nonlocal vdW interactions are considered. The two-phase strategy resolves this limitation by enabling consistent coupling. Each bi-Helmholtz integral constitutive equation is equivalently transformed into a differential form requiring four additional constitutive boundary conditions (CBCs). The numerical solutions are obtained with the generalized differential quadrature method (GDQM) for these coupled higher-order equations. The parametric studies on double-walled CNTs (DWCNTs) and triple-walled CNTs (TWCNTs) elucidate the nonlocal effects predicted by both formulations. Additionally, the influence of nonlocal parameters within vdW forces is systematically evaluated to comprehensively characterize the size effects in MWCNTs.展开更多
Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes...Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.展开更多
Understanding the complex plasma dynamics in ultra-intense relativistic laser-solid interactions is of fundamental importance for applications of laser-plasma-based particle accelerators,the creation of high-energy-de...Understanding the complex plasma dynamics in ultra-intense relativistic laser-solid interactions is of fundamental importance for applications of laser-plasma-based particle accelerators,the creation of high-energy-density matter,understanding planetary science,and laser-driven fusion energy.However,experimental efforts in this regime have been limited by the lack of accessibility of over-critical densities and the poor spatiotemporal resolution of conventional diagnostics.Over the last decade,the advent of femtosecond brilliant hard X-ray free-electron lasers(XFELs)has opened new horizons to overcome these limitations.Here,for the first time,we present full-scale spatiotemporal measurements of solid-density plasma dynamics,including preplasma generation with tens of nanometer scale length driven by the leading edge of a relativistic laser pulse,ultrafast heating and ionization at the main pulse arrival,the laser-driven blast wave,and transient surface return current-induced compression dynamics up to hundreds of picoseconds after interaction.These observations are enabled by utilizing a novel combination of advanced X-ray diagnostics including small-angle X-ray scattering,resonant X-ray emission spectroscopy,and propagation-based X-ray phase-contrast imaging simultaneously at the European XFEL-HED beamline station.展开更多
Based on Hamilton principle,the governing differential equations and the corresponding boundary conditions of steel-concrete composite box girder with consideration of the shear lag effect meeting self equilibrated st...Based on Hamilton principle,the governing differential equations and the corresponding boundary conditions of steel-concrete composite box girder with consideration of the shear lag effect meeting self equilibrated stress,shear deformation,slip,as well as rotational inertia were induced.Therefore,natural frequency equations were obtained for the boundary types,such as simple support,cantilever,continuous girder and fixed support at two ends.The ANSYS finite element solutions were compared with the analytical solutions by calculation examples and the validity of the proposed approach was verified,which also shows the correctness of longitudinal warping displacement functions.Some meaningful conclusions for engineering design were obtained.The decrease extent of each order natural frequency of the steel-concrete composite box-girder is great under action of the shear lag effect.The shear-lag effect of steel-concrete composite box girder increases when frequency order rises,and increases while span-width ratio decreases.The proposed approach provides theoretical basis for further research of free vibration characteristics of steel-concrete composite box-girder.展开更多
The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of ...The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of the yield stress and the Soret effect. The governing boundary layer equations and boundary conditions are cast into a dimen- sionless form by similarity transformations, and the resulting system of equations is solved by a finite difference method. The results are preSented and discussed for concentration profiles, as well as the Nusselt number and the Sherwood number for various values of the parameters, which govern the problem. The results obtained show that the flow field is influenced appreciably by the presence of the chemical reaction parameter γ the order of.the chemical reaction parameter m, the Soret number St, the buoyancy ratio N, the Lewis number Le, and the dimensionless rheological parameter Ω.展开更多
In order to better describe the phenomenon of biological invasion,this paper introduces a free boundary model of biological invasion.Firstly,the right free boundary is added to the equation with logistic terms.Secondl...In order to better describe the phenomenon of biological invasion,this paper introduces a free boundary model of biological invasion.Firstly,the right free boundary is added to the equation with logistic terms.Secondly,the existence and uniqueness of local solutions are proved by the Sobolev embedding theorem and the comparison principle.Finally,according to the relevant research data and contents of red fire ants,the diffusion area and nest number of red fire ants were simulated without external disturbance.This paper mainly simulates the early diffusion process of red fire ants.In the early diffusion stage,red fire ants grow slowly and then spread over a large area after reaching a certain number.展开更多
