A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulen...A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulent kinetic energy-turbulent dissipation rate(k-ε)turbulence model,volume-of-fluid multiphase model,discrete-phase model,and unreacted core model for the reaction between the hot metal and particles were coupled.The measured sulfur content of the hot metal with time during the actual KR process was employed to validate the current mathematical model.The distance from the lowest point of the liquid level to the bottom of the ladle decreased from 3170 to2191 mm when the rotation speed increased from 30 to 110 r/min,which had a great effect on the dispersion of desulfurizer particles.The critical rotation speed for the vortex to reach the upper edge of the stirring impeller was 70 r/min when the immersion depth was 1500 mm.The desulfurization rate increased with the increase in the impeller rotation speed,whereas the influence of the immersion depth was relatively small.Formulas for different rotation parameters on the desulfurization rate constant and turbulent energy dissipation rate were proposed to evaluate the variation in sulfur content over time.展开更多
This paper introduces the results of selecting and breeding a micro-organism, Strain I, and its core model experiment investigation for microbial enhanced oil recovery (MEOR). Strain I was separated from the formation...This paper introduces the results of selecting and breeding a micro-organism, Strain I, and its core model experiment investigation for microbial enhanced oil recovery (MEOR). Strain I was separated from the formation water of the Dagang oil field, with analytical results showing that Strain I is a gram-positive bacillus. A further study revealed that this strain has an excellent tolerance of environmental stresses: It can survive in conditions of 70℃, 30 wt% salinity and pH3.5-9.4. Strain I can metabolize biosurfactants that could increase the oil recovery ratio, use crude oil as the single carbon source, and decompose long-chain paraffin with a large molecular weight into short-chain paraffin with a small molecular weight. The core model experiment shows that Strain I enhances oil recovery well. Using 2 vol% of the fermentation solution of Strain I to displace the crude oil in the synthetic plastic bonding core could increase the recovery ratio by 21.6%.展开更多
Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, ...Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, and these kinetic factors are very important to the quality of slab. The basic kinetic theory of unreacted core model was used to build the mathematical model for the growth of inclusions and the concerned software was developed through Visual Basic 6.0. The time that different radius inclusions attain saturation was calculated to determine the controlling step of reaction between steel and inclusions. The time for the growth of inclusion obtained from the model was in good agreement with the data measured by Japanese Okuyama G, which indicated that the model is reasonable.展开更多
The kinetics of H<sub>2</sub>S removal by zinc oxide desulfurizer was studied through thermogravimetricanalysis.The experimental results show that desulfurization rate was controlled,at high temperatureand...The kinetics of H<sub>2</sub>S removal by zinc oxide desulfurizer was studied through thermogravimetricanalysis.The experimental results show that desulfurization rate was controlled,at high temperatureand low conversion,by the chemical reaction rate,and at low temperature and high conversion by thegrain diffusion rate.The reaction is first order with respect to H<sub>2</sub>S concentration in the differentcontrolled stages.The kinetic behavior can be modeled through the employment of the shrinking coremodel.The values of the model parameters were determined.The variation tendencies with temperatureand concentration of H<sub>2</sub>S at the controlled stages were discussed.展开更多
The effect of rotation on the shape (figure) and gravitational quadrupole of astronomical bodies is calculated by using an approximate point core model: A point mass at the center of an ellipsoidal homogeneous fluid. ...The effect of rotation on the shape (figure) and gravitational quadrupole of astronomical bodies is calculated by using an approximate point core model: A point mass at the center of an ellipsoidal homogeneous fluid. Maclaurin’s analytical result for homogenous bodies generalizes to this model and leads to very accurate analytical results connecting the three observables: oblateness (ò), gravitational quadrupole (J2), and angular velocity parameter (q). The analytical results are compared to observational data for the planets and a good agreement is found. Oscillations near equilibrium are studied within the model.展开更多
