In this study, S-doped NbSea （NbSo.aSel.8） powders were fabricated, and the corresponding Cu-based composites （Cu/NbSo.eSe1.8） were obtained by powder metallurgy technique. The phase compositions, physical, and tr...In this study, S-doped NbSea （NbSo.aSel.8） powders were fabricated, and the corresponding Cu-based composites （Cu/NbSo.eSe1.8） were obtained by powder metallurgy technique. The phase compositions, physical, and tribological properties of Cu-based composites were investigated systematically. The results show that Cu matrix reacts with NbSo.2Sel.8 to produce Cu2Se and Cu0.38NbSo.2Se1.8 during sintering process, which influences the physical and tribological properties of Cu-based composites significantly. Specially, with NbS0.2Se1.8 content increasing, the density of Cu/ NbSo.2Se1.8 composites decreases, and the hardness increases firstly and then decreases, while the electric resistivity in- creases slightly. In addition, the incorporation of NbSo.2Se1.8 enhances the tribological properties of Cu greatly, which is attributed to the lubricating effect of Cuo,38NbSo.2Se1.8 and the reinforcement effect of Cu2Se. In particular, when the content of NbSo.2Sel.8 is 6 wt%, the Cu-based composite has the best tribological properties.展开更多
Cu and Nb powders were used as starting materials to produce Cu-Nb and Cu-NbC-WC composites by mechanical alloying.X-ray diffraction,scanning electron microscopy,transmission electron microscopy observations and micro...Cu and Nb powders were used as starting materials to produce Cu-Nb and Cu-NbC-WC composites by mechanical alloying.X-ray diffraction,scanning electron microscopy,transmission electron microscopy observations and microhardness measurements have been used to study the effects of milling tools on the phase,microstructure and property of the composites.The results revealed that a single-phase nanocrystalline solid solution was obtained using stainless steel vials and balls(Alloy 1).Nevertheless,Cu-7 wt%Nb powders milled by tungsten carbon vials and balls exhibited an amorphous phase(Alloy 2).The as-milled powders were then vacuum hot-pressing sintered.The microstructure of sintered Alloy 1 consisted of Nb nanoparticles and Cu nanograins.Instead,Alloy 2 showed a microstructure with NbC nanoparticles and WC submicron-sized particles dispersed throughout the Cu matrix.Furthermore,Alloy 2(~322 HV)had a higher microhardness than Alloy 1(~302 HV).展开更多
The mechanical and tribological properties of Cu-based powder metallurgy （P/M） friction composites containing 10wt%-50wt% oxide-dispersion-strengthened （ODS） Cu reinforced with nano-Al2O3 were investigated. Additi...The mechanical and tribological properties of Cu-based powder metallurgy （P/M） friction composites containing 10wt%-50wt% oxide-dispersion-strengthened （ODS） Cu reinforced with nano-Al2O3 were investigated. Additionally, the friction and wear behaviors as well as the wear mechanism of the Cu-based composites were characterized by scanning electron microscopy （SEM） in conjunction with energy-dispersive X-ray spectroscopy （EDS） elemental mapping. The results indicated that the Cu-based friction composite containing 30wt% ODS Cu exhibited the highest hardness and shear strength. The average and instantaneous friction coefficient curves of this sample, when operated in a high-speed train at a speed of 300 km/h, were similar to those of a commercial disc brake pad produced by Knorr-Bremse AG （Germany）. Additionally, the lowest linear wear loss of the obtained samples was （0.008 ± 0.001） mm per time per face, which is much lower than that of the Knorr-Bremse pad （（0.01 ± 0.001） mm）. The excellent performance of the developed pad is a consequence of the formation of a dense oxide composite layer and its close combination with the pad body.展开更多
Thermodynamically stable and ultra-thin “phase” at the interface, known as complexions, can significantly improve the mechanical properties of nanolayered composites. However, the effect of complexions features (e.g...Thermodynamically stable and ultra-thin “phase” at the interface, known as complexions, can significantly improve the mechanical properties of nanolayered composites. However, the effect of complexions features (e.g., crystalline orientation, crystalline structure and amorphous composition) on the plastic deformation remains inadequately investigated, and the correlation with the plastic transmission and mechanical response has not been fully established. Here, using atomistic simulations, we elucidate the different complexions-dominated plastic transmission and mechanical response. Complexions can alter the preferred slip system of dislocation nucleation, depending on the Schmid factor and interface structure. After nucleation, the dislocation density exhibits an inverse correlation with the stress magnitude, because the number of dislocations influences the initiation of plastic deformation and determines the stress release. For crystalline complexions with different structures and orientations, the ability of dislocation transmission is mainly dependent on the continuity of the slip system. The plastic transmission can easily proceed and exhibits relatively low flow stress when the slip system is well-aligned. In the case of amorphous complexions with different compositions, compositional variations impact the atomic percentage of shear transformation zones after loading, resulting in different magnitudes of plastic deformation. When smaller plastic deformation is produced, less stress can be released contributing to higher flow stress. These findings reveal the role of the complexions on plasticity behavior and provide valuable insights for the design of nanolayered composites.展开更多
