The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it i...The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it is of great scientific significance to study the accumulation conditions of oil sand in different strata and mining areas of the Junggar Basin.Through a large number of field investigations,drilling verification and sampling tests,it is found that the oil sand in the region covers an area of 2000 km^(2),with shallow and thick reservoir,and predicted resource of 180 million tons.The oil sand resources are mainly distributed in four geological strata,namely the Middle Triassic Karamay Formation,Early Jurassic Badaowan Formation,Late Jurassic Qigu Formation,and Early Cretaceous Qingshuihe Formation.The reservoir is mainly composed of sandstone with high porosity and permeability,and the reservoir space is mainly intergranular pores with a medium average oil content.The oil sand deposit in the region is a typical destructive oil reservoir.The crude oil in the oil sand layer is degraded and thickened from the deep to the shallow,the content of saturated hydrocarbon decreased,and the content of aromatic hydrocarbon,non-hydrocarbon and asphaltene increased.The oil source comes from the deep Permian hydrocarbon-generating depression.Unconformities,faults and marginal fan delta-braided river depositional systems constitute effective migration and storage systems.Caprocks of the Upper Triassic Baijiantan Formation,Lower Jurassic Sangonghe Formation and Lower Cretaceous Hutubihe Formation were formed by three large scale lake transgressions.The Indosinian,Yanshan and Late Yanshan movements are the main driving forces for the migration of deep oil and gas to the shallow edge to form oil sand deposits.It is considered that the oil sand in the northwestern margin of Junggar Basin is of a slope complex migration type.展开更多
The exploration targets in the Kuqa Depression at present are mainly structure traps in Cretaceous-Tertiary.Due to the complexity of mountain distribution and reservoir forming conditions, the exploration of Jurassic ...The exploration targets in the Kuqa Depression at present are mainly structure traps in Cretaceous-Tertiary.Due to the complexity of mountain distribution and reservoir forming conditions, the exploration of Jurassic in the eastern Kuqa Depression has been in a state of semi-stagnation since the discovery of the Yinan-2 gas reservoir.According to the concept and theory of 'continuous petroleum reservoirs' and the re-analysis of the forming conditions of the Yinan-2 gas reservoir and regional natural gas in the eastern Kuqa Depression,it is believed that the deep Jurassic has good natural gas accumulation conditions as well as geological conditions for forming continuous tight gas reservoirs.The boundary of the Yinan-2 gas reservoir is not controlled by a structural spillpoint.The downdip part of the structure is dominated by gas,while the hanging wall of the fault is filled by water and forming obvious inverted gas and water.The gas reservoir has the normal temperature and ultrahigh pressure which formed in the near source or inner-source.All of these characteristics indicate that the Yinan-2 gas reservoir is different from conventional gas reservoirs.The deep Jurassic in the eastern Kuqa Depression has multisets of source-reservoir-cap assemblages,which comprise interbedded sandstones and mudstones.These assemblages are characterized by a self-generation,self-preserving and self-coverage model.Reservoir sandstones and coal measure mudstones are interbedded with each other at a large scale.As the source rocks,Triassic-Jurassic coal measure mudstones distribute continuously at a large scale and can generate and expel hydrocarbon.Source rocks contact intimately with the overlying sandstone reservoirs.During the late stage of hydrocarbon expulsion,natural gas charged continuously and directly into the neighboring reservoirs.Petroleum migrated mainly in a vertical direction over short distances.With ultra-high pressure and strong charging intensity,natural gas accumulated continuously.Reservoirs are dominated by sandstones of braided delta facies.The sand bodies distribute continuously horizontal.With low porosity and low permeability,the reservoirs are featured by strong heterogeneity.It is hypothesized that the sandstones of the interior depression tend to be relatively tight with increasing depth and structure stress weakness.Thus,it is predicted that continuous tight gas reservoirs of ultra-high pressure may exist in the deep formations of the eastern and even the whole Kuqa Depression.So,it is worth evaluating the exploration potential.展开更多
