Based on the fact that the real inductor and the real capacitor are fractional order in nature and the fractional calculus,the transfer function modeling and analysis of the open-loop Buck converter in a continuous co...Based on the fact that the real inductor and the real capacitor are fractional order in nature and the fractional calculus,the transfer function modeling and analysis of the open-loop Buck converter in a continuous conduction mode（CCM） operation are carried out in this paper.The fractional order small signal model and the corresponding equivalent circuit of the open-loop Buck converter in a CCM operation are presented.The transfer functions from the input voltage to the output voltage,from the input voltage to the inductor current,from the duty cycle to the output voltage,from the duty cycle to the inductor current,and the output impedance of the open-loop Buck converter in CCM operation are derived,and their bode diagrams and step responses are calculated,respectively.It is found that all the derived fractional order transfer functions of the system are influenced by the fractional orders of the inductor and the capacitor.Finally,the realization of the fractional order inductor and the fractional order capacitor is designed,and the corresponding PSIM circuit simulation results of the open-loop Buck converter in CCM operation are given to confirm the correctness of the derivations and the theoretical analysis.展开更多
Trend forecasting is an important aspect in fault diagnosis and work state supervision. The principle, where Grey theory is applied in fault forecasting, is that the forecast system is considered as a Grey system; the...Trend forecasting is an important aspect in fault diagnosis and work state supervision. The principle, where Grey theory is applied in fault forecasting, is that the forecast system is considered as a Grey system; the existing known information is used to infer the unknown information's character, state and development trend in a fault pattern, and to make possible forecasting and decisions for future development. It involves the whitenization of a Grey process. But the traditional equal time interval Grey GM (1,1) model requires equal interval data and needs to bring about accumulating addition generation and reversion calculations. Its calculation is very complex. However, the non equal interval Grey GM (1,1) model decreases the condition of the primitive data when establishing a model, but its requirement is still higher and the data were pre processed. The abrasion primitive data of plant could not always satisfy these modeling requirements. Therefore, it establishes a division method suited for general data modeling and estimating parameters of GM (1,1), the standard error coefficient that was applied to judge accuracy height of the model was put forward; further, the function transform to forecast plant abrasion trend and assess GM (1,1) parameter was established. These two models need not pre process the primitive data. It is not only suited for equal interval data modeling, but also for non equal interval data modeling. Its calculation is simple and convenient to use. The oil spectrum analysis acted as an example. The two GM (1,1) models put forward in this paper and the new information model and its comprehensive usage were investigated. The example shows that the two models are simple and practical, and worth expanding and applying in plant fault diagnosis.展开更多
The internal structures of cells as the basic units of life are a major wonder of the microscopic world.Cellular images provide an intriguing window to help explore and understand the composition and function of these...The internal structures of cells as the basic units of life are a major wonder of the microscopic world.Cellular images provide an intriguing window to help explore and understand the composition and function of these structures.Scientific imagery combined with artistic expression can further expand the potential of imaging in educational dissemination and interdisciplinary applications.展开更多
Applying 3-dimension finite difference method, the distribution characteristics of horizontal field transfer functions for rectangular conductor have been computed, and the law of distribution for Re-part and Im-part ...Applying 3-dimension finite difference method, the distribution characteristics of horizontal field transfer functions for rectangular conductor have been computed, and the law of distribution for Re-part and Im-part has been given. The influences of source field period, the conductivity, the buried depth and the length of the conductor on the transfer functions were studied. The extrema of transfer functions appear at the center, the four corners and around the edges of conductor, and move with the edges. This feature demonstrates that around the edges are best places for transfer functions' observation.展开更多
Biological inspirations are good design mimicry resources. This paper proposes a function based approach for modeling and transformation of bio-inspiration design knowledge. A general functional modeling method for bi...Biological inspirations are good design mimicry resources. This paper proposes a function based approach for modeling and transformation of bio-inspiration design knowledge. A general functional modeling method for biological domain and engineering domain design knowledge is introduced. Functional similarity based bio-inspiration transformation between biological domain and engineering domain is proposed. The biological function topology transfer and analog solution recomposition are also discussed in this paper.展开更多