Bulk Cu50Zr40Ti10 amorphous alloy composites reinforced with carbon nanotube （CNT） were successfully fabricated by hot pressing technique. Their density, thermal conductivity, and mechanical properties were systemic...Bulk Cu50Zr40Ti10 amorphous alloy composites reinforced with carbon nanotube （CNT） were successfully fabricated by hot pressing technique. Their density, thermal conductivity, and mechanical properties were systemically investigated. The density and the compression strength of the compacts both decrease with increasing CNT content. The thermal conductivity of the compacts decreases when the CNT content is less than 0.10% or exceeds 0.60% （mass fraction）, while increases when the CNT content is in the range of 0.1%-0.6%. The strain limit and the modulus of the compacts are obviously improved when the CNT content is less than 1.0% and then decrease significantly when the CNT content exceeds 1.00%. The optimum CNT addition is less than 0.20% at the comprehensive properties point of view.展开更多
Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynam...Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.展开更多
A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and...A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.展开更多
KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to eva...KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).展开更多
The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecul...The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
There is an urgent need to develop magnesium-matrix materials that exhibit both high thermal conductivity and low thermal expansion to ensure compatibility with chips.This study aims to develop a Mg-Zn-Cu alloy with h...There is an urgent need to develop magnesium-matrix materials that exhibit both high thermal conductivity and low thermal expansion to ensure compatibility with chips.This study aims to develop a Mg-Zn-Cu alloy with high thermal conductivity.Furthermore,it explores the preparation of AlN_(P)/Mg-Zn-Cu composites featuring low coefficients of thermal expansion.The stir casting method was utilized to fabricate the composites and an investigation was conducted to examine their microstructure and thermal properties.Results indicate that the addition of AlN_(P)reduces the thermal expansion coefficient while maintaining relatively high thermal conductivity.Specifically,the AlN_(P)/Mg-0.5Zn-0.5Cu composite with 30wt.%AlN_(P)achieves a thermal conductivity of 132.7 W·m^(-1)·K^(-1)and a thermal expansion coefficient of 18.5×10^(-6)K^(-1),rendering it suitable for electronic packaging applications where thermal management is critical.展开更多
In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires...In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.展开更多
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu...A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.展开更多
To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8＋20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by las...To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8＋20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by laser cladding, respectively. SEM （scanning electron microscopy）, EDS （energy dispersive X-ray spectroscopy）, XRD （X-ray diffraction） and TEM （transmission electron microscopy） techniques were employed to study the phases of the coatings. The results show that the coatings mainly consist of amorphous phase and different intermetallic compounds. The reason of formation of amorphous phase and the function of SiC particles were explained in details.展开更多
Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied....Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied.Therefore,to analyze its bearing characteristics under complex conditions-such as silty soil,chalky soil,and shallow bedrock-this paper employs finite element software to establish various soil combination scenarios.The load-displacement curves of the foundations under these scenarios are calculated to subsequently evaluate the horizontal ultimate bearing capacity.This study investigates the effects of shallow bedrock depth,the type of soil above the bedrock,the thickness of layered soil,and the quality of layered soil on the bearing characteristics of the monocolumn composite bucket foundation.Based on the principle of single-variable control,the ultimate bearing capacity characteristics of the foundation under different conditions are compared.The distribution of soil pressure inside and outside the bucket wall