In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy sy...In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy systems(IES)is becoming increasingly obvious.In this case,to promote the low-carbon operation of IES and renewable energy consumption,and to improve the IES anti-interference ability,this paper proposes an IES scheduling strategy that considers CCS-P2G and concentrating solar power(CSP)station.Firstly,CSP station,gas hydrogen doping mode and variable hydrogen doping ratio mode are applied to IES,and combined with CCS-P2G coupling model,the IES low-carbon economic dispatch model is established.Secondly,the stepped carbon trading mechanism is applied,and the sensitivity analysis of IES carbon trading is carried out.Finally,an IES optimal scheduling strategy based on fuzzy opportunity constraints and an IES risk assessment strategy based on CVaR theory are established.The simulation shows that the gas-hydrogen doping model proposed in this paper reduces the operating cost and carbon emission of IES by 1.32%and 7.17%,and improves the carbon benefit by 5.73%;variable hydrogen doping ratio model reduces the operating cost and carbon emission of IES by 3.75%and 1.70%,respectively;CSP stations reduce 19.64%and 38.52%of the operating costs of IES and 1.03%and 1.80%of the carbon emissions of IES respectively compared to equal-capacity photovoltaic and wind turbines;the baseline price of carbon trading of IES and its rate of change jointly affect the carbon emissions of IES;evaluating the anti-interference capability of IES through trapezoidal fuzzy number and weighting coefficients,enabling IES to guarantee operation at the lowest cost.展开更多
Sweet cherries ( Prunus avium L. cv. Napoleon) were stored in controlled atmospheres (CA) of high O(2) (70% O(2) + 0% CO(2)) or high CO(2) (5% O(2) + 10% CO(2)), in modified atmosphere package (MAP, (13% - 18%) O(2) +...Sweet cherries ( Prunus avium L. cv. Napoleon) were stored in controlled atmospheres (CA) of high O(2) (70% O(2) + 0% CO(2)) or high CO(2) (5% O(2) + 10% CO(2)), in modified atmosphere package (MAP, (13% - 18%) O(2) + (2% -4%) CO(2)) and in air (control) at 1 degreesC to investigate the effects of different O(2) and CO(2) concentrations on physiological properties, quality and storability of the fruits during storage. The results indicated that compared with other treatments, CA with high O(2) concentration decreased fruit decay and ethanol content, but increased the accumulation of malondialdehyde (MDA) and stimulated browning. CA with high CO(2) concentration inhibited polyphenol oxidase (PPO) activity, reduced MDA content, maintained vitamin C content and firmness, decreased fruit decay and browning. Soluble solids contents (SSC) were not significantly affected by different atmosphere treatments. 'Napoleon' fruits stored in 5% O(2) + 10% CO(2) for as long as 80 d were of good quality, but only 40, 20 and 30 d stored in MAP, 70% O(2) + 0% CO(2) and air, re-spectively.展开更多
The effects of CO 2 concentration on the morphological and anatomical characters of soybean (Glycine max) leaf were investigated by means of light microscopy and SEM.It was noticed that exomorphology did not show dra...The effects of CO 2 concentration on the morphological and anatomical characters of soybean (Glycine max) leaf were investigated by means of light microscopy and SEM.It was noticed that exomorphology did not show dramatic change,while stomatal density decreased with increasing CO 2 concentration.Under SEM,no epicuticular wax was observed on both abaxial and adaxial sides of the control group as well as on adaxial side of the treatment group.However,leaf surface of abaxial side was noticed to be densely covered with microasterisk epicuticular wax when they were exposed to CO 2 enriched environment.The epicuticular wax deposition was present in equal abundance on both stomatal and nonstomatal areas.Furthermore,leaf thickness increased significantly due largely to the origin of an extra layer of palisade in the treatment group.The results confirmed that CO 2 enrichment might enhance cell division and induce greater quantity of epicuticular wax.展开更多
Wheat ( Triticum aestivum L.) plants were grown under ambient and doubled_CO 2(plus 350 μL/L) concentration in cylindrical open_top chamber to examine their effects on the ultrastructure, supramolecular architect...Wheat ( Triticum aestivum L.) plants were grown under ambient and doubled_CO 2(plus 350 μL/L) concentration in cylindrical open_top chamber to examine their effects on the ultrastructure, supramolecular architecture, absorption spectrum and low temperature (77 K) fluorescence emission spectrum of the chloroplasts from wheat leaves. The results were briefly summarized as follows: (1) The wheat leaves possessed normally developed chloroplasts with intact grana and stroma thylakoid membranes; The grana intertwined with stroma thylakoid membranes and increased slightly in stacking degree and the width of granum, in spite of more accumulated starch grains within the chloroplasts than those in control; (2) The particle density in the stacked region of the endoplasmic fracture face (EFs) and protoplasmic fracture face (PFs) and in the unstacked region the endoplasmic fracture face (EFu) and the protoplasmic fracture face (PFu) was significantly higher than that of control. Furthermore, in some cases many more particles on EFs faces of thylakoid membranes appeared as a paracrystalline particle array; (3) The variations in the structure of chloroplasts were consistent with the absorption spectra and the low temperature (77 K) fluorescence emission spectra of the chloroplasts developed under the doubled_CO 2 concentration. Results indicate that the capability of light energy absorption of chloroplasts and regulative capability of excitation energy distribution between PSⅡ and PSⅠ were raised by doubled_CO 2 concentration. This is very favorable for final productivity of wheat.展开更多
