The ability of a novel nonionic CO2 -soluble surfactant to propagate foam in porous media was compared with that of a conventional anionic surfactant（aqueous soluble only）through core floods with Berea sandstone cor...The ability of a novel nonionic CO2 -soluble surfactant to propagate foam in porous media was compared with that of a conventional anionic surfactant（aqueous soluble only）through core floods with Berea sandstone cores.Both simultaneous and alternating injections have been tested.The novel foam outperforms the conventional one with respect to faster foam propagation and higher desaturation rate.Furthermore,the novel injection strategy,CO2 continuous injection with dissolved CO2 -soluble surfactant,has been tested in the laboratory.Strong foam presented without delay.It is the first time the measured surfactant properties have been used to model foam transport on a field scale to extend our findings with the presence of gravity segregation.Different injection strategies have been tested under both constant rate and pressure constraints.It was showed that novel foam outperforms the conventional one in every scenario with much higher sweep efficiency and injectivity as well as more even pressure redistribution.Also,for this novel foam,it is not necessary that constant pressure injection is better,which has been concluded in previous literature for conventional foam.Furthermore,the novel injection strategy,CO2 continuous injection with dissolved CO2 -soluble surfactant,gave the best performance,which could lower the injection and water treatment cost.展开更多
The photochemical conversion of SO_(2) to sulfates on 4-(benzoyl)benzoic acid(4-BBA)was investigated deeply in the presence of anionic and cationic surfactants.The types of surfactants determined their effect behavior...The photochemical conversion of SO_(2) to sulfates on 4-(benzoyl)benzoic acid(4-BBA)was investigated deeply in the presence of anionic and cationic surfactants.The types of surfactants determined their effect behaviors,and cationic surfactants can significantly enhance the SO_(2) oxidation on 4-BBA under irradiation,as shown by larger SO_(2) uptake coefficients and sulfate production.Hydrophilic moieties in cationic surfactants have a greater enhancement effect on the photochemical conversion of SO_(2) to sulfates than the corresponding hydrophobic moieties.Cationic surfactants obviously increased the accumulation of H_(2)O on the surface,which was proved to be the main factor influencing the SO_(2) uptake and the sulfate formation on 4-BBA.SO_(2) lifetime and sulfate formation rate in the mixture system of photosensitive substances with surfactants were evaluated to be 2.25 days and 0.09μg/(m^(3)·h),respectively.展开更多
As one promising CO_(2)capture,utilization and storage(CCUS)technology,miscible CO_(2)-enhanced oil recovery(CO_(2)-EOR)significantly outperforms immiscible flooding in enhancing oil production and storing CO_(2).Howe...As one promising CO_(2)capture,utilization and storage(CCUS)technology,miscible CO_(2)-enhanced oil recovery(CO_(2)-EOR)significantly outperforms immiscible flooding in enhancing oil production and storing CO_(2).However,achieving CO_(2)miscible flooding is often hindered by the high minimum miscibility pressure of CO_(2)-oil system in many reservoirs.To address this issue,this study focuses on the mechanisms for enhancing CO_(2)-oil miscibility using different types of surfactants and their blends with ethanol.The effects of fatty alcohol polyoxyethylene ethers(EO),fatty alcohol polyoxypropylene ethers(PO),tributyl citrate(TC),and glyceryl triacetate(GT)on the CO_(2)-oil miscibility pressure are quantitatively analyzed,as well as their synergy with ethanol.Results demonstrated that all tested surfactant additives reduce the CO_(2)-oil miscibility pressu re.For ethe r-based surfactant additives,an increase in the degree of polymerization(CO_(2)-philic groups)weakens the effectiveness to reduce miscibility pressure.Oxygen atoms in the functional group contribute more significantly to miscibility enhancement than carbon atoms.Among ester surfactants,GT achieved the best reduction effect of miscibility pressure(11.82%at 3.0 wt%),attributed to its symmetrical short side-chain structure and ester groups.Furthermore,ethanol exhibited a significant improvement for surfactants in enhancing miscibility.Notably,the reduction of CO_(2)-oil miscibility pressure increases to 27.9%by 3.0 wt%GT blended with 5.0 wt%ethanol.These findings demonstrate that blending surfactants with ethanol is a feasible and effective strategy to facilitate miscible CO_(2)flooding.This study provides valuable insights and practical guidance for the field implementation of miscible CO_(2)-EOR.展开更多
