Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of...Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.展开更多
Lakes are carbon dioxide(CO_(2))and methane(CH_(4))emission hotspots,whose associated flux is spatially vari-able.Many studies have investigated the impact of microorganisms and environmental factors on CO_(2) and CH_...Lakes are carbon dioxide(CO_(2))and methane(CH_(4))emission hotspots,whose associated flux is spatially vari-able.Many studies have investigated the impact of microorganisms and environmental factors on CO_(2) and CH_(4) emissions between different lakes.However,the carbon emissions and their influencing factors of different areas within a single lake remain poorly understood.Accordingly,this study investigates CO_(2) and CH_(4) emission hetero-geneity in a large floodplain lake system and distribution characteristics of associated functional microorganisms.Findings show that mean CO_(2) and CH_(4) flux values in the sub lake area were 62.03±24.21 mg/(m2·day)and 5.97±3.2μg/(m2·day),which were greater by factors of 1.78 and 2.96 compared to the water channel and the main lake area,respectively.The alpha diversity of methanogens in the sub lake area was lower than that in the main lake and water channel areas.The abundance of methanogens in bottom water layer was higher compared with the middle and surface layers.Conversely,the abundance of methane(CH_(4))-oxidizing bacteria in the surface layer was higher than that in the bottom layer.Additionally,the composition of methanogen and CH_(4)-oxidizing bacterial community,chlorophyll a(Chl-a),pH,total phosphorus(TP)and dissolved organic carbon(DOC)con-tent constituted the dominate driving factors affecting lake C emissions.Results from this study can be used to improve our understanding of lake spatial heterogeneous of CO_(2) and CH_(4) emission and the driving mechanisms within floodplain lakes under the coupling effects of functional C microorganisms and environmental factors.展开更多
The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide ele...The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide electricity users in carbon reduction and promote power industry low-carbon transformation.Fundamentally,calculating indirect carbon emissions involves allocating direct carbon emission data from the power source side,indicating that accurate indirect emission results rely on the precise measurement of power source emissions.However,existing research on indirect carbon emissions in large-scale power systems rarely accounts for variations in carbon emission characteristics under different operating conditions of power sources,such as rated/non-rated operating conditions and ramping up/down conditions,making it difficult to reflect source-side and load-side carbon emission information variation during providing ancillary services.Quadratic and exponential functions are proposed to characterize the energy consumption profiles of coal-fired and gas-fired power generation,respectively,to construct a refined carbon emission model for power sources.By leveraging the theory of power system carbon flow,we analyze how variable operating conditions of power sources impact indirect carbon emissions.Case studies demonstrate that changes in power source emissions under variable conditions have a significant effect on the indirect carbon emissions of power grids.展开更多
The direct reduction process can reduce carbon emissions by over 50%compared to traditional blast furnace ironmaking.Carbon deposition and carburization are critical for ensuring process stability and economic viabili...The direct reduction process can reduce carbon emissions by over 50%compared to traditional blast furnace ironmaking.Carbon deposition and carburization are critical for ensuring process stability and economic viability.Thermodynamic phase diagrams were developed to intuitively represent carbon deposition and carburization preferences in CH4-CO-H_(2) ternary atmospheres.High carbon potential and low oxygen potential significantly enhance carbon deposition and carburization.Increasing temperature from 500 to 1000℃ shifts the dominant reactions from CO-based to CH_(4)-based,increasing maximum carbon deposition from 0.55 to 0.80 mol and carburization from 0.25 to 0.80 mol per mole of reducing gas.Increasing pressure suppresses CH4-based reactions while promoting CO-based reactions,reducing maximum carbon deposition from 0.8 to~0.7 mol and increasing maximum carburization from 0.80 to 0.85 mol per mole of reducing gas.Equilibrium phase diagrams for various carbides were also developed,revealing preferences for Fe_(3)C_(2),Fe_(7)C_(3),Fe_(5)C_(2),and Fe_(3)C as the Fe/C ratio increases.Higher temperatures and CH_(4) concentrations favor the formation of carbides with higher carbon content.Carburization preferences under typical Energiron ZR and Midrex atmospheres were highlighted,and the higher carbon content in direct reduction iron produced by the Energiron ZR process was thermodynamically confirmed.展开更多
The energy transition inspired by carbon neutrality targets and the increasing threat of extreme events raise multi-objective development requirements for power systems.This paper proposes a multi-objective resource a...The energy transition inspired by carbon neutrality targets and the increasing threat of extreme events raise multi-objective development requirements for power systems.This paper proposes a multi-objective resource allocation model to determine the type,number and location of flexible resources to increase the values of resilience,carbon reduction and renewable energy consumption.To evaluate the values of resilience,a restoration model for transmission systems is established that considers the coordination of fossil-fuel generators,energy storage systems(ESSs)and renewable energy generators in building restoration paths.The collaborative power-carbon-tradable green certificate(TGC)market model is then applied to evaluate the resource values in terms of carbon reduction and renewable energy consumption.Finally,the model is formulated as a mixed-integer linear programming(MILP)with a nonconvex feasible domain,and the normalized normal constraint(NNC)method is applied to obtain approximate Pareto frontiers for decision makers.Case studies validate the effectiveness of the proposed model in improving multi-factor values and analyze the impact of resource regulation capacity on values of restoration and carbon reduction.展开更多
Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In ...Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.展开更多
Driven by the global energy transition and the urgent“dual carbon”goals,regional integrated energy system(RIES)planning is undergoing a paradigm shift from carbon reduction to negative carbon emissions.This paper pr...Driven by the global energy transition and the urgent“dual carbon”goals,regional integrated energy system(RIES)planning is undergoing a paradigm shift from carbon reduction to negative carbon emissions.This paper provides a comprehensive review of the theoretical frameworks and technical pathways for RIES planning from a carbon-centric perspective.A key contribution is the proposed Carbon-Energy-Economy(CEE)triple-dimensional governance framework,which endogenizes carbon factors into planning decisions through emission constraints,trading mechanisms,and capture technologies.We first analyze the fundamental characteristics of RIES and their critical role in achieving carbon neutrality,detailing advancements in multi-energy coupling models,energy router concepts,and standardized energy hub modeling.The paper further explores multi-energy flow analysis methods,and systematically compares the applicability and limitations of various planning algorithms,with emphasis on addressing uncertainties from renewable integration.Finally,we highlight the integration of artificial intelligence with traditional optimization methods,offering new pathways for intelligent,adaptive,and low-carbon RIES planning.This review underscores the transition towards data-physical fusion models,cooperative uncertainty optimization,multi-market planning,and innovative zero/negative-carbon technological routes.展开更多
