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Magnetic Properties of Fe/RE Multilayers and Change Mechanism
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作者 李胜利 王长征 +1 位作者 王佩璇 马如璋 《Journal of Rare Earths》 SCIE EI CAS CSCD 1999年第3期203-206,共4页
Magnetic properties and microstructure of Fe/RE multilayers(thickness of Fe single layers less than or equal to 2.0 nm) both as-deposited state and after annealing( T greater than or equal to 473 K) were studied, and ... Magnetic properties and microstructure of Fe/RE multilayers(thickness of Fe single layers less than or equal to 2.0 nm) both as-deposited state and after annealing( T greater than or equal to 473 K) were studied, and the reason of the change of magnetic properties was analyzed. The Fe single layers are considered to be composed of insular Fe domains in as-deposited films. Super-paramagnetic nature of the Fe domains of small size causes the films to exhibit paramagnetism. During annealing the growth of Fe domains results in the transformation of films from paramagnetic into ferromagnetic, which leads to the increase in H-c and M-s. 展开更多
关键词 rare earths fe/re multilayer magnetic properties microstructure
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Intralayer structure reconstruction of general weighted output-coupling multilayer complex networks
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作者 Xinwei Wang Yayong Wu +1 位作者 Ying Zheng Guo-Ping Jiang 《Chinese Physics B》 2026年第2期287-299,共13页
Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to ... Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method. 展开更多
关键词 multilayer network structure reconstruction cross-layer coupling modulator output coupling
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Vertical propagation behavior of hydraulic fracture guided by radial borehole:Insight for horizontal well stimulation in multilayered reservoirs
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作者 Tengda Long Gensheng Li +10 位作者 Xiaoguang Wu Zhongwei Huang Zixiao Xie Rui Yang Xianzhi Song Shouceng Tian Haizhu Wang Naikun Hu Xiaohua Wang Xiangyang Wang Xiaoxuan Li 《International Journal of Mining Science and Technology》 2026年第2期229-249,共21页
The strong vertical discontinuities pose a fundamental challenge to optimizing stimulated reservoir volume(SRV)in multilayered reservoirs.This research proposes a radial borehole-assisted horizontal well fracturing te... The strong vertical discontinuities pose a fundamental challenge to optimizing stimulated reservoir volume(SRV)in multilayered reservoirs.This research proposes a radial borehole-assisted horizontal well fracturing technology,which is expected to achieve effective vertical stimulation and commingled production across multiple pay zones.Under different geological and engineering conditions,the vertical propagation behavior of hydraulic fractures guided by radial boreholes can be determined by adjusting the interlayered lithologies and radial borehole configurations in experimental samples.Experimental results reveal four fracture network patterns:passivated,cross-layer,skip-layer,and hybrid fractures in the radial borehole fracturing.The radial boreholes perform better fracture guiding performances in the high-brittleness interlayers,which form cross-layer and hybrid fracture networks to improve the growth height.Hydraulic fractures tend to propagate from high-strength to low-strength layers under radial borehole guidance.When radial boreholes interconnect multiple lithology layers,hydraulic fractures initiate preferentially in lower-strength zones rather than remaining confined to borehole root ends.Increased radial borehole length