Bulge is a defect that causes geometrical inaccuracy and premature failure in the innovative incremental sheet forming (ISF) process. This study has two-fold objectives:(1) knowing the bulging behavior of a Cu clad tr...Bulge is a defect that causes geometrical inaccuracy and premature failure in the innovative incremental sheet forming (ISF) process. This study has two-fold objectives:(1) knowing the bulging behavior of a Cu clad tri-layered steel sheet as a function of forming conditions, and (2) analyzing the bending effect on bulging in an attempt to identify the associated mechanism. A series of ISF tests and bending analysis are performed to realize these objectives. From the cause-effect analysis, it is found that bulge formation in the layered sheet is sensitive to forming conditions in a way that bulging can be minimized utilizing annealed material and performing ISF with larger tool diameter and step size. The bending under tension analysis reveals that the formation of bulge is an outgrowth of bending moment that the forming tool applies on the sheet during ISF. Furthermore, the magnitude of bending moment depending upon the forming conditions varies from 0.046 to 10.24 N·m/m and causes a corresponding change in the mean bulge height from 0.07 to 0.91 mm. The bending moment governs bulging in layered sheet through a linear law. These findings lead to a conclusion that the bulge defect can be overcome by controlling the bending moment and the formula proposed can be helpful in this regards.展开更多
1 Introduction As new exploration domain for oil and gas,reservoirs with low porosity and low permeability have become a hotspot in recent years(Li Daopin,1997).With the improvement of technology,low porosity and low
The NiAl–TiC–TiB2 composites were processed by self-propagating high-temperature synthesis(SHS) method using raw powders of Ni, Al, Ti, B4 C, TiC, and TiB2, and their microstructure and micro-hardness were investi...The NiAl–TiC–TiB2 composites were processed by self-propagating high-temperature synthesis(SHS) method using raw powders of Ni, Al, Ti, B4 C, TiC, and TiB2, and their microstructure and micro-hardness were investigated. The TiC–TiB2 in NiAl matrix, with contents from 10 to 30 wt%, emerged with the use of two methods: in situ formed and externally added. The results show that all final products are composed of three phases of NiAl, TiC, and TiB2. The microstructures of NiAl–TiC–TiB2 composites with in situ-formed TiC and TiB2 are fine, and all the three phases are distributed uniformly. The grains of NiAl matrix in the composites have been greatly refined, and the micro-hardness of NiAl increases from 381 HV100 to 779 HV100. However, the microstructures of NiAl–TiC–TiB2 composites with externally added TiC and TiB2 are coarse and inhomogeneous, with severe agglomeration of TiC and TiB2 particles. The samples containing externally added 30 wt% TiC–TiB2attain the micro-hardness of 485 HV100. The microstructure evolution and fracture mode of the two kinds of NiAl–TiC–TiB2 composites are different.展开更多
Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs,two kinds of natural gas...Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs,two kinds of natural gases with different relationships between C_(2)/C_(3)and C_(1)/C_(2),C_(2)/C_(3)and C_(1)/C_(3),C_(2)/C_(3)and 100×C_(1)/(C_(1)-C5)were identified in the Tarim Basin,and proposed further by the authors.The relationship charts of C_(2)/C_(3)and C_(1)/C_(2),C_(2)/C_(3)and C_(1)/C_(3),C_(2)/C_(3)and 100×C_(1)/(C_(1)-C_(5))can be used to effectively distinguish oil-cracking gas from kerogen-cracking gas.Petro-leum geological analysis of the oil-cracking gas reservoirs showed that the distribution of oil-cracking gas is mostly related with deep-seated faults or faults with a large fault throw,and the burial depth of paleo-oil reservoir is rela-tively high;crude oil-cracking gas resources have been evaluated by using both forward and inversion methods.The plots of C_(2)/C_(3)vs.C_(1)/C_(2),C_(2)/C_(3)vs.C_(1)/C_(3),and C_(2)/C_(3)vs.100×C_(1)/(C_(1)-C_(5))were used to distinguish between oil-crack-ing gas and kerogen-cracking gas,and estimate the mixed ratios of the two kinds of natural gases in the main gas reservoirs of the platform area.展开更多
In the present study,numerical simulation method was used to analyze the conditions,resulting in the formation of blisters during solution heat treatment.Blister formation is considered to occur as the height of blist...In the present study,numerical simulation method was used to analyze the conditions,resulting in the formation of blisters during solution heat treatment.Blister formation is considered to occur as the height of blister reaches 5μm.The effects of process parameters on the magnitude of the forming temperatures of blister(Tb)were discussed.Two kinds of Al-Si alloys were used to analyze the effect of mechanical properties of the alloys on blister forming conditions.Simulation results show that decreasing the initial pressure in gas hole,the long-short axial ratio of gas hole and the size of gas hole,as well as increasing the depth of gas hole and the strength of alloy are helpful to increase the critical temperature of forming blister.These conclusions are helpful for casters to understand the conditions controlling blister formation during solution heat treatment and take actions to avoid the blister defects.展开更多