To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon...To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon capture and storage(CCS),hydrogen fuel cell(HFC),and combined heat and power(CHP).The P2G process is refined into a two-stage structure,and HFC is introduced to enhance hydrogen utilization.Together with CCS and CHP,these devices form a multi-energy conversion system coupling electricity,heat,cooling,and gas.A laddertype carbon trading approach is adopted to flexibly manage carbon output by leveraging marginal cost adjustments.To evaluate the resilience of the proposed low-carbon scheduling strategy involving multiple energy units under the variability of renewable energy,a two-level robust optimization framework is developed.This model captures the most adverse scenarios of wind and solar generation.The dispatch strategy is validated against these extreme conditions to demonstrate its flexibility and effectiveness.The problem is solved using the GUROBI optimization tool.Results from simulations indicate that themodel increases renewable energy integration by 39.1%,and achieves reductions of 15.96%in carbon emissions and 16.29%in operational expenditures.The results demonstrate that the strategy ensures both economic efficiency and environmental performance under uncertain conditions.Compared with existing studies that separately model two-stage P2G or CCS devices,this paper integrates HFC,CHP,and CCS into a unified dispatchable system,enabling refined hydrogen utilization and flexible carbon circulation.Furthermore,the introduction of a laddertype carbon pricing mechanism,combined with multi-energy storage participation in implicit demand response,creates a dynamic and cost-sensitive dispatch framework.These modeling strategies go beyond conventional linear IES formulations and provide more realistic system representations.The proposed approach not only deepens the coupling among electric,thermal,and gas systems,but also offers a feasible pathway for high-penetration renewable integration in low-carbon energy systems.展开更多
The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering c...The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering can optimize the electrochemical performance of MnO_(2).Here,based on the metal-organic frameworks(MOFs)-derived method and electrochemical reconstruction,a coral-like MnO_(2)structure integrated with a functional nitrogen-doped carbon(NC)coating is designed for Na-SC application.The bioinspired coral-like structure captures numerous electrolyte ions and increases the Na+concentration on the electrode surface,which is beneficial for optimizing the Na+transport pathway and accelerating the electrode reaction kinetics.Moreover,the coral-like crosslinked structure effectively enhances the mechanical properties,enabling the maintenance of the structure of MnO_(2)-based electrodes during long-term operation.Furthermore,in/ex-situ characterizations are performed to elucidate the mechanism of lattice transformation during electrochemical phase reconstruction.Additionally,the theoretical calculation and simulation results reveal the ion/electron dynamics in the fabricated electrode.The prepared electrode demonstrates excellent capacitance storage ability(340.7 F g^(−1)at 0.5 A g^(−1))and cycling stability(85.1%capacitance retention after 10,000 cycles).The assembled hybrid device exhibits exceptional life-span(82.0%capacitance retention after 10,000 cycles)and exceptional energy density(36.5 Wh kg^(−1)).This study provides a reliable biomimetic morphology design strategy for MnO_(2)cathodes,paving the way for the fabrication of high-performance Na-SCs.展开更多
Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis ...Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis and later reconverted to electricity using fuel cells or gas turbines,enhancing the system’s flexibility and reliability in support of deep decarbonization.This study constructs an electricity–hydrogen energy-recycling model based on a coupling relationship considering the bidirectional conversion between electricity and hydrogen.A multistage carbon-emission-reduction indicator constraint is also established.Additionally,the green-certificate and carbon trading markets are introduced to optimize equipment investment and operation costs while achieving carbon-emission reduction.A case study reveals that the proposed EHCS planning model effectively allocates carbon emissions across different system stages,while mitigating economic repercussions,thus ensuring closer alignment with China’s emission-reduction policies.Incorporating diverse market mechanisms significantly enhances the system’s economy and decision-making flexibility,particularly in addressing future challenges in the energy market.展开更多
Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human...Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human and environmental pressures remain poorly understood.In this study,we analyzed the spatiotemporal evolution of NEP in the Horqin Sandy Land,China from 2000 to 2020,and observed the variation in NEP across different land use types.We further identified and quantified the effects of human activities,topographical features,climatic conditions,and soil properties on NEP through the application of structural equation modeling(SEM)and boosted regression trees(BRT).The results showed that the multi-year average NEP ranged from–137.79 to 461.96 g C/m^(2) in the Horqin Sandy Land,with 88.21%of the area showing a significant increasing trend.Among different land use types,forestland exhibited the highest NEP values,followed by cropland,grassland,impervious land,and unused land.The NEP in carbon sink areas was primarily regulated by potential evapotranspiration(negatively correlated)and precipitation(positively correlated).Slope was identified as the most significant positive determinant in carbon source areas.Forestland exhibited climate–topography interactions driving NEP,whereas cropland and grassland relied on temperature;unused land and impervious land were susceptible to land use/cover change and human footprint.This study has significant implications for maintaining the carbon sink function and promoting ecological engineering programs that aim to enhance the capacity of terrestrial carbon sinks in the semi-arid agro-pastoral ecotone.展开更多
In this paper,a bilevel optimization model of an integrated energy operator(IEO)–load aggregator(LA)is constructed to address the coordinate optimization challenge of multiple stakeholder island integrated energy sys...In this paper,a bilevel optimization model of an integrated energy operator(IEO)–load aggregator(LA)is constructed to address the coordinate optimization challenge of multiple stakeholder island integrated energy system(IIES).The upper level represents the integrated energy operator,and the lower level is the electricity-heatgas load aggregator.Owing to the benefit conflict between the upper and lower levels of the IIES,a dynamic pricing mechanism for coordinating the interests of the upper and lower levels is proposed,combined with factors such as the carbon emissions of the IIES,as well as the lower load interruption power.The price of selling energy can be dynamically adjusted to the lower LA in the mechanism,according to the information on carbon emissions and load interruption power.Mutual benefits and win-win situations are achieved between the upper and lower multistakeholders.Finally,CPLEX is used to iteratively solve the bilevel optimization model.The optimal solution is selected according to the joint optimal discrimination mechanism.Thesimulation results indicate that the sourceload coordinate operation can reduce the upper and lower operation costs.Using the proposed pricingmechanism,the carbon emissions and load interruption power of IEO-LA are reduced by 9.78%and 70.19%,respectively,and the capture power of the carbon capture equipment is improved by 36.24%.The validity of the proposed model and method is verified.展开更多