Under the guidance of Deng Xiao-ping’s strategic think-ing of openning to the outside world, the structure of om-nibearing openness has basically taken shape in China. Follow-
The results of computer simulations of the binding of etravirine (TMC125) and rilpivirine (TMC278) to HIV reverse transcriptase are reported. It is confirmed that consistent binding free energy estimates are obtained ...The results of computer simulations of the binding of etravirine (TMC125) and rilpivirine (TMC278) to HIV reverse transcriptase are reported. It is confirmed that consistent binding free energy estimates are obtained with or without the application of torsional restraints when the free energies of imposing the restraints are taken into account. The restraints have a smaller influence on the thermodynamics and apparent kinetics of binding of TMC125 compared to the more flexible TMC278 inhibitor. The concept of the reorganization free energy of binding is useful to understand and categorize these effects. Contrary to expectations, the use of conformational restraints did not consistently enhance convergence of binding free energy estimates due to suppression of binding/unbinding pathways and due to the influence of rotational degrees of freedom not directly controlled by the restraints. Physical insights concerning the thermodynamic driving forces for binding and the role of “jiggling” and “wiggling” motion of the ligands are discussed. Based on these insights we conclude that an ideal inhibitor, if chemically realizable, would possess the electrostatic charge distribution of TMC125, so as to form strong interactions with the receptor, and the larger and more flexible substituents of TMC278, so as to minimize reorganization free energy penalties and the effects of resistance mutations, suitably modified, as in TMC125, so as to disfavor the formation of non-binding competent extended conformations when free in solution.展开更多
Comprehensive utilization of phosphogypsum(PG)has attracted much attention,especially for the recovery of rare earth elements(REEs)and gypsum due to the issues of stockpile,environmental pollution,and waste of associa...Comprehensive utilization of phosphogypsum(PG)has attracted much attention,especially for the recovery of rare earth elements(REEs)and gypsum due to the issues of stockpile,environmental pollution,and waste of associated resources.Traditional utilization methods suffered the issues of low REEs leaching efficiency,huge amount of CaSO_(4)saturated wastewater and high recovery cost.To solve these issues,this study investigated the occurrence of REEs in PG and the leaching of REEs.The results show that REEs in PG are in the forms of(1)REEs mineral inclusions,(2)REEs isomorphous substitution of Ca^(2+)in gypsum lattice,(3)dispersed soluble REEs salts.Acid leaching results demonstrate that(1)the dissolution of gypsum matrix is the control factor of REEs leaching;(2)H_(2)SO_(4)is a promising leachant considering the recycle of leachate;(3)the gypsum matrix suffers a recrystallization during the acid leaching and releases the soluble REEs from PG to aqueous solution.For the recovery of the undissolved REEs mineral inclusions,wet sieving concentrated 37.1 wt%of the REEs in a 10.7 wt%mass,increasing REEs content from 309 to 1071 ppm.Finally,a green process combining gravity separation and hydrometallurgy is proposed.This process owns the merits of wastewater free,considerable REEs recovery(about 10%increase compared with traditional processes),excellent gypsum purification(>95 wt%CaSO_(4)·2H_(2)O,with<0.06 wt%of soluble P_(2)O_(5) and<0.015 wt%of soluble F)and reagent saving(about 2/3less reagent consumption than non-cyclical leaching).展开更多
The Makran Accretionary Prism is one of the largest accretionary prisms in the world and hosts substantial natural gas hydrate resources.However,research on the distribution characteristics and accumulation mechanisms...The Makran Accretionary Prism is one of the largest accretionary prisms in the world and hosts substantial natural gas hydrate resources.However,research on the distribution characteristics and accumulation mechanisms of free gas remains limited.This study identifies structural elements associated with free gas,such as thrust faults,piggyback basins,unconformities,and décollements,through detailed interpretation of newly acquired seismic data.Free gas reservoirs within piggyback basins are located in the folded zone of the accretionary prism,whereas unconformity-type and horizontal sandstone-type free gas reservoirs are identified in undeformed areas.In the folded zone,décollement,thrust faults,and permeable sand layers act as primary migration pathways for free gas,which accumulates in turbidite sands beneath bottom simulating reflectors(BSRs)in piggyback basins.In the undeformed zone,free gas migrates along décollements and thrust faults into horizontal sandstones,where substantial accumulations are found near unconformities below BSRs.The distribution of free gas reservoirs across the study area is extensive and diverse.This study is the first to document unconformity-type and horizontal sandstone-type free gas reservoirs in the undeformed zone,highlighting their considerable resource potential.The findings are of substantial value for oil and gas exploration at the front of the accretionary prism and provide important theoretical and practical insights into natural gas accumulation systems along active continental margins.展开更多