1 Introduction Currently,all six different continents have discovered potash deposits and potash-bearing salt lake saline water.However,the distribution is extremely uneven,which is mostly concentrated in Canada,Russi...1 Introduction Currently,all six different continents have discovered potash deposits and potash-bearing salt lake saline water.However,the distribution is extremely uneven,which is mostly concentrated in Canada,Russia,Middle-Asia and展开更多
The effect of the deformation condition on the axial compressive precision forming process of tube with curling die was investigated by using a rigid-plastic FEM. The results show that the forming accuracy depends mai...The effect of the deformation condition on the axial compressive precision forming process of tube with curling die was investigated by using a rigid-plastic FEM. The results show that the forming accuracy depends mainly on geometric condition rp/d0, little on tube material properties and friction condition; the relative gap △/2rp of double-walled tubes obtained decreases with Increasing rp/d0, and there is a parameter k for a given to/do or rp/t0, when rp/d0 >k, △/2rp< 1, otherwise △/2rp>1.展开更多
We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based ...We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based on the 1959 van der Waals--Platteeuw model, angle-dependent ab initio intermolecular potentials, the DMW-92 equation of state and Pitzer theory. Comparison with all available experimental data shows that this model can accurately predict the effects of temperature, pressure, salinity and capillary radius on the formation and dissociation of methane hydrate. Online calculations of the p-T conditions for the formation of methane hydrate at given salinities and pore sizes of sediments are available on: www.geochem-model.org/models.htm.展开更多
Electron probe micro-analysis(EPMA)and scanning electron microscopy(SEM)equipped with energy dispersive spectrometry(EDS)have been used to investigate the principal ore minerals and coexisting metallic mineral inclusi...Electron probe micro-analysis(EPMA)and scanning electron microscopy(SEM)equipped with energy dispersive spectrometry(EDS)have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit,which consists of a high-sulfidation epithermal system(HSES)and a porphyry system(PS).Molybdenite,chalcopyrite,bornite,tennantite,enargite,digenite,anilite,covellite,and tetrahedrite have been identified by EPMA.Intergrowth,cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite±bornite±hematite(stage 2),then bornite±Cu-sulfides±Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides±Cu-sulfides(stage 4).Pyrite is developed throughout all the stages.Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite,chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier.The pervasive binary equilibrium phases of calaverite and altaite constrain fin the range from~-6.5 to~-8 and f<-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly,the dominance of chalcopyrite in the PS,with minor bornite,suggests relatively high temperature conditions.These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems.展开更多
基金granted by the Xinjiang Geological Exploration Fund。
文摘The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it is of great scientific significance to study the accumulation conditions of oil sand in different strata and mining areas of the Junggar Basin.Through a large number of field investigations,drilling verification and sampling tests,it is found that the oil sand in the region covers an area of 2000 km^(2),with shallow and thick reservoir,and predicted resource of 180 million tons.The oil sand resources are mainly distributed in four geological strata,namely the Middle Triassic Karamay Formation,Early Jurassic Badaowan Formation,Late Jurassic Qigu Formation,and Early Cretaceous Qingshuihe Formation.The reservoir is mainly composed of sandstone with high porosity and permeability,and the reservoir space is mainly intergranular pores with a medium average oil content.The oil sand deposit in the region is a typical destructive oil reservoir.The crude oil in the oil sand layer is degraded and thickened from the deep to the shallow,the content of saturated hydrocarbon decreased,and the content of aromatic hydrocarbon,non-hydrocarbon and asphaltene increased.The oil source comes from the deep Permian hydrocarbon-generating depression.Unconformities,faults and marginal fan delta-braided river depositional systems constitute effective migration and storage systems.Caprocks of the Upper Triassic Baijiantan Formation,Lower Jurassic Sangonghe Formation and Lower Cretaceous Hutubihe Formation were formed by three large scale lake transgressions.The Indosinian,Yanshan and Late Yanshan movements are the main driving forces for the migration of deep oil and gas to the shallow edge to form oil sand deposits.It is considered that the oil sand in the northwestern margin of Junggar Basin is of a slope complex migration type.