Confinement of rock bolts by the surrounding rock formation has long been recognized as a positive contributor to the pull-out behavior,yet only a few experimental works and analytical models have been reported,most o...Confinement of rock bolts by the surrounding rock formation has long been recognized as a positive contributor to the pull-out behavior,yet only a few experimental works and analytical models have been reported,most of which are based on the global rock bolt response evaluated in pull-out tests.This paper presents a laboratory experimental setup aiming to capture the rock formation effect,while using distributed fiber optic sensing to quantify the effect of the confinement and the reinforcement pull-out behavior on a more local level.It is shown that the behavior along the sample itself varies,with certain points exhibiting stress drops with crack formation.Some edge effects related to the kinematic freedom of the grout to dilate are also observed.Regardless,it was found that the mid-level response is quite similar to the average response along the sample.The ability to characterize the variation of the response along the sample is one of the many advantages high-resolution fiber optic sensing allows in such investigations.The paper also offers a plasticity-based hardening load transfer function,representing a"slice"of the anchor.The paper describes in detail the development of the model and the calibration/determination of its parameters.The suggested model captures well the coupled behavior in which the pull-out process leads to an increase in the confining stress due to dilative behavior.展开更多
This paper explores the model reference adaptive control problem for a class of switched linear systems under arbitrary switching with no need for the measurability of the system state.Based on the state of reference ...This paper explores the model reference adaptive control problem for a class of switched linear systems under arbitrary switching with no need for the measurability of the system state.Based on the state of reference model and the measurable output error, adaptive laws and controllers are designed for switched systems.Each subsystem may have its individual reference model and controller, which increases the design flexibility.The introduction of the closed-loop reference model is to get a better transient performance of the whole switched systems.A numerical example is provided to verify the effectiveness of the main results.展开更多
The key difficulty of restoring a fuzzy image is to estimate its point spread function( PSF). In the paper,PSF is modelled based on modulation transfer function( MTF). The first step is calculating the image MTF. In t...The key difficulty of restoring a fuzzy image is to estimate its point spread function( PSF). In the paper,PSF is modelled based on modulation transfer function( MTF). The first step is calculating the image MTF. In the traditional slanted-edge method,a sub-block is always manually extracted from original image and its MTF will be viewed as the result of the whole image. However,handcraft extraction is inefficient and will lead to inaccurate results. Given this,an automatic MTF computation algorithm is proposed,which extracts and screens out all the effective sub-blocks and calculates their average MTF as the final result. Then,a two-dimensional MTF restoration model is constructed by multiplying the horizontal and vertical MTF,and it is combined with conventional image restoration methods to restore fuzzy image. Experimental results indicate the proposed method implementes a fast and accurate MTF computation and the MTF model improves the performance of conventional restoration methods significantly.展开更多
3D chip stacking is considered known to overcome conventional 2D-IC issues, using through silicon vias to ensure vertical signal transmission. From any point source, embedded or not, we calculate the impedance spread ...3D chip stacking is considered known to overcome conventional 2D-IC issues, using through silicon vias to ensure vertical signal transmission. From any point source, embedded or not, we calculate the impedance spread out;our ultimate goal will to study substrate noise via impedance field method. For this, our approach is twofold: a compact Green function or a Transmission Line Model over a multi-layered substrate is derived by solving Poisson’s equation analytically. The Discrete Cosine Transform (DCT) and its variations are used for rapid evaluation. Using this technique, the substrate coupling and loss in IC’s can be analyzed. We implement our algorithm in MATLAB;it permits to extract impedances between any pair of embedded contacts. Comparisons are performed using finite element methods.展开更多