In this study,a series of polyetherimide/SBA-15： 2-D hexagonal P6 mm,Santa Barbara USA（PEI/SBA-15） adsorbents modified by phosphoric ester based surfactants（including tri（2-ethylhexyl）phosphate（TEP）,bis（2-eth...In this study,a series of polyetherimide/SBA-15： 2-D hexagonal P6 mm,Santa Barbara USA（PEI/SBA-15） adsorbents modified by phosphoric ester based surfactants（including tri（2-ethylhexyl）phosphate（TEP）,bis（2-ethylhexyl） phosphate（BEP） and trimethyl phosphonoacetate（TMPA））were prepared for CO2 adsorption.Experimental results indicated that the addition of TEP and BEP had positive effects on CO2 adsorption capacity over PEI/SBA-15.In particular,the CO2 adsorption amount could be improved by around 20% for 45PEI-5TEP/SBA-15 compared to the additive-free adsorbent.This could be attributed to the decrease of CO2 diffusion resistance in the PEI bulk network due to the interactions between TEP and loaded PEI molecules,which was further confirmed by adsorption kinetics results.In addition,it was also found that the cyclic performance of the TEP-modified adsorbent was better than the surfactant-free one.This could be due to two main reasons,based on the results of in situ DRIFT and TG-DSC tests.First and more importantly,adsorbed CO2 species could be desorbed more rapidly over TEP-modified adsorbent during the thermal desorption process.Furthermore,the enhanced thermal stability after TEP addition ensured lower degradation of amine groups during adsorption/desorption cycles.展开更多
In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. T...In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures.展开更多
The effect of Ca 2+ on the removal of Alexandrium sp. LC3 under HDTMAB stress was investigated. The results showed that the toxic effect of HDTMAB on Alexandrium sp. LC3 was significantly reduced in the presence of C...The effect of Ca 2+ on the removal of Alexandrium sp. LC3 under HDTMAB stress was investigated. The results showed that the toxic effect of HDTMAB on Alexandrium sp. LC3 was significantly reduced in the presence of Ca 2+, especially under 4 mmol/L of Ca 2+. To understand the underlying mechanism, the SH group and MDA content of the cell membrane and membrane permeability were measured. It was found that the SH content of cell member increased, the MDA content and membrane permeability decreased when Alexandrium sp. was treated with Ca 2+ and HDTMAB complex, compared with using HDTMAB only. The data suggested that Ca 2+ might promote HDTMAB stress resistance of Alexandrium sp. LC3 by reducing the permeability and increasing the stability of cell membrane.展开更多
Perfluorooctanoic acid(PFOA) or perfluorooctane sulphonate(PFOS) was one of the most prominent fluorosurfactants and applied widely in firefighting and daily chemical, etc. However, these surfactants have recently bee...Perfluorooctanoic acid(PFOA) or perfluorooctane sulphonate(PFOS) was one of the most prominent fluorosurfactants and applied widely in firefighting and daily chemical, etc. However, these surfactants have recently been identified as toxic and undegradability in the environment. Developing an efficient approach to environment-friendly fluorosurfactants is essential. A fluorocarbon branched chain strategy was adopted to develop/PFOS substitutes. A series of intermediates of novel branched fluorinated surfactants with CF_3 CF_2CF_2C(CF3)_2 group were synthesized from perfluoro-2-methyl-2-pentene. All the steps were mild, easy-handled and cheap. It is expected to be a very significant direction for the development of non-bioaccumulable alternatives of PFOA or PFOS.展开更多
Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling...Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes.展开更多
The combined ecological toxicity of TiO2 nanoparticles（nano-TiO2） and heavy metals has been paid more attention. As the common pollutants in water environment, surfactants could affect the properties of nanoparticle...The combined ecological toxicity of TiO2 nanoparticles（nano-TiO2） and heavy metals has been paid more attention. As the common pollutants in water environment, surfactants could affect the properties of nanoparticles and heavy metals, and thus further influence the combined toxicity of nano-TiO2 and heavy metals. In this study, the effects of sodium dodecyl benzene sulfonate（SDBS） and Tween 80 on the single and combined toxicities of Cd2＋ and nano-TiO2 to Escherichia coli（E. coli） were examined, and the underlying influence mechanism was further discussed. The results showed both SDBS and Tween 80 enhanced the toxicity of Cd2＋ to E. coli in varying degrees. The reaction of SDBS and Cd2＋ could increase the outer membrane permeability and the bioavailability of Cd, while Tween 80 itself could enhance the outer membrane permeability. The combined toxicity of nano-TiO2 and Cd2＋ to E. coli in absence of surfactant was antagonistic because of the adsorption of Cd2＋ to nanoTiO2 particles. However, in the presence of SDBS, both SDBS and nano-TiO2 influenced the toxicity of Cd2＋ , and also SDBS could adsorb to nano-TiO2 by binding to Cd2＋ . The combined toxicity was reduced at Cd2＋ lower than 4 mg/L and enhanced at Cd2＋ higher than 4 mg/L under multiple interactions. Tween 80 enhanced the combined toxicity of nano-TiO2 and Cd2＋ by increasing the outer membrane permeability. Our study firstly elucidated the effects of surfactants on the combined toxicity of nano-TiO2 and Cd2＋ to bacteria, and the underlying influencing mechanism was proposed.展开更多