To prevent the spread of pine wilt disease(PWD),a transportable carbonization equipment was designed for in-situ treatment of infected pine wood(IPW).The equipment killed all pine wood nematodes(PWNs)in IPW when carbo...To prevent the spread of pine wilt disease(PWD),a transportable carbonization equipment was designed for in-situ treatment of infected pine wood(IPW).The equipment killed all pine wood nematodes(PWNs)in IPW when carbonization temperature was up to 200℃.The optimal laboratory process of infected pine wood charcoal(IPWC)was carbonization temperature of 500℃,heating rate of 3℃min^(−1)and holding time of 0 min.Based on the optimal laboratory process,the transportable carbonization equipment produced IPWC with a fixed carbon content of 79.82%,and ash content of 1.14%and a moisture content of 7.83%,which meets the requirements of EN 1860-2:2005(E)standard.The economic efficiency of incineration(T1 mode),crushing(T2 mode),and transportable carbonization(T3 mode)was evaluated.For each ton of IPW treatment,the profit generated was−75.48 USD in T1 mode,26.28 USD in T2 mode,and 51.91 USD in T3 mode.T3 mode had the highest economic efficiency.These findings will be helpful to provide guidance for the control of PWD and value-added utilization of IPW.展开更多
Lignin has been proved to be a promising precursor for producing carbon foam.The thermal and chemistry properties of lignin during its thermal conversion make it quite unique comparing with other precursors,and the co...Lignin has been proved to be a promising precursor for producing carbon foam.The thermal and chemistry properties of lignin during its thermal conversion make it quite unique comparing with other precursors,and the conversion parameters can clearly affect the properties of the derived products.Therefore,this study systematically investigated the effects of key carbonization parameters on the properties of the resulting carbon foam materials.The findings demonstrate that the performance of the self-shaping lignin-derived carbon foam is simultaneously influenced by the factors that carbonization temperature,heating rate,and carbonization duration.Specifically,the carbonization temperature and carbonization duration have a significant impact on the mechanical performance,where higher temperatures and long carbonization time improve compressive strength and specific strength.Moreover,the data revealed that elevated temperatures,rapid heating rates,and shortened carbonization periods collectively promoted the development of higher porosities and larger pore diameters within the carbon foam structure.Conversely,lower carbonization temperatures,slower heating rates,and extended carbonization durations facilitated the formation of microporous in the carbon foam.This study provides a scientific foundation for optimizing the production of lignin-derived carbon foam with tailored properties and performance characteristics.展开更多
In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy sy...In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy systems(IES)is becoming increasingly obvious.In this case,to promote the low-carbon operation of IES and renewable energy consumption,and to improve the IES anti-interference ability,this paper proposes an IES scheduling strategy that considers CCS-P2G and concentrating solar power(CSP)station.Firstly,CSP station,gas hydrogen doping mode and variable hydrogen doping ratio mode are applied to IES,and combined with CCS-P2G coupling model,the IES low-carbon economic dispatch model is established.Secondly,the stepped carbon trading mechanism is applied,and the sensitivity analysis of IES carbon trading is carried out.Finally,an IES optimal scheduling strategy based on fuzzy opportunity constraints and an IES risk assessment strategy based on CVaR theory are established.The simulation shows that the gas-hydrogen doping model proposed in this paper reduces the operating cost and carbon emission of IES by 1.32%and 7.17%,and improves the carbon benefit by 5.73%;variable hydrogen doping ratio model reduces the operating cost and carbon emission of IES by 3.75%and 1.70%,respectively;CSP stations reduce 19.64%and 38.52%of the operating costs of IES and 1.03%and 1.80%of the carbon emissions of IES respectively compared to equal-capacity photovoltaic and wind turbines;the baseline price of carbon trading of IES and its rate of change jointly affect the carbon emissions of IES;evaluating the anti-interference capability of IES through trapezoidal fuzzy number and weighting coefficients,enabling IES to guarantee operation at the lowest cost.展开更多
Moso bamboo(Phyllostachys edulis)forests are a vital resource in subtropical China,known for their high carbon(C)sequestration capacity.However,the dynamic processes of C fluxes within each component(canopy,culm,and s...Moso bamboo(Phyllostachys edulis)forests are a vital resource in subtropical China,known for their high carbon(C)sequestration capacity.However,the dynamic processes of C fluxes within each component(canopy,culm,and soil)and their individual contributions,particularly during on-and off-years,remain unclear.A 2-year field experiment was conducted to investigate the dynamics of C fluxes from the canopy,culm,and soil(partitioned into heterotrophic,rhizome,and stump respiration)and their contributions to net ecosystem productivity(NEP)in a representative Moso bamboo forest in the subtropical region of China.The average annual NEP of the Moso bamboo forest was 7.31±2.76 t C·ha^(-1).Specifically,the canopy's annual net C uptake was 17.30±3.23 tC·ha^(-1),accounting for 237%of NEP.In contrast,C emissions from heterotrophs,culms,rhizomes,and stumps were 5.37±1.20,2.18±1.05,1.29±0.04,and 1.15±0.33 t C·ha^(-1),accounting for73%,30%,18%,and16%of NEP,respectively.The NEP,net cumulative C uptake in the canopy,and C emissions from the respiration of heterotrophs and stumps were all significantly higher during on-years when compared to off-years,whereas C emissions from bamboo culms displayed opposite trends.These findings offer a new approach for quantifying the C budgets of Moso bamboo forests and provide valuable insights into the C cycling processes in forest ecosystems.展开更多