基金funded by the National Science and technology Major Project(2008ZX05001)
文摘The exploration targets in the Kuqa Depression at present are mainly structure traps in Cretaceous-Tertiary.Due to the complexity of mountain distribution and reservoir forming conditions, the exploration of Jurassic in the eastern Kuqa Depression has been in a state of semi-stagnation since the discovery of the Yinan-2 gas reservoir.According to the concept and theory of 'continuous petroleum reservoirs' and the re-analysis of the forming conditions of the Yinan-2 gas reservoir and regional natural gas in the eastern Kuqa Depression,it is believed that the deep Jurassic has good natural gas accumulation conditions as well as geological conditions for forming continuous tight gas reservoirs.The boundary of the Yinan-2 gas reservoir is not controlled by a structural spillpoint.The downdip part of the structure is dominated by gas,while the hanging wall of the fault is filled by water and forming obvious inverted gas and water.The gas reservoir has the normal temperature and ultrahigh pressure which formed in the near source or inner-source.All of these characteristics indicate that the Yinan-2 gas reservoir is different from conventional gas reservoirs.The deep Jurassic in the eastern Kuqa Depression has multisets of source-reservoir-cap assemblages,which comprise interbedded sandstones and mudstones.These assemblages are characterized by a self-generation,self-preserving and self-coverage model.Reservoir sandstones and coal measure mudstones are interbedded with each other at a large scale.As the source rocks,Triassic-Jurassic coal measure mudstones distribute continuously at a large scale and can generate and expel hydrocarbon.Source rocks contact intimately with the overlying sandstone reservoirs.During the late stage of hydrocarbon expulsion,natural gas charged continuously and directly into the neighboring reservoirs.Petroleum migrated mainly in a vertical direction over short distances.With ultra-high pressure and strong charging intensity,natural gas accumulated continuously.Reservoirs are dominated by sandstones of braided delta facies.The sand bodies distribute continuously horizontal.With low porosity and low permeability,the reservoirs are featured by strong heterogeneity.It is hypothesized that the sandstones of the interior depression tend to be relatively tight with increasing depth and structure stress weakness.Thus,it is predicted that continuous tight gas reservoirs of ultra-high pressure may exist in the deep formations of the eastern and even the whole Kuqa Depression.So,it is worth evaluating the exploration potential.
基金the financial help and technical support that King Abdulaziz University provided for this research work
文摘Bulge is a defect that causes geometrical inaccuracy and premature failure in the innovative incremental sheet forming (ISF) process. This study has two-fold objectives:(1) knowing the bulging behavior of a Cu clad tri-layered steel sheet as a function of forming conditions, and (2) analyzing the bending effect on bulging in an attempt to identify the associated mechanism. A series of ISF tests and bending analysis are performed to realize these objectives. From the cause-effect analysis, it is found that bulge formation in the layered sheet is sensitive to forming conditions in a way that bulging can be minimized utilizing annealed material and performing ISF with larger tool diameter and step size. The bending under tension analysis reveals that the formation of bulge is an outgrowth of bending moment that the forming tool applies on the sheet during ISF. Furthermore, the magnitude of bending moment depending upon the forming conditions varies from 0.046 to 10.24 N·m/m and causes a corresponding change in the mean bulge height from 0.07 to 0.91 mm. The bending moment governs bulging in layered sheet through a linear law. These findings lead to a conclusion that the bulge defect can be overcome by controlling the bending moment and the formula proposed can be helpful in this regards.