and diameter facilitate fracture skip-layer initiation and cross-layer propagation,while multiple borehole branches enhance fracture penetration across high-strength interlayers.Radial boreholes with inclination angles below 30°enhance fracture height by generating cross-layer and hybrid fracture networks.Furthermore,an inter-borehole phase angle of less than 180°facilitates single-wing fracture cross-layer propagation.Fracture height is primarily governed by radial borehole length,followed by quantity,inclination angle,and diameter.Based on the geometric similarity criteria,the recommended parameters for radial borehole-assisted fracturing in a 5 1/2-inch horizontal well include a length>15 m,an inclination angle<30°,and a diameter>52 mm to ensure effective stimulation across three or more pay zones.Finally,the field-scale numerical model was developed to simulate the optimized radial borehole fracturing and demonstrate the technical superiority.These findings are expected to provide an in-depth understanding of the effective stimulation in multilayered reservoirs. 展开更多
关键词 multilayered reservoirs Radial borehole fracturing Interlayered lithologies Radial borehole configurations Field-scale numerical model
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Electron doping in FeSe monolayer and multilayer via metal phthalocyanine adsorption:A first-principles investigation
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作者 Fangyu Yang Yan-Fang Zhang +1 位作者 Peixuan Li Shixuan Du 《Chinese Physics B》 2025年第11期236-240,共5页
Electron doping has been established as an effective method to enhance the superconducting transition temperature and superconducting energy gap of FeSe thin films on strontium titanate(SrTiO_(3))substrates.Previous s... Electron doping has been established as an effective method to enhance the superconducting transition temperature and superconducting energy gap of FeSe thin films on strontium titanate(SrTiO_(3))substrates.Previous studies have demonstrated that electron/hole doping can be achieved through the adsorption of metal phthalocyanine(MPc,M=Co,Cu,Mn,Fe,and Ni)molecules on surfaces.This work explores the electron doping induced by the adsorption of MPc molecules,specifically cobalt phthalocyanine(CoPc)and copper phthalocyanine(CuPc),onto FeSe monolayer and multilayers.Utilizing first-principles calculations based on density functional theory,we demonstrate that charge rearrangement occurs when MPc molecules adsorb on the FeSe substrate,contributing to an accumulation of electrons at the interface.In the CoPc/FeSe systems,the electron accumulation increases with the layer number of FeSe substrate,converging for substrates with 3-5 layers.The analysis of the integrated planar charge difference up to the position with zero integrated charge transfer reveals that all the five MPc molecules donate electrons to the uppermost FeSe layer.The electron donation suggests that MPc adsorption can be a promising strategy to modulate the superconductivity of FeSe layers. 展开更多
关键词 metal-phthalocyanine multilayer feSe electron doping INTERFACES
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Effects of information and policy regulation on green behavior propagation in multilayer networks: Modeling, analysis,and optimal allocation
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作者 Xian-Li Sun Ling-Hua Zhang 《Chinese Physics B》 2025年第6期635-646,共12页