on the compressed side of the foundation,along with the plastic strain of the soil at the base of the foundation,is also analyzed.In conclusion,shallow bedrock somewhat reduces foundation bearing capacity.Under shallow bedrock conditions,the degree of influence on foundation bearing capacity characteristics can considerably vary on different upper soils.The thickness of each soil layer and the depth to bedrock in stratified soils also affect the bearing capacity of the foundation.The findings of this paper provide a theoretical reference for related foundation design and construction.In practice,the bearing performance of the foundation can be enhanced by improvingthe soil quality in the bucket,adjusting the penetration depth,adjusting the percentage of different types of soil layers in the bucket,and applying other technical construction methods.展开更多
To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as wel...To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as well.Herein,we suggest an effective approach to control the micropore structure of silicon oxide(SiO_(x))/artificial graphite(AG)composite electrodes using a perforated current collector.The electrode features a unique pore structure,where alternating high-porosity domains and low-porosity domains markedly reduce overall electrode resistance,leading to a 20%improvement in rate capability at a 5C-rate discharge condition.Using microstructure-resolved modeling and simulations,we demonstrate that the patterned micropore structure enhances lithium-ion transport,mitigating the electrolyte concentration gradient of lithium-ion.Additionally,perforating current collector with a chemical etching process increases the number of hydrogen bonding sites and enlarges the interface with the SiO_(x)/AG composite electrode,significantly improving adhesion strength.This,in turn,suppresses mechanical degradation and leads to a 50%higher capacity retention.Thus,regularly arranged micropore structure enabled by the perforated current collector successfully improves both rate capability and cycle life in SiO_(x)/AG composite electrodes,providing valuable insights into electrode engineering.展开更多
In-situ formed （Cu0.6Zr0.3Ti0.1）95Nb5 bulk metallic glass （BMG） composite with Nb-rich dendrite randomly dispersed in hard glassy matrix was prepared by casting into a water-cooled copper mold. The dendrite has mu...In-situ formed （Cu0.6Zr0.3Ti0.1）95Nb5 bulk metallic glass （BMG） composite with Nb-rich dendrite randomly dispersed in hard glassy matrix was prepared by casting into a water-cooled copper mold. The dendrite has much smaller hardness and elastic modulus than glassy matrix, and the stress concentration at interface provides a channel for the initiating and branching of shear bands upon loading, thus leading to a high compressive fracture strain of 6.08% and fracture strength about 2200 MPa. Comparing with other Cu-based BMG composite, the fracture strength of present （Cu0.6Zr0.3Ti0.1）95Nb5 composite is not significantly reduced, indicating that the addition of Nb in the current work is an effective and effortless way to fabricate new practical BMG composites with enhanced strength and good plasticity.展开更多
Variable stiffness composites present a promising solution for mitigating impact loads via varying the fiber volume fraction layer-wise,thereby adjusting the panel's stiffness.Since each layer of the composite may...Variable stiffness composites present a promising solution for mitigating impact loads via varying the fiber volume fraction layer-wise,thereby adjusting the panel's stiffness.Since each layer of the composite may be affected by a different failure mode,the optimal fiber volume fraction to suppress damage initiation and evolution is different across the layers.This research examines how re-allocating the fibers layer-wise enhances the composites'impact resistance.In this study,constant stiffness panels with the same fiber volume fraction throughout the layers are compared to variable stiffness ones by varying volume fraction layer-wise.A method is established that utilizes numerical analysis coupled with optimization techniques to determine the optimal fiber volume fraction in both scenarios.Three different reinforcement fibers(Kevlar,carbon,and glass)embedded in epoxy resin were studied.Panels were manufactured and tested under various loading conditions to validate results.Kevlar reinforcement revealed the highest tensile toughness,followed by carbon and then glass fibers.Varying reinforcement volume fraction significantly influences failure modes.Higher fractions lead to matrix cracking and debonding,while lower fractions result in more fiber breakage.The optimal volume fraction for maximizing fiber breakage energy is around 45%,whereas it is about 90%for matrix cracking and debonding.A drop tower test was used to examine the composite structure's behavior under lowvelocity impact,confirming the superiority of Kevlar-reinforced composites with variable stiffness.Conversely,glass-reinforced composites with constant stiffness revealed the lowest performance with the highest deflection.Across all reinforcement materials,the variable stiffness structure consistently outperformed its constant stiffness counterpart.展开更多