Macroscopic SiO2 spheres with a homogeneous amine distribution were synthesized by a one-step emulsion based synthesis approach in a flow column reactor. The CO2 adsorption capacity of the nanostructured amine-functio...Macroscopic SiO2 spheres with a homogeneous amine distribution were synthesized by a one-step emulsion based synthesis approach in a flow column reactor. The CO2 adsorption capacity of the nanostructured amine-functionalized silica spheres was studied in absence and presence of H2O. The structural properties were adjusted by varying solvents and surfactants during the synthesis and, at constant amine loadings, were found to be the main factor for influencing the CO2 sorption capacities. Under water-free conditions CO2 is bound to the amino groups via the formation of carbamates, which require two neighboring amino groups to adsorb one CO2 molecule. At constant amine concentrations sorbents with lower surface area allow to establish a higher amine density on the surface, which enhances the CO2 uptake capacities under dry conditions. In presence of H2O the CO2 adsorption changes to 1：1 stoichiometry due to stabilization of carbamates by protonation of H2O and formation of further species such as bicarbonates, which should in principle double the adsorption capacities. Low concentrations of physisorbed H2O（0.3 mmol/g） did not impair the adsorption capacity of the adsorbents for CO2, while at higher water uptakes（0.6 and 1.1 mmol/g） the CO2 uptake is reduced, which could be attributed to capillary condensation of H2O or formation of bulky reaction products blocking inner pores and access to active sites.展开更多
Sodium silicate（NazSiO3） was used to improve the elution of super heavy oil from weathered soil on an ultrasound-enhanced elution system by the solution containing 0-6000 mg/L surfactant Triton X-100. The removal ex...Sodium silicate（NazSiO3） was used to improve the elution of super heavy oil from weathered soil on an ultrasound-enhanced elution system by the solution containing 0-6000 mg/L surfactant Triton X-100. The removal extent of three markers[C26-34 17a 25-norhopanes, C26-28triaromatic steroids（TAS）, and C27-29methyl triaromatic steroids（MTAS）] was monitored. The average elution percentages of C26-34 norhopanes, C26-28 TAS, and C27-29 MTAS by Triton X-100/Na2SiO3 solutions were increased by 11%-13%, 9%-11% and 8%-13% with increasing Triton X-100 concentrations from 150 mg/L to 6000 mg/L. All the concentrations of Triton X-100 improved the elu- tion of TAS homologs containing fewer carbon atoms, whereas high concentrations improved the elution of larger 17a 25-norhopane and MTAS species. Addition of Na2SiO3 produced a noticeable increase in elution, particularly for lower-weight species. Scanning electron microscope（SEM） images and energy spectroscopy data reveal that surfac- rant solution of 6000 mg/L Triton X-100 and 4000 mg/L Na2SiO3 produced the greatest improvement in the elution of super heavy oil aggregates encapsulating the soil surface and the emulsification of particle dispersions. That is to say mixed solutions of Triton X-100 and Na2SiO3 in combination with ultrasound are a potential means of removing super heavy oil from weathered soils.展开更多
Five new zwitterionic surfactants with long chain alkyl betaine structure incorporated with hydroxylpropyl group have been synthesized. Their structures were identified by elemental analysis, IR (HNMR)-H-1, and (CNMR)...Five new zwitterionic surfactants with long chain alkyl betaine structure incorporated with hydroxylpropyl group have been synthesized. Their structures were identified by elemental analysis, IR (HNMR)-H-1, and (CNMR)-C-13. Surface tension experiments showed that these surfactants have higher surface activity than those without hydroxypropyl group. The values of CMC and gamma(CMC) of these surfactants have been determined.展开更多
The SiO_2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO_2 particles can be ameliorated after adsorbing Y_2(CO_3)_3. In this paper, the effect of Y_2(CO_3)_3 and different s...The SiO_2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO_2 particles can be ameliorated after adsorbing Y_2(CO_3)_3. In this paper, the effect of Y_2(CO_3)_3 and different surfactants on the ER performance of the SiO_2 particle materials is investigated. The results show that anionic or cationic surfactants maybe enhance the ER activity of SiO_2 material, and nonionic surfactants cannot when surfactants are added during the process of the SiO_2 particle preparation, only the anionic surfactant, AES, can enhance markedly the ER performance of the material. The surface area, pore volume and pore diameter of the particles were measured. The effect of Y_2(CO_3)_3 and the surfactants on the microstructure of SiO_2 materials and the relationship between ER effect and the microstructure are described.展开更多
Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated poly...Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated polymer, which can only be dissolved in strong acids such as formic acid) and allows mixing the protonated polymers with other chloroform soluble conju- gated polymers for use in electronic devices. The protonating behavior of poly(pyridine-2,5-diyl) with two kinds of surfactants is different in some levels. Dodecybenzenesulfonic acid has higher protonating ability than camphorsulphonic acid.展开更多
Environment friendly and intelligent surfactants have attracted great attention in recent years.A bio-based CO_(2)responsive surfactant rosin acid dimaleimide choline(R-BMI-C)with an extremely rigid skeleton was prepa...Environment friendly and intelligent surfactants have attracted great attention in recent years.A bio-based CO_(2)responsive surfactant rosin acid dimaleimide choline(R-BMI-C)with an extremely rigid skeleton was prepared using rosin and choline as raw materials by Diels-Alder addition reaction and acid-base neutralization reactions.Its structure was confirmed by IR and^(1)H NMR spectra.The foams’properties of R-BMI-C could be adjusted by bubbling CO_(2)/N_(2)to change the structure of the surfactant.At pH 10.4,R-BMI-C forms an unstable foam with a half-life of 1.5 h.When the pH was reduced to 7.4 by bubbling CO_(2),R-BMI-C forms an extremely stable foam with a half-life of 336 h.The surfactant R-BMI-C changed from bola type to conventional type when bubbling CO_(2).And the internal aggregation structure of R-BMI-C aqueous solution changed from spherical micelles to laminar micelles according to the cryogenic-transmission electron microscope.We know that the lamellar structure tends to adsorb at the air/water interface or is trapped in the foam film,which slows down the foam coarsening and agglomeration process,resulting in a significant increase in foam stability.R-BMI-C could be used in oil extraction,fire-fighting and chemical decontamination due to its excellent foaming,stabilization and defoaming properties.展开更多
Electrolytic manganese metal residue(EMMR)harmless treatment has always lacked a low-cost and quick processing technology.In this study,surfactants,namely tetradecyl trimethylammonium chloride(TTC),sodium dodecyl benz...Electrolytic manganese metal residue(EMMR)harmless treatment has always lacked a low-cost and quick processing technology.In this study,surfactants,namely tetradecyl trimethylammonium chloride(TTC),sodium dodecyl benzene sulfonate(SDBS),sodium lignin sulfonate(SLS),and octadecyl trimethylammonium chloride(OTC),were used in the solidification of Mn^(2+)and removal of NH_(4)^(+)-N from EMMR.The Mn^(2+)and NH_(4)^(+)-N concentrations under different reaction conditions,Mn^(2+)solidification and NH_(4)^(+)-N removal mechanisms,and leaching behavior were studied.The results revealed that the surfactants could enhance the Mn^(2+)solidification and NH_(4)^(+)-N removal from EMMR,and the order of enhancement was as follows:TTC>SDBS>OTC>SLS.The NH_(4)^(+)-N and Mn^(2+)concentrations were 12.3 and 0.05 mg·L^(-1)with the use of 60.0 mg·kg^(-1)TTC under optimum conditions(solid–liquid ratio of 1.5:1,EMMR to BRM mass ratio of 100:8,temperature of 20℃,and reaction duration of 12 h),which met the integrated wastewater discharge standard(GB8978-1996).Mn^(2+)was mainly solidified as Mn(OH)_(2),MnOOH and MnSiO_(3),and NH_(4)^(+)-N in EMMR was mostly removed in the form of ammonia.The results of this study could provide a new idea for cost-effective EMMR harmless treatment.展开更多
A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfoni...A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.展开更多
文摘The ability of a novel nonionic CO2 -soluble surfactant to propagate foam in porous media was compared with that of a conventional anionic surfactant（aqueous soluble only）through core floods with Berea sandstone cores.Both simultaneous and alternating injections have been tested.The novel foam outperforms the conventional one with respect to faster foam propagation and higher desaturation rate.Furthermore,the novel injection strategy,CO2 continuous injection with dissolved CO2 -soluble surfactant,has been tested in the laboratory.Strong foam presented without delay.It is the first time the measured surfactant properties have been used to model foam transport on a field scale to extend our findings with the presence of gravity segregation.Different injection strategies have been tested under both constant rate and pressure constraints.It was showed that novel foam outperforms the conventional one in every scenario with much higher sweep efficiency and injectivity as well as more even pressure redistribution.Also,for this novel foam,it is not necessary that constant pressure injection is better,which has been concluded in previous literature for conventional foam.Furthermore,the novel injection strategy,CO2 continuous injection with dissolved CO2 -soluble surfactant,gave the best performance,which could lower the injection and water treatment cost.
