Sensitivity analysis is one of the effective methods in the dynamic modification. The sensitivity of the modal parameters such as the natural frequencies and mode shapes in undamped free vibration of mechanical transm...Sensitivity analysis is one of the effective methods in the dynamic modification. The sensitivity of the modal parameters such as the natural frequencies and mode shapes in undamped free vibration of mechanical transmission system is analyzed in this paper.In particular,the sensitivities of the modal parameters to physical parameters of shaft system such as the inertia and stiffness are given.A calculation formula for dynamic modification is presented based on the analysis of modal parameter.With a mechanical transmission system as an example, the sensitivities of natural frequencies and modes shape are calculated and analyzed. Furthermore, the dynamic modification is also carried out and a good result is obtained.展开更多
Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLD...Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLDPEs)with comparable molecular weights but different short-chain branch(SCB)contents(ranging of 5-66 per 1000 carbon atoms)were modified via dynamic melt mixing using 2 wt% benzoyl peroxide at 145℃ and 50 r/min for 30 min.The influence of SCB content on the processability and structure of the resulting products was systematically investigated.All modified products exhibited good melt processability with melt flow rates(MFR)ranging from 0.46 g/10min to 1.07 g/10min.Products derived from low-SCB LLDPEs showed a lower MFR,higher cross-linking content,a larger number of long-chain branches,and a higher degree of benzoyl grafting.In contrast,those produced from high-SCB LLDPEs exhibited improved processability,reduced cross-linking,fewer long-chain branches,and lower benzoyl grafting levels.A detailed structural investigation of the soluble and insoluble fractions,which were separated using trichlorobenzene fractionation,was conducted to analyze the structural features of various modified products and demonstrate that the SCB content(i.e.,tertiary carbon density)significantly influences radical coupling during dynamic modification.Elevated tertiary carbon density,by introducing greater steric hindrance,suppresses radical coupling during dynamic modification,thereby reducing the efficiency of both crosslinking and peroxide fragment grafting.These findings provide new insights into the structure-reactivity relationships in peroxide-induced polyethylene modification and lay the foundation for tailoring material properties via dynamic processing.展开更多
A modification of central profile with trigonometric curve is proposed based on the theory of engagement of scroll compressor. General modification equations for central profile of a pair of scrolls are given and vari...A modification of central profile with trigonometric curve is proposed based on the theory of engagement of scroll compressor. General modification equations for central profile of a pair of scrolls are given and various modification patterns are discussed. The equidistant method is employed to calculate the volume of a sealed chamber and a set of general equations is represented. Modification parameters affecting geometric and dynamic property of a scroll compressor are analyzed systematically, and the relations between them are accurately determined. The condition for transforming a trigonometric curve modification into an arc-curve modification is explained. The conclusions can also be applied to other scroll fluid machines.展开更多
As fundamental components of life,biomacromolecules such as proteins,nucleic acids,and polysaccharides are constantly undergoing chemical modifications that are versatile,site-specific,and dynamic,and are often tightl...As fundamental components of life,biomacromolecules such as proteins,nucleic acids,and polysaccharides are constantly undergoing chemical modifications that are versatile,site-specific,and dynamic,and are often tightly regulated.This review summarizes recent advances in the study of dynamic modifications and chemical interventions of biomacromolecules that are supported by the major research plan(MRP)of the National Natural Science Foundation of China(NSFC).Firstly,we will introduce novel methods and techniques in chemical labeling,detection,as well as manipulation of dynamic biomacromolecular modifications.We will next discuss the molecular mechanisms and biological functions of the dynamic modifications of biomacromolecules,particularly of newly discovered modifications.Finally,we will explore chemical intervention strategies targeting these modifications and the associated disease.This review selectively highlights significant recent progress beingmade by the researchers supported byMRP,with a particular emphasis on representative chemical techniques and their biomedical applications along this exciting direction.展开更多
文摘Sensitivity analysis is one of the effective methods in the dynamic modification. The sensitivity of the modal parameters such as the natural frequencies and mode shapes in undamped free vibration of mechanical transmission system is analyzed in this paper.In particular,the sensitivities of the modal parameters to physical parameters of shaft system such as the inertia and stiffness are given.A calculation formula for dynamic modification is presented based on the analysis of modal parameter.With a mechanical transmission system as an example, the sensitivities of natural frequencies and modes shape are calculated and analyzed. Furthermore, the dynamic modification is also carried out and a good result is obtained.
基金financially supported by the Science and Technology Project of PetroChina Company Limited,China(No.2022DJ6314)the National Natural Science Foundation of China(No.52173056)。
文摘Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLDPEs)with comparable molecular weights but different short-chain branch(SCB)contents(ranging of 5-66 per 1000 carbon atoms)were modified via dynamic melt mixing using 2 wt% benzoyl peroxide at 145℃ and 50 r/min for 30 min.The influence of SCB content on the processability and structure of the resulting products was systematically investigated.All modified products exhibited good melt processability with melt flow rates(MFR)ranging from 0.46 g/10min to 1.07 g/10min.Products derived from low-SCB LLDPEs showed a lower MFR,higher cross-linking content,a larger number of long-chain branches,and a higher degree of benzoyl grafting.In contrast,those produced from high-SCB LLDPEs exhibited improved processability,reduced cross-linking,fewer long-chain branches,and lower benzoyl grafting levels.A detailed structural investigation of the soluble and insoluble fractions,which were separated using trichlorobenzene fractionation,was conducted to analyze the structural features of various modified products and demonstrate that the SCB content(i.e.,tertiary carbon density)significantly influences radical coupling during dynamic modification.Elevated tertiary carbon density,by introducing greater steric hindrance,suppresses radical coupling during dynamic modification,thereby reducing the efficiency of both crosslinking and peroxide fragment grafting.These findings provide new insights into the structure-reactivity relationships in peroxide-induced polyethylene modification and lay the foundation for tailoring material properties via dynamic processing.
基金This project is supported by Provincial Natural Science Foundation of Gansu(No.ZS032-B25-026).
文摘A modification of central profile with trigonometric curve is proposed based on the theory of engagement of scroll compressor. General modification equations for central profile of a pair of scrolls are given and various modification patterns are discussed. The equidistant method is employed to calculate the volume of a sealed chamber and a set of general equations is represented. Modification parameters affecting geometric and dynamic property of a scroll compressor are analyzed systematically, and the relations between them are accurately determined. The condition for transforming a trigonometric curve modification into an arc-curve modification is explained. The conclusions can also be applied to other scroll fluid machines.
文摘As fundamental components of life,biomacromolecules such as proteins,nucleic acids,and polysaccharides are constantly undergoing chemical modifications that are versatile,site-specific,and dynamic,and are often tightly regulated.This review summarizes recent advances in the study of dynamic modifications and chemical interventions of biomacromolecules that are supported by the major research plan(MRP)of the National Natural Science Foundation of China(NSFC).Firstly,we will introduce novel methods and techniques in chemical labeling,detection,as well as manipulation of dynamic biomacromolecular modifications.We will next discuss the molecular mechanisms and biological functions of the dynamic modifications of biomacromolecules,particularly of newly discovered modifications.Finally,we will explore chemical intervention strategies targeting these modifications and the associated disease.This review selectively highlights significant recent progress beingmade by the researchers supported byMRP,with a particular emphasis on representative chemical techniques and their biomedical applications along this exciting direction.