The co-adsorption behaviors of SO2 and H2 O on face-centered cubic Cu（100） ideal surface were studied using the GGA-r PBE method of density functional theory（DFT） with slab models. The optimized structures of sing...The co-adsorption behaviors of SO2 and H2 O on face-centered cubic Cu（100） ideal surface were studied using the GGA-r PBE method of density functional theory（DFT） with slab models. The optimized structures of single H2 O and SO2 on Cu（100） surface were calculated at the coverage of 0.25 ML（molecular layer） and 0.5 ML. The results show that there was no obvious chemical adsorption of them on Cu（100） surface. The adsorbed structures, adsorption energy and electronic properties including difference charge density, valence charge density, Bader charge analysis and partial density of states（PDOS） of co-adsorbed structures of H2 O and SO2 were investigated to illustrate the interaction between adsorbates and surface. H2 O and SO2 can adsorb on surface of Cu atoms chemically via molecule form at the coverage of 0.25 ML, while H2 O dissociated into OH adsorbed on surface and H bonded with SO2 which keeps away from surface at the coverage of 0.5 ML.展开更多
Two mono iron complexes Fe（CO）2PR3（NN） （R = Cy （3）, Ph （4）, NN = o-phenylenediamine dianion ligand, N2H2Ph2-） derived from the ligand substitution of Fe（CO）3hPR3 by the NN ligand were isolated and structur...Two mono iron complexes Fe（CO）2PR3（NN） （R = Cy （3）, Ph （4）, NN = o-phenylenediamine dianion ligand, N2H2Ph2-） derived from the ligand substitution of Fe（CO）3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.展开更多
U型中深层地埋管换热器(U-bend Deep Borehole Heat Exchanger,UDBHE)具有广阔的应用前景。文章基于无限柱热源(Infinite Cylindrical Source,ICS)和无限线热源(Infinite Line Source,ILS)模型的G函数,建立了4种UDBHE传热模型,采用ICS或...U型中深层地埋管换热器(U-bend Deep Borehole Heat Exchanger,UDBHE)具有广阔的应用前景。文章基于无限柱热源(Infinite Cylindrical Source,ICS)和无限线热源(Infinite Line Source,ILS)模型的G函数,建立了4种UDBHE传热模型,采用ICS或ILS模型的G函数,考虑或忽略钻孔壁热流随时间变化,分别简称为ICS-q,ILS-q,ICS-c,ILS-c模型。通过与较为准确的二维数值模型及实验数据在2种边界条件下的对比,分析了这4种模型的准确性。结果表明:ILS-q模型在整体上最为准确,而ICS-q模型在分析UDBHE长期性能时最为准确;4种模型在前期均存在较大误差,但在足够长时间后,除了ILS-c和ICS-c模型在入口温度边界下仍有较大误差外,其他模型的误差均较小。研究结果可为UDBHE传热模型研究提供参考。展开更多
The interstand tension control is one of the most important ways to meet tight tolerances for strip product quality during tandem cold rolling process. Using coordinate analysis and parabolic approximation for the mas...The interstand tension control is one of the most important ways to meet tight tolerances for strip product quality during tandem cold rolling process. Using coordinate analysis and parabolic approximation for the mass flow balance principle, the strip velocities eliminating the use of forward slips and backward slips were calculated. In order to reduce the effect of roll eccentricity on the tension measurement, a filter based on bilinear transformation was de- signed. Applying a first-order Taylor series approximation, the transfer function matrix model of interstand tension stress was derived. The actual measurements on-site and the final calculation results showed that the established model had high calculation accuracy and was beneficial for interstand tension control of random cold rolling process.展开更多
Spray cooling has proved its superior heat transfer performance in removing high heat flux for ground applications. However, the dissipation of vapor liquid mixture from the heat sur- face and the closed-loop circulat...Spray cooling has proved its superior heat transfer performance in removing high heat flux for ground applications. However, the dissipation of vapor liquid mixture from the heat sur- face and the closed-loop circulation of the coolant are two challenges in reduced or zero gravity space enviromnents. In this paper, an ejected spray cooling system for space closed-loop application was proposed and the negative pressure in the ejected condenser chamber was applied to sucking the two-phase mixture from the spray chamber. Its ground experimental setup was built and exper- imental investigations on the smooth circle heat surface with a diameter of 5 mm were conducted with distilled water as the coolant spraying from a nozzle of 0.51 mm orifice diameter at the inlet temperatures of 69.2 ℃ and 78.2 ℃ under the conditions of heat flux ranging from 69.76 W/cm2 to 311.45 W/cm2, volume flow through the spray nozzle varying from 11,22 L：h to 15.76 L·h. Work performance of the spray nozzle and heat transfer performance of the spray cooling system were analyzed; results show that this ejected spray cooling system has a good heat transfer performance and provides valid foundation for space closed-loop application in the near future.展开更多
Establishing a suitable closed-loop transfer function model for the grid-connected PMSG system is the key basis in performing inter-harmonic characteristics analysis.Multiple closed-loop transfer functions can be cons...Establishing a suitable closed-loop transfer function model for the grid-connected PMSG system is the key basis in performing inter-harmonic characteristics analysis.Multiple closed-loop transfer functions can be constructed when different components of the converter controller are taken into account.However,the effect of different components of the converter controller on inter-harmonic stability analysis is not clear.In this paper,the complete transfer function,considering different loops,is first given.Based on the complete closed-loop transfer function,the DC-link,PLL and voltage forward-feed are removed step by step to derive different closed-loop transfer functions.The inter-harmonic related poles of different closed-loop transfer functions are further calculated to analyze the effect of closedloop transfer functions on inter-harmonic characteristics analysis.Finally,by performing time domain simulation,the correctness of the theoretical analysis results is verified.The results show that under the conditions of a weak AC system,each loop of the converter control system will reduce the stability of the interharmonic in the sub-synchronous frequency range and influence the inter-harmonic oscillation frequency.The transfer function needs to consider the influence of each loop to accurately calculate the inter-harmonic stability of the system.展开更多