As the economy grows, environmental issues are becoming increasingly severe, making the promotion of green behavior more urgent. Information dissemination and policy regulation play crucial roles in influencing and am... As the economy grows, environmental issues are becoming increasingly severe, making the promotion of green behavior more urgent. Information dissemination and policy regulation play crucial roles in influencing and amplifying the spread of green behavior across society. To this end, a novel three-layer model in multilayer networks is proposed. In the novel model, the information layer describes green information spreading, the physical contact layer depicts green behavior propagation, and policy regulation is symbolized by an isolated node beneath the two layers. Then, we deduce the green behavior threshold for the three-layer model using the microscopic Markov chain approach. Moreover, subject to some individuals who are more likely to influence others or become green nodes and the limitations of the capacity of policy regulation, an optimal scheme is given that could optimize policy interventions to most effectively prompt green behavior.Subsequently, simulations are performed to validate the preciseness and theoretical results of the new model. It reveals that policy regulation can prompt the prevalence and outbreak of green behavior. Then, the green behavior is more likely to spread and be prevalent in the SF network than in the ER network. Additionally, optimal allocation is highly successful in facilitating the dissemination of green behavior. In practice, the optimal allocation strategy could prioritize interventions at critical nodes or regions, such as highly connected urban areas, where the impact of green behavior promotion would be most significant. 展开更多
关键词 green behavior propagation multilayer networks information dissemination optimal allocation
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Compact Integrated Lumped-Element Bandpass Filter Loaded with Defected Ground Structure Based on Multilayer Liquid Crystal Polymer Substrate
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作者 LIU Weihong CHEN Yuan +1 位作者 HUANG Qian LIU Qingran 《Journal of Shanghai Jiaotong university(Science)》 2025年第2期227-232,共6页
Design of a miniaturized lumped-element bandpass filter in multilayer liquid crystal polymer technology is proposed.Fractional bandwidth of the bandpass filter is 20%,operating at a center frequency of 500 MHz.In orde... Design of a miniaturized lumped-element bandpass filter in multilayer liquid crystal polymer technology is proposed.Fractional bandwidth of the bandpass filter is 20%,operating at a center frequency of 500 MHz.In order to further reduce the size and improve the performance of the proposed filter,defected ground structure(DGS)has been implemented in the filter.Based on this structure,the volume of the inductor is reduced by 60%eficiently compared with the inductor without DGS,and the Q-factor is increased up to 257%compared with the traditional multilayer spiral inductor.The measured results indicate that the designed filter has a very sharp stopband,an insertion loss of 2.3dB,and a return loss of 18.6dB in the passband.The whole volume of the fabricated filter is 0.032入_(g)×0.05入_(g)×0.00075入_(g),where Ag is the guided wavelength of the center frequency.The proposed filter is easily integrated into radio-frequency/microwave circuitry at a low manufacturing cost,especially wireless communication. 展开更多
关键词 multilayer liquid crystal polymer defected ground structure bandpass filter MINIATURIZATION lumped element
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Core-shell nickel@copper nanowires associated with multilayered gradient architecture design towards excellent absorption-dominant electromagnetic interference shielding
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作者 Peng Ai Xiaoping Mai +1 位作者 Bai Xue Lan Xie 《Journal of Materials Science & Technology》 2025年第27期21-31,共11页