This research introduces an equivalent circuitmodel and a computational method to address complex mechanical motion issues through electromechanical analogies.The study initially refines core vibration characteristics...This research introduces an equivalent circuitmodel and a computational method to address complex mechanical motion issues through electromechanical analogies.The study initially refines core vibration characteristics using single-and multi-degree-of-freedom models,subsequently establishing equivalent circuit models for these various degrees of freedom.However,employing high degree-of-freedom models for detailed modelling of the core proves overly cumbersome.The research advocates for a distributed equivalent circuit model to more accurately represent the core's layered structure,thus facilitating enhanced core modelling.Moreover,the study formulates a mechanical wave transmission equation pertinent to the vibration of the iron core,which constitutes the foundation of the distributed mechanical vibration model.This model comprehensively assesses the impact of three critical factors on core vibration:the non-linearity of winding resistance,the elec-tromechanical coupling coefficient,and the dynamic stiffness of the core.A case study elucidates the distinct influences of each factor on vibration characteristics.Furthermore,this study derives vibration calculations from a 60-day overload ageing test conducted on a 10 kV transformer under 135℃overloadconditions.The methodology involves integrating measured compression force values and the calculated dynamic stiffness of the core into an equivalent circuit model.Subsequent analysis compares the results from the equivalent circuit model with experimental measurements.These comparisons indicate an agreement between the calculated and measured values in the time-frequency domain,thereby con-firming the accuracy of the equivalent circuit model calculations.展开更多
The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction te...The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction tempera ture （170℃-220℃） and reaction time （150-1800 s） during the hydrolysis process of five kinds of crop straw （rice, wheat, cotton, rape and corn）, the shrinking core model was established, and the differential equation of the model and its analytical solution were obtained. With a numerical calculation method, the kinetic equation was estimated, and the degradation of reducing sugar obeyed firstorder kinetics was obtained. The calculated results from the equations agreed well with the original experimental data. The calculation by the model showed that the reducing sugar concentration increases as the size of the particles decrease, and the uniform particles increase.展开更多
A simple Core-SOL-Divertor （C-S-D） model has been developed to investigate qualitatively the overall features of the operational space for the integrated core and edge plasma. To construct the simple C-S-D model, a ...A simple Core-SOL-Divertor （C-S-D） model has been developed to investigate qualitatively the overall features of the operational space for the integrated core and edge plasma. To construct the simple C-S-D model, a simple core plasma model of ITER physics guidelines and a two-point SOL-divertor model are used. The simple C-S-D model is applied to the study of the EAST operational space with lower hybrid current drive experiments under various kinds of trade-off for the basic plasma parameters. Effective methods for extending the operational space are also presented, From this study for the EAST operational space, it is evident that the C-S-D model is a useful tool for understanding qualitatively the overall features of the plasma operational space.展开更多
The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption...The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption process with shell diffusion as the controlling step were determined by semi-empirical and semi-theoretical methods, and the apparent activation energy of the hydrogen absorption process was obtained. The calculation results can well accord with the experimental data, and can well forecast the hydrogen storage capacity and absorption rate at different times. By using the kinetics equation, the effects of temperature and pressure on the hydrogen storage process can also be well understood. The kinetics equation is helpful for the design of the hydrogen storage container.展开更多
