Three high-acidity crudes, Dar, SZ36-1, and QHD326, were separated through distillation into several fractions, including diesel distillates, and VGOs. Samples were characterized by negative-ion ESI FT-ICR MS. The O2 ...Three high-acidity crudes, Dar, SZ36-1, and QHD326, were separated through distillation into several fractions, including diesel distillates, and VGOs. Samples were characterized by negative-ion ESI FT-ICR MS. The O2 class species （petroleum carboxylic acids）, which have a close relationship with corrosion of equipment caused by high-acidity crudes, were put in the focus of attention and were discussed in this paper. Monocyclic, bicyclic, and tricyclic naphthenic acids are the main types of petroleum carboxylic acids in naphthenic-base crudes （SZ36-1 and QHD326）. But the main types of petroleum carboxylic acids in paraffinic-base crude （Dar） are aliphatic acids and monocyclic naphthenic acids. The O2 class species in SZ36-1 and QHD326 are distributed in a wider range and have bigger DBE value （double-bond equivalence value） and carbon number than Dar. Bicyclic naphthenic acids have the highest proportion among petroleum carboxylie acids in diesel distillates, but monocyclic and tricyclic naphthenic acids also occupy a high proportion. Particularly, aliphatic acids in the diesel distillate of Dar still have high proportion among petroleum carboxylic acids. The distribution of petroleum carboxylic acids in VGO is basically identical. The bicyclic naphthenic acids assume the first place （about 25 m%）, while the monocyclic and tricyclic naphthenic acids take the next place. The comparison of petroleum carboxylic acids in diesel distillates and VGOs has revealed that the molecules of carboxylic acids in VGOs are not only bigger but also more complicated.展开更多
The Dar crude oil produced in Sudan was distilled into several fractions. The heteroatom class species in crude and its fractions were characterized by the negative-ion ESI FT-ICR MS. The major emphasis was put upon t...The Dar crude oil produced in Sudan was distilled into several fractions. The heteroatom class species in crude and its fractions were characterized by the negative-ion ESI FT-ICR MS. The major emphasis was put upon the study on the O2 class species (petroleum carboxylic acids). The test results revealed that aliphatic acids and monocyclic naphthenic acids accounted for a large proportion in petroleum carboxylic acids of the Dar crude. The relative abundance of aliphatic acids and monocyclic naphthenic acids decreased with an increasing boiling point of fractions. Meanwhile, the relative abundance of bicyclic and tricyclic naphthenic acids increased at first and then decreased, whereas the relative abundance of petroleum carboxylic acids with higher double-bond equivalence (DBE) values increased. The high abundance of aliphatic acids in the Dar crude and its fractions covered the carbon numbers in a range of 16 to 18 which had important geochemical signifi- cance. The O2 class species were distributed in a broad range of DBE values and carbon numbers with increasing boiling points of fractions.展开更多
A group H is said to be autocapable if there exists a group M such that H is isomorphic to the absolute central factor group M/L(M)of M.In this paper,we first prove that if N is a characteristic subgroup of an autocap...A group H is said to be autocapable if there exists a group M such that H is isomorphic to the absolute central factor group M/L(M)of M.In this paper,we first prove that if N is a characteristic subgroup of an autocapable group H,then N is neither the generalized quaternion group nor the semi-dihedral group.Next,we give the classification of finite groups G if G/L(G)is a 2-group of maximal class.展开更多
The Bogomolov multiplier B0 （G） of a finite group G is defined as the subgroup of the Schur multiplier consisting of the cohomology classes vanishing after restriction to all abelian subgroups of G. The triviality o...The Bogomolov multiplier B0 （G） of a finite group G is defined as the subgroup of the Schur multiplier consisting of the cohomology classes vanishing after restriction to all abelian subgroups of G. The triviality of the Bogomolov multiplier is an obstruction to Noether＇s problem. We show that if G is a central product of G1 and G2, regarding Ki ≤ Z（Gi）,i = 1,2, and θ ： G1 →G2 is a group homomorphism such that its restriction θ｜K1 ： K1 → K2 is an isomorphism, then the triviality of Bo（G1/K1）, Bo（G1） and B0（G2） implies the triviality of Bo（G）. We give a positive answer to Noether＇s problem for all 2-generator p-groups of nilpotency class 2, and for one series of 4-generator p-groups of nilpotency class 2 （with the usual requirement for the roots of unity）.展开更多
In this paper, concerned with the Cauchy problem for 2D nonlinear hyperbolic conservation laws,we construct a class of uniformly second order accurate finite difference schemes, which are based on the E-schemes. By ap...In this paper, concerned with the Cauchy problem for 2D nonlinear hyperbolic conservation laws,we construct a class of uniformly second order accurate finite difference schemes, which are based on the E-schemes. By applying the conver gence theorem of Coquel-Le Floch [1], the family of approximate solutions defined by the scheme is proven to converge to the unique entropy weak L∞-solution. Furthermore, some numerical experiments on the Cauchy problem for the advection equation and the Riemann problem for the 2D Burgers equation are given and the relatively satisfied result is obtained.展开更多