The Qinghai-Xizang Plateau(QXP)serves as a crucial ecological barrier in China and Asia,exerting profound influences on global climate and biodiversity conservation.Gannan Tibetan Autonomous Prefecture(hereinafter ref...The Qinghai-Xizang Plateau(QXP)serves as a crucial ecological barrier in China and Asia,exerting profound influences on global climate and biodiversity conservation.Gannan Tibetan Autonomous Prefecture(hereinafter referred as Gannan Prefecture),located on the northeastern edge of the QXP,represents a fragile alpine ecosystem in which land use change significantly impacts ecosystem services(ESs).This study established a comprehensive framework,utilizing the Patch-generating Land-Use Simulation(PLUS)model coupled with the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model to predict land use patterns under the natural development scenario,cultivated land protection scenario,and ecological protection scenario for Gannan Prefecture by 2030 and evaluated four critical ESs:habitat quality(HQ),water yield(WY),soil retention(SR),and carbon storage(CS).The primary aim is to elucidate the impacts of dynamic land use change on ESs.The results revealed that,from 2000 to 2020,HQ exhibited minimal variation,whereas CS experienced a slight decline.Conversely,WY and SR showed significant improvements.Under the natural development scenario,construction land was projected to increase by 4247.74 hm^(2),primarily at the expense of forest land.The cultivated land protection scenario anticipated an increase in farmland by 2634.36 hm^(2),which was crucial for maintaining food security.The ecological protection scenario predicted a notable expansion of forest land,accompanied by a restrained development rate of construction land.The ecological protection scenario also showed an increase in the ecosystem service index(ESI),encompassing 26.07%of the region.Forest land and grassland emerged as the primary contributors to ESs,while construction land substantially impacted WY.Water bodies exhibited minimal contribution to ESs.This study enhanced the understanding of land use change impacts on ESs in fragile and high-altitude ecosystems,offering essential theoretical frameworks and practical direction for forthcoming ecological policy and regional planning endeavors.展开更多
Herein,we report a simple self-charging hybrid power system(SCHPS)based on binder-free zinc copper selenide nanostructures(ZnCuSe_(2) NSs)deposited carbon fabric(CF)(i.e.,ZnCuSe_(2)/CF),which is used as an active mate...Herein,we report a simple self-charging hybrid power system(SCHPS)based on binder-free zinc copper selenide nanostructures(ZnCuSe_(2) NSs)deposited carbon fabric(CF)(i.e.,ZnCuSe_(2)/CF),which is used as an active material in the fabrication of supercapacitor(SC)and triboelectric nanogenerator(TENG).At first,a binder-free ZnCuSe_(2)/CF was synthesized via a simple and facial hydrothermal synthesis approach,and the electrochemical properties of the obtained ZnCuSe_(2)/CF were evaluated by fabricating a symmetric quasi-solid-state SC(SQSSC).The ZCS-2(Zn:Cu ratio of 2:1)material deposited CF-based SQSSC exhibited good electrochemical properties,and the obtained maximum energy and power densities were 7.5 Wh kg^(-1)and 683.3 W kg^(-1),respectively with 97.6%capacitance retention after 30,000 cycles.Furthermore,the ZnCuSe_(2)/CF was coated with silicone rubber elastomer using a doctor blade technique,which is used as a negative triboelectric material in the fabrication of the multiple TENG(M-TENG).The fabricated M-TENG exhibited excellent electrical output performance,and the robustness and mechanical stability of the device were studied systematically.The practicality and applicability of the proposed M-TENG and SQSSC were systematically investigated by powering various low-power portable electronic components.Finally,the SQSSC was combined with the M-TENG to construct a SCHPS.The fabricated SCHPS provides a feasible solution for sustainable power supply,and it shows great potential in self-powered portable electronic device applications.展开更多
The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanis...The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanisms lack sufficient incentives for emission reductions,and traditional optimization algorithms often face challenges with convergence and local optima in complex PIES scheduling.To address these issues,this paper introduces a low-carbon dispatch strategy that combines a reward-penalty tiered carbon trading model with P2G-CCS integration,hydrogen utilization,and the Secretary Bird Optimization Algorithm(SBOA).Key innovations include:(1)A dynamic reward-penalty carbon trading mechanism with coefficients(μ=0.2,λ=0.15),which reduces carbon trading costs by 47.2%(from$694.06 to$366.32)compared to traditional tiered models,incentivizing voluntary emission reductions.(2)The integration of P2G-CCS coupling,which lowers natural gas consumption by 41.9%(from$4117.20 to$2389.23)and enhances CO_(2) recycling efficiency,addressing the limitations of standalone P2G or CCS technologies.(3)TheSBOA algorithm,which outperforms traditionalmethods(e.g.,PSO,GWO)in convergence speed and global search capability,avoiding local optima and achieving 24.39%faster convergence on CEC2005 benchmark functions.(4)A four-energy PIES framework incorporating electricity,heat,gas,and hydrogen,where hydrogen fuel cells and CHP systems improve demand response flexibility,reducing gas-related emissions by 42.1%and generating$13.14 in demand response revenue.Case studies across five scenarios demonstrate the strategy’s effectiveness:total operational costs decrease by 14.7%(from$7354.64 to$6272.59),carbon emissions drop by 49.9%(from 5294.94 to 2653.39kg),andrenewable energyutilizationincreases by24.39%(from4.82%to8.17%).These results affirmthemodel’s ability to reconcile economic and environmental goals,providing a scalable approach for low-carbon transitions in industrial parks.展开更多
Under the pressure of environmental issues,decarbonization of the entire energy system has emerged as a prevalent strategy worldwide.The evolution of China’s power system will increasingly emphasize the integration o...Under the pressure of environmental issues,decarbonization of the entire energy system has emerged as a prevalent strategy worldwide.The evolution of China’s power system will increasingly emphasize the integration of variable renewable energy(VRE).However,the rapid growth of VRE will pose substantial challenges to the power system,highlighting the importance of power system planning.This letter introduces Grid Optimal Planning Tool(GOPT),a planning tool,and presents the key findings of our research utilizing GOPT to analyze the transition pathway of China’s power system towards dual carbon goals.Furthermore,the letter offers insights into key technologies essential for driving the future transition of China’s power system.展开更多
基金supported by National Natural Science Foundation of China(22578155,22478147)the Natural Science Foundation of Huaian City(HAB2024051).
文摘Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.
基金supported by the National Natural Science Foundation of China(No.42225103).
文摘Lakes are carbon dioxide(CO_(2))and methane(CH_(4))emission hotspots,whose associated flux is spatially vari-able.Many studies have investigated the impact of microorganisms and environmental factors on CO_(2) and CH_(4) emissions between different lakes.However,the carbon emissions and their influencing factors of different areas within a single lake remain poorly understood.Accordingly,this study investigates CO_(2) and CH_(4) emission hetero-geneity in a large floodplain lake system and distribution characteristics of associated functional microorganisms.Findings show that mean CO_(2) and CH_(4) flux values in the sub lake area were 62.03±24.21 mg/(m2·day)and 5.97±3.2μg/(m2·day),which were greater by factors of 1.78 and 2.96 compared to the water channel and the main lake area,respectively.The alpha diversity of methanogens in the sub lake area was lower than that in the main lake and water channel areas.The abundance of methanogens in bottom water layer was higher compared with the middle and surface layers.Conversely,the abundance of methane(CH_(4))-oxidizing bacteria in the surface layer was higher than that in the bottom layer.Additionally,the composition of methanogen and CH_(4)-oxidizing bacterial community,chlorophyll a(Chl-a),pH,total phosphorus(TP)and dissolved organic carbon(DOC)con-tent constituted the dominate driving factors affecting lake C emissions.Results from this study can be used to improve our understanding of lake spatial heterogeneous of CO_(2) and CH_(4) emission and the driving mechanisms within floodplain lakes under the coupling effects of functional C microorganisms and environmental factors.
