Internal erosion occurs when fine particles escape from the soil driven by seepage flow,which is considered to be the crucial factor causing the failure of earth structures filled with gravelly soil.The objective of t...Internal erosion occurs when fine particles escape from the soil driven by seepage flow,which is considered to be the crucial factor causing the failure of earth structures filled with gravelly soil.The objective of this paper is to suggest an appropriate method to assess internal erosion potential of gravelly soil.By analyzing the sensitivity of soil material to internal erosion,the variable(Dc15/df85)max and the content of coarse particles(Pc)are selected as the evaluation indexes(Dc15 and df85 are the diameters of 15%mass passing in the coarse component and 85%mass passing in the fine component,respectively).A series of gravelly soils with different particle size distributions are tested for internal erosion by the self-made permeameter.Based on the test results,an evaluation method for the internal erosion of gravelly soil is proposed.Gravelly soil is prone to internal erosion when 60%≤Pc<95%and(Dc15/df85)max≥9.5.The proposed method shows good accuracy in evaluating the internal erosion of 36 soil samples from other studies,which confirms the reliability of the method.The proposed method makes it possible to accurately assess internal erosion of gravelly soil,and an alternative method is provided for engineers to determine whether there is a risk of internal erosion in earth structures consisting of gravelly soil.展开更多
Particle size fraction(clay, silt, and sand) is an important characteristic that influences several soil functions. The laser-diffraction method(LDM) provides a fast and cost-effective measurement of particle size dis...Particle size fraction(clay, silt, and sand) is an important characteristic that influences several soil functions. The laser-diffraction method(LDM) provides a fast and cost-effective measurement of particle size distribution, but the results usually differ from those obtained by the traditional sieve-pipette method(SPM). This difference can persist even when calibration is applied between the two methods. This partly relates to the different size ranges of particles measured by the two methods as a result of different operational principles, i.e., particle sedimentation according to Stokes’ Law vs. Mie theory for laser beam scattering. The objective of this study was to identify particle size ranges of LDM equivalent to those measured by SPM and evaluate whether new calibration models based on size range correction can be used to improve LDM-estimated particle size fractions, using 51 soil samples with various texture collected from five soil orders in New Zealand. Particle size distribution was determined using both LDM and SPM. Compared with SPM, original data from LDM underestimated the clay fraction(< 2 μm), overestimated the silt fraction(2–53 μm), but provided a good estimation of the sand fraction(53–2 000 μm).Results from three statistical indices, including Pearson’s correlation coefficient, slope, and Lin’s concordance correlation coefficient, showed that the size ranges of < 2 and 2–53 μm defined by SPM corresponded with the < 5 and 5–53 μm size ranges by LDM, respectively. Compared with the traditional calibration(based on the same particle size ranges), new calibration models(based on the corrected size ranges of these two methods) improved the estimation of clay and silt contents by LDM. Compared with soil-specific models(i.e., different models were developed for different soils), a universal model may be more parsimonious for estimating particle size fractions if the samples to be assessed represent multiple soil orders.展开更多
The effect of spherical particle size on the surface morphology, electrochemical property and processability of lithium iron phosphate was systematically studied. Spherical lithium iron phosphate with different partic...The effect of spherical particle size on the surface morphology, electrochemical property and processability of lithium iron phosphate was systematically studied. Spherical lithium iron phosphate with different particle size distributions controlled with ball time of precursor slurry was prepared by spray drying method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), charge and discharge measurements and EIS. The electrochemical performances of the sample materials were measured by coin cells and 14500 batteries. XRD shows that the spherical lithium iron phosphate with different particle sizes all have good crystal structure due to the perfect mixing of the raw materials and rapid drying. The lithium iron phosphate microsphere with different particle sizes self-assembled with submicron primary particles has a core-shell structure. The longer ball time the precursors are, the smaller the active material particles are prepared. The electrode material with 6 h ball time of precursor slurry has the best physical properties and the processability. The composite has a uniform particle size and higher tap density of 1.46 g/cm3, which delivers a discharge capacity of 167.6 mAh/g at a discharge rate of 0.5 C. The results were confirmed by the 14 500 mA h cylindrical batteries, which delivers a discharge capacity of 579 mAh at 0.5 C. And low-temperature performance with capacity of 458.5 mA h at -20 °C under a discharge rate of 0.5 C is the 79.2% of the same discharge rate at 25 °C. Otherwise, the 14500 batteries also exhibit excellent cycling performance and the capacity maintains 93% after 2 000 cycles.展开更多
The particle size ratio(PSR)is an important parameter for binary granular materials,which may aect the microstructure and macro behaviors of granular materials.However,the eect of particle ratio on granular assembli...The particle size ratio(PSR)is an important parameter for binary granular materials,which may aect the microstructure and macro behaviors of granular materials.However,the eect of particle ratio on granular assemblies with dierent arrangements is still unclear.To explore and further clarify the eect of PSR in dierent packing structures,three types of numerical samples with regular,layered,and random packing are designed.Numerical results show that PSR has signicant eects on binary granular samples with regular packing.The larger the PSR,the stronger the strength,the larger the modulus,and the smaller the angle between the shear band and the load direction.And a theoretical solution of the peak stress ratio vs.PSR is obtained for regular packing,and the results by DEM are in good agreement with the theoretical solution.Under layered packing,PSR has little eect on peak stress ratio due to similar microstructure obtained with the changing of PSR.The modulus slightly increased with the increase of PSR.Under random packing with small grain content of 50%,PSR has little eect in the range of 0.5–0.9,but in a larger range,larger PSR leads to greater modulus.展开更多