Designing materials with both structural load-bearing capacity and broadband electromagnetic(EM)wave absorption properties remains a significant challenge.In this work,SiOC/SiC/SiO_(2)composite with gyroid structures ...Designing materials with both structural load-bearing capacity and broadband electromagnetic(EM)wave absorption properties remains a significant challenge.In this work,SiOC/SiC/SiO_(2)composite with gyroid structures were prepared through digital light processing(DLP)3D printing,polymer-derived ceramics(PDCs),chemical vapor infiltration(CVI),and oxidation technologies.The incorporation of the CVISiC phase effectively increases the dissipation capability,while the synergistic interaction between the gyroid structure and SiO_(2)phase significantly improves impedance matching performance.The SiOC/SiC/SiO_(2)composite achieved a minimum reflection loss(RL min)of-62.2 d B at 4.3 mm,and the effective absorption bandwidth(EAB)covered the X-band,with a thickness range of 4.1 mm-4.65 mm.The CST simulation results explain the broadband and low-frequency absorption characteristics,with an EAB of 8.4 GHz(9.6-18 GHz)and an RL min of-21.5 dB at 5 GHz.The excellent EM wave attenuation performance is associated primarily with polarization loss,conduction loss,the gyroid structure's enhancement of multiple reflections and scattering of EM waves,and the resonance effect between the structural units.The SiOC/SiC/SiO_(2)composite also demonstrated strong mechanical properties,with a maximum compressive failure strength of 31.6 MPa in the height direction.This work opens novel prospects for the development of multifunctional structural wave-absorbing materials suitable for broadband microwave absorption and load-bearing properties.展开更多
Electroslag remelting(ESR) is an important metallurgical process for producing high-purity materials with homogeneous compositions and sound microstructures,and its typical products are ingots or simple castings.The c...Electroslag remelting(ESR) is an important metallurgical process for producing high-purity materials with homogeneous compositions and sound microstructures,and its typical products are ingots or simple castings.The core principle involves the resistive melting of a consumable electrode within a slag pool,followed by the refining of molten metal droplets as they traverse the slag,and subsequent sequential solidification in a water-cooled mold.However,conventional ESR processes face limitations in producing large or complex-shaped components,enhancing production efficiency,achieving highly specialized microstructures,and meeting ultra-high purity demands for advanced applications.Advanced composite ESR technologies have been developed to overcome these limitations by innovatively modifying key process aspects.For instance,electrode systems are improved using vibration,rotation,or multiple electrodes.Enhanced mold design and solidification control are achieved through techniques including conductive molds,mold rotation,and ingot withdrawal.Precise control of the process is realized through the use of protective gas,vacuum,or elevated pressure,as well as the application of external fields such as magnetic fields or ultrasonic vibration.This review comprehensively summarizes these advanced techniques,examining their principles and characteristics,and discussing their specific advantages and challenges.展开更多
基金financially supported by the National Nature Science Foundation of China(Nos.51405199 and21301075)the Natural Science Foundation of Jiangsu Province(Nos.BK20140551 and BK20140562)+4 种基金the Postdoctoral Science Foundation of China(No.2014M561579)the Postdoctoral Science Foundation of Jiangsu Province(No.1401106C)the Opening Foundation of Jiangsu Province Material Tribology Key Laboratory(No.Kjsmcx201304)the Senior Intellectuals Fund of Jiangsu University(No.13JDG099)the Industry-Academy-Research Union Foundation of Jiangsu Province(No.BY2013065-05)
文摘In this study, S-doped NbSea （NbSo.aSel.8） powders were fabricated, and the corresponding Cu-based composites （Cu/NbSo.eSe1.8） were obtained by powder metallurgy technique. The phase compositions, physical, and tribological properties of Cu-based composites were investigated systematically. The results show that Cu matrix reacts with NbSo.2Sel.8 to produce Cu2Se and Cu0.38NbSo.2Se1.8 during sintering process, which influences the physical and tribological properties of Cu-based composites significantly. Specially, with NbS0.2Se1.8 content increasing, the density of Cu/ NbSo.2Se1.8 composites decreases, and the hardness increases firstly and then decreases, while the electric resistivity in- creases slightly. In addition, the incorporation of NbSo.2Se1.8 enhances the tribological properties of Cu greatly, which is attributed to the lubricating effect of Cuo,38NbSo.2Se1.8 and the reinforcement effect of Cu2Se. In particular, when the content of NbSo.2Sel.8 is 6 wt%, the Cu-based composite has the best tribological properties.