Plant capacity for water storage leads to time lags between basal stem sap flow and transpiration in various woody plants. Internal water storage depends on the sizes of woody plants. However, the changes and its infl...Plant capacity for water storage leads to time lags between basal stem sap flow and transpiration in various woody plants. Internal water storage depends on the sizes of woody plants. However, the changes and its influencing factors in time lags of basal stem flow during the development of herbaceous plants including crops remain unclear. A field experiment was conducted in an arid region of Northwest China to examine the time lag characteristics of sap flow in seed-maize and to calibrate the transpiration modeling. Cross-correlation analysis was used to estimate the time lags between stem sap flow and meteorological driving factors including solar radiation（R_s） and vapor pressure deficit of the air（VPD_（air））. Results indicate that the changes in seed-maize stem sap flow consistently lagged behind the changes in R_s and preceded the changes in VPD_（air） both on hourly and daily scales, suggesting that light-mediated stomatal closures drove sap flow responses. The time lag in the maize＇s sap flow differed significantly during different growth stages and the difference was potentially due to developmental changes in capacitance tissue and/or xylem during ontogenesis. The time lags between stem sap flow and R_s in both female plants and male plants corresponded to plant use of stored water and were independent of total plant water use. Time lags of sap flow were always longer in male plants than in female plants. Theoretically, dry soil may decrease the speed by which sap flow adjusts ahead of shifts in VPD_（air） in comparison with wet soil and also increase the speed by which sap flow adjusts to R_s. However, sap flow lags that were associated with R_s before irrigation and after irrigation in female plants did not shift. Time series analysis method provided better results for simulating seed-maize sap flow with advantages of allowing for fewer variables to be included. This approach would be helpful in improving the accuracy of estimation for canopy transpiration and conductance using meteorological measurements.展开更多
In this paper, a free-space vortex channel model of the radio vortex system is proposed to describe the propagation characteristics of vortex signals over the vortex channel. The key idea is to combine the Laguerre-Ga...In this paper, a free-space vortex channel model of the radio vortex system is proposed to describe the propagation characteristics of vortex signals over the vortex channel. The key idea is to combine the Laguerre-Gaussian(LG) modes in the optical field with the free-space propagation model in the radio field. The proposed free-space vortex channel model is derived from the electric field expression of the LG modes and the freespace channel transfer function of the freespace propagation model theoretically. Simulation results verify that the proposed model could reflect the vortex channel characteristics better than the currently used free-space propagation model.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 51007068)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20100201120028)+2 种基金the Natural Science Basic Research Plan in Shaanxi Province of China (Grant No. 2012JQ7026)the Fundamental Research Funds for the Central Universities of China (Grant No. 2012jdgz09)the State Key Laboratory of Electrical Insulation and Power Equipment of China (Grant No. EIPE12303)
文摘Based on the fact that the real inductor and the real capacitor are fractional order in nature and the fractional calculus,the transfer function modeling and analysis of the open-loop Buck converter in a continuous conduction mode（CCM） operation are carried out in this paper.The fractional order small signal model and the corresponding equivalent circuit of the open-loop Buck converter in a CCM operation are presented.The transfer functions from the input voltage to the output voltage,from the input voltage to the inductor current,from the duty cycle to the output voltage,from the duty cycle to the inductor current,and the output impedance of the open-loop Buck converter in CCM operation are derived,and their bode diagrams and step responses are calculated,respectively.It is found that all the derived fractional order transfer functions of the system are influenced by the fractional orders of the inductor and the capacitor.Finally,the realization of the fractional order inductor and the fractional order capacitor is designed,and the corresponding PSIM circuit simulation results of the open-loop Buck converter in CCM operation are given to confirm the correctness of the derivations and the theoretical analysis.