Fluidized bed superheated steam drying is one of the technologies successfully applied to drying pulp in the sugar beet industry. It has the technological advantages of energy efficiency and safety (inert environment)...Fluidized bed superheated steam drying is one of the technologies successfully applied to drying pulp in the sugar beet industry. It has the technological advantages of energy efficiency and safety (inert environment) required for use in drying bagasse. A comparison of the particle size distribution of bagasse and beet pulp was evaluated in terms of fluidization. The size distribution of bagasse particles is from 2 to 10 times broader than the equivalent distribution of beet pulp particles. The mean particle size of the bagasse is 1/3 of the mean size of the beet pulp. Fluidization tests proved that bagasse fluidization is possible. It was found that beet pulp and bagasse particles clearly differ on shape and size distribution which in turn will affect the design of the ancillary equipment and the fluidization systems if sugarcane bagasse is to be dried using superheated steam technology.展开更多
The synthesis of magnetic spinel ferrites at the nanoscale is a field of intense study, because the meso- scopic properties enable their novel applications. Spinel nanoparticles have a promising role because of their ...The synthesis of magnetic spinel ferrites at the nanoscale is a field of intense study, because the meso- scopic properties enable their novel applications. Spinel nanoparticles have a promising role because of their extraordinary properties compared with those of micro and macro scale particles. Several colloidal chemical synthetic procedures have been developed to produce monodisperse nanoparticles of spinel let- rites and other materials using sol-gel, co-precipitation, hydrothermal, and microemulsion techniques. To improve the synthesis method and conditions, quality and productivity of these nanoparticles, understanding the effect of extrinsic （pH, temperature, and molecular concentration） and intrinsic parameters （site preferences, latent heat, lattice parameters, electronic configuration, and bonding energy） on the particle size during synthesis is crucial. In this review, we discuss the effect of the intrinsic parameters on particle size of spinel ferrites to provide an insight to control their particle size more precisely.展开更多
We investigated the effects of model size and particle size on the simulated macroscopic mechanical properties, uniaxial compressive strength, Young＇s modulus, and flexural strength of sea-ice samples, using the disc...We investigated the effects of model size and particle size on the simulated macroscopic mechanical properties, uniaxial compressive strength, Young＇s modulus, and flexural strength of sea-ice samples, using the discrete-element method （DEM） with a bonded-particle model. Many different samples with a hexagonal-close-packing pattern and a unique particle size were considered, and several ratios of particle size to sample dimension （D/L） were studied for each sample. The macroscopic mechanical properties simulated by the DEM decrease monotonously with an increase in D/L. For different samples with different particle sizes, the macroscopic mechanical properties will be identical when D/L is constant. The quanti- tative relationships between macroscopic mechanical properties and ratio of particle size to sample size are important aspects in engineering applications of the DEM method. The results provide guidance on the choice of a particle size in the DEM simulation for numerical samples with a hexagonal-close-packing pattern.展开更多
The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stabili...The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stability of the solution obtained from DDF method has been investigated through optimizing the coefficient matrix, introducing a damping factor and a least square treatment. All calculations were accomplished with a microcomputer. It was shown that the average deviations of the size distribution obtained are not larger than the assigned random errors to the scattering intensities as long as the corresponding requirements are satisfied.展开更多
A feasible criterion was established to determine the lower size limit of raw coal(d_(pRm))for efficient beneficiation in the air-fluidized bed with magnetite particles.The feasibility of using small magnetite particl...A feasible criterion was established to determine the lower size limit of raw coal(d_(pRm))for efficient beneficiation in the air-fluidized bed with magnetite particles.The feasibility of using small magnetite particles to accommodate the fine raw coal was demonstrated from the experimental perspective.The minimum size for the magnetite particles to be fluidized smoothly was clarified as 47.1μm,which corresponded to the border between Geldart-B and-A groups.Since the gangue and coal components in the raw coal were crushed into the same size,d_(pRm)depended on the greater one between d_(pGm)(minimum size required for the gangue particles to sink towards the bottom)and d_(pCm)(minimum size required for the coal particles to float towards the top).dpcm was determined as 259μm by supposing that provided the gangue particles accumulated in the lower half bed,they could be potentially extracted from the bottom.On the other hand,it was observed that the coal particles could always accumulate in the upper half bed.Under such circumstances,dpcm was revealed as 9.8μm since finer coal particles would be blown out by air before the 47.1μm sized magnetite particles became fluidized.Eventually,dpRm was clarified as 259μm,agreeing with the common view that raw coal coarser than 6 mm could be effectively beneficiated in the air-fluidized bed with magnetite particles.Additionally,the difficulty in beneficiating the fine raw coal was revealed to arise more from the remixing of sorted gangue particles than that of separated coal particles.展开更多
Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shea...Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shear stiffness at the particle level. The results indicate that the mean particle size has a negligible effect on the small strain shear modulus. The observed increase of the shear modulus with increasing particle size is caused by a scale effect. It is suggested that the ratio of sample size to the mean particle size should be larger than 11.5 to avoid this possible scale effect. At the same confining pressure and void ratio, the small strain shear modulus decreases as the coefficient of uniformity of the soil increases. The Poisson＇s ratio decreases with decreasing void ratio and increasing confining pressure instead of being constant as is commonly assumed. Microscopic analyses indicate that the small strain shear stiffness and Poisson＇s ratio depend uniquely on the soil＇s coordination number.展开更多
