Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important eval...Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.展开更多
一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家...一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家赫拉克利特所说的“万物流转”,又说“你不能两次踏进同一条河流,因为新的水不断地流过你的身旁”,他所表达的意思是“世界上唯一不变的就是变化”。展开更多
Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role...Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role in driving foreshocks and mainshock nucleation for given cases.In this study,we focus on the relationship between an intensive earthquake swarm that started beneath the Noto Peninsula in Central Japan since November 2020 and the nucleation of the 2024 M 7.6 Noto Hanto earthquake.We relocate earthquakes listed in the standard Japan Meteorological Agency(JMA)catalog since 2018 with the double-different relocation method.Relocated seismicity revealed that the 2024 M 7.6 mainshock likely ruptured a thrust fault above a parallel fault where the M 6.5 Suzu earthquake occurred in May 2023.We find possible along-strike and along-dip expansion of seismicity in the first few months at the beginning of the swarm sequence,while no obvious migration pattern in the last few days before the M 7.6 mainshock was observed.Several smaller events occurred in between the M 5.5 and M 4.6 foreshocks that occurred about 4min and 2 min before the M 7.6 mainshock.The Coulomb stress changes from the M 5.5 foreshock were negative at the hypocenter of the M 7.6 mainshock,which is inconsistent with a simple cascade triggering model.Moreover,an M 5.9 foreshock was identified in the JMA catalog 14 s before the mainshock.Results from backprojection of high-frequency teleseismic P waves show a prolonged initial rupture process near the mainshock hypocenter lasting for~25 s,before propagating bilaterally outward.Our results suggest a complex evolution process linking the earthquake swarm to the nucleation of the M 7.6 mainshock at a region of complex structures associated with the bend of a mapped large-scale reverse fault.A combination of fluid migration,aseismic slip and elastic stress triggering likely work in concert to drive both the prolonged earthquake swarm and the nucleation of the M 7.6 mainshock.展开更多
Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional ...Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional surface strengthening technologies,laser shock peening(LSP)has increasingly attracted attention from researchers and industries,since it significantly improves the surface strength,biocompatibility,fa-tigue resistance,and anti-corrosion ability of Ti and its alloys.Despite numerous studies that have been carried out to elucidate the effects of LSP on microstructural evolution and mechanical properties of Ti and its alloys in recent years,a comprehensive review of recent advancements in the field of Ti and its alloys subjected to LSP is still lacking.In this review,the standard LSP and the novel process designs of LSP assisted by thermal,cryogenic,electropulsing and magnetic fields are discussed and compared.Microstructural evolution,with focuses on the dislocation dynamics,deformation twinning,grain refine-ment and surface amorphization,during LSP processing of Ti alloys is reviewed.Furthermore,the en-hanced engineering performance of the L SP-processed(L SPed)Ti alloys,including surface hardness,wear resistance,fatigue life and corrosion resistance are summarized.Finally,this review concludes by present-ing an overview of the current challenges encountered in this field and offering insights into anticipated future trends.展开更多
The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase preci...The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.展开更多
Organic nanophotocatalysts are promising candidates for solar fuels production,but they still face the challenge of unfavorable geminate recombination due to the limited exciton diffusion lengths.Here,we introduce a b...Organic nanophotocatalysts are promising candidates for solar fuels production,but they still face the challenge of unfavorable geminate recombination due to the limited exciton diffusion lengths.Here,we introduce a binary nanophotocatalyst fabricated by blending two polymers,PS-PEG5(PS)and PBT-PEG5(PBT),with matched absorption and emission spectra,enabling a Forster resonance energy transfer(FRET)process for enhanced photocatalysis.These heterostructure nanophotocatalysts are processed using a facile and scalable flash nanoprecipitation(FNP)technique with precious kinetic control over binary nanoparticle formation.The resulting nanoparticles exhibit an exceptional photocatalytic hydrogen evolution rate up to 65 mmol g^(-1) h^(-1),2.5 times higher than that single component nanoparticles.Characterizations through fluorescence spectra and transient absorption spectra confirm the hetero-energy transfer within the binary nanoparticles,which prolongs the excited-state lifetime and extends the namely“effective exciton diffusion length”.Our finding opens new avenues for designing efficient organic photocatalysts by improving exciton migration.展开更多
Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in thi...Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in this study.The microstructure of the WE43 and CNTs/WE43 layers was systematically compared.The dissolution of divorced eutectics at the grain boundaries was retarded by CNTs during solution treatment.The spot segregation composed of Mg_(24)Y_(5),CNTs,and Zr cores in the solution treated CNTs/WE43 layer presented a slight decreasing in Y content.The grain growth of both types of layers underwent three stages:slow,rapid,and steady-state.The significant inhibitory effect of CNTs on the grain growth of the LDED WE43 matrix was more pronounced than the promoting effect of temperature,resulting in a 47%increase at 510℃ and a 35%increase at 540℃ in the grain growth exponent compared to the WE43 layers at 510℃.During the subsequent aging treatment at 225℃,the precipitation sequences from plate-shaped β″to plate-shaped and globular β′ were observed in both types of layers.CNTs can facilitate an increase in the nucleation rate of precipitates,but without accelerating precipitation hardening rate.The long and short diameters of the precipitates in peak-aged state were decreased by 48.5%and 43.1%by addition of CNTs,respectively.The wear resistance of both the WE43 and CNTs/WE43 layers can be significantly enhanced through solution and aging treatment.The enhancement in wear resistance for the CNTs/WE43 layers is considerably greater than that of the WE43 layers.展开更多
The hot deformation behavior of GH3230 superalloy under selected deformation conditions ranging from 950 to 1150℃with strain rates ranging from 0.01 to 10 s^(–1)was studied through isothermal hot compression experim...The hot deformation behavior of GH3230 superalloy under selected deformation conditions ranging from 950 to 1150℃with strain rates ranging from 0.01 to 10 s^(–1)was studied through isothermal hot compression experiments.Based on the obtained flow stresses,a strain-compensated Arrhenius-type model was developed for the description of hot deformation behavior,and the consistency of the predicted flow stresses with the experimental values confirms the accuracy of the developed model.Furthermore,the processing maps were constructed and classified into the instability domain,low-dissipation stability domain and high-dissipation stability domain in accordance with the dynamic material model and the instability criterion.Microstructure observations indicated that the instability domain exhibits the adiabatic shear bands formation,and the low-power dissipation domain exhibits partial dynamic recrystallization(DRX),with the temperature increase/strain rate decrease being favorable for the DRX.The high-dissipation stability domain was occupied by uniformly fine equiaxed grains,and was identified as the optimal processing window,which corresponds to the deformation conditions at 1070–1150℃ with strain rates ranging from 0.01 to 0.15 s^(–1).Moreover,various DRX mechanisms are observed to occur during the hot deformation,which include the discontinuous dynamic recrystallization,characterized by nucleation at bulged boundaries,the continuous dynamic recrystallization with subgrain progressive rotation and the particle stimulated nucleation mechanism with stimulated nucleation of carbide particles.展开更多
The microstructure and texture evolutions during extrusion and rolling processes of the 2195 Al−Li alloy were investigated.The EBSD technique was employed to reveal the microscopic evolution mechanisms of different te...The microstructure and texture evolutions during extrusion and rolling processes of the 2195 Al−Li alloy were investigated.The EBSD technique was employed to reveal the microscopic evolution mechanisms of different texture components.The findings reveal that the texture evolution is governed by two mechanisms:an overall orientation transformation induced by plastic strain and a localized transformation occurring at the shearing bands within grains.During the rolling process,the extrusion texture components of Ex{123}<111>and Cu{112}<111>evolve into S{123}<634>,and the Bs{011}<211>rotates into the orientations near R-Bs and S.With increasing deformation,the S,Bs,and R-Bs orientations further rotate around the TD axis and disperse into new orientations,forming recrystallized grains.The shearing bands with different initial orientations exhibit similar orientation evolution patterns,all of which evolve from the initial orientation to a series of recrystallization orientations.展开更多
The initial microstructure of titanium alloy in theα+βphase region is pivotal in dictating the performance of the final products after thermomechanical processing.Microstructures and textures of three rods,each prep...The initial microstructure of titanium alloy in theα+βphase region is pivotal in dictating the performance of the final products after thermomechanical processing.Microstructures and textures of three rods,each prepared through distinct pretreatments,were systematically analyzed.Morphological analysis reveals that while both thickαplatelets and coarse priorβgrains impede the spheroidization of lamellar structures,the influence of the former is more pronounced.Variations inαplatelet thickness priorβgrain size exhibit limited impact on the macro-texture type after deformation and annealing.The proportion of low-angle interfaces between the c-axis of the primaryαphase and the<110>direction of the priorβgrains was elevated in rods with thicker platelets compared to thinner ones.展开更多
Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durabili...Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.展开更多
The fact that Morocco is an agricultural country and the large volume of biodegradable waste produced by the population make composting so important.The degradation of organic matter is facilitated by faunal and flora...The fact that Morocco is an agricultural country and the large volume of biodegradable waste produced by the population make composting so important.The degradation of organic matter is facilitated by faunal and floral macro and micro-organisms that act in different stages of maturation;studies on this fauna are quite rare both nationally and internationally.On a sample of two tons of household waste,we documented invertebrates that colonized compost heaps and then assessed the changes in the structure of the invertebrate population during the different phases.Our study revealed the presence of several zoological groups colonizing the compost heaps during the different composting phases;we noted the presence of:(1)Macroscopic invertebrates,in order of number of individuals:insect larvae,ants,earthworms,sowbugs,spiders,springtails,and millipedes,and(2)Microscopic invertebrates,the most abundant in terms of individuals:mites and nematodes.As for the order of appearance,we observed that insect larvae were the first to colonize the compost heap from the very first days of installation,followed by woodlice observed during the thermophilic phase and disappearing towards the end of the process.Earthworms were observed during the end of the thermophilic phase,while springtails were observed more during the cooling and maturation phases.Our study revealed the presence of a good quality of fauna during the composting process,which are indicators of good compost quality and play a major role in the circulation of nutrients,thus ensuring the provision of essential elements for plant nutrition.展开更多
The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the micr...The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the microstructure feature,texture evolution,mechanical properties,and electrical conductivity of ultrafine wires ranging fromΦ361μm toΦ18μm is performed.Specially,the microstructure feature and texture type covering the whole longitudinal section of ultrafine wires are elaborately characterized.The results show that the average lamella thickness decreases from 1.63μm to 102 nm during the drawing process.Whereas,inhomogeneous texture evolution across different wire sections was observed.The main texture types of copper wires are comprised of<111>,<001>and<112>orientations.Specifically,the peripheral region is primarily dominated by<111>and<112>,while the central region is dominated by<001>and<111>.As the drawing strain increases,the volume fraction of hard orientation<111>with low Schmid factor increases,where notably higher fraction of<111>is resulted from the consumption of<112>and<001>for the wire ofΦ18μm.For drawn copper wire of 18μm,superior properties are obtained with a tensile strength of 729.8 MPa and an electrical conductivity of 86.9%IACS.Furthermore,it is found that grain strengthening,dislocation strengthening,and texture strengthening are three primary strengthening mechanisms of drawn copper wire,while the dislocation density is the main factor on the reducing of conductivity.展开更多
This study investigated the effects of high-energy-density femtosecond laser pulses on diamond under different pulse counts,revealing the resulting structural changes and defect-formation mechanisms.Raman spectroscopy...This study investigated the effects of high-energy-density femtosecond laser pulses on diamond under different pulse counts,revealing the resulting structural changes and defect-formation mechanisms.Raman spectroscopy and low-temperature fluorescence spectroscopy were used to examine the surface damage,stress,and defect evolution of diamond under varying numbers of pulses.The results revealed the generation of nitrogen-vacancy color centers in diamond under high-energy-density pulsed laser irradiation without requiring annealing treatment.Additionally,confocal spectroscopy provided a distribution model for the evolution of damage and defects in diamond after femtosecond laser processing.This research provides valuable insights into optimizing femtosecond laser processing techniques and improves our understanding of the structural changes and defect-formation mechanisms in diamond.展开更多