基金supported by the Science and Technology Project of China Southern Power Grid Co.,Ltd.(ZBKTM20232244)the Project of National Natural of Science Foundation of China(52477103).
文摘The real-time and accurate calculation of electricity indirect carbon emissions is not only the critical component for quantifying the carbon emission levels of the power system but also an effective mean to guide electricity users in carbon reduction and promote power industry low-carbon transformation.Fundamentally,calculating indirect carbon emissions involves allocating direct carbon emission data from the power source side,indicating that accurate indirect emission results rely on the precise measurement of power source emissions.However,existing research on indirect carbon emissions in large-scale power systems rarely accounts for variations in carbon emission characteristics under different operating conditions of power sources,such as rated/non-rated operating conditions and ramping up/down conditions,making it difficult to reflect source-side and load-side carbon emission information variation during providing ancillary services.Quadratic and exponential functions are proposed to characterize the energy consumption profiles of coal-fired and gas-fired power generation,respectively,to construct a refined carbon emission model for power sources.By leveraging the theory of power system carbon flow,we analyze how variable operating conditions of power sources impact indirect carbon emissions.Case studies demonstrate that changes in power source emissions under variable conditions have a significant effect on the indirect carbon emissions of power grids.
基金the financial support from the National Key R&D Program of China(No.2024YFC2910800)National Natural Science Foundation of China(52404336)+6 种基金China Postdoctoral Science Foundation(2024M750176)Postdoctoral Fellowship Program of CPSF(GZC20240109)the Young Elite Scientist Sponsorship Program by CAST(YESS20210090)Beijing Natural Science Foundation(J210017)the Project of SKLAM(No.KF24-14)China Baowu Low Carbon Metallurgical Technology Innovation Fund under Grant No.20210901Anhui Major Industrial Innovation Program under Contract No.AHZDCYCX-LSDT2023-01.
文摘The direct reduction process can reduce carbon emissions by over 50%compared to traditional blast furnace ironmaking.Carbon deposition and carburization are critical for ensuring process stability and economic viability.Thermodynamic phase diagrams were developed to intuitively represent carbon deposition and carburization preferences in CH4-CO-H_(2) ternary atmospheres.High carbon potential and low oxygen potential significantly enhance carbon deposition and carburization.Increasing temperature from 500 to 1000℃ shifts the dominant reactions from CO-based to CH_(4)-based,increasing maximum carbon deposition from 0.55 to 0.80 mol and carburization from 0.25 to 0.80 mol per mole of reducing gas.Increasing pressure suppresses CH4-based reactions while promoting CO-based reactions,reducing maximum carbon deposition from 0.8 to~0.7 mol and increasing maximum carburization from 0.80 to 0.85 mol per mole of reducing gas.Equilibrium phase diagrams for various carbides were also developed,revealing preferences for Fe_(3)C_(2),Fe_(7)C_(3),Fe_(5)C_(2),and Fe_(3)C as the Fe/C ratio increases.Higher temperatures and CH_(4) concentrations favor the formation of carbides with higher carbon content.Carburization preferences under typical Energiron ZR and Midrex atmospheres were highlighted,and the higher carbon content in direct reduction iron produced by the Energiron ZR process was thermodynamically confirmed.
基金supported by the Science and Technology Project of the State Grid Corporation of China“Research on Comprehensive Value Evaluation Method of Flexible Adjusting Resources under Carbon-electricity-certificate Market Coupling Environment”(No.5108-202455038A-1-1-ZN).
文摘The energy transition inspired by carbon neutrality targets and the increasing threat of extreme events raise multi-objective development requirements for power systems.This paper proposes a multi-objective resource allocation model to determine the type,number and location of flexible resources to increase the values of resilience,carbon reduction and renewable energy consumption.To evaluate the values of resilience,a restoration model for transmission systems is established that considers the coordination of fossil-fuel generators,energy storage systems(ESSs)and renewable energy generators in building restoration paths.The collaborative power-carbon-tradable green certificate(TGC)market model is then applied to evaluate the resource values in terms of carbon reduction and renewable energy consumption.Finally,the model is formulated as a mixed-integer linear programming(MILP)with a nonconvex feasible domain,and the normalized normal constraint(NNC)method is applied to obtain approximate Pareto frontiers for decision makers.Case studies validate the effectiveness of the proposed model in improving multi-factor values and analyze the impact of resource regulation capacity on values of restoration and carbon reduction.
基金financially supported by the National Natural Science Foundation of China (42477044,32171648 and U23A2017)the Hubei Provincial Science and Technology Program,China (2025AFD451 and 2022CFB030)。
文摘Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.
基金supported by the Natural Science Foundation of China(Grants U2166211)Zhejiang Provincial Natural Science Foundation of China(Grants LY24E070006 and LMS25E070002).
文摘Driven by the global energy transition and the urgent“dual carbon”goals,regional integrated energy system(RIES)planning is undergoing a paradigm shift from carbon reduction to negative carbon emissions.This paper provides a comprehensive review of the theoretical frameworks and technical pathways for RIES planning from a carbon-centric perspective.A key contribution is the proposed Carbon-Energy-Economy(CEE)triple-dimensional governance framework,which endogenizes carbon factors into planning decisions through emission constraints,trading mechanisms,and capture technologies.We first analyze the fundamental characteristics of RIES and their critical role in achieving carbon neutrality,detailing advancements in multi-energy coupling models,energy router concepts,and standardized energy hub modeling.The paper further explores multi-energy flow analysis methods,and systematically compares the applicability and limitations of various planning algorithms,with emphasis on addressing uncertainties from renewable integration.Finally,we highlight the integration of artificial intelligence with traditional optimization methods,offering new pathways for intelligent,adaptive,and low-carbon RIES planning.This review underscores the transition towards data-physical fusion models,cooperative uncertainty optimization,multi-market planning,and innovative zero/negative-carbon technological routes.
基金supported by the Key Project of Shanghai(Project Number A1-0224-25-002-02-040,Municipal Key Course—Heat Transfer)funded by the National Natural Science Foundation of China(Grant No.52077137).