Dry powder inhalers(DPIs) had been widely used in lung diseases on account of direct pulmonary delivery, good drug stability and satisfactory patient compliance. However, an indistinct understanding of pulmonary deliv...Dry powder inhalers(DPIs) had been widely used in lung diseases on account of direct pulmonary delivery, good drug stability and satisfactory patient compliance. However, an indistinct understanding of pulmonary delivery processes(PDPs) hindered the development of DPIs. Most current evaluation methods explored the PDPs with over-simplified models, leading to uncompleted investigations of the whole or partial PDPs. In the present research, an innovative modular process analysis platform(MPAP) was applied to investigate the detailed mechanisms of each PDP of DPIs with different carrier particle sizes(CPS). The MPAP was composed of a laser particle size analyzer, an inhaler device,an artificial throat and a pre-separator, to investigate the fluidization and dispersion, transportation,detachment and deposition process of DPIs. The release profiles of drug, drug aggregation and carrier were monitored in real-time. The influence of CPS on PDPs and corresponding mechanisms were explored. The powder properties of the carriers were investigated by the optical profiler and Freeman Technology four powder rheometer. The next generation impactor was employed to explore the aerosolization performance of DPIs. The novel MPAP was successfully applied in exploring the comprehensive mechanism of PDPs, which had enormous potential to be used to investigate and develop DPIs.展开更多
This paper uses the discrete element method to model the size and cushion effects during single-particle crushing tests.We propose simplified numerical modeling to examine the effects of particle size and coordination...This paper uses the discrete element method to model the size and cushion effects during single-particle crushing tests.We propose simplified numerical modeling to examine the effects of particle size and coordination number on particle breakage behavior.We validate the proposed modeling by comparing the numerical results with the experimental data reported in the literature,in terms of the variability of particle tensile strength and axial force-displacement responses.Based on the numerical results,it is clear that a larger particle size entails a higher tensile strength with a larger discreteness.In addition,the characteristic tensile strength increases linearly with an increasing coordination number.Moreover,smaller particles are more susceptible to the cushion effect than larger particles.The numerical results also indicate that an increasing coordination number induces a more ductile mode of failure.Based on these results,we propose an empirical equation for calculating tensile strength,incorporating both the cushion effect and the size effect.展开更多
The present study aimed to numerically simulate the rapid expansion of the supercritical solution(RESS)process including particle generation,hydrodynamics,and solving the population balance equation(PBE)to predict the...The present study aimed to numerically simulate the rapid expansion of the supercritical solution(RESS)process including particle generation,hydrodynamics,and solving the population balance equation(PBE)to predict the particle-size distribution(PSD)of solid-supercritical carbon dioxide binary systems.Energy,momentum,and mass equations,in addition to the extended generalized Bender equation of state(EoS),were applied to predict the hydrodynamic behavior of a supercritical solution under several operating conditions using a nozzle and expansion vessel.The tetraphenylporphyrin(TBTPP)solubility in supercritical carbon dioxide was calculated using the Peng-Robinson EoS/Kwak-Mansoori as a mixing rule.Subsequently,TBTPP,aspirin,ibuprofen,and salicylic acid nucleation as well as the supersaturation rate were calculated.Finally,we solved the time dependence of the parameters of the size distribution numerically.The established models are compared over a wide parameter range using a reference model that refers to the method of moment log-normal size distribution functions through the RESS process to predict a solid PSD.The results obtained are presented with and without coagulation phenomena.The average absolute percent deviation of solubility of TBTPP was 3.98,and the hydrodynamic behavior of supercritical carbon dioxide showed a similar trend as the results presented in the published research work.Furthermore,a particle size distribution prediction using coagulation showed acceptable agreement with the experimental PSDs.展开更多
The effect of dust particles on electric contacts and a hazardous size range of hard dust particles using a rigid model were discussed before. As further research, elastic-plastic model of finite element analysis was ...The effect of dust particles on electric contacts and a hazardous size range of hard dust particles using a rigid model were discussed before. As further research, elastic-plastic model of finite element analysis was established in this work, which is closer to real condition. In this work, the behavior of large size and small size particles, and the influence of particles hardness were investigated. The calculating result of small-size particles presents a general hazardous size coefficient for different contact surface morphology; for large-size particles, it presents a hazardous size coefficient for complicated composition of the dust. And the effect of the dust shape is also discussed.展开更多
Particle hydrogel composite(PHC)combines the characteristics of at least two mat erials and has pot ential applications in many fields.Different functions require the particle size to range from nanometer to millimete...Particle hydrogel composite(PHC)combines the characteristics of at least two mat erials and has pot ential applications in many fields.Different functions require the particle size to range from nanometer to millimeter,which has a noticeable effect on the mechanical properties of the hydrogel composites.In this paper,the mechanical properties of silica-inlaid PAAM hydrogel are measured with various particle diameters from 75 nm to 50|im.Experimental results show no obvious size effect on the mechanical properties of PHC when the particle diameter falls in micron scale.However,as the particle size decreases to nanoscale,the modulus of the PHC begins to increase rapidly.The size-irrelevant moduli and stress fields of PHCs with random and uniform particle distributions under different loading conditions are obtained based on the finite element method.Meanwhile,the toughening mechanism and the failure of the PHC are investigated.The size-irrelevant modulus of the PHC is also predicted by the equivalent inclusion theory.Finally,the interaction between the hydrogel polymer chains and the particles is described from the microscopic point of view,requiring the nanoscale size-dependent theory and new experimental approach to further explore the mechanical proper ties of PHC.展开更多