文摘Three high-acidity crudes, Dar, SZ36-1, and QHD326, were separated through distillation into several fractions, including diesel distillates, and VGOs. Samples were characterized by negative-ion ESI FT-ICR MS. The O2 class species （petroleum carboxylic acids）, which have a close relationship with corrosion of equipment caused by high-acidity crudes, were put in the focus of attention and were discussed in this paper. Monocyclic, bicyclic, and tricyclic naphthenic acids are the main types of petroleum carboxylic acids in naphthenic-base crudes （SZ36-1 and QHD326）. But the main types of petroleum carboxylic acids in paraffinic-base crude （Dar） are aliphatic acids and monocyclic naphthenic acids. The O2 class species in SZ36-1 and QHD326 are distributed in a wider range and have bigger DBE value （double-bond equivalence value） and carbon number than Dar. Bicyclic naphthenic acids have the highest proportion among petroleum carboxylie acids in diesel distillates, but monocyclic and tricyclic naphthenic acids also occupy a high proportion. Particularly, aliphatic acids in the diesel distillate of Dar still have high proportion among petroleum carboxylic acids. The distribution of petroleum carboxylic acids in VGO is basically identical. The bicyclic naphthenic acids assume the first place （about 25 m%）, while the monocyclic and tricyclic naphthenic acids take the next place. The comparison of petroleum carboxylic acids in diesel distillates and VGOs has revealed that the molecules of carboxylic acids in VGOs are not only bigger but also more complicated.
文摘The Dar crude oil produced in Sudan was distilled into several fractions. The heteroatom class species in crude and its fractions were characterized by the negative-ion ESI FT-ICR MS. The major emphasis was put upon the study on the O2 class species (petroleum carboxylic acids). The test results revealed that aliphatic acids and monocyclic naphthenic acids accounted for a large proportion in petroleum carboxylic acids of the Dar crude. The relative abundance of aliphatic acids and monocyclic naphthenic acids decreased with an increasing boiling point of fractions. Meanwhile, the relative abundance of bicyclic and tricyclic naphthenic acids increased at first and then decreased, whereas the relative abundance of petroleum carboxylic acids with higher double-bond equivalence (DBE) values increased. The high abundance of aliphatic acids in the Dar crude and its fractions covered the carbon numbers in a range of 16 to 18 which had important geochemical signifi- cance. The O2 class species were distributed in a broad range of DBE values and carbon numbers with increasing boiling points of fractions.
基金National Natural Science Foundation of China(12171302,11801334)Natural Science Foundation of Shanxi Province(202103021224287)+1 种基金Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L278)Science&Technology Development Fund of Tianjin Education Commission for Higher Education(2019KJ141).
文摘A group H is said to be autocapable if there exists a group M such that H is isomorphic to the absolute central factor group M/L(M)of M.In this paper,we first prove that if N is a characteristic subgroup of an autocapable group H,then N is neither the generalized quaternion group nor the semi-dihedral group.Next,we give the classification of finite groups G if G/L(G)is a 2-group of maximal class.
基金Supported by Grant No.RD-08-82/03.02.2016 of Shumen University
文摘The Bogomolov multiplier B0 （G） of a finite group G is defined as the subgroup of the Schur multiplier consisting of the cohomology classes vanishing after restriction to all abelian subgroups of G. The triviality of the Bogomolov multiplier is an obstruction to Noether＇s problem. We show that if G is a central product of G1 and G2, regarding Ki ≤ Z（Gi）,i = 1,2, and θ ： G1 →G2 is a group homomorphism such that its restriction θ｜K1 ： K1 → K2 is an isomorphism, then the triviality of Bo（G1/K1）, Bo（G1） and B0（G2） implies the triviality of Bo（G）. We give a positive answer to Noether＇s problem for all 2-generator p-groups of nilpotency class 2, and for one series of 4-generator p-groups of nilpotency class 2 （with the usual requirement for the roots of unity）.
文摘In this paper, concerned with the Cauchy problem for 2D nonlinear hyperbolic conservation laws,we construct a class of uniformly second order accurate finite difference schemes, which are based on the E-schemes. By applying the conver gence theorem of Coquel-Le Floch [1], the family of approximate solutions defined by the scheme is proven to converge to the unique entropy weak L∞-solution. Furthermore, some numerical experiments on the Cauchy problem for the advection equation and the Riemann problem for the 2D Burgers equation are given and the relatively satisfied result is obtained.