Based on regional paleoclimate sequences,records of human activities,paleoclimate simulations,and detailed environmental historical records,we discuss the impacts of Holocene climate change and human activities on the...Based on regional paleoclimate sequences,records of human activities,paleoclimate simulations,and detailed environmental historical records,we discuss the impacts of Holocene climate change and human activities on the evolution of the Shule River in the western Qilian Mountains,China.The results indicate that during the early to mid-Holocene,the river evolution of the Shule River alluvial fan was closely related to regional climate fluctuations.In the late Holocene,flood agriculture began to emerge along the Shule River.During the historical period,population growth and the expansion of arable land led to increased river water usage,resulting in decreased access to the expected distribution of water resources in other regions,which in turn has caused imbalances in the regional hydrological ecosystem.展开更多
Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure ...Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure Expo Garden as a case study,utilizing a land use change index model to analyze the spatial evolution characteristics and dynamic processes of creative urban tourism complexes,as well as to explore their spatial differentiation mechanisms.The analysis indicates that Hangzhou Leisure Expo Garden,initially a derelict industrial area dominated by production and residential land use,has evolved into a creative urban tourism complex with tourism comprehensive service land at its core,going through the pattern evolution processes of“constrained sprawl,”“intensive expansion,”and“random integration.”From the perspective of tourism human-land relationships,the formation of land use evolution patterns in creative urban tourism complexes results from various stakeholders(government,tourism enterprises,residents,tourists,etc.),as humanistic factors,continuously adapting to specific urban spaces,which are considered as geographical elements and have locational advantages and are oriented towards economic and social values.Based on the acquisition of stakeholder interests,the transformation of resource-disadvantaged areas into tourism advantage areas is facilitated,thereby achieving the re-creation of tourism creative space and promoting intensive spatial growth.展开更多
Oxygen evolution reaction(OER) is one of the most important half-reactions related to metal-air batteries,fuel cells, and water-splitting. Due to the sluggish kinetic and multi-electron transfer, catalysts appear to b...Oxygen evolution reaction(OER) is one of the most important half-reactions related to metal-air batteries,fuel cells, and water-splitting. Due to the sluggish kinetic and multi-electron transfer, catalysts appear to be particularly important for the OER. Knowing the reaction mechanism is fundamental to developing new catalysts and improving OER efficiency. In this work, phase transition and atomic reconstruction on Co O(111) plane were revealed through ex-situ diffraction methods and X-ray absorption spectroscopy.At the same time, the electronic state evolution of Co(Ⅱ)/Co(Ⅲ) during the OER process has also been concluded by analyzing the magnetic properties. This work shows that during the OER process, Co(Ⅲ)experiences surface electron rearrangement from IS(intermediate-spin state) to LS(low-spin state) and then returns to IS/HS(high-spin state) under high voltage region. This work provides a new view to reveal the reaction mechanism through the magnetic property and it can be extended to more magnetic 3d transition metals for future catalyst design.展开更多
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ...Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of significant,novel,and high-impact research in the fields of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.展开更多
This study systematically investigates the hot deformation behavior and microstructural evolution of CoNiV medium-entropy alloy(MEA)in the temperature range of 950-1100℃ and strain rates of 0.001-1 s^(-1).The Arrheni...This study systematically investigates the hot deformation behavior and microstructural evolution of CoNiV medium-entropy alloy(MEA)in the temperature range of 950-1100℃ and strain rates of 0.001-1 s^(-1).The Arrhenius model and machine learning model were developed to forecast flow stresses at various conditions.The predictive capability of both models was assessed using the coefficients of determination(R^(2)),average absolute relative error(AARE),and root mean square error(RMSE).The findings show that the osprey optimization algorithm convolutional neural network(OOA-CNN)model outperforms the Arrhenius model,achieving a high R^(2) value of 0.99959 and lower AARE and RMSE values.The flow stress that the OOA-CNN model predicted was used to generate power dissipation maps and instability maps under different strains.Finally,combining the processing map and microstructure characterization,the ideal processing domain was identified as 1100℃ at strain rates of 0.01-0.1 s^(-1).This study provided key insights into optimizing the hot working process of CoNiV MEA.展开更多
A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and...A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.展开更多
基金supported by the National Key R&D Program of China(No.2023YFC3904304)the National Natural Science Foundation of China(No.52304158)Jiangsu Key Laboratory for Clean Utilization of Carbon Resources Research Project(No.BM2024007)。
文摘Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.