The structural and morphological properties of mesoporous silica nanoparticles( MSNs) have dramatical influence on their in vivo biological behaviors,and thereby synthesis of MSNs with well-defined shape and size has ...The structural and morphological properties of mesoporous silica nanoparticles( MSNs) have dramatical influence on their in vivo biological behaviors,and thereby synthesis of MSNs with well-defined shape and size has recently attracted much more attention in the biomedical field. The synthesis of MSNs with controllable size and shape was presented by controlling the reaction temperature and the concentration of templating agent(cetyltrimethylammonium bromide,CTAB). The results indicated that MSNs were larger in particle size and more round in shape with increasing of the reaction temperature,but their particle size and dispersivity became smaller and poorer as CTAB concentration increased. Therefore,the particle size and shape of MSNs can be tuned by using the optimal synthesis conditions for specific biomedical applications.展开更多
The particle composition and spatial distribution of landslide-induced dam bodies are critical geotechnical parameters for studying the hazards of dam-break floods.However,current research often neglects the influence...The particle composition and spatial distribution of landslide-induced dam bodies are critical geotechnical parameters for studying the hazards of dam-break floods.However,current research often neglects the influence of the initial particle composition and spatial distribution of the landslide on the particle composition and spatial distribution of the landslide dam.This study investigated the impact of initial particle size distribution,volume,and sliding length on the energy and velocity changes of characteristic particles during the sliding process and the spatial distribution of particle sizes in the landslide dam body.Numerical simulations and physical models were employed to examine the effects of sequential gradient arrangements(where particle sizes decrease from top to bottom)and four other different initial particle arrangements on the energy and velocity changes of particles and the spatial distribution of particle sizes in the dam body.The study reveals the characteristics of translational and rotational energy of different particles and the laws of mechanical energy conversion,obtaining the spatial distribution patterns of particle sizes in landslide-induced dams.The results show that under the sequential gradient arrangement,the energy dissipation of the landslide movement is lower,with larger particles mainly distributed at the distal end and smaller particles at the proximal end of the landslide dam.In contrast,under the reverse gradient arrangement,the energy dissipation of the landslide movement is higher,and the distribution pattern of the dam particles is opposite to that of the sequential gradient arrangement.For the other arrangement modes,the spatial distribution of dam particles falls between the aforementioned two.There is a positive correlation between particle size and translational kinetic energy within the particle flow during the landslide process,and rotational motion increases energy dissipation.Under constant slope conditions,sliding length does not affect the movement pattern of the particle flow or the spatial distribution of particles in the dam body.The findings of this study provide a scientific basis for the accurate simulation and prediction of dam-break flood processes.展开更多
While spray-drying has been widely utilized to improve the bioavailability of poorly water-soluble drugs,the outcomes often exhibit suboptimal particle size distribution and large particle sizes,limiting their effecti...While spray-drying has been widely utilized to improve the bioavailability of poorly water-soluble drugs,the outcomes often exhibit suboptimal particle size distribution and large particle sizes,limiting their effectiveness.In this study,we introduce electrostatic spraying as an advanced technology tailored for poorly water-soluble drugs,enabling the fabrication of nanoparticles with fine and uniform particle size distribution.Regorafenib(1 g),as a model drug,copovidone(5 g),and sodium dodecyl sulfate(0.1 g)were dissolved in 200 ml ethanol and subjected to conventional-spray-dryer and electrostatic spray dryer.The electrostatic spray-dried nanoparticles(ESDN)showed smaller particle sizes with better uniformity compared to conventional spray-dried nanoparticles(CSDN).ESDN demonstrated significantly enhanced solubility and rapid release in water.In vitro studies revealed that ESDN induced apoptosis in HCT-116 cells to a greater extent,exhibiting superior cytotoxicity compared to CSDN.Furthermore,ESDN substantially improved oral bioavailability and antitumor efficacy compared to CSDN.These findings suggest that ESD shows potential in developing enhanced drug delivery systems for poorly water-soluble drugs,effectively addressing the limitations associated with CSD methods.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant No.41790432)Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA20030301)。
文摘Internal erosion occurs when fine particles escape from the soil driven by seepage flow,which is considered to be the crucial factor causing the failure of earth structures filled with gravelly soil.The objective of this paper is to suggest an appropriate method to assess internal erosion potential of gravelly soil.By analyzing the sensitivity of soil material to internal erosion,the variable(Dc15/df85)max and the content of coarse particles(Pc)are selected as the evaluation indexes(Dc15 and df85 are the diameters of 15%mass passing in the coarse component and 85%mass passing in the fine component,respectively).A series of gravelly soils with different particle size distributions are tested for internal erosion by the self-made permeameter.Based on the test results,an evaluation method for the internal erosion of gravelly soil is proposed.Gravelly soil is prone to internal erosion when 60%≤Pc<95%and(Dc15/df85)max≥9.5.The proposed method shows good accuracy in evaluating the internal erosion of 36 soil samples from other studies,which confirms the reliability of the method.The proposed method makes it possible to accurately assess internal erosion of gravelly soil,and an alternative method is provided for engineers to determine whether there is a risk of internal erosion in earth structures consisting of gravelly soil.