基金supported by the National Natural Science Foundation of China(Nos.42077198 and 22206023)Liaoning Revitalization Talents Program(No.XLYC1907185)+1 种基金Liaoning Science and Technology Joint Project(No.2023-MSBA-109)the Fundamental Research Funds for the Central Universities(Nos.N2325019 and N2325034).
文摘The photochemical conversion of SO_(2) to sulfates on 4-(benzoyl)benzoic acid(4-BBA)was investigated deeply in the presence of anionic and cationic surfactants.The types of surfactants determined their effect behaviors,and cationic surfactants can significantly enhance the SO_(2) oxidation on 4-BBA under irradiation,as shown by larger SO_(2) uptake coefficients and sulfate production.Hydrophilic moieties in cationic surfactants have a greater enhancement effect on the photochemical conversion of SO_(2) to sulfates than the corresponding hydrophobic moieties.Cationic surfactants obviously increased the accumulation of H_(2)O on the surface,which was proved to be the main factor influencing the SO_(2) uptake and the sulfate formation on 4-BBA.SO_(2) lifetime and sulfate formation rate in the mixture system of photosensitive substances with surfactants were evaluated to be 2.25 days and 0.09μg/(m^(3)·h),respectively.
基金supported by the National Natural Science Foundation of China(52374063,52204065 and 52304098)the Shandong Provincial Natural Science Foundation(ZR2023ME049)+2 种基金the Fundamental Research Funds for the Central Universities(25CX07004A)State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(SDGZK2429)Shenzhen Science and Technology Program(JCYJ20220818095605012)。
文摘As one promising CO_(2)capture,utilization and storage(CCUS)technology,miscible CO_(2)-enhanced oil recovery(CO_(2)-EOR)significantly outperforms immiscible flooding in enhancing oil production and storing CO_(2).However,achieving CO_(2)miscible flooding is often hindered by the high minimum miscibility pressure of CO_(2)-oil system in many reservoirs.To address this issue,this study focuses on the mechanisms for enhancing CO_(2)-oil miscibility using different types of surfactants and their blends with ethanol.The effects of fatty alcohol polyoxyethylene ethers(EO),fatty alcohol polyoxypropylene ethers(PO),tributyl citrate(TC),and glyceryl triacetate(GT)on the CO_(2)-oil miscibility pressure are quantitatively analyzed,as well as their synergy with ethanol.Results demonstrated that all tested surfactant additives reduce the CO_(2)-oil miscibility pressu re.For ethe r-based surfactant additives,an increase in the degree of polymerization(CO_(2)-philic groups)weakens the effectiveness to reduce miscibility pressure.Oxygen atoms in the functional group contribute more significantly to miscibility enhancement than carbon atoms.Among ester surfactants,GT achieved the best reduction effect of miscibility pressure(11.82%at 3.0 wt%),attributed to its symmetrical short side-chain structure and ester groups.Furthermore,ethanol exhibited a significant improvement for surfactants in enhancing miscibility.Notably,the reduction of CO_(2)-oil miscibility pressure increases to 27.9%by 3.0 wt%GT blended with 5.0 wt%ethanol.These findings demonstrate that blending surfactants with ethanol is a feasible and effective strategy to facilitate miscible CO_(2)flooding.This study provides valuable insights and practical guidance for the field implementation of miscible CO_(2)-EOR.