文摘一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家赫拉克利特所说的“万物流转”,又说“你不能两次踏进同一条河流,因为新的水不断地流过你的身旁”,他所表达的意思是“世界上唯一不变的就是变化”。
基金partially supported by U.S.National Science Foundation grants EAR1925965 and RISE-2425889support from the European Research Council under the European Union Horizon 2020 research and innovation program(grant agreement no.742335,FIMAGE)。
文摘Several physical mechanisms of earthquake nucleation,such as pre-slip,cascade triggering,aseismic slip,and fluid-driven models,have been proposed.However,it is still not clear which model plays the most important role in driving foreshocks and mainshock nucleation for given cases.In this study,we focus on the relationship between an intensive earthquake swarm that started beneath the Noto Peninsula in Central Japan since November 2020 and the nucleation of the 2024 M 7.6 Noto Hanto earthquake.We relocate earthquakes listed in the standard Japan Meteorological Agency(JMA)catalog since 2018 with the double-different relocation method.Relocated seismicity revealed that the 2024 M 7.6 mainshock likely ruptured a thrust fault above a parallel fault where the M 6.5 Suzu earthquake occurred in May 2023.We find possible along-strike and along-dip expansion of seismicity in the first few months at the beginning of the swarm sequence,while no obvious migration pattern in the last few days before the M 7.6 mainshock was observed.Several smaller events occurred in between the M 5.5 and M 4.6 foreshocks that occurred about 4min and 2 min before the M 7.6 mainshock.The Coulomb stress changes from the M 5.5 foreshock were negative at the hypocenter of the M 7.6 mainshock,which is inconsistent with a simple cascade triggering model.Moreover,an M 5.9 foreshock was identified in the JMA catalog 14 s before the mainshock.Results from backprojection of high-frequency teleseismic P waves show a prolonged initial rupture process near the mainshock hypocenter lasting for~25 s,before propagating bilaterally outward.Our results suggest a complex evolution process linking the earthquake swarm to the nucleation of the M 7.6 mainshock at a region of complex structures associated with the bend of a mapped large-scale reverse fault.A combination of fluid migration,aseismic slip and elastic stress triggering likely work in concert to drive both the prolonged earthquake swarm and the nucleation of the M 7.6 mainshock.
基金supported by the National Key R&D Plan of China(No.2022YFB3705603)the National Natural Science Foundation of China(No.52101046)+1 种基金the Excellent Youth Overseas Project of National Science and Natural Foundation of China,the Baowu Special Metallurgy Cooperation Limited(No.22H010101336)the Medicine-Engineering Interdisciplinary Project of Shanghai Jiao Tong University(No.YG2022QN076).
文摘Titanium(Ti)and its alloys are frequently utilized as critical components in a variety of engineering ap-plications because of their high specific strength and excellent corrosion resistance.Compared to conven-tional surface strengthening technologies,laser shock peening(LSP)has increasingly attracted attention from researchers and industries,since it significantly improves the surface strength,biocompatibility,fa-tigue resistance,and anti-corrosion ability of Ti and its alloys.Despite numerous studies that have been carried out to elucidate the effects of LSP on microstructural evolution and mechanical properties of Ti and its alloys in recent years,a comprehensive review of recent advancements in the field of Ti and its alloys subjected to LSP is still lacking.In this review,the standard LSP and the novel process designs of LSP assisted by thermal,cryogenic,electropulsing and magnetic fields are discussed and compared.Microstructural evolution,with focuses on the dislocation dynamics,deformation twinning,grain refine-ment and surface amorphization,during LSP processing of Ti alloys is reviewed.Furthermore,the en-hanced engineering performance of the L SP-processed(L SPed)Ti alloys,including surface hardness,wear resistance,fatigue life and corrosion resistance are summarized.Finally,this review concludes by present-ing an overview of the current challenges encountered in this field and offering insights into anticipated future trends.
基金the National Natural Science Foundation of China(Key Program)(52031004).
文摘The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.
基金supported by National Natural Science Foundation of China(NSFC,22338006,92356301,9235630033 and 22375062)Shanghai Municipal Science and Technology Major Project(21JC1401700)+4 种基金Shanghai Pilot Program for Basic Research(22TQ1400100-10)Fundamental Research Funds for the Central UniversitiesShanghai Pujiang Program(22PJ1402400)“Chenguang Program”supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(22CGA32)the Young Elite Scientists Sponsorship Program by CAST(2023QNRC001).
文摘Organic nanophotocatalysts are promising candidates for solar fuels production,but they still face the challenge of unfavorable geminate recombination due to the limited exciton diffusion lengths.Here,we introduce a binary nanophotocatalyst fabricated by blending two polymers,PS-PEG5(PS)and PBT-PEG5(PBT),with matched absorption and emission spectra,enabling a Forster resonance energy transfer(FRET)process for enhanced photocatalysis.These heterostructure nanophotocatalysts are processed using a facile and scalable flash nanoprecipitation(FNP)technique with precious kinetic control over binary nanoparticle formation.The resulting nanoparticles exhibit an exceptional photocatalytic hydrogen evolution rate up to 65 mmol g^(-1) h^(-1),2.5 times higher than that single component nanoparticles.Characterizations through fluorescence spectra and transient absorption spectra confirm the hetero-energy transfer within the binary nanoparticles,which prolongs the excited-state lifetime and extends the namely“effective exciton diffusion length”.Our finding opens new avenues for designing efficient organic photocatalysts by improving exciton migration.