基金completed as part of the Manaaki Whenua–Landcare Research-led MBIE Program,Soil Health and Resilience—A Pathway to Prosperity and Wellbeing(No.P/442062/01)Next Generation S-Map—Smarter Decisions(No.P/443063/01)+1 种基金the Plant&Food Research-led Strategic Science Investment Fund Program,Sustainable Agro-Ecosystemsfunded by the New Zealand Ministry of Business,Innovation and Employment。
文摘Particle size fraction(clay, silt, and sand) is an important characteristic that influences several soil functions. The laser-diffraction method(LDM) provides a fast and cost-effective measurement of particle size distribution, but the results usually differ from those obtained by the traditional sieve-pipette method(SPM). This difference can persist even when calibration is applied between the two methods. This partly relates to the different size ranges of particles measured by the two methods as a result of different operational principles, i.e., particle sedimentation according to Stokes’ Law vs. Mie theory for laser beam scattering. The objective of this study was to identify particle size ranges of LDM equivalent to those measured by SPM and evaluate whether new calibration models based on size range correction can be used to improve LDM-estimated particle size fractions, using 51 soil samples with various texture collected from five soil orders in New Zealand. Particle size distribution was determined using both LDM and SPM. Compared with SPM, original data from LDM underestimated the clay fraction(< 2 μm), overestimated the silt fraction(2–53 μm), but provided a good estimation of the sand fraction(53–2 000 μm).Results from three statistical indices, including Pearson’s correlation coefficient, slope, and Lin’s concordance correlation coefficient, showed that the size ranges of < 2 and 2–53 μm defined by SPM corresponded with the < 5 and 5–53 μm size ranges by LDM, respectively. Compared with the traditional calibration(based on the same particle size ranges), new calibration models(based on the corrected size ranges of these two methods) improved the estimation of clay and silt contents by LDM. Compared with soil-specific models(i.e., different models were developed for different soils), a universal model may be more parsimonious for estimating particle size fractions if the samples to be assessed represent multiple soil orders.
文摘The effect of spherical particle size on the surface morphology, electrochemical property and processability of lithium iron phosphate was systematically studied. Spherical lithium iron phosphate with different particle size distributions controlled with ball time of precursor slurry was prepared by spray drying method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), charge and discharge measurements and EIS. The electrochemical performances of the sample materials were measured by coin cells and 14500 batteries. XRD shows that the spherical lithium iron phosphate with different particle sizes all have good crystal structure due to the perfect mixing of the raw materials and rapid drying. The lithium iron phosphate microsphere with different particle sizes self-assembled with submicron primary particles has a core-shell structure. The longer ball time the precursors are, the smaller the active material particles are prepared. The electrode material with 6 h ball time of precursor slurry has the best physical properties and the processability. The composite has a uniform particle size and higher tap density of 1.46 g/cm3, which delivers a discharge capacity of 167.6 mAh/g at a discharge rate of 0.5 C. The results were confirmed by the 14 500 mA h cylindrical batteries, which delivers a discharge capacity of 579 mAh at 0.5 C. And low-temperature performance with capacity of 458.5 mA h at -20 °C under a discharge rate of 0.5 C is the 79.2% of the same discharge rate at 25 °C. Otherwise, the 14500 batteries also exhibit excellent cycling performance and the capacity maintains 93% after 2 000 cycles.
基金supported by the National Natural Science Foundation of China (Nos.12172263,11772237).
文摘The particle size ratio(PSR)is an important parameter for binary granular materials,which may aect the microstructure and macro behaviors of granular materials.However,the eect of particle ratio on granular assemblies with dierent arrangements is still unclear.To explore and further clarify the eect of PSR in dierent packing structures,three types of numerical samples with regular,layered,and random packing are designed.Numerical results show that PSR has signicant eects on binary granular samples with regular packing.The larger the PSR,the stronger the strength,the larger the modulus,and the smaller the angle between the shear band and the load direction.And a theoretical solution of the peak stress ratio vs.PSR is obtained for regular packing,and the results by DEM are in good agreement with the theoretical solution.Under layered packing,PSR has little eect on peak stress ratio due to similar microstructure obtained with the changing of PSR.The modulus slightly increased with the increase of PSR.Under random packing with small grain content of 50%,PSR has little eect in the range of 0.5–0.9,but in a larger range,larger PSR leads to greater modulus.
