In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings ...In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings on AZ31B magnesium alloy.The main novelty is the successful incorporation of calcium,zinc,manganese and phosphate species into the Flash-PEO coatings via a precursor layer rather than using the electrolyte.The precursor also led to longer lasting and more intense discharges during the PEO process,resulting in increased pore size.Corrosion studies revealed similar short-term performance for all coatings,with impedance modulus at low frequencies above 10^(7)Ωcm^(2),and slightly better performance for the SiPF-based coating.Nonetheless,the enlarged pores in the PEO coatings functionalized with the PCC precursor compromised the effectiveness of self-healing mechanisms by creating diffusion pathways for corrosive species,leading to earlier failure.These phenomena were effectively monitored by recording the open circuit potential during immersion in 0.5 wt.%NaCl solution.In summary,this study demonstrates that conversion coatings are a viable option for the functionalization of PEO coatings on magnesium alloys,as they allow for the incorporation of cationic and other species.However,it is crucial to maintain a small pore size to facilitate effective blockage through self-healing mechanisms.展开更多
Among natural disasters,flash floods are the most destructive events,causing signif-icant damage to the economy and posing a serious threat to human life and property.Comprehensive risk assessment of these sudden floo...Among natural disasters,flash floods are the most destructive events,causing signif-icant damage to the economy and posing a serious threat to human life and property.Comprehensive risk assessment of these sudden floods is a key strategy to mitigate their impact.Accurate analysis of flash flood hazards can greatly enhance prevention efforts and inform critical decision-making processes,ultimately improving our ability to protect communities from these fast-onset disasters.This study analyzed the driving forces of flash flood disaster-causing factors in Heilongjiang Province.Meanwhile,nine different categories of variables affecting the occurrence of flash floods were selected,and the degree of influence of each driving factor on flash floods was quantitatively analyzed,and the driving force analysis of the driving factors of flash floods in Hei-longjiang Province was carried out by using the geographic probe model.This paper employs an uncertainty approach,utilizing a statistical-based interval weight deter-mination technique for evaluation indices and a two-dimensional information-based interval number sorting method.These methodologies are combined to construct a comprehensive flash flood risk assessment model.On this basis,the model was implemented in six regions within China's Heilongjiang province to evaluate and prioritize flash flood risks.The resulting risk ranking for these areas was as follows:Bayan≻Shuangcheng≻Boli≻Suibin≻Hailun≻Yian.The findings demonstrate that the interval number-based evaluation method effectively handles uncertainty,providing a more reliable risk grading system.This approach,by leveraging modern scientific advances and risk quantification techniques,is crucial for improving disaster management and mitigating flash flood impacts.展开更多
Rainstorm-induced flood hazards in mountainous areas often result in complex cascading effects by interacting with environmental and human systems.However,traditional studies typically categorize them simply as clearw...Rainstorm-induced flood hazards in mountainous areas often result in complex cascading effects by interacting with environmental and human systems.However,traditional studies typically categorize them simply as clearwater floods or debris floods/flows,overlooking their evolutionary characteristics and compound impacts.This study presents a novel classification-based approach to investigate the formation and destructive mechanisms of a catastrophic composite disaster of flash flood and debris flow in the Dayao Gully(DYG)catchment in Hanyuan County,Sichuan Province,China.The event resulted in 14 fatalities,25 missing persons,and extensive infrastructure damage.Through comprehensive field investigations and multi-method analysis,three distinct disaster zones were identified with different magnitudes and impacts:(1)a clearwater flood disaster region with minimal geomorphological changes under a 5-year return period rainfall;(2)a debris flood disaster region triggered by a 30-year return period rainfall,leading to intense sediment transport with a total deposit volume of 52,511 m^(3);and(3)a sediment-induced flood disaster region characterized by significant riverbed aggradation and infrastructure destruction due to sediment-induced blockage effects.The results reveal that the cascading characteristics of this composite disaster were primarily driven by intense rainfall,enhanced sediment transport motivated by supracritical shear stress,and interactions with human infrastructure(e.g.,bridges and buildings).This classification-based approach provides a quantitative assessment of spatial characteristics of cascading flood disasters,offering new insights into their evolutionary characteristics and highlighting the necessity for targeted disaster mitigation strategies in sedimentprone mountainous regions.展开更多
基金support of the PID2021-124341OB-C22/AEI/10.13039/501100011033/FEDER,UE(MICIU)J.M.Vega also acknowledges the Grant RYC2021-034384-I funded by MICIU/AEI/10.13039/501100011033 and by“European Union Next Generation EU/PRTR”.
