Flash Joule heating(FJH),as a high-efficiency and low-energy consumption technology for advanced materials synthesis,has shown significant potential in the synthesis of graphene and other functional carbon materials.B...Flash Joule heating(FJH),as a high-efficiency and low-energy consumption technology for advanced materials synthesis,has shown significant potential in the synthesis of graphene and other functional carbon materials.Based on the Joule effect,the solid carbon sources can be rapidly heated to ultra-high temperatures(>3000 K)through instantaneous high-energy current pulses during FJH,thus driving the rapid rearrangement and graphitization of carbon atoms.This technology demonstrates numerous advantages,such as solvent-and catalyst-free features,high energy conversion efficiency,and a short process cycle.In this review,we have systematically summarized the technology principle and equipment design for FJH,as well as its raw materials selection and pretreatment strategies.The research progress in the FJH synthesis of flash graphene,carbon nanotubes,graphene fibers,and anode hard carbon,as well as its by-products,is also presented.FJH can precisely optimize the microstructures of carbon materials(e.g.,interlayer spacing of turbostratic graphene,defect concentration,and heteroatom doping)by regulating its operation parameters like flash voltage and flash time,thereby enhancing their performances in various applications,such as composite reinforcement,metal-ion battery electrodes,supercapacitors,and electrocatalysts.However,this technology is still challenged by low process yield,macroscopic material uniformity,and green power supply system construction.More research efforts are also required to promote the transition of FJH from laboratory to industrial-scale applications,thus providing innovative solutions for advanced carbon materials manufacturing and waste management toward carbon neutrality.展开更多
Coherent perfect absorption(CPA)and coherent perfect transmission(CPT)are two extreme states arising from the manipulation of optical fields.Generally,CPA and CPT occur under different input-field phases.Therefore,we ...Coherent perfect absorption(CPA)and coherent perfect transmission(CPT)are two extreme states arising from the manipulation of optical fields.Generally,CPA and CPT occur under different input-field phases.Therefore,we propose a scheme to realize an all-optical switch based on phase-dependent CPA–CPT conversion.In our proposal,the CPT state and the CPA state are treated as the on state and the off state,respectively.Consequently,the efficiency of this all-optical switch can reach the maximum value of 1.With the introduction of an incoherent pump field,the CPA state can be achieved under a weaker input probe field or can be converted into a CPT state.The results show that the optical switch can operate with weaker fields and can be further optimized by the application of an incoherent field.展开更多
Field-effect nanofluidic transistors(FENTs),biomimicking the structure and functionality of neuron,act as biological transistors with the ability to gate switching responses to external stimuli.The switching ratio has...Field-effect nanofluidic transistors(FENTs),biomimicking the structure and functionality of neuron,act as biological transistors with the ability to gate switching responses to external stimuli.The switching ratio has been verified to evaluate the performance of FENTs,but until recently,the response time,another crucial indicator,has been ignored.Employing finite-element method,we investigated the relationship among gate charge,switching ratio and response time by divisionally manipulating gate charge,including entrance surface and the surface of confinement space,for ion transport to optimize switching capability.The dual-split gate charge on FENTs exhibits synergistic effect on switching response.Based on the two regional gate charge on FENTs,multivalence ions in lower concentration,high aspect ratio and single channel show higher switching ratio but longer response time compared to monovalent ions.The findings highlight the necessity of balancing these two signals in FENTs and offer insights for optimizing their design and expanding applications to dual-signal-detection iontronics.展开更多