基金supported by the National Natural Science Foundation of China(52005264).
文摘Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in this study.The microstructure of the WE43 and CNTs/WE43 layers was systematically compared.The dissolution of divorced eutectics at the grain boundaries was retarded by CNTs during solution treatment.The spot segregation composed of Mg_(24)Y_(5),CNTs,and Zr cores in the solution treated CNTs/WE43 layer presented a slight decreasing in Y content.The grain growth of both types of layers underwent three stages:slow,rapid,and steady-state.The significant inhibitory effect of CNTs on the grain growth of the LDED WE43 matrix was more pronounced than the promoting effect of temperature,resulting in a 47%increase at 510℃ and a 35%increase at 540℃ in the grain growth exponent compared to the WE43 layers at 510℃.During the subsequent aging treatment at 225℃,the precipitation sequences from plate-shaped β″to plate-shaped and globular β′ were observed in both types of layers.CNTs can facilitate an increase in the nucleation rate of precipitates,but without accelerating precipitation hardening rate.The long and short diameters of the precipitates in peak-aged state were decreased by 48.5%and 43.1%by addition of CNTs,respectively.The wear resistance of both the WE43 and CNTs/WE43 layers can be significantly enhanced through solution and aging treatment.The enhancement in wear resistance for the CNTs/WE43 layers is considerably greater than that of the WE43 layers.
基金the National Key Research and Development Program of China(No.2016YFB0700505)the National Natural Science Foundation of China(No.51571020).
文摘The hot deformation behavior of GH3230 superalloy under selected deformation conditions ranging from 950 to 1150℃with strain rates ranging from 0.01 to 10 s^(–1)was studied through isothermal hot compression experiments.Based on the obtained flow stresses,a strain-compensated Arrhenius-type model was developed for the description of hot deformation behavior,and the consistency of the predicted flow stresses with the experimental values confirms the accuracy of the developed model.Furthermore,the processing maps were constructed and classified into the instability domain,low-dissipation stability domain and high-dissipation stability domain in accordance with the dynamic material model and the instability criterion.Microstructure observations indicated that the instability domain exhibits the adiabatic shear bands formation,and the low-power dissipation domain exhibits partial dynamic recrystallization(DRX),with the temperature increase/strain rate decrease being favorable for the DRX.The high-dissipation stability domain was occupied by uniformly fine equiaxed grains,and was identified as the optimal processing window,which corresponds to the deformation conditions at 1070–1150℃ with strain rates ranging from 0.01 to 0.15 s^(–1).Moreover,various DRX mechanisms are observed to occur during the hot deformation,which include the discontinuous dynamic recrystallization,characterized by nucleation at bulged boundaries,the continuous dynamic recrystallization with subgrain progressive rotation and the particle stimulated nucleation mechanism with stimulated nucleation of carbide particles.
基金supported by the National Natural Science Foundation of China(No.52205393)the Natural Science Foundation of Shandong Province,China(No.ZR2022QE263)+1 种基金the Science and Technology Commission of Shanghai Municipality,Shanghai Rising-Star Program,China(No.23YF1413900)the Science and Technology Innovation Plan of Shanghai Science and Technology Commission,China(Nos.21010500800,23010501100).
文摘The microstructure and texture evolutions during extrusion and rolling processes of the 2195 Al−Li alloy were investigated.The EBSD technique was employed to reveal the microscopic evolution mechanisms of different texture components.The findings reveal that the texture evolution is governed by two mechanisms:an overall orientation transformation induced by plastic strain and a localized transformation occurring at the shearing bands within grains.During the rolling process,the extrusion texture components of Ex{123}<111>and Cu{112}<111>evolve into S{123}<634>,and the Bs{011}<211>rotates into the orientations near R-Bs and S.With increasing deformation,the S,Bs,and R-Bs orientations further rotate around the TD axis and disperse into new orientations,forming recrystallized grains.The shearing bands with different initial orientations exhibit similar orientation evolution patterns,all of which evolve from the initial orientation to a series of recrystallization orientations.
基金supported by the National Science and Technology Major Project(No.J2019-VI-0012-0126).