文摘To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon capture and storage(CCS),hydrogen fuel cell(HFC),and combined heat and power(CHP).The P2G process is refined into a two-stage structure,and HFC is introduced to enhance hydrogen utilization.Together with CCS and CHP,these devices form a multi-energy conversion system coupling electricity,heat,cooling,and gas.A laddertype carbon trading approach is adopted to flexibly manage carbon output by leveraging marginal cost adjustments.To evaluate the resilience of the proposed low-carbon scheduling strategy involving multiple energy units under the variability of renewable energy,a two-level robust optimization framework is developed.This model captures the most adverse scenarios of wind and solar generation.The dispatch strategy is validated against these extreme conditions to demonstrate its flexibility and effectiveness.The problem is solved using the GUROBI optimization tool.Results from simulations indicate that themodel increases renewable energy integration by 39.1%,and achieves reductions of 15.96%in carbon emissions and 16.29%in operational expenditures.The results demonstrate that the strategy ensures both economic efficiency and environmental performance under uncertain conditions.Compared with existing studies that separately model two-stage P2G or CCS devices,this paper integrates HFC,CHP,and CCS into a unified dispatchable system,enabling refined hydrogen utilization and flexible carbon circulation.Furthermore,the introduction of a laddertype carbon pricing mechanism,combined with multi-energy storage participation in implicit demand response,creates a dynamic and cost-sensitive dispatch framework.These modeling strategies go beyond conventional linear IES formulations and provide more realistic system representations.The proposed approach not only deepens the coupling among electric,thermal,and gas systems,but also offers a feasible pathway for high-penetration renewable integration in low-carbon energy systems.
基金supported by the National Natural Science Foundation of China(22409065)the Guangdong Basic and Applied Basic Research Foundation(2022A1515011906)+2 种基金the China Postdoctoral Science Foundation(2023M731153)the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technologythe Postdoctoral Fellowship Program of CPSF(GZC20230868).
文摘The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering can optimize the electrochemical performance of MnO_(2).Here,based on the metal-organic frameworks(MOFs)-derived method and electrochemical reconstruction,a coral-like MnO_(2)structure integrated with a functional nitrogen-doped carbon(NC)coating is designed for Na-SC application.The bioinspired coral-like structure captures numerous electrolyte ions and increases the Na+concentration on the electrode surface,which is beneficial for optimizing the Na+transport pathway and accelerating the electrode reaction kinetics.Moreover,the coral-like crosslinked structure effectively enhances the mechanical properties,enabling the maintenance of the structure of MnO_(2)-based electrodes during long-term operation.Furthermore,in/ex-situ characterizations are performed to elucidate the mechanism of lattice transformation during electrochemical phase reconstruction.Additionally,the theoretical calculation and simulation results reveal the ion/electron dynamics in the fabricated electrode.The prepared electrode demonstrates excellent capacitance storage ability(340.7 F g^(−1)at 0.5 A g^(−1))and cycling stability(85.1%capacitance retention after 10,000 cycles).The assembled hybrid device exhibits exceptional life-span(82.0%capacitance retention after 10,000 cycles)and exceptional energy density(36.5 Wh kg^(−1)).This study provides a reliable biomimetic morphology design strategy for MnO_(2)cathodes,paving the way for the fabrication of high-performance Na-SCs.
基金supported by State Grid Jiangsu Electric Power Co.,Ltd.Technology Project(Research on Planning and Operation Technology of Electric–Hydrogen Coupling System Driven by the Electric–Carbon–Green Certificate Market):J2024005.
文摘Hydrogen,as a zero-carbon secondary energy carrier,provides a unified pathway for low-carbon energy transformation.In electro–hydrogen coupling systems(EHCSs),surplus renewable power is stored via water electrolysis and later reconverted to electricity using fuel cells or gas turbines,enhancing the system’s flexibility and reliability in support of deep decarbonization.This study constructs an electricity–hydrogen energy-recycling model based on a coupling relationship considering the bidirectional conversion between electricity and hydrogen.A multistage carbon-emission-reduction indicator constraint is also established.Additionally,the green-certificate and carbon trading markets are introduced to optimize equipment investment and operation costs while achieving carbon-emission reduction.A case study reveals that the proposed EHCS planning model effectively allocates carbon emissions across different system stages,while mitigating economic repercussions,thus ensuring closer alignment with China’s emission-reduction policies.Incorporating diverse market mechanisms significantly enhances the system’s economy and decision-making flexibility,particularly in addressing future challenges in the energy market.
基金funded by the National Major Science and Technology Program for Water Pollution Control and Treatment(2017ZX07101-002)the Discipline Construction Program of ZHANG Huayong,Distinguished Professor of School of Life Sciences,Shandong University(61200082363001).
文摘Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human and environmental pressures remain poorly understood.In this study,we analyzed the spatiotemporal evolution of NEP in the Horqin Sandy Land,China from 2000 to 2020,and observed the variation in NEP across different land use types.We further identified and quantified the effects of human activities,topographical features,climatic conditions,and soil properties on NEP through the application of structural equation modeling(SEM)and boosted regression trees(BRT).The results showed that the multi-year average NEP ranged from–137.79 to 461.96 g C/m^(2) in the Horqin Sandy Land,with 88.21%of the area showing a significant increasing trend.Among different land use types,forestland exhibited the highest NEP values,followed by cropland,grassland,impervious land,and unused land.The NEP in carbon sink areas was primarily regulated by potential evapotranspiration(negatively correlated)and precipitation(positively correlated).Slope was identified as the most significant positive determinant in carbon source areas.Forestland exhibited climate–topography interactions driving NEP,whereas cropland and grassland relied on temperature;unused land and impervious land were susceptible to land use/cover change and human footprint.This study has significant implications for maintaining the carbon sink function and promoting ecological engineering programs that aim to enhance the capacity of terrestrial carbon sinks in the semi-arid agro-pastoral ecotone.
