Double perovskite matrix materials have recently attracted considerable interest due to their structural flexibility,ease of doping,and excellent thermal stability.While photoluminescence(PL)studies of rare-earth-dope...Double perovskite matrix materials have recently attracted considerable interest due to their structural flexibility,ease of doping,and excellent thermal stability.While photoluminescence(PL)studies of rare-earth-doped double perovskites are common,research on their thermoluminescence(TL)properties is less extensive.This study synthesized a series of Y_(2-x)Sm_(x)MgTiO_(6)(0≤x≤0.1)samples using a high-temperature solid-state method.X-ray diffraction(XRD)analysis confirmed a monoclinic crystal structure(space group P2_(1)∕n),with Sm^(3+)ions substituting for Y^(3+)ions in Y_(2)MgTiO_(6).The PL results indicated that the optimal doping concentration was Y_(1.95)Sm_(0.05)MgTiO_(6),exhibiting emission peaks at 568,605,652,and 715 nm under 409 nm blue light excitation.The TL measurements for different doping concentrations showed that the Y_(1.98)Sm_(0.02)MgTiO_(6)phosphors exhibited the strongest TL signals.The TL peaks observed at 530 and 610 K correspond to defects in the matrix and Sm^(3+)dopants,respectively.The T_(m)-T_(stop)analysis revealed that the TL curve of Y_(1.98)Sm_(0.02)MgTiO_(6)phosphors was a superposition of seven peaks.Computerized glow curve deconvolution(CGCD)was performed on the TL of the sample according to the results of three-dimensional thermoluminescence spectra(3D-TL)and T_(m)-T_(stop),and the trap depths in the sample were estimated to range from 0.69 to 1.49 eV.Additionally,the lifetimes of each overlapping peak were calculated using the fitting parameters.Furthermore,the dose-response test showed that the saturation dose of the sample was high(9956 Gy).Therefore,this material can serve as a thermoluminescent dosimeter for high-dose measurements.The saturation dose for the lowest-temperature overlapping peak was 102 Gy,which correlated with its specific energy-level lifetime,whereas the other overlapping peaks also exhibited favorable linear relationships.展开更多
In this article, different population contributions of quartz powders to chemical reactivity in pozzolanic reaction were studied. Deconvolution software was used to show the different particle populations of each prod...In this article, different population contributions of quartz powders to chemical reactivity in pozzolanic reaction were studied. Deconvolution software was used to show the different particle populations of each product. Reaction of quartz powder with lime in the pozzolanic reaction at 20 ℃ shows that reactivity of each powder population depends on its particle size. Adsorbed fine particles on coarse particle surfaces have a significant role in the first term of the reaction. In a second term, the micropowders react. The mesopowders react only in the last reaction terms. Until now, the reactivity of adsorbed powder has been attributed to amorphization of the particle surface.展开更多
基金supported by the Zhanjiang Science and Technology Plan Project(No.2022A05022)Science and Technology Development Special Project of Zhanjiang(No.2023A21616)Research Project of Guangdong Ocean University(No.060302112102).
文摘Double perovskite matrix materials have recently attracted considerable interest due to their structural flexibility,ease of doping,and excellent thermal stability.While photoluminescence(PL)studies of rare-earth-doped double perovskites are common,research on their thermoluminescence(TL)properties is less extensive.This study synthesized a series of Y_(2-x)Sm_(x)MgTiO_(6)(0≤x≤0.1)samples using a high-temperature solid-state method.X-ray diffraction(XRD)analysis confirmed a monoclinic crystal structure(space group P2_(1)∕n),with Sm^(3+)ions substituting for Y^(3+)ions in Y_(2)MgTiO_(6).The PL results indicated that the optimal doping concentration was Y_(1.95)Sm_(0.05)MgTiO_(6),exhibiting emission peaks at 568,605,652,and 715 nm under 409 nm blue light excitation.The TL measurements for different doping concentrations showed that the Y_(1.98)Sm_(0.02)MgTiO_(6)phosphors exhibited the strongest TL signals.The TL peaks observed at 530 and 610 K correspond to defects in the matrix and Sm^(3+)dopants,respectively.The T_(m)-T_(stop)analysis revealed that the TL curve of Y_(1.98)Sm_(0.02)MgTiO_(6)phosphors was a superposition of seven peaks.Computerized glow curve deconvolution(CGCD)was performed on the TL of the sample according to the results of three-dimensional thermoluminescence spectra(3D-TL)and T_(m)-T_(stop),and the trap depths in the sample were estimated to range from 0.69 to 1.49 eV.Additionally,the lifetimes of each overlapping peak were calculated using the fitting parameters.Furthermore,the dose-response test showed that the saturation dose of the sample was high(9956 Gy).Therefore,this material can serve as a thermoluminescent dosimeter for high-dose measurements.The saturation dose for the lowest-temperature overlapping peak was 102 Gy,which correlated with its specific energy-level lifetime,whereas the other overlapping peaks also exhibited favorable linear relationships.
文摘In this article, different population contributions of quartz powders to chemical reactivity in pozzolanic reaction were studied. Deconvolution software was used to show the different particle populations of each product. Reaction of quartz powder with lime in the pozzolanic reaction at 20 ℃ shows that reactivity of each powder population depends on its particle size. Adsorbed fine particles on coarse particle surfaces have a significant role in the first term of the reaction. In a second term, the micropowders react. The mesopowders react only in the last reaction terms. Until now, the reactivity of adsorbed powder has been attributed to amorphization of the particle surface.