文摘Trend forecasting is an important aspect in fault diagnosis and work state supervision. The principle, where Grey theory is applied in fault forecasting, is that the forecast system is considered as a Grey system; the existing known information is used to infer the unknown information's character, state and development trend in a fault pattern, and to make possible forecasting and decisions for future development. It involves the whitenization of a Grey process. But the traditional equal time interval Grey GM (1,1) model requires equal interval data and needs to bring about accumulating addition generation and reversion calculations. Its calculation is very complex. However, the non equal interval Grey GM (1,1) model decreases the condition of the primitive data when establishing a model, but its requirement is still higher and the data were pre processed. The abrasion primitive data of plant could not always satisfy these modeling requirements. Therefore, it establishes a division method suited for general data modeling and estimating parameters of GM (1,1), the standard error coefficient that was applied to judge accuracy height of the model was put forward; further, the function transform to forecast plant abrasion trend and assess GM (1,1) parameter was established. These two models need not pre process the primitive data. It is not only suited for equal interval data modeling, but also for non equal interval data modeling. Its calculation is simple and convenient to use. The oil spectrum analysis acted as an example. The two GM (1,1) models put forward in this paper and the new information model and its comprehensive usage were investigated. The example shows that the two models are simple and practical, and worth expanding and applying in plant fault diagnosis.
基金supported by the Fundamental Research Funds for the Central Universities(No.226-2024-00038),China.
文摘The internal structures of cells as the basic units of life are a major wonder of the microscopic world.Cellular images provide an intriguing window to help explore and understand the composition and function of these structures.Scientific imagery combined with artistic expression can further expand the potential of imaging in educational dissemination and interdisciplinary applications.
文摘Applying 3-dimension finite difference method, the distribution characteristics of horizontal field transfer functions for rectangular conductor have been computed, and the law of distribution for Re-part and Im-part has been given. The influences of source field period, the conductivity, the buried depth and the length of the conductor on the transfer functions were studied. The extrema of transfer functions appear at the center, the four corners and around the edges of conductor, and move with the edges. This feature demonstrates that around the edges are best places for transfer functions' observation.
基金the National Basic Research Program(973)of China(Nos.2011CB707503 and2011CB013305)the National Natural Science Foundation of China(Nos.51075262,51305260,51275293,51121063,50575142 and 51005148)+4 种基金the"ShuGuang"Project of Shanghai Municipal Education Commissionand Shanghai Education Development Foundation(No.12SG14)the Project of Shanghai Committee of Science and Technology(Nos.11JC1406100,13111102800 and 11BA1405300)the National KeyScientific Instruments and Equipment Development Program of China(Nos.2013YQ03065105 and2011YQ030114)the Program for New Century Excellent Talents in University(No.NCET-08-0361)the National High Technology Research and DevelopmentProgram(863)of China(No.2008AA04Z113)
文摘Biological inspirations are good design mimicry resources. This paper proposes a function based approach for modeling and transformation of bio-inspiration design knowledge. A general functional modeling method for biological domain and engineering domain design knowledge is introduced. Functional similarity based bio-inspiration transformation between biological domain and engineering domain is proposed. The biological function topology transfer and analog solution recomposition are also discussed in this paper.
基金funding support from the Israeli Ministry of Housing and Construction(Grant No.2028286).