文摘The initial microstructure of titanium alloy in theα+βphase region is pivotal in dictating the performance of the final products after thermomechanical processing.Microstructures and textures of three rods,each prepared through distinct pretreatments,were systematically analyzed.Morphological analysis reveals that while both thickαplatelets and coarse priorβgrains impede the spheroidization of lamellar structures,the influence of the former is more pronounced.Variations inαplatelet thickness priorβgrain size exhibit limited impact on the macro-texture type after deformation and annealing.The proportion of low-angle interfaces between the c-axis of the primaryαphase and the<110>direction of the priorβgrains was elevated in rods with thicker platelets compared to thinner ones.
基金National MCF Energy R&D Program(2024YFE03260300)。
文摘Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.
文摘The fact that Morocco is an agricultural country and the large volume of biodegradable waste produced by the population make composting so important.The degradation of organic matter is facilitated by faunal and floral macro and micro-organisms that act in different stages of maturation;studies on this fauna are quite rare both nationally and internationally.On a sample of two tons of household waste,we documented invertebrates that colonized compost heaps and then assessed the changes in the structure of the invertebrate population during the different phases.Our study revealed the presence of several zoological groups colonizing the compost heaps during the different composting phases;we noted the presence of:(1)Macroscopic invertebrates,in order of number of individuals:insect larvae,ants,earthworms,sowbugs,spiders,springtails,and millipedes,and(2)Microscopic invertebrates,the most abundant in terms of individuals:mites and nematodes.As for the order of appearance,we observed that insect larvae were the first to colonize the compost heap from the very first days of installation,followed by woodlice observed during the thermophilic phase and disappearing towards the end of the process.Earthworms were observed during the end of the thermophilic phase,while springtails were observed more during the cooling and maturation phases.Our study revealed the presence of a good quality of fauna during the composting process,which are indicators of good compost quality and play a major role in the circulation of nutrients,thus ensuring the provision of essential elements for plant nutrition.
基金Project supported by“Unveiled the List of Commanders”Key Core Common Technology Projects of Ji’an,ChinaProject(LJKMZ20220591)supported by the Basic Scientific Research Project of the Education Department of Liaoning Province,ChinaProject(CSTB2023NSCQ-LZX0116)supported by the Natural Science Foundation Joint Fund for Innovation and Development Projects of Chongqing,China。
文摘The ultrafine copper wire with a diameter of 18μm is prepared via cold drawing process from the single crystal downcast billet(Φ8 mm),taking a drawing strain to 12.19.In this paper,in-depth investigation of the microstructure feature,texture evolution,mechanical properties,and electrical conductivity of ultrafine wires ranging fromΦ361μm toΦ18μm is performed.Specially,the microstructure feature and texture type covering the whole longitudinal section of ultrafine wires are elaborately characterized.The results show that the average lamella thickness decreases from 1.63μm to 102 nm during the drawing process.Whereas,inhomogeneous texture evolution across different wire sections was observed.The main texture types of copper wires are comprised of<111>,<001>and<112>orientations.Specifically,the peripheral region is primarily dominated by<111>and<112>,while the central region is dominated by<001>and<111>.As the drawing strain increases,the volume fraction of hard orientation<111>with low Schmid factor increases,where notably higher fraction of<111>is resulted from the consumption of<112>and<001>for the wire ofΦ18μm.For drawn copper wire of 18μm,superior properties are obtained with a tensile strength of 729.8 MPa and an electrical conductivity of 86.9%IACS.Furthermore,it is found that grain strengthening,dislocation strengthening,and texture strengthening are three primary strengthening mechanisms of drawn copper wire,while the dislocation density is the main factor on the reducing of conductivity.
基金funded by the Henan Key Laboratory of Intelligent Manufacturing Equipment Integration for Superhard Materials(Grant No.JDKJ2022-01)the Key Lab of Modern Optical Technologies of Education Ministry of China,Soochow University.
文摘This study investigated the effects of high-energy-density femtosecond laser pulses on diamond under different pulse counts,revealing the resulting structural changes and defect-formation mechanisms.Raman spectroscopy and low-temperature fluorescence spectroscopy were used to examine the surface damage,stress,and defect evolution of diamond under varying numbers of pulses.The results revealed the generation of nitrogen-vacancy color centers in diamond under high-energy-density pulsed laser irradiation without requiring annealing treatment.Additionally,confocal spectroscopy provided a distribution model for the evolution of damage and defects in diamond after femtosecond laser processing.This research provides valuable insights into optimizing femtosecond laser processing techniques and improves our understanding of the structural changes and defect-formation mechanisms in diamond.