基金supported by the Central Government Guides Local Science and Technology Development Fund Project(2023ZY0020)Key R&D and Achievement Transformation Project in InnerMongolia Autonomous Region(2022YFHH0019)+3 种基金the Fundamental Research Funds for Inner Mongolia University of Science&Technology(2022053)Natural Science Foundation of Inner Mongolia(2022LHQN05002)National Natural Science Foundation of China(52067018)Metallurgical Engineering First-Class Discipline Construction Project in Inner Mongolia University of Science and Technology,Control Science and Engineering Quality Improvement and Cultivation Discipline Project in Inner Mongolia University of Science and Technology。
文摘In this paper,a bilevel optimization model of an integrated energy operator(IEO)–load aggregator(LA)is constructed to address the coordinate optimization challenge of multiple stakeholder island integrated energy system(IIES).The upper level represents the integrated energy operator,and the lower level is the electricity-heatgas load aggregator.Owing to the benefit conflict between the upper and lower levels of the IIES,a dynamic pricing mechanism for coordinating the interests of the upper and lower levels is proposed,combined with factors such as the carbon emissions of the IIES,as well as the lower load interruption power.The price of selling energy can be dynamically adjusted to the lower LA in the mechanism,according to the information on carbon emissions and load interruption power.Mutual benefits and win-win situations are achieved between the upper and lower multistakeholders.Finally,CPLEX is used to iteratively solve the bilevel optimization model.The optimal solution is selected according to the joint optimal discrimination mechanism.Thesimulation results indicate that the sourceload coordinate operation can reduce the upper and lower operation costs.Using the proposed pricingmechanism,the carbon emissions and load interruption power of IEO-LA are reduced by 9.78%and 70.19%,respectively,and the capture power of the carbon capture equipment is improved by 36.24%.The validity of the proposed model and method is verified.
基金supported by the"National Natural Science Foundation of China"(Grant numbers 31971742)"Basic Scientific Research Funds of International Centre"(1632023003).
文摘To prevent the spread of pine wilt disease(PWD),a transportable carbonization equipment was designed for in-situ treatment of infected pine wood(IPW).The equipment killed all pine wood nematodes(PWNs)in IPW when carbonization temperature was up to 200℃.The optimal laboratory process of infected pine wood charcoal(IPWC)was carbonization temperature of 500℃,heating rate of 3℃min^(−1)and holding time of 0 min.Based on the optimal laboratory process,the transportable carbonization equipment produced IPWC with a fixed carbon content of 79.82%,and ash content of 1.14%and a moisture content of 7.83%,which meets the requirements of EN 1860-2:2005(E)standard.The economic efficiency of incineration(T1 mode),crushing(T2 mode),and transportable carbonization(T3 mode)was evaluated.For each ton of IPW treatment,the profit generated was−75.48 USD in T1 mode,26.28 USD in T2 mode,and 51.91 USD in T3 mode.T3 mode had the highest economic efficiency.These findings will be helpful to provide guidance for the control of PWD and value-added utilization of IPW.
基金funding support from Taishan Scholars Program of Shandong Province(tsqn201909132)National Natural Science Foundation of China(22208183)+1 种基金Startup Foundation from Qingdao Agricultural University(663-1120040,665-1119020)Technology development project from Jinan Shengquan Company(20233702031771)。
文摘Lignin has been proved to be a promising precursor for producing carbon foam.The thermal and chemistry properties of lignin during its thermal conversion make it quite unique comparing with other precursors,and the conversion parameters can clearly affect the properties of the derived products.Therefore,this study systematically investigated the effects of key carbonization parameters on the properties of the resulting carbon foam materials.The findings demonstrate that the performance of the self-shaping lignin-derived carbon foam is simultaneously influenced by the factors that carbonization temperature,heating rate,and carbonization duration.Specifically,the carbonization temperature and carbonization duration have a significant impact on the mechanical performance,where higher temperatures and long carbonization time improve compressive strength and specific strength.Moreover,the data revealed that elevated temperatures,rapid heating rates,and shortened carbonization periods collectively promoted the development of higher porosities and larger pore diameters within the carbon foam structure.Conversely,lower carbonization temperatures,slower heating rates,and extended carbonization durations facilitated the formation of microporous in the carbon foam.This study provides a scientific foundation for optimizing the production of lignin-derived carbon foam with tailored properties and performance characteristics.
基金State Grid Gansu Electric Power Company Science and Technology Program(Grant No.W24FZ2730008)National Natural Science Foundation of China(Grant No.51767017).
文摘In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy systems(IES)is becoming increasingly obvious.In this case,to promote the low-carbon operation of IES and renewable energy consumption,and to improve the IES anti-interference ability,this paper proposes an IES scheduling strategy that considers CCS-P2G and concentrating solar power(CSP)station.Firstly,CSP station,gas hydrogen doping mode and variable hydrogen doping ratio mode are applied to IES,and combined with CCS-P2G coupling model,the IES low-carbon economic dispatch model is established.Secondly,the stepped carbon trading mechanism is applied,and the sensitivity analysis of IES carbon trading is carried out.Finally,an IES optimal scheduling strategy based on fuzzy opportunity constraints and an IES risk assessment strategy based on CVaR theory are established.The simulation shows that the gas-hydrogen doping model proposed in this paper reduces the operating cost and carbon emission of IES by 1.32%and 7.17%,and improves the carbon benefit by 5.73%;variable hydrogen doping ratio model reduces the operating cost and carbon emission of IES by 3.75%and 1.70%,respectively;CSP stations reduce 19.64%and 38.52%of the operating costs of IES and 1.03%and 1.80%of the carbon emissions of IES respectively compared to equal-capacity photovoltaic and wind turbines;the baseline price of carbon trading of IES and its rate of change jointly affect the carbon emissions of IES;evaluating the anti-interference capability of IES through trapezoidal fuzzy number and weighting coefficients,enabling IES to guarantee operation at the lowest cost.
基金sponsored by the National Natural Science Foundation of China(Grant Nos.32125027,31930075)Zhejiang A&F University Research and Development Fund(No.2022LFR006).
文摘Moso bamboo(Phyllostachys edulis)forests are a vital resource in subtropical China,known for their high carbon(C)sequestration capacity.However,the dynamic processes of C fluxes within each component(canopy,culm,and soil)and their individual contributions,particularly during on-and off-years,remain unclear.A 2-year field experiment was conducted to investigate the dynamics of C fluxes from the canopy,culm,and soil(partitioned into heterotrophic,rhizome,and stump respiration)and their contributions to net ecosystem productivity(NEP)in a representative Moso bamboo forest in the subtropical region of China.The average annual NEP of the Moso bamboo forest was 7.31±2.76 t C·ha^(-1).Specifically,the canopy's annual net C uptake was 17.30±3.23 tC·ha^(-1),accounting for 237%of NEP.In contrast,C emissions from heterotrophs,culms,rhizomes,and stumps were 5.37±1.20,2.18±1.05,1.29±0.04,and 1.15±0.33 t C·ha^(-1),accounting for73%,30%,18%,and16%of NEP,respectively.The NEP,net cumulative C uptake in the canopy,and C emissions from the respiration of heterotrophs and stumps were all significantly higher during on-years when compared to off-years,whereas C emissions from bamboo culms displayed opposite trends.These findings offer a new approach for quantifying the C budgets of Moso bamboo forests and provide valuable insights into the C cycling processes in forest ecosystems.