基金funded by Major Projects of National Science and Technology "Large Oil and Gas Fields and CBM development"(Grant No. 2016ZX05027)
文摘1 Introduction As new exploration domain for oil and gas,reservoirs with low porosity and low permeability have become a hotspot in recent years(Li Daopin,1997).With the improvement of technology,low porosity and low
基金financially supported by the National Natural Science Foundation of China(Nos.51072104 and 51272141)Tai Shan Scholars Project of Shandong Province,China(No.ts20110828)
文摘The NiAl–TiC–TiB2 composites were processed by self-propagating high-temperature synthesis(SHS) method using raw powders of Ni, Al, Ti, B4 C, TiC, and TiB2, and their microstructure and micro-hardness were investigated. The TiC–TiB2 in NiAl matrix, with contents from 10 to 30 wt%, emerged with the use of two methods: in situ formed and externally added. The results show that all final products are composed of three phases of NiAl, TiC, and TiB2. The microstructures of NiAl–TiC–TiB2 composites with in situ-formed TiC and TiB2 are fine, and all the three phases are distributed uniformly. The grains of NiAl matrix in the composites have been greatly refined, and the micro-hardness of NiAl increases from 381 HV100 to 779 HV100. However, the microstructures of NiAl–TiC–TiB2 composites with externally added TiC and TiB2 are coarse and inhomogeneous, with severe agglomeration of TiC and TiB2 particles. The samples containing externally added 30 wt% TiC–TiB2attain the micro-hardness of 485 HV100. The microstructure evolution and fracture mode of the two kinds of NiAl–TiC–TiB2 composites are different.
基金the National Natural Science Foundation of China(Grant No.40973041)
文摘Based on the geochemical characteristics of oil-cracking gas and kerogen-cracking gas revealed by simu-lation experiments and the chemical composition of natural gases in actual gas reservoirs,two kinds of natural gases with different relationships between C_(2)/C_(3)and C_(1)/C_(2),C_(2)/C_(3)and C_(1)/C_(3),C_(2)/C_(3)and 100×C_(1)/(C_(1)-C5)were identified in the Tarim Basin,and proposed further by the authors.The relationship charts of C_(2)/C_(3)and C_(1)/C_(2),C_(2)/C_(3)and C_(1)/C_(3),C_(2)/C_(3)and 100×C_(1)/(C_(1)-C_(5))can be used to effectively distinguish oil-cracking gas from kerogen-cracking gas.Petro-leum geological analysis of the oil-cracking gas reservoirs showed that the distribution of oil-cracking gas is mostly related with deep-seated faults or faults with a large fault throw,and the burial depth of paleo-oil reservoir is rela-tively high;crude oil-cracking gas resources have been evaluated by using both forward and inversion methods.The plots of C_(2)/C_(3)vs.C_(1)/C_(2),C_(2)/C_(3)vs.C_(1)/C_(3),and C_(2)/C_(3)vs.100×C_(1)/(C_(1)-C_(5))were used to distinguish between oil-crack-ing gas and kerogen-cracking gas,and estimate the mixed ratios of the two kinds of natural gases in the main gas reservoirs of the platform area.