Owing to their low toxicity and remarkable stability, perovskites based on antimony and bismuth have garnered significant interest in recent years. However, A_(3)B_(2)X_(9) perovskite materials derived from antimony a...Owing to their low toxicity and remarkable stability, perovskites based on antimony and bismuth have garnered significant interest in recent years. However, A_(3)B_(2)X_(9) perovskite materials derived from antimony and bismuth face several challenges, including excessively wide band gaps, elevated defect densities, and suboptimal film quality, all of which hinder advancements in device efficiency. While extensive studies have been undertaken to investigate the effects of modulating the A-site and X-site elements in lead-free A_(3)B_(2)X_(9) perovskites, there remains a notable scarcity of reports addressing the impact of modifications to the B-site element. In this study, we investigated the alloying of antimony and bismuth within the 2D Cs_(3)B_(2)I_(6)Br_(3) perovskite. By systematically varying the ratios of two elements, we found that the incorporation of both antimony and bismuth at the B-site significantly enhances the quality of the perovskite films. Our findings indicate that a 1 : 1 ratio of antimony to bismuth produces the densest films, the highest photoluminescence intensity, and superior photovoltaic performance. Ultimately,the devices fabricated using this optimal ratio achieved an open-circuit voltage(VOC) of 1.01 V and a power conversion efficiency(PCE) of 0.645%.展开更多
Let G be a group.The family of all sets which are closed in every Hausdorf group topology of G form the family of closed sets of a T_(1) topology M_(G) on G called the Markov topology.Similarly,the family of all algeb...Let G be a group.The family of all sets which are closed in every Hausdorf group topology of G form the family of closed sets of a T_(1) topology M_(G) on G called the Markov topology.Similarly,the family of all algebraic subsets of G forms a family of closed sets for another T_(1)topology Z_(G) on G called the Zarski topology.A subgroup H of G is said to be Markov(resp.Zarski)embedded if the equality M_(G|H)=M_(H)(resp.Z_(G|H)=Z_(H))holds.I's proved that an abirary subgroup of a free group is both Zariski and Markov embedded in it.展开更多
Labor provisions have become a fundamental trade rule in regional and bilateral trade agreements.Although China’s legislation on pilot Free Trade Zones includes content related to labor protection,it primarily aligns...Labor provisions have become a fundamental trade rule in regional and bilateral trade agreements.Although China’s legislation on pilot Free Trade Zones includes content related to labor protection,it primarily aligns with labor indicators in“Doing Business”,the assessment of business situations issued by the World Bank.It differs from the labor rights protection focus emphasized in trade agreements.The latest strategic documents issued by the State Council of China have addressed this issue to fully achieve the goal of aligning Free Trade Zones with high-standard trade agreements.Building on the development of Free Trade Zone legislation and domestic labor law governance,China should proactively explore a tailored approach to labor provisions in Free Trade Agreements.In this approach,it should explicitly define the“baseline”and“ceiling”for labor provisions during negotiations and,within this framework,establish benchmarks for labor rights protection,enforcement mechanisms,and cross-border regulatory mechanisms suited to the specific conditions of the agreement parties.展开更多
Too much screen time is bad for your brain and body.It can also waste your time.So,try to spend less time on scree ns.Changing habits is not easy,but you can do it.Use an app to track your time on your smartphone.Do y...Too much screen time is bad for your brain and body.It can also waste your time.So,try to spend less time on scree ns.Changing habits is not easy,but you can do it.Use an app to track your time on your smartphone.Do you waste a lot of time on some ofyour phone apps?Take them off or set time limits for them.Less screen time means more free time for other things.Go hiking,visit a museum or try a new hobby.Use your phone less and appreciate life more.展开更多