文摘Fluidized bed superheated steam drying is one of the technologies successfully applied to drying pulp in the sugar beet industry. It has the technological advantages of energy efficiency and safety (inert environment) required for use in drying bagasse. A comparison of the particle size distribution of bagasse and beet pulp was evaluated in terms of fluidization. The size distribution of bagasse particles is from 2 to 10 times broader than the equivalent distribution of beet pulp particles. The mean particle size of the bagasse is 1/3 of the mean size of the beet pulp. Fluidization tests proved that bagasse fluidization is possible. It was found that beet pulp and bagasse particles clearly differ on shape and size distribution which in turn will affect the design of the ancillary equipment and the fluidization systems if sugarcane bagasse is to be dried using superheated steam technology.
文摘The synthesis of magnetic spinel ferrites at the nanoscale is a field of intense study, because the meso- scopic properties enable their novel applications. Spinel nanoparticles have a promising role because of their extraordinary properties compared with those of micro and macro scale particles. Several colloidal chemical synthetic procedures have been developed to produce monodisperse nanoparticles of spinel let- rites and other materials using sol-gel, co-precipitation, hydrothermal, and microemulsion techniques. To improve the synthesis method and conditions, quality and productivity of these nanoparticles, understanding the effect of extrinsic （pH, temperature, and molecular concentration） and intrinsic parameters （site preferences, latent heat, lattice parameters, electronic configuration, and bonding energy） on the particle size during synthesis is crucial. In this review, we discuss the effect of the intrinsic parameters on particle size of spinel ferrites to provide an insight to control their particle size more precisely.
基金This work was supported by the National Natural Science Foundation of China （NSFC） （Grant Nos. 41606213, 51639004, 51579054）.
文摘We investigated the effects of model size and particle size on the simulated macroscopic mechanical properties, uniaxial compressive strength, Young＇s modulus, and flexural strength of sea-ice samples, using the discrete-element method （DEM） with a bonded-particle model. Many different samples with a hexagonal-close-packing pattern and a unique particle size were considered, and several ratios of particle size to sample dimension （D/L） were studied for each sample. The macroscopic mechanical properties simulated by the DEM decrease monotonously with an increase in D/L. For different samples with different particle sizes, the macroscopic mechanical properties will be identical when D/L is constant. The quanti- tative relationships between macroscopic mechanical properties and ratio of particle size to sample size are important aspects in engineering applications of the DEM method. The results provide guidance on the choice of a particle size in the DEM simulation for numerical samples with a hexagonal-close-packing pattern.
文摘The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stability of the solution obtained from DDF method has been investigated through optimizing the coefficient matrix, introducing a damping factor and a least square treatment. All calculations were accomplished with a microcomputer. It was shown that the average deviations of the size distribution obtained are not larger than the assigned random errors to the scattering intensities as long as the corresponding requirements are satisfied.
基金supported by Shandong Provincial Natural Science Foundation(ZR2023MB038)Youth Innovation Team Program of Shandong Higher Education Institution(2022KJ156)。
文摘A feasible criterion was established to determine the lower size limit of raw coal(d_(pRm))for efficient beneficiation in the air-fluidized bed with magnetite particles.The feasibility of using small magnetite particles to accommodate the fine raw coal was demonstrated from the experimental perspective.The minimum size for the magnetite particles to be fluidized smoothly was clarified as 47.1μm,which corresponded to the border between Geldart-B and-A groups.Since the gangue and coal components in the raw coal were crushed into the same size,d_(pRm)depended on the greater one between d_(pGm)(minimum size required for the gangue particles to sink towards the bottom)and d_(pCm)(minimum size required for the coal particles to float towards the top).dpcm was determined as 259μm by supposing that provided the gangue particles accumulated in the lower half bed,they could be potentially extracted from the bottom.On the other hand,it was observed that the coal particles could always accumulate in the upper half bed.Under such circumstances,dpcm was revealed as 9.8μm since finer coal particles would be blown out by air before the 47.1μm sized magnetite particles became fluidized.Eventually,dpRm was clarified as 259μm,agreeing with the common view that raw coal coarser than 6 mm could be effectively beneficiated in the air-fluidized bed with magnetite particles.Additionally,the difficulty in beneficiating the fine raw coal was revealed to arise more from the remixing of sorted gangue particles than that of separated coal particles.
基金The work presented in this paper was supported by the National Natural Science Foundation of China （Grant Nos. 51308408, 41272291,51238009） and the Fundamental Research Funds for the Central Universities, and the Open Foundation of State Key Labo- ratory of Hydrology-Water Resources and Hydraulic Engineering （Grant No. 2014492311 ）.