基金financially supported by the National Natural Science Foundation of China(No.51401197)
文摘Cu and Nb powders were used as starting materials to produce Cu-Nb and Cu-NbC-WC composites by mechanical alloying.X-ray diffraction,scanning electron microscopy,transmission electron microscopy observations and microhardness measurements have been used to study the effects of milling tools on the phase,microstructure and property of the composites.The results revealed that a single-phase nanocrystalline solid solution was obtained using stainless steel vials and balls(Alloy 1).Nevertheless,Cu-7 wt%Nb powders milled by tungsten carbon vials and balls exhibited an amorphous phase(Alloy 2).The as-milled powders were then vacuum hot-pressing sintered.The microstructure of sintered Alloy 1 consisted of Nb nanoparticles and Cu nanograins.Instead,Alloy 2 showed a microstructure with NbC nanoparticles and WC submicron-sized particles dispersed throughout the Cu matrix.Furthermore,Alloy 2(~322 HV)had a higher microhardness than Alloy 1(~302 HV).
基金financially supported by the National High Technology Research and Development Program of China (No. 2013AA031104)
文摘The mechanical and tribological properties of Cu-based powder metallurgy （P/M） friction composites containing 10wt%-50wt% oxide-dispersion-strengthened （ODS） Cu reinforced with nano-Al2O3 were investigated. Additionally, the friction and wear behaviors as well as the wear mechanism of the Cu-based composites were characterized by scanning electron microscopy （SEM） in conjunction with energy-dispersive X-ray spectroscopy （EDS） elemental mapping. The results indicated that the Cu-based friction composite containing 30wt% ODS Cu exhibited the highest hardness and shear strength. The average and instantaneous friction coefficient curves of this sample, when operated in a high-speed train at a speed of 300 km/h, were similar to those of a commercial disc brake pad produced by Knorr-Bremse AG （Germany）. Additionally, the lowest linear wear loss of the obtained samples was （0.008 ± 0.001） mm per time per face, which is much lower than that of the Knorr-Bremse pad （（0.01 ± 0.001） mm）. The excellent performance of the developed pad is a consequence of the formation of a dense oxide composite layer and its close combination with the pad body.
基金supported by the National Natural Science Foundation of China(Nos.U23A20543,52071124)the Natural Science Foundation of the Hebei Province(No.E2021202135).
文摘Thermodynamically stable and ultra-thin “phase” at the interface, known as complexions, can significantly improve the mechanical properties of nanolayered composites. However, the effect of complexions features (e.g., crystalline orientation, crystalline structure and amorphous composition) on the plastic deformation remains inadequately investigated, and the correlation with the plastic transmission and mechanical response has not been fully established. Here, using atomistic simulations, we elucidate the different complexions-dominated plastic transmission and mechanical response. Complexions can alter the preferred slip system of dislocation nucleation, depending on the Schmid factor and interface structure. After nucleation, the dislocation density exhibits an inverse correlation with the stress magnitude, because the number of dislocations influences the initiation of plastic deformation and determines the stress release. For crystalline complexions with different structures and orientations, the ability of dislocation transmission is mainly dependent on the continuity of the slip system. The plastic transmission can easily proceed and exhibits relatively low flow stress when the slip system is well-aligned. In the case of amorphous complexions with different compositions, compositional variations impact the atomic percentage of shear transformation zones after loading, resulting in different magnitudes of plastic deformation. When smaller plastic deformation is produced, less stress can be released contributing to higher flow stress. These findings reveal the role of the complexions on plasticity behavior and provide valuable insights for the design of nanolayered composites.