文摘Confinement of rock bolts by the surrounding rock formation has long been recognized as a positive contributor to the pull-out behavior,yet only a few experimental works and analytical models have been reported,most of which are based on the global rock bolt response evaluated in pull-out tests.This paper presents a laboratory experimental setup aiming to capture the rock formation effect,while using distributed fiber optic sensing to quantify the effect of the confinement and the reinforcement pull-out behavior on a more local level.It is shown that the behavior along the sample itself varies,with certain points exhibiting stress drops with crack formation.Some edge effects related to the kinematic freedom of the grout to dilate are also observed.Regardless,it was found that the mid-level response is quite similar to the average response along the sample.The ability to characterize the variation of the response along the sample is one of the many advantages high-resolution fiber optic sensing allows in such investigations.The paper also offers a plasticity-based hardening load transfer function,representing a"slice"of the anchor.The paper describes in detail the development of the model and the calibration/determination of its parameters.The suggested model captures well the coupled behavior in which the pull-out process leads to an increase in the confining stress due to dilative behavior.
基金Sponsored by the National Natural Science Foundation of China(Grant No.61233002)the 111 Project(Grant No.B16009)the IAPI Fundamental Research Funds(Grant No.2013ZCX03-01)
文摘This paper explores the model reference adaptive control problem for a class of switched linear systems under arbitrary switching with no need for the measurability of the system state.Based on the state of reference model and the measurable output error, adaptive laws and controllers are designed for switched systems.Each subsystem may have its individual reference model and controller, which increases the design flexibility.The introduction of the closed-loop reference model is to get a better transient performance of the whole switched systems.A numerical example is provided to verify the effectiveness of the main results.
基金Supported by the National High Technology Research and Development Programme of China(No.2012AA12A305)the National Key Technology R&D Program of the Ministry of Science and Technology(No.2013BAH03B01)+1 种基金Fundamental Research Funds for the Central Universities of China(No.2042015kf0059)China Postdoctoral Science Foundation(No.2015M582277)
文摘The key difficulty of restoring a fuzzy image is to estimate its point spread function( PSF). In the paper,PSF is modelled based on modulation transfer function( MTF). The first step is calculating the image MTF. In the traditional slanted-edge method,a sub-block is always manually extracted from original image and its MTF will be viewed as the result of the whole image. However,handcraft extraction is inefficient and will lead to inaccurate results. Given this,an automatic MTF computation algorithm is proposed,which extracts and screens out all the effective sub-blocks and calculates their average MTF as the final result. Then,a two-dimensional MTF restoration model is constructed by multiplying the horizontal and vertical MTF,and it is combined with conventional image restoration methods to restore fuzzy image. Experimental results indicate the proposed method implementes a fast and accurate MTF computation and the MTF model improves the performance of conventional restoration methods significantly.
文摘3D chip stacking is considered known to overcome conventional 2D-IC issues, using through silicon vias to ensure vertical signal transmission. From any point source, embedded or not, we calculate the impedance spread out;our ultimate goal will to study substrate noise via impedance field method. For this, our approach is twofold: a compact Green function or a Transmission Line Model over a multi-layered substrate is derived by solving Poisson’s equation analytically. The Discrete Cosine Transform (DCT) and its variations are used for rapid evaluation. Using this technique, the substrate coupling and loss in IC’s can be analyzed. We implement our algorithm in MATLAB;it permits to extract impedances between any pair of embedded contacts. Comparisons are performed using finite element methods.
基金Project(51222106)supported by the National Natural Science Foundation of ChinaProject(230201306500002)supported by the Fundamental Research Funds for the Central Universities+1 种基金ChinaProject(2014CB643300)supported by National Basic Research Program of China
文摘The co-adsorption behaviors of SO2 and H2 O on face-centered cubic Cu（100） ideal surface were studied using the GGA-r PBE method of density functional theory（DFT） with slab models. The optimized structures of single H2 O and SO2 on Cu（100） surface were calculated at the coverage of 0.25 ML（molecular layer） and 0.5 ML. The results show that there was no obvious chemical adsorption of them on Cu（100） surface. The adsorbed structures, adsorption energy and electronic properties including difference charge density, valence charge density, Bader charge analysis and partial density of states（PDOS） of co-adsorbed structures of H2 O and SO2 were investigated to illustrate the interaction between adsorbates and surface. H2 O and SO2 can adsorb on surface of Cu atoms chemically via molecule form at the coverage of 0.25 ML, while H2 O dissociated into OH adsorbed on surface and H bonded with SO2 which keeps away from surface at the coverage of 0.5 ML.