基金funded by the National Natural Science Foundation of China(42101276)the Major Project of Key Research Bases for Humanities and Social Sciences Funded by the Ministry of Education of China(22JJD790015)the Science and Technology Project of Gansu Province,China(20JR5RA529).
文摘The Qinghai-Xizang Plateau(QXP)serves as a crucial ecological barrier in China and Asia,exerting profound influences on global climate and biodiversity conservation.Gannan Tibetan Autonomous Prefecture(hereinafter referred as Gannan Prefecture),located on the northeastern edge of the QXP,represents a fragile alpine ecosystem in which land use change significantly impacts ecosystem services(ESs).This study established a comprehensive framework,utilizing the Patch-generating Land-Use Simulation(PLUS)model coupled with the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model to predict land use patterns under the natural development scenario,cultivated land protection scenario,and ecological protection scenario for Gannan Prefecture by 2030 and evaluated four critical ESs:habitat quality(HQ),water yield(WY),soil retention(SR),and carbon storage(CS).The primary aim is to elucidate the impacts of dynamic land use change on ESs.The results revealed that,from 2000 to 2020,HQ exhibited minimal variation,whereas CS experienced a slight decline.Conversely,WY and SR showed significant improvements.Under the natural development scenario,construction land was projected to increase by 4247.74 hm^(2),primarily at the expense of forest land.The cultivated land protection scenario anticipated an increase in farmland by 2634.36 hm^(2),which was crucial for maintaining food security.The ecological protection scenario predicted a notable expansion of forest land,accompanied by a restrained development rate of construction land.The ecological protection scenario also showed an increase in the ecosystem service index(ESI),encompassing 26.07%of the region.Forest land and grassland emerged as the primary contributors to ESs,while construction land substantially impacted WY.Water bodies exhibited minimal contribution to ESs.This study enhanced the understanding of land use change impacts on ESs in fragile and high-altitude ecosystems,offering essential theoretical frameworks and practical direction for forthcoming ecological policy and regional planning endeavors.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIP)(No.2018R1A6A1A03025708)partly supported by the GRRC program of Gyeonggi province(GRRCKyungHee2023-B03).
文摘Herein,we report a simple self-charging hybrid power system(SCHPS)based on binder-free zinc copper selenide nanostructures(ZnCuSe_(2) NSs)deposited carbon fabric(CF)(i.e.,ZnCuSe_(2)/CF),which is used as an active material in the fabrication of supercapacitor(SC)and triboelectric nanogenerator(TENG).At first,a binder-free ZnCuSe_(2)/CF was synthesized via a simple and facial hydrothermal synthesis approach,and the electrochemical properties of the obtained ZnCuSe_(2)/CF were evaluated by fabricating a symmetric quasi-solid-state SC(SQSSC).The ZCS-2(Zn:Cu ratio of 2:1)material deposited CF-based SQSSC exhibited good electrochemical properties,and the obtained maximum energy and power densities were 7.5 Wh kg^(-1)and 683.3 W kg^(-1),respectively with 97.6%capacitance retention after 30,000 cycles.Furthermore,the ZnCuSe_(2)/CF was coated with silicone rubber elastomer using a doctor blade technique,which is used as a negative triboelectric material in the fabrication of the multiple TENG(M-TENG).The fabricated M-TENG exhibited excellent electrical output performance,and the robustness and mechanical stability of the device were studied systematically.The practicality and applicability of the proposed M-TENG and SQSSC were systematically investigated by powering various low-power portable electronic components.Finally,the SQSSC was combined with the M-TENG to construct a SCHPS.The fabricated SCHPS provides a feasible solution for sustainable power supply,and it shows great potential in self-powered portable electronic device applications.
基金funded by State Grid Beijing Electric Power Company Technology Project,grant number 520210230004.
文摘The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanisms lack sufficient incentives for emission reductions,and traditional optimization algorithms often face challenges with convergence and local optima in complex PIES scheduling.To address these issues,this paper introduces a low-carbon dispatch strategy that combines a reward-penalty tiered carbon trading model with P2G-CCS integration,hydrogen utilization,and the Secretary Bird Optimization Algorithm(SBOA).Key innovations include:(1)A dynamic reward-penalty carbon trading mechanism with coefficients(μ=0.2,λ=0.15),which reduces carbon trading costs by 47.2%(from$694.06 to$366.32)compared to traditional tiered models,incentivizing voluntary emission reductions.(2)The integration of P2G-CCS coupling,which lowers natural gas consumption by 41.9%(from$4117.20 to$2389.23)and enhances CO_(2) recycling efficiency,addressing the limitations of standalone P2G or CCS technologies.(3)TheSBOA algorithm,which outperforms traditionalmethods(e.g.,PSO,GWO)in convergence speed and global search capability,avoiding local optima and achieving 24.39%faster convergence on CEC2005 benchmark functions.(4)A four-energy PIES framework incorporating electricity,heat,gas,and hydrogen,where hydrogen fuel cells and CHP systems improve demand response flexibility,reducing gas-related emissions by 42.1%and generating$13.14 in demand response revenue.Case studies across five scenarios demonstrate the strategy’s effectiveness:total operational costs decrease by 14.7%(from$7354.64 to$6272.59),carbon emissions drop by 49.9%(from 5294.94 to 2653.39kg),andrenewable energyutilizationincreases by24.39%(from4.82%to8.17%).These results affirmthemodel’s ability to reconcile economic and environmental goals,providing a scalable approach for low-carbon transitions in industrial parks.
基金supported by the National Natural Science Foundation of China(No.52130702,No.52177093)。
文摘Under the pressure of environmental issues,decarbonization of the entire energy system has emerged as a prevalent strategy worldwide.The evolution of China’s power system will increasingly emphasize the integration of variable renewable energy(VRE).However,the rapid growth of VRE will pose substantial challenges to the power system,highlighting the importance of power system planning.This letter introduces Grid Optimal Planning Tool(GOPT),a planning tool,and presents the key findings of our research utilizing GOPT to analyze the transition pathway of China’s power system towards dual carbon goals.Furthermore,the letter offers insights into key technologies essential for driving the future transition of China’s power system.