Flash droughts(FDs)develop quickly and can rapidly deplete soil moisture,posing significant threats to agriculture and pastoral systems.To investigate the spatiotemporal characteristics and development mechanisms of F...Flash droughts(FDs)develop quickly and can rapidly deplete soil moisture,posing significant threats to agriculture and pastoral systems.To investigate the spatiotemporal characteristics and development mechanisms of FDs in Inner Mongolia,China,and to assess the roles of key meteorological drivers in driving soil moisture variability,FD events were identified using root-zone soil moisture data during the growing seasons from 1982 to 2022.The results indicate the presence of five FD hotspot regions,located in the southern Alxa Plateau,the Hetao Plain in Bayannur,the northwestern Xilingol Plain,the western Liaohe River Plain,and the northern Da Hinggan Ling.Over 41 years,FDs occurred on average 7.44 events across the study area,with a mean duration of 9.17 pentads(1 pentad equals 5 days).The duration exhibited a significant increasing trend of 0.39 pentads/10 years.FD onsets primarily lasted for 2-3 pentads.During the FD development phase,precipitation and evapotranspiration decreased while temperature,potential evapotranspiration,incoming solar radiation,and vapor pressure deficit increased.The dominant meteorological drivers of FD development exhibited notable spatial heterogeneity across hotspot regions,and vapor pressure deficit consistently was the most influential factor.These findings improve the understanding of climate drivers at different stages of FD development and provide scientific support for early warning and prevention of droughts in Inner Mongolia.展开更多
Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrate...Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.展开更多
A trigger device and a triggered pseudospark switch （TPSS） were designed based on surface flashover technology, in order to meet the requirements from present pulse power technology and pulse current test technology...A trigger device and a triggered pseudospark switch （TPSS） were designed based on surface flashover technology, in order to meet the requirements from present pulse power technology and pulse current test technology such as a long lifetime, reliability in a wide voltage range, a short delay time, as well as small delay jitters. The trigger devices were made from different dielectric materials, with their permittivities from tens to thousands. The trigger characteristics of TPSS were investigated. The results indicate that the high-dielectric trigger device shows better performance and higher emitted charge of the electron emission within all adjusted parameters including the gas pressure and applied voltage. For the dielectric material with relative permittivity εr of 3460, when the gas pressure is 7 Pa, the hold-off voltage of TPSS is 28 kV, the minimum trigger switch voltage drops to 128 V, the minimum discharging delay time and delay jitter are less than 35ns and 6ns, respectively, and the reliable operation can be reached within a very large range of charging voltage, between 0.46% and 99% of its self-breakdown voltage.展开更多
Triggering characteristics of triggered vacuum switch （TVS）, including the discharge delay time, delay jitter, range of operational voltage and peak of pulsed current, are investigated. Both structure and experiment...Triggering characteristics of triggered vacuum switch （TVS）, including the discharge delay time, delay jitter, range of operational voltage and peak of pulsed current, are investigated. Both structure and experimental circuit of TVS are presented. The results indicate that TVS, as a surface flashover triggering device with high dielectric permittivity material, is with excellent triggering characteristics. When the hold-off voltage reaches 120 kV, the minimum operational voltage is 1.3 kV, and the minimum discharge delay time and jitter are 100 ns and ±10 ns, respectively. The peak current is up to 240 kA when the operational voltage reaches 100 kV. TVS can well satisfy the main demands of high voltage and current applications, and can also be used under a multi-crowbar circuit.展开更多
In this paper,the reliability of sense-switch p-channel flash is evaluated extensively.The endurance result indicates that the p-channel flash could be programmed and erased for more than 10000 cycles;the room tempera...In this paper,the reliability of sense-switch p-channel flash is evaluated extensively.The endurance result indicates that the p-channel flash could be programmed and erased for more than 10000 cycles;the room temperature read stress shows negligible influence on the p-channel flash cell;high temperature data retention at 150℃ is extrapolated to be about 5 years and 53 years corresponding to 30% and 40% degradation in the drive current,respectively.Moreover,the electrical parameters of the p-channel flash at different operation temperature are found to be less affected.All the results above indicate that the sense-switch p-channel flash is suitable to be used as the configuration cell in flash-based FPGA.展开更多
基金supported by the National Natural Science Foundation of China(52276196)the Foundation of State Key Laboratory of Coal Combustion(FSKLCCA2508)the High-level Talent Foundation of Anhui Agricultural University(rc412307).