文摘In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings on AZ31B magnesium alloy.The main novelty is the successful incorporation of calcium,zinc,manganese and phosphate species into the Flash-PEO coatings via a precursor layer rather than using the electrolyte.The precursor also led to longer lasting and more intense discharges during the PEO process,resulting in increased pore size.Corrosion studies revealed similar short-term performance for all coatings,with impedance modulus at low frequencies above 10^(7)Ωcm^(2),and slightly better performance for the SiPF-based coating.Nonetheless,the enlarged pores in the PEO coatings functionalized with the PCC precursor compromised the effectiveness of self-healing mechanisms by creating diffusion pathways for corrosive species,leading to earlier failure.These phenomena were effectively monitored by recording the open circuit potential during immersion in 0.5 wt.%NaCl solution.In summary,this study demonstrates that conversion coatings are a viable option for the functionalization of PEO coatings on magnesium alloys,as they allow for the incorporation of cationic and other species.However,it is crucial to maintain a small pore size to facilitate effective blockage through self-healing mechanisms.
基金Basic Scientific Research Expense Project of IWHR-Extreme rainstorm development trends and prediction techniques,Grant/Award Number:JZ0145B142024National Natural Science Foundation of China,Grant/Award Number:42271095。
文摘Among natural disasters,flash floods are the most destructive events,causing signif-icant damage to the economy and posing a serious threat to human life and property.Comprehensive risk assessment of these sudden floods is a key strategy to mitigate their impact.Accurate analysis of flash flood hazards can greatly enhance prevention efforts and inform critical decision-making processes,ultimately improving our ability to protect communities from these fast-onset disasters.This study analyzed the driving forces of flash flood disaster-causing factors in Heilongjiang Province.Meanwhile,nine different categories of variables affecting the occurrence of flash floods were selected,and the degree of influence of each driving factor on flash floods was quantitatively analyzed,and the driving force analysis of the driving factors of flash floods in Hei-longjiang Province was carried out by using the geographic probe model.This paper employs an uncertainty approach,utilizing a statistical-based interval weight deter-mination technique for evaluation indices and a two-dimensional information-based interval number sorting method.These methodologies are combined to construct a comprehensive flash flood risk assessment model.On this basis,the model was implemented in six regions within China's Heilongjiang province to evaluate and prioritize flash flood risks.The resulting risk ranking for these areas was as follows:Bayan≻Shuangcheng≻Boli≻Suibin≻Hailun≻Yian.The findings demonstrate that the interval number-based evaluation method effectively handles uncertainty,providing a more reliable risk grading system.This approach,by leveraging modern scientific advances and risk quantification techniques,is crucial for improving disaster management and mitigating flash flood impacts.
基金supported by National Natural Science Foundation of Joint Fund for Changjiang River Water Science Research(U2340201)National Natural Science Foundation of China(52239006)Natural Science Foundation of Sichuan Province(2024NSFSC0005).
文摘Rainstorm-induced flood hazards in mountainous areas often result in complex cascading effects by interacting with environmental and human systems.However,traditional studies typically categorize them simply as clearwater floods or debris floods/flows,overlooking their evolutionary characteristics and compound impacts.This study presents a novel classification-based approach to investigate the formation and destructive mechanisms of a catastrophic composite disaster of flash flood and debris flow in the Dayao Gully(DYG)catchment in Hanyuan County,Sichuan Province,China.The event resulted in 14 fatalities,25 missing persons,and extensive infrastructure damage.Through comprehensive field investigations and multi-method analysis,three distinct disaster zones were identified with different magnitudes and impacts:(1)a clearwater flood disaster region with minimal geomorphological changes under a 5-year return period rainfall;(2)a debris flood disaster region triggered by a 30-year return period rainfall,leading to intense sediment transport with a total deposit volume of 52,511 m^(3);and(3)a sediment-induced flood disaster region characterized by significant riverbed aggradation and infrastructure destruction due to sediment-induced blockage effects.The results reveal that the cascading characteristics of this composite disaster were primarily driven by intense rainfall,enhanced sediment transport motivated by supracritical shear stress,and interactions with human infrastructure(e.g.,bridges and buildings).This classification-based approach provides a quantitative assessment of spatial characteristics of cascading flood disasters,offering new insights into their evolutionary characteristics and highlighting the necessity for targeted disaster mitigation strategies in sedimentprone mountainous regions.