The SMART （System-integrated Modular Advanced ReacTor） which is a 330 MWt advanced integral PWR was developed by the KAERI （Korea Atomic Energy Institute） for electricity generation and seawater desalination. To e...The SMART （System-integrated Modular Advanced ReacTor） which is a 330 MWt advanced integral PWR was developed by the KAERI （Korea Atomic Energy Institute） for electricity generation and seawater desalination. To enhance its safety, the various design concepts were adopted such as the most containing of the RCS （reactor coolant system） components and a PRHRS （passive residual heat removal system）. To ensure the safety and performance of the SMART, a thermal hydraulic evaluation and safety analysis are performed by the TASS/SMR-S code. It uses a one dimensional node/path modeling and point kinetics for the core power simulation. The code also has specific models reflecting the design features of the SMART such as a helical tube and PRHRS heat transfer models. In this study, the validation of the core heat transfer model in the TASS/SMR-S code on the steady conditions was performed with the Bennett＇s heated tube tests and THTF （thermal hydraulic test facility） experiment. From the results of the TASS/SMR-S code calculation, the CHF （critical heat flux） point and the fuel rod surface temperature were predicted conservatively compared to the test results.展开更多
Scattering attenuation in short wavelengths has long been interesting to geophysicists. Ultrasonic coda waves, observed as the tail portion of ultrasonic wavetrains in laboratory ultrasonic measurements, are important...Scattering attenuation in short wavelengths has long been interesting to geophysicists. Ultrasonic coda waves, observed as the tail portion of ultrasonic wavetrains in laboratory ultrasonic measurements, are important for such studies where ultrasonic waves interact with smallscale random heterogeneities on a scale of micrometers, but often ignored as noises because of the contamination of boundary reflections from the side ends of a sample core. Numerical simulations with accurate absorbing boundary can provide insight into the effect of boundary reflections on coda waves in laboratory experiments. The simulation of wave propagation in digital and heterogeneous porous cores really challenges numerical techniques by digital image of poroelastic properties, numerical dispersion at high frequency and strong heterogeneity, and accurate absorbing boundary schemes at grazing incidence. To overcome these difficulties, we present a staggered-grid high-order finite-difference （FD） method of Biot＇s poroelastic equations, with an arbitrary even-order （2L） accuracy to simulate ultrasonic wave propagation in digital porous cores with strong heterogeneity. An unsplit convolutional perfectly matched layer （CPML） absorbing boundary, which improves conventional PML methods at grazing incidence with less memory and better computational efficiency, is employed in the simulation to investigate the influence of boundary reflections on ultra- sonic coda waves. Numerical experiments with saturated poroelastic media demonstrate that the 2L FD scheme with the CPML for ultrasonic wave propagation significantly improves stability conditions at strong heterogeneity and absorbing performance at grazing incidence. The boundary reflections from the artificial boundary surrounding the digital core decay fast with the increase of CPML thick- nesses, almost disappearing at the CPML thickness of 15 grids. Comparisons of the resulting ultrasonic coda Qsc values between the numerical and experimental ultrasonic S waveforms for a cylindrical rock sample demonstrate that the boundary reflection may contribute around one-third of the ultrasonic coda attenuation observed in laboratory experiments.展开更多
The paper is devoted to mathematical modelling of static and dynamic stability of a simply supported three-layered beam with a metal foam core. Mechanical properties of the core vary along the vertical direction. The ...The paper is devoted to mathematical modelling of static and dynamic stability of a simply supported three-layered beam with a metal foam core. Mechanical properties of the core vary along the vertical direction. The field of displacements is for- mulated using the classical broken line hypothesis and the proposed nonlinear hypothesis that generalizes the classical one. Using both hypotheses, the strains are determined as well as the stresses of each layer. The kinetic energy, the elastic strain energy, and the work of load are also determined. The system of equations of motion is derived using Hamilton＇s principle. Finally, the system of three equations is reduced to one equation of motion, in particular, the Mathieu equation. The Bubnov-Galerkin method is used to solve the system of equations of motion, and the Runge-Kutta method is used to solve the second-order differential equation. Numerical calculations are done for the chosen family of beams. The critical loads, unstable regions, angular frequencies of the beam, and the static and dynamic equilibrium paths are calculated analytically and verified numerically. The results of this study are presented in the forms of figures and tables.展开更多