基金supported by the National Natural Science Foundation of China(21103121,21276187)Tianjin Municipal Natural Science Foundation(13JCQNJC05800)the Specialized Research Fund for the Doctoral Program of Higher Education(20121317110009)~~
文摘Two mono iron complexes Fe（CO）2PR3（NN） （R = Cy （3）, Ph （4）, NN = o-phenylenediamine dianion ligand, N2H2Ph2-） derived from the ligand substitution of Fe（CO）3hPR3 by the NN ligand were isolated and structurally characterized by single crystal X-ray diffraction. They have a similar first coordination sphere and oxidation state of the iron center as the [Fe]-hydrogenase active site, and can be a model of it IR demonstrated that the effect of the NN ligand on the coordinated CO stretch- ing frequencies was due to its excellent electron donating ability. The reversible protonation/deprotonation of the NN ligand was identified by infrared spectroscopy and density functional theory computation. The NN ligand is an effective proton acceptor as the internal base of the cysteine thiolate ligand in [Fe]-hydrogenase. The electrochemical properties of complexes 3, 4 were investigated by cyclic voltammograms. Complex 3 catalyzed the transfer hydrogenation of benzoquinone to hydroquinone effectively under mild conditions.
文摘U型中深层地埋管换热器(U-bend Deep Borehole Heat Exchanger,UDBHE)具有广阔的应用前景。文章基于无限柱热源(Infinite Cylindrical Source,ICS)和无限线热源(Infinite Line Source,ILS)模型的G函数,建立了4种UDBHE传热模型,采用ICS或ILS模型的G函数,考虑或忽略钻孔壁热流随时间变化,分别简称为ICS-q,ILS-q,ICS-c,ILS-c模型。通过与较为准确的二维数值模型及实验数据在2种边界条件下的对比,分析了这4种模型的准确性。结果表明:ILS-q模型在整体上最为准确,而ICS-q模型在分析UDBHE长期性能时最为准确;4种模型在前期均存在较大误差,但在足够长时间后,除了ILS-c和ICS-c模型在入口温度边界下仍有较大误差外,其他模型的误差均较小。研究结果可为UDBHE传热模型研究提供参考。
基金Item Sponsored by Fundamental Research Funds for the Central Universities of China(N110307001)
文摘The interstand tension control is one of the most important ways to meet tight tolerances for strip product quality during tandem cold rolling process. Using coordinate analysis and parabolic approximation for the mass flow balance principle, the strip velocities eliminating the use of forward slips and backward slips were calculated. In order to reduce the effect of roll eccentricity on the tension measurement, a filter based on bilinear transformation was de- signed. Applying a first-order Taylor series approximation, the transfer function matrix model of interstand tension stress was derived. The actual measurements on-site and the final calculation results showed that the established model had high calculation accuracy and was beneficial for interstand tension control of random cold rolling process.
基金supported by the National Natural Science Foundation of China(No.50506003)
文摘Spray cooling has proved its superior heat transfer performance in removing high heat flux for ground applications. However, the dissipation of vapor liquid mixture from the heat sur- face and the closed-loop circulation of the coolant are two challenges in reduced or zero gravity space enviromnents. In this paper, an ejected spray cooling system for space closed-loop application was proposed and the negative pressure in the ejected condenser chamber was applied to sucking the two-phase mixture from the spray chamber. Its ground experimental setup was built and exper- imental investigations on the smooth circle heat surface with a diameter of 5 mm were conducted with distilled water as the coolant spraying from a nozzle of 0.51 mm orifice diameter at the inlet temperatures of 69.2 ℃ and 78.2 ℃ under the conditions of heat flux ranging from 69.76 W/cm2 to 311.45 W/cm2, volume flow through the spray nozzle varying from 11,22 L：h to 15.76 L·h. Work performance of the spray nozzle and heat transfer performance of the spray cooling system were analyzed; results show that this ejected spray cooling system has a good heat transfer performance and provides valid foundation for space closed-loop application in the near future.