Silicon,a leading candidate for electrode material for lithium-ion batteries,has garnered significant attention.During the initial lithiation process,the alloying reaction between silicon and lithium transforms the pr...Silicon,a leading candidate for electrode material for lithium-ion batteries,has garnered significant attention.During the initial lithiation process,the alloying reaction between silicon and lithium transforms the pristine silicon microstructure from crystalline to amorphous,resulting in plastic deformation of the amorphous phase.This study proposes the free volume theory to develop a fully coupled Cahn-Hilliard phase-field model that integrates viscoplastic deformation,free volume evolution,and diffusion.This model investigates the chemophysical phenomenon of self-limiting behavior occurring during the initial lithiation of silicon anodes.Unlike most existing models,the proposed model considers free volume-dependent diffusion using a physically-based approach.The model’s temporal variation in the lithiated phase thickness aligns well with experimental results,confirming the model’s accuracy.Stress field calculations reveal the coexistence of compressive and tensile stresses within the lithiated phase,which may not cause the limiting effect under the frame of the stress-induced diffusion.Analyses indicate that high effective stress increases free volume,enhancing lithium diffusion and augmenting the diffusion coefficient.Reducing the diffusion coefficient in the lithiated phase due to free volume evolution is the primary cause of self-limiting lithiation.展开更多
Against the backdrop of digital education,the campus network has become an indispensable infrastructure in universities,yet the limitations of traditional operation models have become increasingly prominent.This paper...Against the backdrop of digital education,the campus network has become an indispensable infrastructure in universities,yet the limitations of traditional operation models have become increasingly prominent.This paper systematically presents the entire process of the free campus network reform initiated by Dalian Jiaotong University,focusing on its background,implementation paths,existing challenges,and optimization strategies.It explores the construction of an on-demand service system for campus networks,and practical experience can provide some reference and guidance for sister universities.展开更多
The high temporal and spatial coherence of free electron lasers(FELs)reduces the uniformity of the illumination field,leading to scattering effects that blur the edges of patterns,resulting in diminished accuracy and ...The high temporal and spatial coherence of free electron lasers(FELs)reduces the uniformity of the illumination field,leading to scattering effects that blur the edges of patterns,resulting in diminished accuracy and clarity.Traditional imaging models regard the light source as fully incoherent,making it difficult to assess the impact of partially coherent light fields on imaging.If FELs are used in imaging systems,their coherence must be considered.To address this issue,this study explores the relationship between coherence,imaging quality and speckle contrast through a simulation method based on random phases.The method divides the light beam into temporal and spatial coherence cells,analyzes their interactions,and simulates imaging results under different coherence conditions.Additionally,speckle patterns for various illumination modes are calculated to evaluate their effects on speckle contrast and illumination uniformity.The results indicate that under different illumination modes,illumination uniformity decreases as coherence increases,while speckle contrast increases with higher coherence.In terms of imaging quality,higher coherence leads to an increase in both line edge roughness(LER)and line width roughness(LWR),thereby reducing the imaging quality.Additionally,the narrower the line width,the greater the impact of coherence on the imaging quality,resulting in poorer imaging performance.展开更多
Ferroelectrics(FEs)have shown great potential in sensors,actuators,and electrocaloric cooling due to their direct cross-couplings between electric polarization and mechanical,thermal,and dielectric properties[1−3]Comp...Ferroelectrics(FEs)have shown great potential in sensors,actuators,and electrocaloric cooling due to their direct cross-couplings between electric polarization and mechanical,thermal,and dielectric properties[1−3]Compared with oxide FEs,polymer FEs possess good flexible and shape adaptability,making them promising candidates for flexible electronics and biocompatible devices[4].展开更多
基金the financial support from the Natural Science Foundation of Jiangsu Province(Grant Nos.BE2022071 and BK20192001)the National Natural Science Foundation of China(Grant Nos.12074194,62471248,12104240,and 62101285)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX220954)。
文摘Quantum digital signature(QDS)can guarantee the information-theoretical security of a signature with the fundamental laws of quantum physics.However,most current QDS protocols do not take source security into account,leading to an overestimation of the signature rate.In this paper,we propose to utilize Hong–Ou–Mandel interference to characterize the upper bound of the source imperfections,and further to quantify information leakage from potential side-channels.Additionally,we combine decoy-state methods and finite-size analysis in analyzing the signature rate.Simulation results demonstrate the performance and feasibility of our approach.Our current work can improve the practical security of QDS systems,thereby promoting their further networked applications.