基金Project (50874045) supported by the National Natural Science Foundation of ChinaProjects (200902472, 20080431021) supported by the China Postdoctoral Science FoundationProject (10A044) supported by the Research Foundation of Education Bureau of Hunan Province of China
文摘Bulk Cu50Zr40Ti10 amorphous alloy composites reinforced with carbon nanotube （CNT） were successfully fabricated by hot pressing technique. Their density, thermal conductivity, and mechanical properties were systemically investigated. The density and the compression strength of the compacts both decrease with increasing CNT content. The thermal conductivity of the compacts decreases when the CNT content is less than 0.10% or exceeds 0.60% （mass fraction）, while increases when the CNT content is in the range of 0.1%-0.6%. The strain limit and the modulus of the compacts are obviously improved when the CNT content is less than 1.0% and then decrease significantly when the CNT content exceeds 1.00%. The optimum CNT addition is less than 0.20% at the comprehensive properties point of view.
基金Supported by the National Natural Science Foundation of China(Nos.52293472,22473096 and 22471164)。
文摘Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.
文摘A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.
基金Supported by the Autonomous Research Project of SKLCC(2024BWZ003)Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0390401)the Doctoral Research Start-up Funding of Shanxi Institute of Technology(026012).
文摘KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).
文摘The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金financially supported by National Natural Science Foundation of China(No.52175321)the Fund of Key Laboratory of High Temperature Electromagnetic Materials and Structure of MOE(No.KB202505)。
文摘There is an urgent need to develop magnesium-matrix materials that exhibit both high thermal conductivity and low thermal expansion to ensure compatibility with chips.This study aims to develop a Mg-Zn-Cu alloy with high thermal conductivity.Furthermore,it explores the preparation of AlN_(P)/Mg-Zn-Cu composites featuring low coefficients of thermal expansion.The stir casting method was utilized to fabricate the composites and an investigation was conducted to examine their microstructure and thermal properties.Results indicate that the addition of AlN_(P)reduces the thermal expansion coefficient while maintaining relatively high thermal conductivity.Specifically,the AlN_(P)/Mg-0.5Zn-0.5Cu composite with 30wt.%AlN_(P)achieves a thermal conductivity of 132.7 W·m^(-1)·K^(-1)and a thermal expansion coefficient of 18.5×10^(-6)K^(-1),rendering it suitable for electronic packaging applications where thermal management is critical.
基金Funded by Hunan Provincial Natural Science Foundation(No.2023JJ40074)Hunan Provincial Education Department Excellent Youth Project(No.21B0757)Hunan Provincial Engineering Technology Center(No.2022TP2036)。
文摘In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.
基金supported by Guangdong Major Project of Basic and Applied Basic Research, China (No. 2020B0301030006)Fundamental Research Funds for the Central Universities, China (No. SWU-XDJH202313)+1 种基金Chongqing Postdoctoral Science Foundation Funded Project, China (No. 2112012728014435)the Chongqing Postgraduate Research and Innovation Project, China (No. CYS23197)。
文摘A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.
基金supported by the Open Fund of the State Key Laboratory of Advanced Welding Production Technology in Harbin Institute of Technology,Chinathe Open Fund of the State Key Laboratory of Materials Processing and Die&Mould Technology in Huazhong University of Science and Technology,China
文摘To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8＋20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by laser cladding, respectively. SEM （scanning electron microscopy）, EDS （energy dispersive X-ray spectroscopy）, XRD （X-ray diffraction） and TEM （transmission electron microscopy） techniques were employed to study the phases of the coatings. The results show that the coatings mainly consist of amorphous phase and different intermetallic compounds. The reason of formation of amorphous phase and the function of SiC particles were explained in details.