In this paper, the influencing factors that affect few-mode and multi core optical fiber channel are analyzed in a comprehensive way. The theoretical modeling and computer simulation of the information channel are car...In this paper, the influencing factors that affect few-mode and multi core optical fiber channel are analyzed in a comprehensive way. The theoretical modeling and computer simulation of the information channel are carried out and then the modeling scheme of few-mode multicore optical fiber channel based on non-uniform mode field distribution is put forward. The proposed modeling scheme can not only exponentially increases the system capacity through fewmode multi-core optical fiber channel, but has better transmission performance compared to the channel of the same type to the uniform channel revealing from the simulation results.展开更多
The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurr...The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurry with ferrous sulfate and sulfuric acidsolution was filled into a vertical tube(9m in height)and air was blown from the bottom of the reactor.The effects of initial acidconcentration,temperature,particle size,initial zinc sulfate concentration,pulp density and the concentration of Fe on the leachingkinetics were investigated.Results of the kinetic analysis indicate that direct leaching of zinc sulfide concentrate follows shrinkingcore model(SCM).This process was controlled by a chemical reaction with the apparent activation energy of49.7kJ/mol.Furthermore,a semi-empirical equation is obtained,showing that the order of the iron,sulfuric acid and zinc sulfate concentrationsand particle radius are0.982,0.189,-0.097and-0.992,respectively.Analysis of the unreacted and reacted sulfide particles bySEM-EDS shows that insensitive agitation in the reactor causes detachment of the sulfur layer from the particles surface in lowerthan60%Zn conversion and lixiviant in the face with sphalerite particles.展开更多
A mathematical model based on the computational fluid dynamics method,heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during p...A mathematical model based on the computational fluid dynamics method,heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during preheating was established.The commercial software COMSOL Multiphysics was used to simulate the change in the oxidation degree of the pellet at different temperatures and oxygen concentrations,and the simulated results were compared with the exper-imental results.The model considered the influence of the exothermic heat of the reaction,and the enthalpy change was added to calculate the heat released by the oxidation.The results show that the oxidation rate on the surface of the pellet is much faster than that of the inside of the pellet.Temperature and oxygen concentration have great influence on the pellet oxidation model.Meanwhile,the exothermic calculation results show that there is a non-isothermal phenomenon inside the pellet,which leads to an increase in temperature inside the single pellet.Under the preheating condition of 873-1273 K(20%oxygen content),the heat released by the pellet oxidation reaction in a chain grate is 7.8×10^(6)-10.8×10^(6) kJ/h,which is very large and needs to be considered in the magnetite pellet oxidation modelling.展开更多
The leaching behavior of Tunceli malachite mineral was investigated in nitric acid solutions by two steps to evaluate the effect of various experimental parameters.In the first step,the optimal conditions for the leac...The leaching behavior of Tunceli malachite mineral was investigated in nitric acid solutions by two steps to evaluate the effect of various experimental parameters.In the first step,the optimal conditions for the leaching process were determined,while in the second step,a kinetic evaluation for the process was performed.In the optimization experiments,the concentration of nitric acid,temperature,stirring speed,and solid-to-liquid ratio were selected as the independent variables,and the central composite design method(CCD)was applied to the experimental data.At the end of the experiments,the optimal values for the concentration of nitric acid,temperature,solid-to-liquid ratio and stirring speed were determined to be 0.5 mol/L,50℃,0.004 g/m L and 500 r/min,respectively.Under the optimal conditions,the leaching rate was found to be 99%for 120 min of reaction time.In the kinetic evaluation tests,the effects of the concentration of nitric acid,temperature,stirring speed,solid-to-liquid ratio and particle size on the leaching rate of copper from malachite were investigated.In these tests,it was determined that the leaching rate increased with the increase in the temperature,acid concentration and stirring speed,and with the decrease in the particle size and solid-to-liquid ratio.In consequence of the kinetic analysis,it was observed that the leaching kinetics followed the mixed kinetic model,and a mathematical model for the leaching process was introduced.The activation energy for this process was calculated to be 36.23 k J/mol.展开更多