基金supported by Research Project Huadong Engineering Corporation Limited,and National Natural Science Foundation of China(U22B20100,52321004).
文摘Establishing a suitable closed-loop transfer function model for the grid-connected PMSG system is the key basis in performing inter-harmonic characteristics analysis.Multiple closed-loop transfer functions can be constructed when different components of the converter controller are taken into account.However,the effect of different components of the converter controller on inter-harmonic stability analysis is not clear.In this paper,the complete transfer function,considering different loops,is first given.Based on the complete closed-loop transfer function,the DC-link,PLL and voltage forward-feed are removed step by step to derive different closed-loop transfer functions.The inter-harmonic related poles of different closed-loop transfer functions are further calculated to analyze the effect of closedloop transfer functions on inter-harmonic characteristics analysis.Finally,by performing time domain simulation,the correctness of the theoretical analysis results is verified.The results show that under the conditions of a weak AC system,each loop of the converter control system will reduce the stability of the interharmonic in the sub-synchronous frequency range and influence the inter-harmonic oscillation frequency.The transfer function needs to consider the influence of each loop to accurately calculate the inter-harmonic stability of the system.
基金support from the National Key Basic Research Program of China (2016YFC0400207)the National Natural Science Foundation of China (51439006, 91425302)the 111 Program of Introducing Talents of Discipline to Universities (B14002)
文摘Plant capacity for water storage leads to time lags between basal stem sap flow and transpiration in various woody plants. Internal water storage depends on the sizes of woody plants. However, the changes and its influencing factors in time lags of basal stem flow during the development of herbaceous plants including crops remain unclear. A field experiment was conducted in an arid region of Northwest China to examine the time lag characteristics of sap flow in seed-maize and to calibrate the transpiration modeling. Cross-correlation analysis was used to estimate the time lags between stem sap flow and meteorological driving factors including solar radiation（R_s） and vapor pressure deficit of the air（VPD_（air））. Results indicate that the changes in seed-maize stem sap flow consistently lagged behind the changes in R_s and preceded the changes in VPD_（air） both on hourly and daily scales, suggesting that light-mediated stomatal closures drove sap flow responses. The time lag in the maize＇s sap flow differed significantly during different growth stages and the difference was potentially due to developmental changes in capacitance tissue and/or xylem during ontogenesis. The time lags between stem sap flow and R_s in both female plants and male plants corresponded to plant use of stored water and were independent of total plant water use. Time lags of sap flow were always longer in male plants than in female plants. Theoretically, dry soil may decrease the speed by which sap flow adjusts ahead of shifts in VPD_（air） in comparison with wet soil and also increase the speed by which sap flow adjusts to R_s. However, sap flow lags that were associated with R_s before irrigation and after irrigation in female plants did not shift. Time series analysis method provided better results for simulating seed-maize sap flow with advantages of allowing for fewer variables to be included. This approach would be helpful in improving the accuracy of estimation for canopy transpiration and conductance using meteorological measurements.
基金supported in part by National Science Foundation for Distinguished Young Scholars of China with Grant number 61325004Major Program of National Natural Science Foundation of Hubei in China with Grant number 2016CFA009+2 种基金the Fundamental Research Funds for the Central Universities with Grant number 2015ZDTD012the National Natural Science Foundation of China under Grant No.61463035the Research Foundation of the Education Department of Jiangxi Province under Grant No.GJJ150198
文摘In this paper, a free-space vortex channel model of the radio vortex system is proposed to describe the propagation characteristics of vortex signals over the vortex channel. The key idea is to combine the Laguerre-Gaussian(LG) modes in the optical field with the free-space propagation model in the radio field. The proposed free-space vortex channel model is derived from the electric field expression of the LG modes and the freespace channel transfer function of the freespace propagation model theoretically. Simulation results verify that the proposed model could reflect the vortex channel characteristics better than the currently used free-space propagation model.