文摘Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied.Therefore,to analyze its bearing characteristics under complex conditions-such as silty soil,chalky soil,and shallow bedrock-this paper employs finite element software to establish various soil combination scenarios.The load-displacement curves of the foundations under these scenarios are calculated to subsequently evaluate the horizontal ultimate bearing capacity.This study investigates the effects of shallow bedrock depth,the type of soil above the bedrock,the thickness of layered soil,and the quality of layered soil on the bearing characteristics of the monocolumn composite bucket foundation.Based on the principle of single-variable control,the ultimate bearing capacity characteristics of the foundation under different conditions are compared.The distribution of soil pressure inside and outside the bucket wall on the compressed side of the foundation,along with the plastic strain of the soil at the base of the foundation,is also analyzed.In conclusion,shallow bedrock somewhat reduces foundation bearing capacity.Under shallow bedrock conditions,the degree of influence on foundation bearing capacity characteristics can considerably vary on different upper soils.The thickness of each soil layer and the depth to bedrock in stratified soils also affect the bearing capacity of the foundation.The findings of this paper provide a theoretical reference for related foundation design and construction.In practice,the bearing performance of the foundation can be enhanced by improvingthe soil quality in the bucket,adjusting the penetration depth,adjusting the percentage of different types of soil layers in the bucket,and applying other technical construction methods.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.NRF-2021M3H4A1A02048529)the Ministry of Trade,Industry and Energy(MOTIE)of the Korean government under grant No.RS-2022-00155854support from the DGIST Supercomputing and Big Data Center.
文摘To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as well.Herein,we suggest an effective approach to control the micropore structure of silicon oxide(SiO_(x))/artificial graphite(AG)composite electrodes using a perforated current collector.The electrode features a unique pore structure,where alternating high-porosity domains and low-porosity domains markedly reduce overall electrode resistance,leading to a 20%improvement in rate capability at a 5C-rate discharge condition.Using microstructure-resolved modeling and simulations,we demonstrate that the patterned micropore structure enhances lithium-ion transport,mitigating the electrolyte concentration gradient of lithium-ion.Additionally,perforating current collector with a chemical etching process increases the number of hydrogen bonding sites and enlarges the interface with the SiO_(x)/AG composite electrode,significantly improving adhesion strength.This,in turn,suppresses mechanical degradation and leads to a 50%higher capacity retention.Thus,regularly arranged micropore structure enabled by the perforated current collector successfully improves both rate capability and cycle life in SiO_(x)/AG composite electrodes,providing valuable insights into electrode engineering.
基金Project(51371149)supported by the National Natural Science Foundation of ChinaProject(151048)supported by the HUO Ying-dong Young Teacher Fund+4 种基金Project(2015ZF53066)supported by the Aeronautical Science Foundation of ChinaProject(92-QZ-2014)supported by the Free Research Fund of State Key Laboratory of Solidification Processing,ChinaProject(2015KJXX-10)supported by Shaanxi Young Stars of Science and Technology,ChinaProejct(2011CB610403)supported by the National Basic Research Program of ChinaProject(51125002)supported by the National Science Funds for Distinguished Young Scientists,China
文摘In-situ formed （Cu0.6Zr0.3Ti0.1）95Nb5 bulk metallic glass （BMG） composite with Nb-rich dendrite randomly dispersed in hard glassy matrix was prepared by casting into a water-cooled copper mold. The dendrite has much smaller hardness and elastic modulus than glassy matrix, and the stress concentration at interface provides a channel for the initiating and branching of shear bands upon loading, thus leading to a high compressive fracture strain of 6.08% and fracture strength about 2200 MPa. Comparing with other Cu-based BMG composite, the fracture strength of present （Cu0.6Zr0.3Ti0.1）95Nb5 composite is not significantly reduced, indicating that the addition of Nb in the current work is an effective and effortless way to fabricate new practical BMG composites with enhanced strength and good plasticity.