基金Project supported by the National Natural Science Foundation of China(Nos.12172169 and 12272064)the Natural Science Foundation of Jiangsu Province of China(No.BK20241773)the Priority Academic Program Development of Jiangsu Higher Education Institutions of China。
文摘Current studies on carbon nanotube (CNT) size effects predominantly employ Eringen’s differential nonlocal model, which is widely recognized as ill-suited for bounded domains. This paper investigates the free vibration of multi-walled CNTs (MWCNTs) with mathematically well-posed two-phase strain-driven and stress-driven nonlocal integral models incorporating the bi-Helmholtz kernel. The van der Waals (vdW) forces coupling MWCNT layers are similarly modeled as size-dependent via the bi-Helmholtz two-phase nonlocal integral framework. Critically, conventional pure strain-driven or stress-driven formulations become over-constrained when nonlocal vdW interactions are considered. The two-phase strategy resolves this limitation by enabling consistent coupling. Each bi-Helmholtz integral constitutive equation is equivalently transformed into a differential form requiring four additional constitutive boundary conditions (CBCs). The numerical solutions are obtained with the generalized differential quadrature method (GDQM) for these coupled higher-order equations. The parametric studies on double-walled CNTs (DWCNTs) and triple-walled CNTs (TWCNTs) elucidate the nonlocal effects predicted by both formulations. Additionally, the influence of nonlocal parameters within vdW forces is systematically evaluated to comprehensively characterize the size effects in MWCNTs.
基金Supported by the National Key Research Program(No.2024-1129-954-112)National Natural Science Foundation of China(No.52372033)Guangxi Science and Technology Major Program(No.AA24263054)。
文摘Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.
基金partially supported by the Helmholtz Imaging platform through the project“SmartPhase.”。
文摘Understanding the complex plasma dynamics in ultra-intense relativistic laser-solid interactions is of fundamental importance for applications of laser-plasma-based particle accelerators,the creation of high-energy-density matter,understanding planetary science,and laser-driven fusion energy.However,experimental efforts in this regime have been limited by the lack of accessibility of over-critical densities and the poor spatiotemporal resolution of conventional diagnostics.Over the last decade,the advent of femtosecond brilliant hard X-ray free-electron lasers(XFELs)has opened new horizons to overcome these limitations.Here,for the first time,we present full-scale spatiotemporal measurements of solid-density plasma dynamics,including preplasma generation with tens of nanometer scale length driven by the leading edge of a relativistic laser pulse,ultrafast heating and ionization at the main pulse arrival,the laser-driven blast wave,and transient surface return current-induced compression dynamics up to hundreds of picoseconds after interaction.These observations are enabled by utilizing a novel combination of advanced X-ray diagnostics including small-angle X-ray scattering,resonant X-ray emission spectroscopy,and propagation-based X-ray phase-contrast imaging simultaneously at the European XFEL-HED beamline station.
基金Projects(51078355,50938008)supported by the National Natural Science Foundation of ChinaProject(094801020)supported by the Academic Scholarship for Doctoral Candidates of the Ministry of Education,China+1 种基金Project(CX2011B093)supported by the Doctoral Candidate Research Innovation Project of Hunan Province,ChinaProject(20117Q008)supported by the Central University Basic Scientific Research Business Expenses Special Fund of China
文摘Based on Hamilton principle,the governing differential equations and the corresponding boundary conditions of steel-concrete composite box girder with consideration of the shear lag effect meeting self equilibrated stress,shear deformation,slip,as well as rotational inertia were induced.Therefore,natural frequency equations were obtained for the boundary types,such as simple support,cantilever,continuous girder and fixed support at two ends.The ANSYS finite element solutions were compared with the analytical solutions by calculation examples and the validity of the proposed approach was verified,which also shows the correctness of longitudinal warping displacement functions.Some meaningful conclusions for engineering design were obtained.The decrease extent of each order natural frequency of the steel-concrete composite box-girder is great under action of the shear lag effect.The shear-lag effect of steel-concrete composite box girder increases when frequency order rises,and increases while span-width ratio decreases.The proposed approach provides theoretical basis for further research of free vibration characteristics of steel-concrete composite box-girder.
