With zirconium oxychloride, nitrate of lime and ammonia as raw materials, nano powder of CaO ZrO 2 was prepared by chemical coprecipitation method. By use of azeotropic distillation processing, chemical coprecipitatio...With zirconium oxychloride, nitrate of lime and ammonia as raw materials, nano powder of CaO ZrO 2 was prepared by chemical coprecipitation method. By use of azeotropic distillation processing, chemical coprecipitation precursor was obtained. Phase transformation of the precursor was observed at the temperature of 593.81 ℃ and 1 234.56 ℃ respectively with DTA analyses. Phase structure was analyzed through XRD and Raman spectra. The average particle size of tetragonal zirconium oxide powder was 9.8 and 43.7 nm after calcination at 600 and 1 100 ℃ respectively which was tested by TEM and BET analyses. Furthermore, the influences of the doping of nitrate of lime and the average particle size of zirconium oxide on the stability of tetragonal zirconium oxide were also discussed.展开更多
The decomposition of K-Feldspar is significant to the development and utilization of K-feldspar as potassium resources. Potassium feldspar powder was decomposed successfully by hydrothermal method using CaO additive. ...The decomposition of K-Feldspar is significant to the development and utilization of K-feldspar as potassium resources. Potassium feldspar powder was decomposed successfully by hydrothermal method using CaO additive. Tobermorite solid and KOH solution were obtained as a result of the hydrothermal decomposition.展开更多
文摘With zirconium oxychloride, nitrate of lime and ammonia as raw materials, nano powder of CaO ZrO 2 was prepared by chemical coprecipitation method. By use of azeotropic distillation processing, chemical coprecipitation precursor was obtained. Phase transformation of the precursor was observed at the temperature of 593.81 ℃ and 1 234.56 ℃ respectively with DTA analyses. Phase structure was analyzed through XRD and Raman spectra. The average particle size of tetragonal zirconium oxide powder was 9.8 and 43.7 nm after calcination at 600 and 1 100 ℃ respectively which was tested by TEM and BET analyses. Furthermore, the influences of the doping of nitrate of lime and the average particle size of zirconium oxide on the stability of tetragonal zirconium oxide were also discussed.
基金Project supported by National Key Technologies Research and Development Program for 11th Five-year Plan (No. 2006 BAD10B04)China Geological Survey Project (No. 12120113087700)
文摘The decomposition of K-Feldspar is significant to the development and utilization of K-feldspar as potassium resources. Potassium feldspar powder was decomposed successfully by hydrothermal method using CaO additive. Tobermorite solid and KOH solution were obtained as a result of the hydrothermal decomposition.