文摘Flash Joule heating(FJH),as a high-efficiency and low-energy consumption technology for advanced materials synthesis,has shown significant potential in the synthesis of graphene and other functional carbon materials.Based on the Joule effect,the solid carbon sources can be rapidly heated to ultra-high temperatures(>3000 K)through instantaneous high-energy current pulses during FJH,thus driving the rapid rearrangement and graphitization of carbon atoms.This technology demonstrates numerous advantages,such as solvent-and catalyst-free features,high energy conversion efficiency,and a short process cycle.In this review,we have systematically summarized the technology principle and equipment design for FJH,as well as its raw materials selection and pretreatment strategies.The research progress in the FJH synthesis of flash graphene,carbon nanotubes,graphene fibers,and anode hard carbon,as well as its by-products,is also presented.FJH can precisely optimize the microstructures of carbon materials(e.g.,interlayer spacing of turbostratic graphene,defect concentration,and heteroatom doping)by regulating its operation parameters like flash voltage and flash time,thereby enhancing their performances in various applications,such as composite reinforcement,metal-ion battery electrodes,supercapacitors,and electrocatalysts.However,this technology is still challenged by low process yield,macroscopic material uniformity,and green power supply system construction.More research efforts are also required to promote the transition of FJH from laboratory to industrial-scale applications,thus providing innovative solutions for advanced carbon materials manufacturing and waste management toward carbon neutrality.
基金supported by the National Natural Science Foundation of China(Grants Nos.12304405,12275203,and 12075176)the Natural Science Foundation of Shaanxi Provincial Department of Education(Grant No.23JK0483)+2 种基金the Natural Science Basic Research Program of Shaanxi(Grant Nos.2024JC-YBMS-521 and 2024JC-YBMS-039)the 2022 Shaanxi University Youth Innovation Team Project(Grant No.K20220186)the College Students’Innovative Entrepreneurial Training Plan Program of Shaanxi(Grant No.S202410702178)。
文摘Coherent perfect absorption(CPA)and coherent perfect transmission(CPT)are two extreme states arising from the manipulation of optical fields.Generally,CPA and CPT occur under different input-field phases.Therefore,we propose a scheme to realize an all-optical switch based on phase-dependent CPA–CPT conversion.In our proposal,the CPT state and the CPA state are treated as the on state and the off state,respectively.Consequently,the efficiency of this all-optical switch can reach the maximum value of 1.With the introduction of an incoherent pump field,the CPA state can be achieved under a weaker input probe field or can be converted into a CPT state.The results show that the optical switch can operate with weaker fields and can be further optimized by the application of an incoherent field.
基金supported by the Natural Science Foundation of Guangdong Province,China (No.2025A1515011654)the National Natural Science Foundation of China (No.22090053)+3 种基金the Fundamental Research Funds for National Universities,China University of Geosciences (Wuhan)support from the program of China Scholarships Council (No.202406410155)Young Elite Scientists Sponsorship Program by CAST-Doctoral Student Special Plansupport from the S&T Special Program of Huzhou (No.2024GZ07)。
文摘Field-effect nanofluidic transistors(FENTs),biomimicking the structure and functionality of neuron,act as biological transistors with the ability to gate switching responses to external stimuli.The switching ratio has been verified to evaluate the performance of FENTs,but until recently,the response time,another crucial indicator,has been ignored.Employing finite-element method,we investigated the relationship among gate charge,switching ratio and response time by divisionally manipulating gate charge,including entrance surface and the surface of confinement space,for ion transport to optimize switching capability.The dual-split gate charge on FENTs exhibits synergistic effect on switching response.Based on the two regional gate charge on FENTs,multivalence ions in lower concentration,high aspect ratio and single channel show higher switching ratio but longer response time compared to monovalent ions.The findings highlight the necessity of balancing these two signals in FENTs and offer insights for optimizing their design and expanding applications to dual-signal-detection iontronics.