文摘The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of the yield stress and the Soret effect. The governing boundary layer equations and boundary conditions are cast into a dimen- sionless form by similarity transformations, and the resulting system of equations is solved by a finite difference method. The results are preSented and discussed for concentration profiles, as well as the Nusselt number and the Sherwood number for various values of the parameters, which govern the problem. The results obtained show that the flow field is influenced appreciably by the presence of the chemical reaction parameter γ the order of.the chemical reaction parameter m, the Soret number St, the buoyancy ratio N, the Lewis number Le, and the dimensionless rheological parameter Ω.
基金Supported by National Natural Science Foundation of China(12101482)Postdoctoral Science Foundation of China(2022M722604)+2 种基金General Project of Science and Technology of Shaanxi Province(2023-YBSF-372)The Natural Science Foundation of Shaan Xi Province(2023-JCQN-0016)Shannxi Mathmatical Basic Science Research Project(23JSQ042)。
文摘In order to better describe the phenomenon of biological invasion,this paper introduces a free boundary model of biological invasion.Firstly,the right free boundary is added to the equation with logistic terms.Secondly,the existence and uniqueness of local solutions are proved by the Sobolev embedding theorem and the comparison principle.Finally,according to the relevant research data and contents of red fire ants,the diffusion area and nest number of red fire ants were simulated without external disturbance.This paper mainly simulates the early diffusion process of red fire ants.In the early diffusion stage,red fire ants grow slowly and then spread over a large area after reaching a certain number.
文摘Under the guidance of Deng Xiao-ping’s strategic think-ing of openning to the outside world, the structure of om-nibearing openness has basically taken shape in China. Follow-
文摘The results of computer simulations of the binding of etravirine (TMC125) and rilpivirine (TMC278) to HIV reverse transcriptase are reported. It is confirmed that consistent binding free energy estimates are obtained with or without the application of torsional restraints when the free energies of imposing the restraints are taken into account. The restraints have a smaller influence on the thermodynamics and apparent kinetics of binding of TMC125 compared to the more flexible TMC278 inhibitor. The concept of the reorganization free energy of binding is useful to understand and categorize these effects. Contrary to expectations, the use of conformational restraints did not consistently enhance convergence of binding free energy estimates due to suppression of binding/unbinding pathways and due to the influence of rotational degrees of freedom not directly controlled by the restraints. Physical insights concerning the thermodynamic driving forces for binding and the role of “jiggling” and “wiggling” motion of the ligands are discussed. Based on these insights we conclude that an ideal inhibitor, if chemically realizable, would possess the electrostatic charge distribution of TMC125, so as to form strong interactions with the receptor, and the larger and more flexible substituents of TMC278, so as to minimize reorganization free energy penalties and the effects of resistance mutations, suitably modified, as in TMC125, so as to disfavor the formation of non-binding competent extended conformations when free in solution.
基金Project supported by the National Natural Science Foundation of China(52104354)the National Natural Science Foundation of China(51674036)+1 种基金Joint Fund for Nuclear Technology Innovation Sponsored by the National Natural Science Foundation of Chinathe China National Nuclear Corporation(U2067201)。
文摘Comprehensive utilization of phosphogypsum(PG)has attracted much attention,especially for the recovery of rare earth elements(REEs)and gypsum due to the issues of stockpile,environmental pollution,and waste of associated resources.Traditional utilization methods suffered the issues of low REEs leaching efficiency,huge amount of CaSO_(4)saturated wastewater and high recovery cost.To solve these issues,this study investigated the occurrence of REEs in PG and the leaching of REEs.The results show that REEs in PG are in the forms of(1)REEs mineral inclusions,(2)REEs isomorphous substitution of Ca^(2+)in gypsum lattice,(3)dispersed soluble REEs salts.Acid leaching results demonstrate that(1)the dissolution of gypsum matrix is the control factor of REEs leaching;(2)H_(2)SO_(4)is a promising leachant considering the recycle of leachate;(3)the gypsum matrix suffers a recrystallization during the acid leaching and releases the soluble REEs from PG to aqueous solution.For the recovery of the undissolved REEs mineral inclusions,wet sieving concentrated 37.1 wt%of the REEs in a 10.7 wt%mass,increasing REEs content from 309 to 1071 ppm.Finally,a green process combining gravity separation and hydrometallurgy is proposed.This process owns the merits of wastewater free,considerable REEs recovery(about 10%increase compared with traditional processes),excellent gypsum purification(>95 wt%CaSO_(4)·2H_(2)O,with<0.06 wt%of soluble P_(2)O_(5) and<0.015 wt%of soluble F)and reagent saving(about 2/3less reagent consumption than non-cyclical leaching).