基金financially supported by the "151" Talent Project of Zhejiang Province (2013)the Key Project of Zhejiang Provincial Science and Technology Program (No.2012C03003-4)the Program for Zhejiang Leading Team of S&T Innovation (No.2013TD07)
文摘In this study,a series of polyetherimide/SBA-15： 2-D hexagonal P6 mm,Santa Barbara USA（PEI/SBA-15） adsorbents modified by phosphoric ester based surfactants（including tri（2-ethylhexyl）phosphate（TEP）,bis（2-ethylhexyl） phosphate（BEP） and trimethyl phosphonoacetate（TMPA））were prepared for CO2 adsorption.Experimental results indicated that the addition of TEP and BEP had positive effects on CO2 adsorption capacity over PEI/SBA-15.In particular,the CO2 adsorption amount could be improved by around 20% for 45PEI-5TEP/SBA-15 compared to the additive-free adsorbent.This could be attributed to the decrease of CO2 diffusion resistance in the PEI bulk network due to the interactions between TEP and loaded PEI molecules,which was further confirmed by adsorption kinetics results.In addition,it was also found that the cyclic performance of the TEP-modified adsorbent was better than the surfactant-free one.This could be due to two main reasons,based on the results of in situ DRIFT and TG-DSC tests.First and more importantly,adsorbed CO2 species could be desorbed more rapidly over TEP-modified adsorbent during the thermal desorption process.Furthermore,the enhanced thermal stability after TEP addition ensured lower degradation of amine groups during adsorption/desorption cycles.
基金supported by the China National Petroleum Corporation (RIPED-2017-JS-87)
文摘In this study, we developed a strategy for using the Scoggins procedure in the synthesis of acetamidines as novel C02-triggered switchable surfactants via acetimidates by effectively tuning the chemical equilibrium. The as-synthesized N'-alkyl-N,Ndiethylacetamidines exhibit excellent CO_2/N_2 switchability and their bicarbonate salts have the ability to emulsify oil-water mixtures.
基金The National Natural Sciences Foundation of China(No. 40406003)
文摘The effect of Ca 2+ on the removal of Alexandrium sp. LC3 under HDTMAB stress was investigated. The results showed that the toxic effect of HDTMAB on Alexandrium sp. LC3 was significantly reduced in the presence of Ca 2+, especially under 4 mmol/L of Ca 2+. To understand the underlying mechanism, the SH group and MDA content of the cell membrane and membrane permeability were measured. It was found that the SH content of cell member increased, the MDA content and membrane permeability decreased when Alexandrium sp. was treated with Ca 2+ and HDTMAB complex, compared with using HDTMAB only. The data suggested that Ca 2+ might promote HDTMAB stress resistance of Alexandrium sp. LC3 by reducing the permeability and increasing the stability of cell membrane.
基金supported by the National Natural Science Foundation of China(No. 2167020782)
文摘Perfluorooctanoic acid(PFOA) or perfluorooctane sulphonate(PFOS) was one of the most prominent fluorosurfactants and applied widely in firefighting and daily chemical, etc. However, these surfactants have recently been identified as toxic and undegradability in the environment. Developing an efficient approach to environment-friendly fluorosurfactants is essential. A fluorocarbon branched chain strategy was adopted to develop/PFOS substitutes. A series of intermediates of novel branched fluorinated surfactants with CF_3 CF_2CF_2C(CF3)_2 group were synthesized from perfluoro-2-methyl-2-pentene. All the steps were mild, easy-handled and cheap. It is expected to be a very significant direction for the development of non-bioaccumulable alternatives of PFOA or PFOS.
基金Financial support from the Natural Science Foundation of Sichuan Province(2022NSFSC0030)National Natural Science Foundation of China(U1762218)is gratefully acknowledged.
文摘Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes.