基金funded by the Inner Mongolia Autonomous Region Natural Science Foundation Youth Fund Project(Grants No.2024QN04020)A Science and technology program of Inner Mongolia Autonomous Region(Grants No.2022YFDZ0027)。
文摘Flash droughts(FDs)develop quickly and can rapidly deplete soil moisture,posing significant threats to agriculture and pastoral systems.To investigate the spatiotemporal characteristics and development mechanisms of FDs in Inner Mongolia,China,and to assess the roles of key meteorological drivers in driving soil moisture variability,FD events were identified using root-zone soil moisture data during the growing seasons from 1982 to 2022.The results indicate the presence of five FD hotspot regions,located in the southern Alxa Plateau,the Hetao Plain in Bayannur,the northwestern Xilingol Plain,the western Liaohe River Plain,and the northern Da Hinggan Ling.Over 41 years,FDs occurred on average 7.44 events across the study area,with a mean duration of 9.17 pentads(1 pentad equals 5 days).The duration exhibited a significant increasing trend of 0.39 pentads/10 years.FD onsets primarily lasted for 2-3 pentads.During the FD development phase,precipitation and evapotranspiration decreased while temperature,potential evapotranspiration,incoming solar radiation,and vapor pressure deficit increased.The dominant meteorological drivers of FD development exhibited notable spatial heterogeneity across hotspot regions,and vapor pressure deficit consistently was the most influential factor.These findings improve the understanding of climate drivers at different stages of FD development and provide scientific support for early warning and prevention of droughts in Inner Mongolia.
基金supported by the National Key R&D Program of China(2023YFA1406200)the National Natural Science Foundation of China(T2521005,12174144,12474009,12174146,and 124B2059)the Special Construction Project Fund for Shan-dong Province Taishan Scholars.
文摘Multifunctional optical responsive materials have grown increasingly pivotal in addressingthe escalating demands of sensing,detection,and anti-counterfeiting applications[1,2].These materials exhibit distinct visible optical variations upon exposure to external stimuli,such as pressure,temperature,light,solvents,pH fluctuations,or mechanical force.Fluorescent sensing and anti-counterfeiting technologies leveraging these optical responses have emerged as highly promising solutions.
基金Project(52373065)supported by the National Natural Science Foundation of ChinaProject(2220004002898)supported by the Zhuhai Industry University Research Cooperation and Basic and Applied Research Projects,China。
文摘Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.
文摘A trigger device and a triggered pseudospark switch （TPSS） were designed based on surface flashover technology, in order to meet the requirements from present pulse power technology and pulse current test technology such as a long lifetime, reliability in a wide voltage range, a short delay time, as well as small delay jitters. The trigger devices were made from different dielectric materials, with their permittivities from tens to thousands. The trigger characteristics of TPSS were investigated. The results indicate that the high-dielectric trigger device shows better performance and higher emitted charge of the electron emission within all adjusted parameters including the gas pressure and applied voltage. For the dielectric material with relative permittivity εr of 3460, when the gas pressure is 7 Pa, the hold-off voltage of TPSS is 28 kV, the minimum trigger switch voltage drops to 128 V, the minimum discharging delay time and delay jitter are less than 35ns and 6ns, respectively, and the reliable operation can be reached within a very large range of charging voltage, between 0.46% and 99% of its self-breakdown voltage.
基金supported by the New Century Talent Foundation of Ministry of Education of China (NCET-08-0438)
文摘Triggering characteristics of triggered vacuum switch （TVS）, including the discharge delay time, delay jitter, range of operational voltage and peak of pulsed current, are investigated. Both structure and experimental circuit of TVS are presented. The results indicate that TVS, as a surface flashover triggering device with high dielectric permittivity material, is with excellent triggering characteristics. When the hold-off voltage reaches 120 kV, the minimum operational voltage is 1.3 kV, and the minimum discharge delay time and jitter are 100 ns and ±10 ns, respectively. The peak current is up to 240 kA when the operational voltage reaches 100 kV. TVS can well satisfy the main demands of high voltage and current applications, and can also be used under a multi-crowbar circuit.
文摘In this paper,the reliability of sense-switch p-channel flash is evaluated extensively.The endurance result indicates that the p-channel flash could be programmed and erased for more than 10000 cycles;the room temperature read stress shows negligible influence on the p-channel flash cell;high temperature data retention at 150℃ is extrapolated to be about 5 years and 53 years corresponding to 30% and 40% degradation in the drive current,respectively.Moreover,the electrical parameters of the p-channel flash at different operation temperature are found to be less affected.All the results above indicate that the sense-switch p-channel flash is suitable to be used as the configuration cell in flash-based FPGA.