Exploiting high-performance absorption-dominant electromagnetic interference(EMI)shielding composites is urgently desired yet challenging for minimizing secondary electromagnetic radiation pollution.Herein,a nickel(Ni... Exploiting high-performance absorption-dominant electromagnetic interference(EMI)shielding composites is urgently desired yet challenging for minimizing secondary electromagnetic radiation pollution.Herein,a nickel(Ni)shell was in-situ grown on a copper nanowires(CuNWs)core to greatly improve the stability of CuNWs,while maintaining excellent electrical conductivity.Afterward,Ni nanowires/Ni@Cu nanowires/graphite paper/waterborne polyurethane(NiNWs/Ni@CuNWs/graphite paper/WPU,n Ni-m Ni@Cu-G)composite foams with the multilayered gradient architectures were fabricated by a facile multi-step freeze-casting method.In the resultant composite foams,the lowly conductive porous NiNWs/WPU layer plays a role as the impedance matching layer,the moderately conductive porous Ni@CuNWs/WPU layer acts as the transition layer,and the highly conductive graphite paper layer serves as the reflection layer.Arising from the rational layout of multilayered gradient magnetic-electrical networks,n Ni-m Ni@Cu-G foam holds the superior averaged total EMI shielding effectiveness(EMI SET)of 75.2 dB and optimal absorption coefficient(A)of 0.93 at the incident direction from NiNWs/WPU layer,suggesting the dominant absorption in EMI shielding mechanism and efficiently alleviating the secondary electromagnetic pollution.Furthermore,n Ni-m Ni@Cu-G foam also exhibits fascinating compressive properties with a compressive strength of 49.3 kPa,which is essential for its practical application.This multilayered gradient architecture design provides valuable insight into high-efficiently constructing absorption-dominant EMI shielding composites. 展开更多
关键词 Core-shell structure multilayered gradient architecture Nickel@copper nanowire Absorption dominance Electromagnetic interference shielding
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MFR-YOLOv10:Object detection in UAV-taken images based on multilayer feature reconstruction network
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作者 Mengchu TIAN Meiji CUI +2 位作者 Zhimin CHEN Yingliang MA Shaohua YU 《Chinese Journal of Aeronautics》 2025年第11期346-364,共19页
When detecting objects in Unmanned Aerial Vehicle(UAV)taken images,large number of objects and high proportion of small objects bring huge challenges for detection algorithms based on the You Only Look Once(YOLO)frame... When detecting objects in Unmanned Aerial Vehicle(UAV)taken images,large number of objects and high proportion of small objects bring huge challenges for detection algorithms based on the You Only Look Once(YOLO)framework,rendering them challenging to deal with tasks that demand high precision.To address these problems,this paper proposes a high-precision object detection algorithm based on YOLOv10s.Firstly,a Multi-branch Enhancement Coordinate Attention(MECA)module is proposed to enhance feature extraction capability.Secondly,a Multilayer Feature Reconstruction(MFR)mechanism is designed to fully exploit multilayer features,which can enrich object information as well as remove redundant information.Finally,an MFR Path Aggregation Network(MFR-Neck)is constructed,which integrates multi-scale features to improve the network's ability to perceive objects of var-ying sizes.The experimental results demonstrate that the proposed algorithm increases the average detection accuracy by 14.15%on the Vis Drone dataset compared to YOLOv10s,effectively enhancing object detection precision in UAV-taken images. 展开更多