CORE糖尿病模型是由IQVIA公司开发的用于糖尿病治疗药物的经济学研究模型,模型使用C++语言编程,通过将马尔可夫模型(Markov Model)结构和使用跟踪变量的蒙特卡罗分析(Monte Carlo Analysis)结合起来模拟糖尿病及其并发症的长期自然进展...CORE糖尿病模型是由IQVIA公司开发的用于糖尿病治疗药物的经济学研究模型,模型使用C++语言编程,通过将马尔可夫模型(Markov Model)结构和使用跟踪变量的蒙特卡罗分析(Monte Carlo Analysis)结合起来模拟糖尿病及其并发症的长期自然进展。近年来我国学者共在国内外发表了11篇基于CORE糖尿病模型的药物经济学研究,文献发表数量随年份增加有所上升。随着药物经济学在我国的不断发展,CORE模型在糖尿病领域的药物经济学研究中有很好的应用前景。展开更多
基金financially supported by the National Science Foundation China(No.52104343)the Natural Science Foundation of Hebei Province,China(No.E2021203222)+1 种基金support from the High Steel Center(HSC)at Yanshan UniversityNorth China University of Technology,China。
文摘A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulent kinetic energy-turbulent dissipation rate(k-ε)turbulence model,volume-of-fluid multiphase model,discrete-phase model,and unreacted core model for the reaction between the hot metal and particles were coupled.The measured sulfur content of the hot metal with time during the actual KR process was employed to validate the current mathematical model.The distance from the lowest point of the liquid level to the bottom of the ladle decreased from 3170 to2191 mm when the rotation speed increased from 30 to 110 r/min,which had a great effect on the dispersion of desulfurizer particles.The critical rotation speed for the vortex to reach the upper edge of the stirring impeller was 70 r/min when the immersion depth was 1500 mm.The desulfurization rate increased with the increase in the impeller rotation speed,whereas the influence of the immersion depth was relatively small.Formulas for different rotation parameters on the desulfurization rate constant and turbulent energy dissipation rate were proposed to evaluate the variation in sulfur content over time.
文摘This paper introduces the results of selecting and breeding a micro-organism, Strain I, and its core model experiment investigation for microbial enhanced oil recovery (MEOR). Strain I was separated from the formation water of the Dagang oil field, with analytical results showing that Strain I is a gram-positive bacillus. A further study revealed that this strain has an excellent tolerance of environmental stresses: It can survive in conditions of 70℃, 30 wt% salinity and pH3.5-9.4. Strain I can metabolize biosurfactants that could increase the oil recovery ratio, use crude oil as the single carbon source, and decompose long-chain paraffin with a large molecular weight into short-chain paraffin with a small molecular weight. The core model experiment shows that Strain I enhances oil recovery well. Using 2 vol% of the fermentation solution of Strain I to displace the crude oil in the synthetic plastic bonding core could increase the recovery ratio by 21.6%.
基金Item Sponsored by National Natural Science Foundation of China and Shanghai Baoshan Steel Group(50674013)
文摘Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, and these kinetic factors are very important to the quality of slab. The basic kinetic theory of unreacted core model was used to build the mathematical model for the growth of inclusions and the concerned software was developed through Visual Basic 6.0. The time that different radius inclusions attain saturation was calculated to determine the controlling step of reaction between steel and inclusions. The time for the growth of inclusion obtained from the model was in good agreement with the data measured by Japanese Okuyama G, which indicated that the model is reasonable.
基金Supported by the National Natural Science Foundation of China.
文摘The kinetics of H<sub>2</sub>S removal by zinc oxide desulfurizer was studied through thermogravimetricanalysis.The experimental results show that desulfurization rate was controlled,at high temperatureand low conversion,by the chemical reaction rate,and at low temperature and high conversion by thegrain diffusion rate.The reaction is first order with respect to H<sub>2</sub>S concentration in the differentcontrolled stages.The kinetic behavior can be modeled through the employment of the shrinking coremodel.The values of the model parameters were determined.The variation tendencies with temperatureand concentration of H<sub>2</sub>S at the controlled stages were discussed.
文摘The effect of rotation on the shape (figure) and gravitational quadrupole of astronomical bodies is calculated by using an approximate point core model: A point mass at the center of an ellipsoidal homogeneous fluid. Maclaurin’s analytical result for homogenous bodies generalizes to this model and leads to very accurate analytical results connecting the three observables: oblateness (ò), gravitational quadrupole (J2), and angular velocity parameter (q). The analytical results are compared to observational data for the planets and a good agreement is found. Oscillations near equilibrium are studied within the model.