文摘Discrete element modeling was used to investigate the effect of particle size distribution on the small strain shear stiffness of granular soils and explore the fundamental mechanism controlling this small strain shear stiffness at the particle level. The results indicate that the mean particle size has a negligible effect on the small strain shear modulus. The observed increase of the shear modulus with increasing particle size is caused by a scale effect. It is suggested that the ratio of sample size to the mean particle size should be larger than 11.5 to avoid this possible scale effect. At the same confining pressure and void ratio, the small strain shear modulus decreases as the coefficient of uniformity of the soil increases. The Poisson＇s ratio decreases with decreasing void ratio and increasing confining pressure instead of being constant as is commonly assumed. Microscopic analyses indicate that the small strain shear stiffness and Poisson＇s ratio depend uniquely on the soil＇s coordination number.
基金funded by the Fundamental Research Funds for the Central Universities(Nos.21620434 and 2162014,China)the National Natural Science Foundation of China(Nos.81673375 and 81703431)+1 种基金the Science and Technology Foundation Guangzhou(No.201509030006,China)the National Students Innovation Training Program of China(No.201901390,China)。
文摘Dry powder inhalers(DPIs) had been widely used in lung diseases on account of direct pulmonary delivery, good drug stability and satisfactory patient compliance. However, an indistinct understanding of pulmonary delivery processes(PDPs) hindered the development of DPIs. Most current evaluation methods explored the PDPs with over-simplified models, leading to uncompleted investigations of the whole or partial PDPs. In the present research, an innovative modular process analysis platform(MPAP) was applied to investigate the detailed mechanisms of each PDP of DPIs with different carrier particle sizes(CPS). The MPAP was composed of a laser particle size analyzer, an inhaler device,an artificial throat and a pre-separator, to investigate the fluidization and dispersion, transportation,detachment and deposition process of DPIs. The release profiles of drug, drug aggregation and carrier were monitored in real-time. The influence of CPS on PDPs and corresponding mechanisms were explored. The powder properties of the carriers were investigated by the optical profiler and Freeman Technology four powder rheometer. The next generation impactor was employed to explore the aerosolization performance of DPIs. The novel MPAP was successfully applied in exploring the comprehensive mechanism of PDPs, which had enormous potential to be used to investigate and develop DPIs.
基金the National Natural Science Foundation of China(Grant Nos.51971188 and 51071134)the Science and Technology Major Project of Hunan Province(Grant No.2019GK 1012)+1 种基金Huxiang High-Level Talent Gathering Program of Hunan Province-In novative team(Grant No.2019RS1059)the Degree and Postgraduate Education Reform Project of Hunan Province(Grant No,CX20190493),All of this support is gratefully acknowledged.
文摘This paper uses the discrete element method to model the size and cushion effects during single-particle crushing tests.We propose simplified numerical modeling to examine the effects of particle size and coordination number on particle breakage behavior.We validate the proposed modeling by comparing the numerical results with the experimental data reported in the literature,in terms of the variability of particle tensile strength and axial force-displacement responses.Based on the numerical results,it is clear that a larger particle size entails a higher tensile strength with a larger discreteness.In addition,the characteristic tensile strength increases linearly with an increasing coordination number.Moreover,smaller particles are more susceptible to the cushion effect than larger particles.The numerical results also indicate that an increasing coordination number induces a more ductile mode of failure.Based on these results,we propose an empirical equation for calculating tensile strength,incorporating both the cushion effect and the size effect.
文摘The present study aimed to numerically simulate the rapid expansion of the supercritical solution(RESS)process including particle generation,hydrodynamics,and solving the population balance equation(PBE)to predict the particle-size distribution(PSD)of solid-supercritical carbon dioxide binary systems.Energy,momentum,and mass equations,in addition to the extended generalized Bender equation of state(EoS),were applied to predict the hydrodynamic behavior of a supercritical solution under several operating conditions using a nozzle and expansion vessel.The tetraphenylporphyrin(TBTPP)solubility in supercritical carbon dioxide was calculated using the Peng-Robinson EoS/Kwak-Mansoori as a mixing rule.Subsequently,TBTPP,aspirin,ibuprofen,and salicylic acid nucleation as well as the supersaturation rate were calculated.Finally,we solved the time dependence of the parameters of the size distribution numerically.The established models are compared over a wide parameter range using a reference model that refers to the method of moment log-normal size distribution functions through the RESS process to predict a solid PSD.The results obtained are presented with and without coagulation phenomena.The average absolute percent deviation of solubility of TBTPP was 3.98,and the hydrodynamic behavior of supercritical carbon dioxide showed a similar trend as the results presented in the published research work.Furthermore,a particle size distribution prediction using coagulation showed acceptable agreement with the experimental PSDs.
文摘The effect of dust particles on electric contacts and a hazardous size range of hard dust particles using a rigid model were discussed before. As further research, elastic-plastic model of finite element analysis was established in this work, which is closer to real condition. In this work, the behavior of large size and small size particles, and the influence of particles hardness were investigated. The calculating result of small-size particles presents a general hazardous size coefficient for different contact surface morphology; for large-size particles, it presents a hazardous size coefficient for complicated composition of the dust. And the effect of the dust shape is also discussed.