基金funded by the American University of Sharjah.United Arab Emirates award number EN 9502-FRG19-M-E75。
文摘Variable stiffness composites present a promising solution for mitigating impact loads via varying the fiber volume fraction layer-wise,thereby adjusting the panel's stiffness.Since each layer of the composite may be affected by a different failure mode,the optimal fiber volume fraction to suppress damage initiation and evolution is different across the layers.This research examines how re-allocating the fibers layer-wise enhances the composites'impact resistance.In this study,constant stiffness panels with the same fiber volume fraction throughout the layers are compared to variable stiffness ones by varying volume fraction layer-wise.A method is established that utilizes numerical analysis coupled with optimization techniques to determine the optimal fiber volume fraction in both scenarios.Three different reinforcement fibers(Kevlar,carbon,and glass)embedded in epoxy resin were studied.Panels were manufactured and tested under various loading conditions to validate results.Kevlar reinforcement revealed the highest tensile toughness,followed by carbon and then glass fibers.Varying reinforcement volume fraction significantly influences failure modes.Higher fractions lead to matrix cracking and debonding,while lower fractions result in more fiber breakage.The optimal volume fraction for maximizing fiber breakage energy is around 45%,whereas it is about 90%for matrix cracking and debonding.A drop tower test was used to examine the composite structure's behavior under lowvelocity impact,confirming the superiority of Kevlar-reinforced composites with variable stiffness.Conversely,glass-reinforced composites with constant stiffness revealed the lowest performance with the highest deflection.Across all reinforcement materials,the variable stiffness structure consistently outperformed its constant stiffness counterpart.
基金financially supported by National Natural Science Foundation of China(Grant Nos.12141203,52202083,W2421013)the Natural Science Foundation Project of Shaanxi Province(Grant No.2024JC-YBMS-450)+1 种基金the Sichuan Science and Technology Program(Grant No.2024YFHZ0265)the Open Project of High-end Equipment Advanced Materials and Manufacturing Technology Laboratory(Grant No.2023KFKT0005)。
文摘Designing materials with both structural load-bearing capacity and broadband electromagnetic(EM)wave absorption properties remains a significant challenge.In this work,SiOC/SiC/SiO_(2)composite with gyroid structures were prepared through digital light processing(DLP)3D printing,polymer-derived ceramics(PDCs),chemical vapor infiltration(CVI),and oxidation technologies.The incorporation of the CVISiC phase effectively increases the dissipation capability,while the synergistic interaction between the gyroid structure and SiO_(2)phase significantly improves impedance matching performance.The SiOC/SiC/SiO_(2)composite achieved a minimum reflection loss(RL min)of-62.2 d B at 4.3 mm,and the effective absorption bandwidth(EAB)covered the X-band,with a thickness range of 4.1 mm-4.65 mm.The CST simulation results explain the broadband and low-frequency absorption characteristics,with an EAB of 8.4 GHz(9.6-18 GHz)and an RL min of-21.5 dB at 5 GHz.The excellent EM wave attenuation performance is associated primarily with polarization loss,conduction loss,the gyroid structure's enhancement of multiple reflections and scattering of EM waves,and the resonance effect between the structural units.The SiOC/SiC/SiO_(2)composite also demonstrated strong mechanical properties,with a maximum compressive failure strength of 31.6 MPa in the height direction.This work opens novel prospects for the development of multifunctional structural wave-absorbing materials suitable for broadband microwave absorption and load-bearing properties.
基金supported by the National Natural Science Foundation of China (NSFC 52175352)。
文摘Electroslag remelting(ESR) is an important metallurgical process for producing high-purity materials with homogeneous compositions and sound microstructures,and its typical products are ingots or simple castings.The core principle involves the resistive melting of a consumable electrode within a slag pool,followed by the refining of molten metal droplets as they traverse the slag,and subsequent sequential solidification in a water-cooled mold.However,conventional ESR processes face limitations in producing large or complex-shaped components,enhancing production efficiency,achieving highly specialized microstructures,and meeting ultra-high purity demands for advanced applications.Advanced composite ESR technologies have been developed to overcome these limitations by innovatively modifying key process aspects.For instance,electrode systems are improved using vibration,rotation,or multiple electrodes.Enhanced mold design and solidification control are achieved through techniques including conductive molds,mold rotation,and ingot withdrawal.Precise control of the process is realized through the use of protective gas,vacuum,or elevated pressure,as well as the application of external fields such as magnetic fields or ultrasonic vibration.This review comprehensively summarizes these advanced techniques,examining their principles and characteristics,and discussing their specific advantages and challenges.