关键词 Object detection YOLOv10 Multi-branch enhancement coordinate attention multilayer feature reconstruction mechanism UAV-taken images
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Two-step growth of 4-inch multilayer MoS_(2) wafers
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作者 Yang-Kun Zhang Yu-Chen Wang +3 位作者 Wei Yang Dong-Xia Shi Luo-Jun Du Guang-Yu Zhang 《Chinese Physics B》 2025年第6期216-222,共7页
Molybdenum disulfide(MoS_(2)) is an emerging two-dimensional(2D) semiconductor and has great potential for highend applications beyond the traditional silicon-based electronics. Compared to the monolayers, multilayer ... Molybdenum disulfide(MoS_(2)) is an emerging two-dimensional(2D) semiconductor and has great potential for highend applications beyond the traditional silicon-based electronics. Compared to the monolayers, multilayer MoS_(2) has improved electron mobility and current density, and therefore provides a more promising platform in terms of thin-film transistors, flexible electronic devices, etc. However, the synthesis of large-area, high-quality multilayer MoS_(2) films with controlled layer number remains a challenge. Here, we develop a two-step oxygen-assisted chemical vapor deposition(OA-CVD) methodology for the synthesis of 4-inch MoS_(2) films from monolayer to trilayer on sapphire substrates. The influence of critical growth parameters on the growth of multilayer MoS_(2) is systematically explored, such as the evaporation temperature of MoO_(3) and the flow rate of O_(2). Flexible field-effect transistor(FET) devices fabricated from bilayer/trilayer MoS_(2) show substantial improvements in mobility compared with flexible FETs based on monolayer films. 展开更多
关键词 two-step growth oxygen-assisted chemical vapor deposition multilayer MoS_(2) flexible field-effect transistor
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Effect of Heat Treatment on Microstructure Evolution and Fracture Mechanism of 30CrMo/316L Multilayered Composites Fabricated by Vacuum Electron Beam Welding and Accumulative Hot Roll Bonding
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作者 Ming-Rong Fan Tian-Yu Wang +3 位作者 Jing-Gang Suo Ming-Kun Wang Ying-Ying Feng Zong-An Luo 《Acta Metallurgica Sinica(English Letters)》 2025年第12期2265-2278,共14页
The effects of accumulative hot rolling followed by solution treatment on the microstructural evolution and fracture behavior of 30CrMo/316L multilayered composites have been investigated.A scanning electron microscop... The effects of accumulative hot rolling followed by solution treatment on the microstructural evolution and fracture behavior of 30CrMo/316L multilayered composites have been investigated.A scanning electron microscope equipped with an electron backscatter diffraction probe,a laser confocal microscope,an electron probe microanalysis,and a universal testing machine were employed to characterize the microstructures and mechanical properties.The results indicate that solution treatment transformed the microstructure of the 30CrMo layer from ferrite to martensite,while the 316L layer remained austenitic but transitioned from the rolled to the recrystallized state.Additionally,solution treatment significantly enhanced the mechanical properties of the composite,leading to an increase in yield strength and ultimate tensile strength to 744 and 1106 MPa,respectively—258 and 276 MPa higher than those of the hot-rolled plate.The enhancement in strength is primarily attributed to the formation of high-strength martensite in the 30CrMo layer.During deformation,the composite interface effectively impeded crack propagation and induced step-like deflection.However,the formation of cross-layer grains facilitated crack nucleation at grain boundaries,leading to rapid crack propagation and instantaneous fracture.Therefore,preventing the formation of cross-layer grains during the heat treatment process is crucial,as their presence weakens the interfacial strengthening effect of the composite plate.This study provides valuable insights for the design and development of multi-layered steels. 展开更多