基金the National Natural Science Foundation of China(Nos.42076069,41406080)the Laoshan Laboratory Science and Technology Innovation Project(No.LSKJ202203401)the China Geological Survey Project(Nos.DD20190581,DD20160155)。
文摘The Makran Accretionary Prism is one of the largest accretionary prisms in the world and hosts substantial natural gas hydrate resources.However,research on the distribution characteristics and accumulation mechanisms of free gas remains limited.This study identifies structural elements associated with free gas,such as thrust faults,piggyback basins,unconformities,and décollements,through detailed interpretation of newly acquired seismic data.Free gas reservoirs within piggyback basins are located in the folded zone of the accretionary prism,whereas unconformity-type and horizontal sandstone-type free gas reservoirs are identified in undeformed areas.In the folded zone,décollement,thrust faults,and permeable sand layers act as primary migration pathways for free gas,which accumulates in turbidite sands beneath bottom simulating reflectors(BSRs)in piggyback basins.In the undeformed zone,free gas migrates along décollements and thrust faults into horizontal sandstones,where substantial accumulations are found near unconformities below BSRs.The distribution of free gas reservoirs across the study area is extensive and diverse.This study is the first to document unconformity-type and horizontal sandstone-type free gas reservoirs in the undeformed zone,highlighting their considerable resource potential.The findings are of substantial value for oil and gas exploration at the front of the accretionary prism and provide important theoretical and practical insights into natural gas accumulation systems along active continental margins.
基金financially supported by the Natural Science Foundation of Zhejiang Province, China (Grant No. LQ22F040001)China Postdoctoral Science Foundation (Grant No. 2022M723281)Science and Technology Planning Project of Shaoxing City (Grant No. 2023B41006)。
文摘Owing to their low toxicity and remarkable stability, perovskites based on antimony and bismuth have garnered significant interest in recent years. However, A_(3)B_(2)X_(9) perovskite materials derived from antimony and bismuth face several challenges, including excessively wide band gaps, elevated defect densities, and suboptimal film quality, all of which hinder advancements in device efficiency. While extensive studies have been undertaken to investigate the effects of modulating the A-site and X-site elements in lead-free A_(3)B_(2)X_(9) perovskites, there remains a notable scarcity of reports addressing the impact of modifications to the B-site element. In this study, we investigated the alloying of antimony and bismuth within the 2D Cs_(3)B_(2)I_(6)Br_(3) perovskite. By systematically varying the ratios of two elements, we found that the incorporation of both antimony and bismuth at the B-site significantly enhances the quality of the perovskite films. Our findings indicate that a 1 : 1 ratio of antimony to bismuth produces the densest films, the highest photoluminescence intensity, and superior photovoltaic performance. Ultimately,the devices fabricated using this optimal ratio achieved an open-circuit voltage(VOC) of 1.01 V and a power conversion efficiency(PCE) of 0.645%.
基金Supported by the Grant-in-Aid for Scientific Research(C)by the Japan Society for the Promotion of Science(20K03615)。
文摘Let G be a group.The family of all sets which are closed in every Hausdorf group topology of G form the family of closed sets of a T_(1) topology M_(G) on G called the Markov topology.Similarly,the family of all algebraic subsets of G forms a family of closed sets for another T_(1)topology Z_(G) on G called the Zarski topology.A subgroup H of G is said to be Markov(resp.Zarski)embedded if the equality M_(G|H)=M_(H)(resp.Z_(G|H)=Z_(H))holds.I's proved that an abirary subgroup of a free group is both Zariski and Markov embedded in it.
基金result of the“Research on ESG Supply Chain Governance and Labor Rights Protection”(Project Number SUFE-ESG-20250315)a general subject project of the Fullgoal Institute for ESG Research,SUFE in 2025.