基金financially supported by the National Key Research and Development Program of China (No.2016YFB0301003)Shenzhen Science and Technology Innovation Commission under Projects (Nos.JCYJ20170307110223452,KQJSCX20170328155402991 and KQTD20170328154443162)。
文摘In the present study,numerical simulation method was used to analyze the conditions,resulting in the formation of blisters during solution heat treatment.Blister formation is considered to occur as the height of blister reaches 5μm.The effects of process parameters on the magnitude of the forming temperatures of blister(Tb)were discussed.Two kinds of Al-Si alloys were used to analyze the effect of mechanical properties of the alloys on blister forming conditions.Simulation results show that decreasing the initial pressure in gas hole,the long-short axial ratio of gas hole and the size of gas hole,as well as increasing the depth of gas hole and the strength of alloy are helpful to increase the critical temperature of forming blister.These conclusions are helpful for casters to understand the conditions controlling blister formation during solution heat treatment and take actions to avoid the blister defects.
基金funded by National Program on Key Basic Research Project of China - 973 Program" Potash formation mechanism, conditions and late evolution in Ordovician ancient epicontinental sea basin, Erdos" (No. 2011CB403001)China Geological survey work Program - " Potash resources investigation and evaluation in Northern Shaanxi Ordovician Salt Basin " (No. 1212011085516)
文摘1 Introduction Currently,all six different continents have discovered potash deposits and potash-bearing salt lake saline water.However,the distribution is extremely uneven,which is mostly concentrated in Canada,Russia,Middle-Asia and
基金The authors would like to thank NSFC for support toenable the performing of this research (No. 59775055).
文摘The effect of the deformation condition on the axial compressive precision forming process of tube with curling die was investigated by using a rigid-plastic FEM. The results show that the forming accuracy depends mainly on geometric condition rp/d0, little on tube material properties and friction condition; the relative gap △/2rp of double-walled tubes obtained decreases with Increasing rp/d0, and there is a parameter k for a given to/do or rp/t0, when rp/d0 >k, △/2rp< 1, otherwise △/2rp>1.
文摘We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based on the 1959 van der Waals--Platteeuw model, angle-dependent ab initio intermolecular potentials, the DMW-92 equation of state and Pitzer theory. Comparison with all available experimental data shows that this model can accurately predict the effects of temperature, pressure, salinity and capillary radius on the formation and dissociation of methane hydrate. Online calculations of the p-T conditions for the formation of methane hydrate at given salinities and pore sizes of sediments are available on: www.geochem-model.org/models.htm.
基金supported by Public Science and Technology Research Funds Projects,Ministry of Land Resources of the People's Republic of China(project No.201511017 and 201511022-05)the Basic Research Fund of Chinese Academy of Geological Sciences(Grant No.YYWF201608)+1 种基金the National Natural Science Foundationof China(Grant No.41402178)Geological Survey Project of the China Geological Survey(project 1212011405040)
文摘Electron probe micro-analysis(EPMA)and scanning electron microscopy(SEM)equipped with energy dispersive spectrometry(EDS)have been used to investigate the principal ore minerals and coexisting metallic mineral inclusions in polished thin sections from the Tiegelongnan deposit,which consists of a high-sulfidation epithermal system(HSES)and a porphyry system(PS).Molybdenite,chalcopyrite,bornite,tennantite,enargite,digenite,anilite,covellite,and tetrahedrite have been identified by EPMA.Intergrowth,cross-cutting and replacement relationships between the metallic minerals suggest that molybdenite formed first(stage 1),followed by chalcopyrite±bornite±hematite(stage 2),then bornite±Cu-sulfides±Cu-Fe-sulfoarsenides(stage 3),and lastly Cu-Fe-sulfoarsenides±Cu-sulfides(stage 4).Pyrite is developed throughout all the stages.Droplet-like inclusions of Au-Te minerals commonly occur in tennantite but not in the other major sulfides(molybdenite,chalcopyrite and bornite),implying that tennantite is the most important Au telluride carrier.The pervasive binary equilibrium phases of calaverite and altaite constrain fin the range from~-6.5 to~-8 and f<-11.The intergrowth of bornite and chalcopyrite and the conversion from bornite to digenite suggest fluctuated and relatively low precipitation temperature conditions in the HSES relative to the PS.Contrastingly,the dominance of chalcopyrite in the PS,with minor bornite,suggests relatively high temperature conditions.These new results are important for further understanding the mineral formation processes superimposed by HSES and PS systems.