基金supported by the National Natural Science Foundation of China(No.21607132)the Natural Science Foundation of Zhejiang Province(No.LQ14B070007)
文摘The combined ecological toxicity of TiO2 nanoparticles（nano-TiO2） and heavy metals has been paid more attention. As the common pollutants in water environment, surfactants could affect the properties of nanoparticles and heavy metals, and thus further influence the combined toxicity of nano-TiO2 and heavy metals. In this study, the effects of sodium dodecyl benzene sulfonate（SDBS） and Tween 80 on the single and combined toxicities of Cd2＋ and nano-TiO2 to Escherichia coli（E. coli） were examined, and the underlying influence mechanism was further discussed. The results showed both SDBS and Tween 80 enhanced the toxicity of Cd2＋ to E. coli in varying degrees. The reaction of SDBS and Cd2＋ could increase the outer membrane permeability and the bioavailability of Cd, while Tween 80 itself could enhance the outer membrane permeability. The combined toxicity of nano-TiO2 and Cd2＋ to E. coli in absence of surfactant was antagonistic because of the adsorption of Cd2＋ to nanoTiO2 particles. However, in the presence of SDBS, both SDBS and nano-TiO2 influenced the toxicity of Cd2＋ , and also SDBS could adsorb to nano-TiO2 by binding to Cd2＋ . The combined toxicity was reduced at Cd2＋ lower than 4 mg/L and enhanced at Cd2＋ higher than 4 mg/L under multiple interactions. Tween 80 enhanced the combined toxicity of nano-TiO2 and Cd2＋ by increasing the outer membrane permeability. Our study firstly elucidated the effects of surfactants on the combined toxicity of nano-TiO2 and Cd2＋ to bacteria, and the underlying influencing mechanism was proposed.
基金supported by the German Research Council(DFG)within the priority program(Schwerpunktprogramm),“Poröse Medien mit definierter Porenstruktur in der Verfahrenstechnik–Modellierung,Anwendngen,Synthese”(SPP 1570)under the projects LE 1187/10 and SP 648/4the framework of the DFG Excellence Initiative the Cluster of Excellence“Engineering of Advanced Materials”(DFG EXC 415)funding via the DFG research training group GRK 1896
文摘Macroscopic SiO2 spheres with a homogeneous amine distribution were synthesized by a one-step emulsion based synthesis approach in a flow column reactor. The CO2 adsorption capacity of the nanostructured amine-functionalized silica spheres was studied in absence and presence of H2O. The structural properties were adjusted by varying solvents and surfactants during the synthesis and, at constant amine loadings, were found to be the main factor for influencing the CO2 sorption capacities. Under water-free conditions CO2 is bound to the amino groups via the formation of carbamates, which require two neighboring amino groups to adsorb one CO2 molecule. At constant amine concentrations sorbents with lower surface area allow to establish a higher amine density on the surface, which enhances the CO2 uptake capacities under dry conditions. In presence of H2O the CO2 adsorption changes to 1：1 stoichiometry due to stabilization of carbamates by protonation of H2O and formation of further species such as bicarbonates, which should in principle double the adsorption capacities. Low concentrations of physisorbed H2O（0.3 mmol/g） did not impair the adsorption capacity of the adsorbents for CO2, while at higher water uptakes（0.6 and 1.1 mmol/g） the CO2 uptake is reduced, which could be attributed to capillary condensation of H2O or formation of bulky reaction products blocking inner pores and access to active sites.
基金Supported by the National Natural Science Foundation of China(Nos.51179001 and 40772146)the Fok Ying Tung Education Foundation,China(No.122041)
文摘Sodium silicate（NazSiO3） was used to improve the elution of super heavy oil from weathered soil on an ultrasound-enhanced elution system by the solution containing 0-6000 mg/L surfactant Triton X-100. The removal extent of three markers[C26-34 17a 25-norhopanes, C26-28triaromatic steroids（TAS）, and C27-29methyl triaromatic steroids（MTAS）] was monitored. The average elution percentages of C26-34 norhopanes, C26-28 TAS, and C27-29 MTAS by Triton X-100/Na2SiO3 solutions were increased by 11%-13%, 9%-11% and 8%-13% with increasing Triton X-100 concentrations from 150 mg/L to 6000 mg/L. All the concentrations of Triton X-100 improved the elu- tion of TAS homologs containing fewer carbon atoms, whereas high concentrations improved the elution of larger 17a 25-norhopane and MTAS species. Addition of Na2SiO3 produced a noticeable increase in elution, particularly for lower-weight species. Scanning electron microscope（SEM） images and energy spectroscopy data reveal that surfac- rant solution of 6000 mg/L Triton X-100 and 4000 mg/L Na2SiO3 produced the greatest improvement in the elution of super heavy oil aggregates encapsulating the soil surface and the emulsification of particle dispersions. That is to say mixed solutions of Triton X-100 and Na2SiO3 in combination with ultrasound are a potential means of removing super heavy oil from weathered soils.