基金The National Natural Science Foundation of China(Grant 42371159)。
文摘Based on regional paleoclimate sequences,records of human activities,paleoclimate simulations,and detailed environmental historical records,we discuss the impacts of Holocene climate change and human activities on the evolution of the Shule River in the western Qilian Mountains,China.The results indicate that during the early to mid-Holocene,the river evolution of the Shule River alluvial fan was closely related to regional climate fluctuations.In the late Holocene,flood agriculture began to emerge along the Shule River.During the historical period,population growth and the expansion of arable land led to increased river water usage,resulting in decreased access to the expected distribution of water resources in other regions,which in turn has caused imbalances in the regional hydrological ecosystem.
文摘Exploring the spatial evolution patterns of land use in creative urban tourism complexes provides theoretical and decision-making support to foster creative tourism projects.This study focuses on the Hangzhou Leisure Expo Garden as a case study,utilizing a land use change index model to analyze the spatial evolution characteristics and dynamic processes of creative urban tourism complexes,as well as to explore their spatial differentiation mechanisms.The analysis indicates that Hangzhou Leisure Expo Garden,initially a derelict industrial area dominated by production and residential land use,has evolved into a creative urban tourism complex with tourism comprehensive service land at its core,going through the pattern evolution processes of“constrained sprawl,”“intensive expansion,”and“random integration.”From the perspective of tourism human-land relationships,the formation of land use evolution patterns in creative urban tourism complexes results from various stakeholders(government,tourism enterprises,residents,tourists,etc.),as humanistic factors,continuously adapting to specific urban spaces,which are considered as geographical elements and have locational advantages and are oriented towards economic and social values.Based on the acquisition of stakeholder interests,the transformation of resource-disadvantaged areas into tourism advantage areas is facilitated,thereby achieving the re-creation of tourism creative space and promoting intensive spatial growth.
基金financially supported by the National Natural Science Foundation of China(No.52171210)the Program for the Development of Science and Technology of Jilin Province(Nos.20240101004JC,20220201130GX,and 20240402072GH)。
文摘Oxygen evolution reaction(OER) is one of the most important half-reactions related to metal-air batteries,fuel cells, and water-splitting. Due to the sluggish kinetic and multi-electron transfer, catalysts appear to be particularly important for the OER. Knowing the reaction mechanism is fundamental to developing new catalysts and improving OER efficiency. In this work, phase transition and atomic reconstruction on Co O(111) plane were revealed through ex-situ diffraction methods and X-ray absorption spectroscopy.At the same time, the electronic state evolution of Co(Ⅱ)/Co(Ⅲ) during the OER process has also been concluded by analyzing the magnetic properties. This work shows that during the OER process, Co(Ⅲ)experiences surface electron rearrangement from IS(intermediate-spin state) to LS(low-spin state) and then returns to IS/HS(high-spin state) under high voltage region. This work provides a new view to reveal the reaction mechanism through the magnetic property and it can be extended to more magnetic 3d transition metals for future catalyst design.
文摘Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of significant,novel,and high-impact research in the fields of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics.
基金supported by the National Natural Science Foundation of China(NSFC)(Grant No.51901078)the Central Guidance for Local Scientific and Technological Development Funding Project(Grant No.236Z1003G)+3 种基金the Science and Technology Plan Project of Tangshan City(Grant No.24130207C)the Natural Science Foundation of Hebei Province(Grant No.E2022209070)the High-level Talent Project of Hebei(Grant No.E2019100007)the Open Project Program of Key Laboratory of Ministry of Education for Modern Metallurgy Technology(Grant No.2024YJKF02).
文摘This study systematically investigates the hot deformation behavior and microstructural evolution of CoNiV medium-entropy alloy(MEA)in the temperature range of 950-1100℃ and strain rates of 0.001-1 s^(-1).The Arrhenius model and machine learning model were developed to forecast flow stresses at various conditions.The predictive capability of both models was assessed using the coefficients of determination(R^(2)),average absolute relative error(AARE),and root mean square error(RMSE).The findings show that the osprey optimization algorithm convolutional neural network(OOA-CNN)model outperforms the Arrhenius model,achieving a high R^(2) value of 0.99959 and lower AARE and RMSE values.The flow stress that the OOA-CNN model predicted was used to generate power dissipation maps and instability maps under different strains.Finally,combining the processing map and microstructure characterization,the ideal processing domain was identified as 1100℃ at strain rates of 0.01-0.1 s^(-1).This study provided key insights into optimizing the hot working process of CoNiV MEA.
文摘A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.