关键词 30CrMo/316L multilayered composite Accumulative rolling Solution treatment Microstructural evolution Fracture mechanism
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Effects of surface roughness of substrate on properties of Ti/TiN/Zr/ZrN multilayer coatings 被引量:9
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作者 林松盛 周克崧 +6 位作者 代明江 胡芳 石倩 侯惠君 韦春贝 李福球 佟鑫 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第2期451-456,共6页
Ti/TiN/Zr/ZrN multilayer coatings were deposited on Cr_17Ni_2 steel substrates with different surface roughnesses by vacuum cathodic arc deposition method. Microstructure, micro-hardness, adhesion strength and cross-s... Ti/TiN/Zr/ZrN multilayer coatings were deposited on Cr_17Ni_2 steel substrates with different surface roughnesses by vacuum cathodic arc deposition method. Microstructure, micro-hardness, adhesion strength and cross-sectional morphology of the obtained multilayer coatings were investigated. The results show that the Vickers hardness of Ti/TiN/Zr/ZrN multilayer coating, with a film thickness of 11.37 μm, is 29.36 GPa. The erosion and salt spray resistance performance of Cr_17Ni_2 steel substrates can be evidently improved by Ti/TiN/Zr/ZrN multilayer coating. The surface roughness of Cr_17Ni_2 steel substrates plays an important role in determining the mechanical and erosion performances of Ti/TiN/Zr/ZrN multilayer coatings. Overall, a low value of the surface roughness of substrates corresponds to an improved performance of erosion and salt spray resistance of multilayer coatings. The optimized performance of Ti/TiN/Zr/ZrN multilayer coatings can be achieved provided that the surface roughness of Cr_17Ni_2 steel substrates is lower than 0.4μm. 展开更多
关键词 Ti/TiN/Zr/ZrN multilayer coatings surface roughness sand erosion resistance corrosion resistance vacuum cathodicarc deposition TIN ZRN
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Effect of bias voltage on compositional, mechanical and corrosion property of ZrNbAlN multilayer films by unbalanced magnetron sputtering 被引量:2
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作者 石永敬 潘复生 +2 位作者 鲍明东 潘虎成 Muhammad RASHAD 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第9期2856-2863,共8页
Nano-scaled ZrNbAlN films with different negative bias voltages(Vb) were deposited on bronze substrate and Si(100) wafers by a reactive unbalanced magnetron sputtering technique. Composition and structure properti... Nano-scaled ZrNbAlN films with different negative bias voltages(Vb) were deposited on bronze substrate and Si(100) wafers by a reactive unbalanced magnetron sputtering technique. Composition and structure properties were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. It is found that mole concentrations of Zr and Nb are affected by Vb, which leads to the increase of binding energy of N 1s and Al 2p and decrease of binding energy of Zr 3d5/2 and Nb 3d5/2. Surface morphologies evolution controlled by Vb could be observed. Furthermore, X-ray diffraction patterns reveal that these films show a(111) preferred orientation. Moreover, mechanical property and corrosion behavior of ZrNbAlN films were characterized by nanoindentation test and corrosion test, respectively. A maximum value of 21.85 GPa at-70 V occurs in the ZrNbAlN- bronze system, which outperforms uncoated bronze. Corrosion experiments in 0.5 mol/L NaCl and 0.5 mol/L HCl solution show that corrosion potential and corrosion current are dependent on Vb, and better anti-corrosion property could be obtained at-90 V. 展开更多