文摘Five new zwitterionic surfactants with long chain alkyl betaine structure incorporated with hydroxylpropyl group have been synthesized. Their structures were identified by elemental analysis, IR (HNMR)-H-1, and (CNMR)-C-13. Surface tension experiments showed that these surfactants have higher surface activity than those without hydroxypropyl group. The values of CMC and gamma(CMC) of these surfactants have been determined.
文摘The SiO_2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO_2 particles can be ameliorated after adsorbing Y_2(CO_3)_3. In this paper, the effect of Y_2(CO_3)_3 and different surfactants on the ER performance of the SiO_2 particle materials is investigated. The results show that anionic or cationic surfactants maybe enhance the ER activity of SiO_2 material, and nonionic surfactants cannot when surfactants are added during the process of the SiO_2 particle preparation, only the anionic surfactant, AES, can enhance markedly the ER performance of the material. The surface area, pore volume and pore diameter of the particles were measured. The effect of Y_2(CO_3)_3 and the surfactants on the microstructure of SiO_2 materials and the relationship between ER effect and the microstructure are described.
文摘Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated polymer, which can only be dissolved in strong acids such as formic acid) and allows mixing the protonated polymers with other chloroform soluble conju- gated polymers for use in electronic devices. The protonating behavior of poly(pyridine-2,5-diyl) with two kinds of surfactants is different in some levels. Dodecybenzenesulfonic acid has higher protonating ability than camphorsulphonic acid.
基金supported by the National Natural Science Foundation of China(32171734)the Scientific Research Funds of Huaqiao University(20BS201).
文摘Environment friendly and intelligent surfactants have attracted great attention in recent years.A bio-based CO_(2)responsive surfactant rosin acid dimaleimide choline(R-BMI-C)with an extremely rigid skeleton was prepared using rosin and choline as raw materials by Diels-Alder addition reaction and acid-base neutralization reactions.Its structure was confirmed by IR and^(1)H NMR spectra.The foams’properties of R-BMI-C could be adjusted by bubbling CO_(2)/N_(2)to change the structure of the surfactant.At pH 10.4,R-BMI-C forms an unstable foam with a half-life of 1.5 h.When the pH was reduced to 7.4 by bubbling CO_(2),R-BMI-C forms an extremely stable foam with a half-life of 336 h.The surfactant R-BMI-C changed from bola type to conventional type when bubbling CO_(2).And the internal aggregation structure of R-BMI-C aqueous solution changed from spherical micelles to laminar micelles according to the cryogenic-transmission electron microscope.We know that the lamellar structure tends to adsorb at the air/water interface or is trapped in the foam film,which slows down the foam coarsening and agglomeration process,resulting in a significant increase in foam stability.R-BMI-C could be used in oil extraction,fire-fighting and chemical decontamination due to its excellent foaming,stabilization and defoaming properties.
基金supported by National Natural Science Foundation of China(52174386,21806132)the National Key Research and Development Program of China(2018YFC1903500)+1 种基金the Science and Technology Plan Project of Sichuan Province(2021YFH0058)the Key Research and Development Program of Guangxi Province(AB18126088)。
文摘Electrolytic manganese metal residue(EMMR)harmless treatment has always lacked a low-cost and quick processing technology.In this study,surfactants,namely tetradecyl trimethylammonium chloride(TTC),sodium dodecyl benzene sulfonate(SDBS),sodium lignin sulfonate(SLS),and octadecyl trimethylammonium chloride(OTC),were used in the solidification of Mn^(2+)and removal of NH_(4)^(+)-N from EMMR.The Mn^(2+)and NH_(4)^(+)-N concentrations under different reaction conditions,Mn^(2+)solidification and NH_(4)^(+)-N removal mechanisms,and leaching behavior were studied.The results revealed that the surfactants could enhance the Mn^(2+)solidification and NH_(4)^(+)-N removal from EMMR,and the order of enhancement was as follows:TTC>SDBS>OTC>SLS.The NH_(4)^(+)-N and Mn^(2+)concentrations were 12.3 and 0.05 mg·L^(-1)with the use of 60.0 mg·kg^(-1)TTC under optimum conditions(solid–liquid ratio of 1.5:1,EMMR to BRM mass ratio of 100:8,temperature of 20℃,and reaction duration of 12 h),which met the integrated wastewater discharge standard(GB8978-1996).Mn^(2+)was mainly solidified as Mn(OH)_(2),MnOOH and MnSiO_(3),and NH_(4)^(+)-N in EMMR was mostly removed in the form of ammonia.The results of this study could provide a new idea for cost-effective EMMR harmless treatment.
文摘A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.