文摘Labor provisions have become a fundamental trade rule in regional and bilateral trade agreements.Although China’s legislation on pilot Free Trade Zones includes content related to labor protection,it primarily aligns with labor indicators in“Doing Business”,the assessment of business situations issued by the World Bank.It differs from the labor rights protection focus emphasized in trade agreements.The latest strategic documents issued by the State Council of China have addressed this issue to fully achieve the goal of aligning Free Trade Zones with high-standard trade agreements.Building on the development of Free Trade Zone legislation and domestic labor law governance,China should proactively explore a tailored approach to labor provisions in Free Trade Agreements.In this approach,it should explicitly define the“baseline”and“ceiling”for labor provisions during negotiations and,within this framework,establish benchmarks for labor rights protection,enforcement mechanisms,and cross-border regulatory mechanisms suited to the specific conditions of the agreement parties.
文摘Too much screen time is bad for your brain and body.It can also waste your time.So,try to spend less time on scree ns.Changing habits is not easy,but you can do it.Use an app to track your time on your smartphone.Do you waste a lot of time on some ofyour phone apps?Take them off or set time limits for them.Less screen time means more free time for other things.Go hiking,visit a museum or try a new hobby.Use your phone less and appreciate life more.
基金the National Natural Science Foundation of China under grant No.12372173the Natural Science Foundation of Shanghai under grant No.23ZR1468600.
文摘Silicon,a leading candidate for electrode material for lithium-ion batteries,has garnered significant attention.During the initial lithiation process,the alloying reaction between silicon and lithium transforms the pristine silicon microstructure from crystalline to amorphous,resulting in plastic deformation of the amorphous phase.This study proposes the free volume theory to develop a fully coupled Cahn-Hilliard phase-field model that integrates viscoplastic deformation,free volume evolution,and diffusion.This model investigates the chemophysical phenomenon of self-limiting behavior occurring during the initial lithiation of silicon anodes.Unlike most existing models,the proposed model considers free volume-dependent diffusion using a physically-based approach.The model’s temporal variation in the lithiated phase thickness aligns well with experimental results,confirming the model’s accuracy.Stress field calculations reveal the coexistence of compressive and tensile stresses within the lithiated phase,which may not cause the limiting effect under the frame of the stress-induced diffusion.Analyses indicate that high effective stress increases free volume,enhancing lithium diffusion and augmenting the diffusion coefficient.Reducing the diffusion coefficient in the lithiated phase due to free volume evolution is the primary cause of self-limiting lithiation.
文摘Against the backdrop of digital education,the campus network has become an indispensable infrastructure in universities,yet the limitations of traditional operation models have become increasingly prominent.This paper systematically presents the entire process of the free campus network reform initiated by Dalian Jiaotong University,focusing on its background,implementation paths,existing challenges,and optimization strategies.It explores the construction of an on-demand service system for campus networks,and practical experience can provide some reference and guidance for sister universities.
文摘The high temporal and spatial coherence of free electron lasers(FELs)reduces the uniformity of the illumination field,leading to scattering effects that blur the edges of patterns,resulting in diminished accuracy and clarity.Traditional imaging models regard the light source as fully incoherent,making it difficult to assess the impact of partially coherent light fields on imaging.If FELs are used in imaging systems,their coherence must be considered.To address this issue,this study explores the relationship between coherence,imaging quality and speckle contrast through a simulation method based on random phases.The method divides the light beam into temporal and spatial coherence cells,analyzes their interactions,and simulates imaging results under different coherence conditions.Additionally,speckle patterns for various illumination modes are calculated to evaluate their effects on speckle contrast and illumination uniformity.The results indicate that under different illumination modes,illumination uniformity decreases as coherence increases,while speckle contrast increases with higher coherence.In terms of imaging quality,higher coherence leads to an increase in both line edge roughness(LER)and line width roughness(LWR),thereby reducing the imaging quality.Additionally,the narrower the line width,the greater the impact of coherence on the imaging quality,resulting in poorer imaging performance.
基金support from the Natural Science Fund for Colleges and Universities in Jiangsu Province(24KJB430029)the Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications(NY224032,NY225006).
文摘Ferroelectrics(FEs)have shown great potential in sensors,actuators,and electrocaloric cooling due to their direct cross-couplings between electric polarization and mechanical,thermal,and dielectric properties[1−3]Compared with oxide FEs,polymer FEs possess good flexible and shape adaptability,making them promising candidates for flexible electronics and biocompatible devices[4].