关键词 ZrNbAlN multilayer film magnetron sputtering COMPOSITION CORROSION
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助剂Fe对Ni/NaY吸附剂脱除氢气中二氯甲烷性能的影响
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作者 周广林 李继聪 +5 位作者 闫超英 宣守国 姜伟丽 崔玉鑫 党杰 何浩燚 《低碳化学与化工》 北大核心 2026年第2期99-106,共8页
氢气中氯化物杂质会对氢燃料电池造成不可逆损害。为提高Ni/NaY吸附剂在常温下对氢气中二氯甲烷的脱除性能,采用等体积浸渍法制备了系列不同助剂Fe负载量(质量分数,下同)的Fe-Ni/NaY吸附剂。通过固定床反应器考察了Fe-Ni/NaY吸附剂对氢... 氢气中氯化物杂质会对氢燃料电池造成不可逆损害。为提高Ni/NaY吸附剂在常温下对氢气中二氯甲烷的脱除性能,采用等体积浸渍法制备了系列不同助剂Fe负载量(质量分数,下同)的Fe-Ni/NaY吸附剂。通过固定床反应器考察了Fe-Ni/NaY吸附剂对氢气中二氯甲烷的吸附性能,并利用XRD、FT-IR和NH_(3)-TPD等手段对吸附剂进行了表征。结果表明,助剂Fe的引入增大了Fe-Ni/NaY吸附剂的比表面积和微孔比表面积,增大了NaY分子筛弱酸位点数量。随着Fe负载量增大,弱酸位点数量显著增大,从而提高了吸附剂在常温下对氢气中二氯甲烷的吸附容量。Fe负载量为0.15%时,在温度为25℃、压力为0.1 MPa和氢气流量为6000 mL/h的条件下,Fe-Ni/NaY吸附剂的吸附氯容可达5.36%。 展开更多
关键词 氢气 二氯甲烷 吸附 Ni/NaY吸附剂 助剂fe
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基于赤泥构建Fe_(x)O_(y)/TiO_(2)/C复合材料及吸波性能研究
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作者 力国民 郭宇杰 +2 位作者 李凌霄 贾琨 梁丽萍 《燃料化学学报(中英文)》 北大核心 2026年第3期159-169,共11页
为了实现赤泥的资源化高效利用和开发,本研究以赤泥为原料、淀粉为碳源,利用溶胶-凝胶技术与碳热还原工艺制备了Fe_(x)O_(y)/TiO_(2)/C复合微波吸收材料,通过调控焙烧温度和原料配比,显著优化了Fe_(x)O_(y)/TiO_(2)/C复合材料的最低反... 为了实现赤泥的资源化高效利用和开发,本研究以赤泥为原料、淀粉为碳源,利用溶胶-凝胶技术与碳热还原工艺制备了Fe_(x)O_(y)/TiO_(2)/C复合微波吸收材料,通过调控焙烧温度和原料配比,显著优化了Fe_(x)O_(y)/TiO_(2)/C复合材料的最低反射损耗值(RL_(min))及有效吸收带宽(EAB)。实验结果表明,RmCT-5.4-700具有最佳的微波吸收性能,当涂层厚度为2.0 mm时,RL_(min)达到-30.2 dB,对应的EAB达到5.3 GHz;Fe_(x)O_(y)/TiO_(2)/C复合材料优异的吸波性能源于多种损耗机制的协同作用。碳热还原过程中碳消耗产生的缺陷会提供偶极位点,进而引发偶极极化现象,有效损耗电磁波能量,从而提升吸波性能。石墨化碳与Fe_(3)O_(4)、Fe颗粒共同构建起导电网络,电子在网络上迁移跳跃,由此产生导电损耗。此外,Fe_(3)O_(4)、F_e与TiO_(2)颗粒均匀分布于赤泥基体上,形成众多的异质界面,从而引发界面极化。Fe_(3)O_(4)和Fe颗粒所具备的磁损耗特性有效改善了材料的阻抗匹配特性,促使更多电磁能量进入复合材料内部并被高效吸收。本工作研究思路不仅为赤泥的资源化利用开辟了新途径,而且助推固体废弃物的高值化利用。 展开更多
关键词 赤泥 溶胶-凝胶 fe_(3)O_(4)/fe 复合吸波材料
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Research on Raman-scattering and Fabrication of Multilayer Thin Film with Different Structures and Components Based on Pt/Ti/Si3N4/SiO2/Si Substrate
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作者 谭秋林 张文栋 +3 位作者 薛晨阳 刘俊 李都泓 熊继军 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第3期333-338,340,共7页
Using the same conditions and various starting materials, such as lead acetate trihydrate, tetrabulyl titanate, zirconium n-butoxide, and acetylacetone, two kinds of solid precursors, lead zirconate titanate (PZT, Zr... Using the same conditions and various starting materials, such as lead acetate trihydrate, tetrabulyl titanate, zirconium n-butoxide, and acetylacetone, two kinds of solid precursors, lead zirconate titanate (PZT, Zr/Ti=15/85) and lead titanate (PT), were fabricated. With three different combinations, namely, PZT, PT/PZT-PZT/PT, and PT/PZT/-/PZT/PT, three multilayer thin films were deposited on three Pt-Ti-Si3N4-SiO2-Si substrates by a modified sol-gel process. The fabrication process of the thin films is discussed in detail. We found that there is a large built-in stress in the thin film, which can be diminished by annealing at 600 ℃, when the gel is turned into solid material through drying and sintering. The Raman scattering spectra of the films with different compositions and structures were investigated. With the help of X-ray diffraction (XRD) analyzer and Raman scattering spectra analyzer, it was found that the thin films with the PT/PZT-PZT/PT structure have reasonable crystallinity and less residual stress. XRD testing shows that the diffraction pattern of the multilayer film results from the superimposition of the PZT and PT patterns. This leads to the conclusion that the PT/PZT-PZT/PT multilayer thin film has a promising future in pyroelectric infrared detectors with high performance. 展开更多