文摘Particle hydrogel composite(PHC)combines the characteristics of at least two mat erials and has pot ential applications in many fields.Different functions require the particle size to range from nanometer to millimeter,which has a noticeable effect on the mechanical properties of the hydrogel composites.In this paper,the mechanical properties of silica-inlaid PAAM hydrogel are measured with various particle diameters from 75 nm to 50|im.Experimental results show no obvious size effect on the mechanical properties of PHC when the particle diameter falls in micron scale.However,as the particle size decreases to nanoscale,the modulus of the PHC begins to increase rapidly.The size-irrelevant moduli and stress fields of PHCs with random and uniform particle distributions under different loading conditions are obtained based on the finite element method.Meanwhile,the toughening mechanism and the failure of the PHC are investigated.The size-irrelevant modulus of the PHC is also predicted by the equivalent inclusion theory.Finally,the interaction between the hydrogel polymer chains and the particles is described from the microscopic point of view,requiring the nanoscale size-dependent theory and new experimental approach to further explore the mechanical proper ties of PHC.
基金National Natural Science Foundation of China(No.31271028)Shanghai Natural Science Foundation,China(No.11ZR1400100)+5 种基金Shanghai Nano Science Program,China(No.11nm0505500)Innovation Program of Shanghai Municipal Education Commission,China(No.13ZZ051)Fundamental Research Funds for the Central Universities,ChinaOpen Foundation of State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,China(No.LK1202)Chinese Universities Scientific Fund(No.13D310608)the Scientific Research Foundation for Returned Scholars,Ministry of Education of China
文摘The structural and morphological properties of mesoporous silica nanoparticles( MSNs) have dramatical influence on their in vivo biological behaviors,and thereby synthesis of MSNs with well-defined shape and size has recently attracted much more attention in the biomedical field. The synthesis of MSNs with controllable size and shape was presented by controlling the reaction temperature and the concentration of templating agent(cetyltrimethylammonium bromide,CTAB). The results indicated that MSNs were larger in particle size and more round in shape with increasing of the reaction temperature,but their particle size and dispersivity became smaller and poorer as CTAB concentration increased. Therefore,the particle size and shape of MSNs can be tuned by using the optimal synthesis conditions for specific biomedical applications.
基金reported in this manuscript is funded by the National Natural Science Foundation of China(Grant No.52130904).
文摘The particle composition and spatial distribution of landslide-induced dam bodies are critical geotechnical parameters for studying the hazards of dam-break floods.However,current research often neglects the influence of the initial particle composition and spatial distribution of the landslide on the particle composition and spatial distribution of the landslide dam.This study investigated the impact of initial particle size distribution,volume,and sliding length on the energy and velocity changes of characteristic particles during the sliding process and the spatial distribution of particle sizes in the landslide dam body.Numerical simulations and physical models were employed to examine the effects of sequential gradient arrangements(where particle sizes decrease from top to bottom)and four other different initial particle arrangements on the energy and velocity changes of particles and the spatial distribution of particle sizes in the dam body.The study reveals the characteristics of translational and rotational energy of different particles and the laws of mechanical energy conversion,obtaining the spatial distribution patterns of particle sizes in landslide-induced dams.The results show that under the sequential gradient arrangement,the energy dissipation of the landslide movement is lower,with larger particles mainly distributed at the distal end and smaller particles at the proximal end of the landslide dam.In contrast,under the reverse gradient arrangement,the energy dissipation of the landslide movement is higher,and the distribution pattern of the dam particles is opposite to that of the sequential gradient arrangement.For the other arrangement modes,the spatial distribution of dam particles falls between the aforementioned two.There is a positive correlation between particle size and translational kinetic energy within the particle flow during the landslide process,and rotational motion increases energy dissipation.Under constant slope conditions,sliding length does not affect the movement pattern of the particle flow or the spatial distribution of particles in the dam body.The findings of this study provide a scientific basis for the accurate simulation and prediction of dam-break flood processes.
基金This work was supported by the National Research Foundation of South Korea(NRF)grants funded by the South Korean government(MEST)(No.2022R1A2C2004197,RS-2024-00407053 and RS-2023-00208448).
文摘While spray-drying has been widely utilized to improve the bioavailability of poorly water-soluble drugs,the outcomes often exhibit suboptimal particle size distribution and large particle sizes,limiting their effectiveness.In this study,we introduce electrostatic spraying as an advanced technology tailored for poorly water-soluble drugs,enabling the fabrication of nanoparticles with fine and uniform particle size distribution.Regorafenib(1 g),as a model drug,copovidone(5 g),and sodium dodecyl sulfate(0.1 g)were dissolved in 200 ml ethanol and subjected to conventional-spray-dryer and electrostatic spray dryer.The electrostatic spray-dried nanoparticles(ESDN)showed smaller particle sizes with better uniformity compared to conventional spray-dried nanoparticles(CSDN).ESDN demonstrated significantly enhanced solubility and rapid release in water.In vitro studies revealed that ESDN induced apoptosis in HCT-116 cells to a greater extent,exhibiting superior cytotoxicity compared to CSDN.Furthermore,ESDN substantially improved oral bioavailability and antitumor efficacy compared to CSDN.These findings suggest that ESD shows potential in developing enhanced drug delivery systems for poorly water-soluble drugs,effectively addressing the limitations associated with CSD methods.