基金Science and Technology Project of State Grid Corporation of China,Grant/Award Number:5500-202113135A-0-0-00。
文摘This research introduces an equivalent circuitmodel and a computational method to address complex mechanical motion issues through electromechanical analogies.The study initially refines core vibration characteristics using single-and multi-degree-of-freedom models,subsequently establishing equivalent circuit models for these various degrees of freedom.However,employing high degree-of-freedom models for detailed modelling of the core proves overly cumbersome.The research advocates for a distributed equivalent circuit model to more accurately represent the core's layered structure,thus facilitating enhanced core modelling.Moreover,the study formulates a mechanical wave transmission equation pertinent to the vibration of the iron core,which constitutes the foundation of the distributed mechanical vibration model.This model comprehensively assesses the impact of three critical factors on core vibration:the non-linearity of winding resistance,the elec-tromechanical coupling coefficient,and the dynamic stiffness of the core.A case study elucidates the distinct influences of each factor on vibration characteristics.Furthermore,this study derives vibration calculations from a 60-day overload ageing test conducted on a 10 kV transformer under 135℃overloadconditions.The methodology involves integrating measured compression force values and the calculated dynamic stiffness of the core into an equivalent circuit model.Subsequent analysis compares the results from the equivalent circuit model with experimental measurements.These comparisons indicate an agreement between the calculated and measured values in the time-frequency domain,thereby con-firming the accuracy of the equivalent circuit model calculations.
文摘The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction tempera ture （170℃-220℃） and reaction time （150-1800 s） during the hydrolysis process of five kinds of crop straw （rice, wheat, cotton, rape and corn）, the shrinking core model was established, and the differential equation of the model and its analytical solution were obtained. With a numerical calculation method, the kinetic equation was estimated, and the degradation of reducing sugar obeyed firstorder kinetics was obtained. The calculated results from the equations agreed well with the original experimental data. The calculation by the model showed that the reducing sugar concentration increases as the size of the particles decrease, and the uniform particles increase.
基金supported in part by the JSPS-CAS Core-University Program in the field of Plasma and Nuclear Fusionalso carried out as a joint project under the Facility Utilization Program of JAERI.
文摘A simple Core-SOL-Divertor （C-S-D） model has been developed to investigate qualitatively the overall features of the operational space for the integrated core and edge plasma. To construct the simple C-S-D model, a simple core plasma model of ITER physics guidelines and a two-point SOL-divertor model are used. The simple C-S-D model is applied to the study of the EAST operational space with lower hybrid current drive experiments under various kinds of trade-off for the basic plasma parameters. Effective methods for extending the operational space are also presented, From this study for the EAST operational space, it is evident that the C-S-D model is a useful tool for understanding qualitatively the overall features of the plasma operational space.
文摘The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption process with shell diffusion as the controlling step were determined by semi-empirical and semi-theoretical methods, and the apparent activation energy of the hydrogen absorption process was obtained. The calculation results can well accord with the experimental data, and can well forecast the hydrogen storage capacity and absorption rate at different times. By using the kinetics equation, the effects of temperature and pressure on the hydrogen storage process can also be well understood. The kinetics equation is helpful for the design of the hydrogen storage container.
文摘The SMART （System-integrated Modular Advanced ReacTor） which is a 330 MWt advanced integral PWR was developed by the KAERI （Korea Atomic Energy Institute） for electricity generation and seawater desalination. To enhance its safety, the various design concepts were adopted such as the most containing of the RCS （reactor coolant system） components and a PRHRS （passive residual heat removal system）. To ensure the safety and performance of the SMART, a thermal hydraulic evaluation and safety analysis are performed by the TASS/SMR-S code. It uses a one dimensional node/path modeling and point kinetics for the core power simulation. The code also has specific models reflecting the design features of the SMART such as a helical tube and PRHRS heat transfer models. In this study, the validation of the core heat transfer model in the TASS/SMR-S code on the steady conditions was performed with the Bennett＇s heated tube tests and THTF （thermal hydraulic test facility） experiment. From the results of the TASS/SMR-S code calculation, the CHF （critical heat flux） point and the fuel rod surface temperature were predicted conservatively compared to the test results.