关键词 multilayer thin film PYROELECTRIC Sol-gel Raman XRD analysis
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利用废弃电蚊香片制备Fe_(x)O_(y)/C复合微波吸收材料
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作者 力国民 李泽宇 +1 位作者 高洁 梁丽萍 《聊城大学学报(自然科学版)》 2026年第2期263-273,共11页
生物质碳因其环境友好、成本低廉和导电性良好等优点,成为研究热点。以废弃电蚊香片为主要原料,通过高温焙烧和引入磁性组分(Fe_(x)O_(y)),制备了Fe_(x)O_(y)/C复合吸波材料。研究发现,负载Fe_(x)O_(y)后,Fe_(x)O_(y)/C复合材料的吸波... 生物质碳因其环境友好、成本低廉和导电性良好等优点,成为研究热点。以废弃电蚊香片为主要原料,通过高温焙烧和引入磁性组分(Fe_(x)O_(y)),制备了Fe_(x)O_(y)/C复合吸波材料。研究发现,负载Fe_(x)O_(y)后,Fe_(x)O_(y)/C复合材料的吸波性能显著提升。其中,FVM-0.6-600在1.5 mm涂层厚度下的最小反射损耗(RLmin)值达到-19.2 dB,有效吸收带宽(EAB)为5.3 GHz;FVM-0.6-800在2 mm涂层厚度下的RLmin值为-25.6 dB,EAB为4.5 GHz。该研究实现了废弃电蚊香片的高值化和资源化利用,具有广阔的应用前景。 展开更多
关键词 废弃电蚊香片 fe3O4/fe/C复合材料 微波吸收
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孔洞缺陷对α-Fe拉伸变形行为影响的分子动力学模拟
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作者 李翔 尹益辉 +2 位作者 张元章 李继承 李洪祥 《稀有金属材料与工程》 北大核心 2026年第2期510-516,共7页
为深入研究孔洞缺陷对α-Fe试样拉伸变形行为的影响,构建含不同大小孔洞缺陷的α-Fe试样计算模型,并进行单轴拉伸应变下的分子动力学模拟。结果表明:整体趋势上,含孔洞缺陷试样的拉伸力学性能损减与孔洞尺寸正相关,孔洞尺寸越大,试样越... 为深入研究孔洞缺陷对α-Fe试样拉伸变形行为的影响,构建含不同大小孔洞缺陷的α-Fe试样计算模型,并进行单轴拉伸应变下的分子动力学模拟。结果表明:整体趋势上,含孔洞缺陷试样的拉伸力学性能损减与孔洞尺寸正相关,孔洞尺寸越大,试样越容易进入塑性变形阶段;含孔洞缺陷试样的杨氏模量、屈服应力、极限强度和拉断延伸率均随着孔洞半径的增大而减小;试样的塑性变形表现为拉伸应力诱发的相变和位错滑移混合的机制;随着孔洞半径的增大,试样的应力-应变曲线特征发生显著变化——试样的塑性屈服段和应变硬化段越来越短,应变硬化段甚至消失。研究有助于深入认识孔洞缺陷对金属变形机制的影响,为后续开展多晶α-Fe材料的物理和力学性质的分析研究奠定有益基础。 展开更多
关键词 Α-fe 孔洞 相变 位错滑移
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溶剂热法制备Fe^(2+)掺杂LiCoPO_(4)及其电极性能
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作者 李志义 王成伟 +3 位作者 孙海礼 魏炜 刘凤霞 刘志军 《精细化工》 北大核心 2026年第1期42-49,59,共9页
以一水合氢氧化锂、四水合醋酸钴为原料,采用抗坏血酸辅助的温和溶剂热法制备了LiCoPO_(4)前驱体,再经煅烧后制备了LiCoPO_(4),最后制备了不同Fe^(2+)掺杂量(x)的LiCo_(1–x)Fe_(x)PO_(4)。通过XRD、SEM表征和电化学性能测试,考察了溶... 以一水合氢氧化锂、四水合醋酸钴为原料,采用抗坏血酸辅助的温和溶剂热法制备了LiCoPO_(4)前驱体,再经煅烧后制备了LiCoPO_(4),最后制备了不同Fe^(2+)掺杂量(x)的LiCo_(1–x)Fe_(x)PO_(4)。通过XRD、SEM表征和电化学性能测试,考察了溶剂热反应时间、煅烧温度和Fe^(2+)掺杂量对LiCoPO_(4)及LiCo_(1–x)Fe_(x)PO_(4)形貌和作为正极材料性能的影响。结果表明,对溶剂热反应时间与煅烧温度的调控可以实现LiCoPO_(4)的形貌和颗粒粒径的优化,进而改善其电化学性能。在溶剂热反应时间为9 h、煅烧温度为700℃的条件下可制备出形貌为板状的LiCoPO_(4)颗粒,其首次放电比容量达到163.21 mA·h/g;当x=0.09时,LiCo_(0.91)Fe_(0.09)PO_(4)表现出最佳的循环性能和倍率性能,在0.1 C倍率下经过30次循环,LiCo_(0.91)Fe_(0.09)PO_(4)与未经Fe^(2+)掺杂的LiCoPO_(4)相比,放电比容量从52.12 mA·h/g提升至111.75 mA·h/g,容量保留率由31.93%提升至77.66%。 展开更多
关键词 磷酸钴锂 溶剂热法 抗坏血酸 形貌 电化学性能 fe^(2+)掺杂 功能材料
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VUV/Fe^(2+)/Ox类芬顿体系对偶氮染料酸性红G的降解机理研究
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作者 王坤 陈伟 +5 位作者 唐玉朝 崔康平 伍昌年 朱先胜 孙海翔 黄显怀 《中国环境科学》 北大核心 2026年第2期785-796,共12页
构建了一种基于真空紫外(VUV)/Fe^(2+)/草酸(Ox)的新型无外源氧化剂类芬顿反应体系,并将其应用于偶氮染料酸性红G(ARG)的降解研究.结果表明,该体系可实现H_(2)O_(2)的动态释放,进而与Fe^(2+)形成类芬顿反应,且在较宽pH值范围内均能保持... 构建了一种基于真空紫外(VUV)/Fe^(2+)/草酸(Ox)的新型无外源氧化剂类芬顿反应体系,并将其应用于偶氮染料酸性红G(ARG)的降解研究.结果表明,该体系可实现H_(2)O_(2)的动态释放,进而与Fe^(2+)形成类芬顿反应,且在较宽pH值范围内均能保持高反应活性.结果表明:在ARG初始质量浓度为60mg/L、Fe^(2+)与Ox浓度分别为0.06和0.7mmol/L的条件下,VUV/Fe^(2+)/Ox体系对ARG的去除率在5min内即可达到96.2%,其降解过程符合准一级动力学模型.随着溶液初始pH值的升高,ARG去除率呈下降趋势,在pH=7时,一级速率常数k值仍可达0.454min⁻1,为pH=3时的69.6%,表明该体系在中性条件下仍能维持较高反应活性.反应初始5min内,体系中H_(2)O_(2)浓度逐渐上升至最高62.5µmol/L,随后缓慢下降,至9min时仍保持在51.8µmol/L.自由基捕获实验与EPR检测结果共同证实,羟基自由基(·OH)和超氧自由基(O_(2)^(·-))是该体系中的主要活性氧化物种.此外,水环境中常见的无机阴离子(HCO_(3)^(-)、NO_(3)^(-)、Cl^(-)、SO_(4)^(2-))均会对ARG降解产生不同程度的抑制作用.通过紫外可见吸收光谱及液相色谱-质谱联用(LC-MS)分析可知,降解过程中生成的活性氧(ROS)通过攻击ARG分子中的偶氮键和苯环结构,实现了染料的脱色与去除. 展开更多
关键词 VUV/fe^(2+)/草酸体系 类芬顿反应 酸性红G 动态H_(2)O_(2)释放
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