基金supported by the National Natural Science Foundation of China (40925013)the Strategic Leading Science and Technology Programme (Class B) of the Chinese Academy of Sciences (Grant No.XDB10010400)the China National Major Science and Technology Project (2011ZX05023-005004)
文摘Scattering attenuation in short wavelengths has long been interesting to geophysicists. Ultrasonic coda waves, observed as the tail portion of ultrasonic wavetrains in laboratory ultrasonic measurements, are important for such studies where ultrasonic waves interact with smallscale random heterogeneities on a scale of micrometers, but often ignored as noises because of the contamination of boundary reflections from the side ends of a sample core. Numerical simulations with accurate absorbing boundary can provide insight into the effect of boundary reflections on coda waves in laboratory experiments. The simulation of wave propagation in digital and heterogeneous porous cores really challenges numerical techniques by digital image of poroelastic properties, numerical dispersion at high frequency and strong heterogeneity, and accurate absorbing boundary schemes at grazing incidence. To overcome these difficulties, we present a staggered-grid high-order finite-difference （FD） method of Biot＇s poroelastic equations, with an arbitrary even-order （2L） accuracy to simulate ultrasonic wave propagation in digital porous cores with strong heterogeneity. An unsplit convolutional perfectly matched layer （CPML） absorbing boundary, which improves conventional PML methods at grazing incidence with less memory and better computational efficiency, is employed in the simulation to investigate the influence of boundary reflections on ultra- sonic coda waves. Numerical experiments with saturated poroelastic media demonstrate that the 2L FD scheme with the CPML for ultrasonic wave propagation significantly improves stability conditions at strong heterogeneity and absorbing performance at grazing incidence. The boundary reflections from the artificial boundary surrounding the digital core decay fast with the increase of CPML thick- nesses, almost disappearing at the CPML thickness of 15 grids. Comparisons of the resulting ultrasonic coda Qsc values between the numerical and experimental ultrasonic S waveforms for a cylindrical rock sample demonstrate that the boundary reflection may contribute around one-third of the ultrasonic coda attenuation observed in laboratory experiments.
基金Project supported by the Ministry of Science and Higher Education of Poland(Nos.04/43/DSPB/0085and 02/21/DSPB/3464)
文摘The paper is devoted to mathematical modelling of static and dynamic stability of a simply supported three-layered beam with a metal foam core. Mechanical properties of the core vary along the vertical direction. The field of displacements is for- mulated using the classical broken line hypothesis and the proposed nonlinear hypothesis that generalizes the classical one. Using both hypotheses, the strains are determined as well as the stresses of each layer. The kinetic energy, the elastic strain energy, and the work of load are also determined. The system of equations of motion is derived using Hamilton＇s principle. Finally, the system of three equations is reduced to one equation of motion, in particular, the Mathieu equation. The Bubnov-Galerkin method is used to solve the system of equations of motion, and the Runge-Kutta method is used to solve the second-order differential equation. Numerical calculations are done for the chosen family of beams. The critical loads, unstable regions, angular frequencies of the beam, and the static and dynamic equilibrium paths are calculated analytically and verified numerically. The results of this study are presented in the forms of figures and tables.
基金supports from National High Technology 863 Program of China(No.2013AA013403,2015AA015501,2015AA015502,2015AA015504)National NSFC(No.61425022/61522501/61307086/61475024/61275158/61201151/61275074/61372109)+4 种基金Beijing Nova Program(No.Z141101001814048)Beijing Excellent Ph.D.Thesis Guidance Foundation(No.20121001302)the Universities Ph.D.Special Research Funds(No.20120005110003/20120005120007)Fund of State Key Laboratory of IPOC(BUPT)P.R.China
文摘In this paper, the influencing factors that affect few-mode and multi core optical fiber channel are analyzed in a comprehensive way. The theoretical modeling and computer simulation of the information channel are carried out and then the modeling scheme of few-mode multicore optical fiber channel based on non-uniform mode field distribution is put forward. The proposed modeling scheme can not only exponentially increases the system capacity through fewmode multi-core optical fiber channel, but has better transmission performance compared to the channel of the same type to the uniform channel revealing from the simulation results.
基金the Zanjan Zinc Khalessazan Industries Company (ZZKICO) for the financial and technical support of this work
文摘The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurry with ferrous sulfate and sulfuric acidsolution was filled into a vertical tube(9m in height)and air was blown from the bottom of the reactor.The effects of initial acidconcentration,temperature,particle size,initial zinc sulfate concentration,pulp density and the concentration of Fe on the leachingkinetics were investigated.Results of the kinetic analysis indicate that direct leaching of zinc sulfide concentrate follows shrinkingcore model(SCM).This process was controlled by a chemical reaction with the apparent activation energy of49.7kJ/mol.Furthermore,a semi-empirical equation is obtained,showing that the order of the iron,sulfuric acid and zinc sulfate concentrationsand particle radius are0.982,0.189,-0.097and-0.992,respectively.Analysis of the unreacted and reacted sulfide particles bySEM-EDS shows that insensitive agitation in the reactor causes detachment of the sulfur layer from the particles surface in lowerthan60%Zn conversion and lixiviant in the face with sphalerite particles.
基金the National Natural Science Foundation of China(51675245).
文摘A mathematical model based on the computational fluid dynamics method,heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during preheating was established.The commercial software COMSOL Multiphysics was used to simulate the change in the oxidation degree of the pellet at different temperatures and oxygen concentrations,and the simulated results were compared with the exper-imental results.The model considered the influence of the exothermic heat of the reaction,and the enthalpy change was added to calculate the heat released by the oxidation.The results show that the oxidation rate on the surface of the pellet is much faster than that of the inside of the pellet.Temperature and oxygen concentration have great influence on the pellet oxidation model.Meanwhile,the exothermic calculation results show that there is a non-isothermal phenomenon inside the pellet,which leads to an increase in temperature inside the single pellet.Under the preheating condition of 873-1273 K(20%oxygen content),the heat released by the pellet oxidation reaction in a chain grate is 7.8×10^(6)-10.8×10^(6) kJ/h,which is very large and needs to be considered in the magnetite pellet oxidation modelling.
基金supported by Munzur University Scientific Investigations Project Unit(PPMUB018-13)。
文摘The leaching behavior of Tunceli malachite mineral was investigated in nitric acid solutions by two steps to evaluate the effect of various experimental parameters.In the first step,the optimal conditions for the leaching process were determined,while in the second step,a kinetic evaluation for the process was performed.In the optimization experiments,the concentration of nitric acid,temperature,stirring speed,and solid-to-liquid ratio were selected as the independent variables,and the central composite design method(CCD)was applied to the experimental data.At the end of the experiments,the optimal values for the concentration of nitric acid,temperature,solid-to-liquid ratio and stirring speed were determined to be 0.5 mol/L,50℃,0.004 g/m L and 500 r/min,respectively.Under the optimal conditions,the leaching rate was found to be 99%for 120 min of reaction time.In the kinetic evaluation tests,the effects of the concentration of nitric acid,temperature,stirring speed,solid-to-liquid ratio and particle size on the leaching rate of copper from malachite were investigated.In these tests,it was determined that the leaching rate increased with the increase in the temperature,acid concentration and stirring speed,and with the decrease in the particle size and solid-to-liquid ratio.In consequence of the kinetic analysis,it was observed that the leaching kinetics followed the mixed kinetic model,and a mathematical model for the leaching process was introduced.The activation energy for this process was calculated to be 36.23 k J/mol.
文摘CORE糖尿病模型是由IQVIA公司开发的用于糖尿病治疗药物的经济学研究模型,模型使用C++语言编程,通过将马尔可夫模型(Markov Model)结构和使用跟踪变量的蒙特卡罗分析(Monte Carlo Analysis)结合起来模拟糖尿病及其并发症的长期自然进展。近年来我国学者共在国内外发表了11篇基于CORE糖尿病模型的药物经济学研究,文献发表数量随年份增加有所上升。随着药物经济学在我国的不断发展,CORE模型在糖尿病领域的药物经济学研究中有很好的应用前景。