An experiments were carried out with treatments differing in nitrogen supply （0, 5 and 15 g N/m^2） and CO2 levels （350 and 700 μmol/mol） using OTC （open top chamber） equipment to investigate the biomass of Cala...An experiments were carried out with treatments differing in nitrogen supply （0, 5 and 15 g N/m^2） and CO2 levels （350 and 700 μmol/mol） using OTC （open top chamber） equipment to investigate the biomass of Calamagrostis angustifolia and soil active carbon contents after two years. The results showed that elevated CO2 concentration increased the biomass of C. angustifolia and the magnitude of response varied with each growth period. Elevated CO2 concentration has increased aboveground biomass by 16.7% and 17.6% during the jointing and heading periods and only 3.5% and 9.4% during dough and maturity periods. The increases in belowground biomass due to CO2 elevation was 26.5%, 34.0% and 28.7% during the heading, dough and maturity periods, respectively. The responses of biomass to enhanced CO2 concentrations are differed in N levels. Both the increase of aboveground biomass and belowground biomass were greater under high level of N supply （15 g N/m^2）. Elevated CO2 concentration also increased the allocation of biomass and carbon in root. Under elevated CO2 concentration, the average values of active carbon tended to increase. The increases of soil active soil contents followed the sequence of microbial biomass carbon （10.6%） 〉 dissolved organic carbon （7.5%） 〉 labile oxidable carbon （6.6%） 〉 carbohydrate carbon （4.1%）. Stepwise regressions indicated there were significant correlations between the soil active carbon contents and plant biomass. Particularly, microbial biomass carbon, labile oxidable carbon and carbohydrate carbon were found to be correlated with belowground biomass, while dissolved organic carbon has correlation with aboveground biomass. Therefore, increased biomass was regarded as the main driving force for the increase in soil active organic carbon under elevated CO2 concentration.展开更多
The objectives of this study were to investigate the effect of higher CO2 concentrations （500 and 700 μmol mol^-1） in atmosphere on total soil respiration and the contribution of root respiration to total soil resp...The objectives of this study were to investigate the effect of higher CO2 concentrations （500 and 700 μmol mol^-1） in atmosphere on total soil respiration and the contribution of root respiration to total soil respiration during seedling growth of Pinus sylvestris vat. sylvestriformis. During the four growing seasons （May-October） from 1999 to 2003, the seedlings were exposed to elevated concentrations of CO2 in open-top chambers. The total soil respiration and contribution of root respiration were measured using an LI-6400-09 soil CO2 flux chamber on June 15 and October 8, 2003. To separate root respiration from total soil respiration, three PVC cylinders were inserted approximately 30 cm deep into the soil in each chamber. There were marked diurnal changes in air and soil temperatures on June 15. Both the total soil respiration and the soil respiration without roots showed a strong diurnal pattern, increasing from before sunrise to about 14：00 in the afternoon and then decreasing before the next sunrise. No increase in the mean total soil respiration and mean soil respiration with roots severed was observed under the elevated CO2 treatments on June 15, 2003, as compared to the open field and control chamber with ambient CO2. However, on October 8, 2003, the total soil respiration and soil respiration with roots severed in the open field were lower than those in the control and elevated CO2 chambers. The mean contribution of root respiration measured on June 15, 2003, ranged from 8.3% to 30.5% and on October 8, 2003, from 20.6% to 48.6%.展开更多
A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0....A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0.1 MPa to 0.4 MPa, and the maximum NH3 mass fraction up to 0.4 are provided. This model agrees with experimental data well (average relative error < 1%) and is useful for analysis of industrial urea production.展开更多
The CO2reforming of CH4is studied over MgO‐promoted Ni catalysts,which were supported on alumina prepared from hydrotalcite.This presents an improved stability compared with non‐promoted catalysts.The introduction o...The CO2reforming of CH4is studied over MgO‐promoted Ni catalysts,which were supported on alumina prepared from hydrotalcite.This presents an improved stability compared with non‐promoted catalysts.The introduction of the MgO promoter was achieved through the‘‘memory effect’’of the Ni‐Al hydrotalcite structure,and ICP‐MS confirmed that only0.42wt.%of Mg2+ions were added into the Ni‐Mg/Al catalyst.Although no differences in the Ni particle size and basicity strength were observed,the Ni‐Mg/Al catalyst showed a higher catalytic stability than the Ni/Al catalyst.A series of surface reaction experiments were used and showed that the addition of a MgO promoter with low concentration can promote CO2dissociation to form active surface oxygen arising from the formation of the Ni‐MgO interface sites.Therefore,the carbon‐resistance promotion by nature was suggested to contribute to an oxidative environment around Ni particles,which would increase the conversion of carbon residues from CH4cracking to yield CO on the Ni metal surface.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
The annual series of δ13C were measured in tree rings of three Cryptomeria fortunei disks （OF-1, OF-2, and OF- 3） collected from West Tianmu Mountain, Zhejiang Province, China, according to cross-dating tree ring a...The annual series of δ13C were measured in tree rings of three Cryptomeria fortunei disks （OF-1, OF-2, and OF- 3） collected from West Tianmu Mountain, Zhejiang Province, China, according to cross-dating tree ring ages. There was no obvious decreasing trend of the δ13C annual time series of CF-2 before 1835. However, from 1835 to 1982 the three tree ring δ13C annual series exhibited similar decreasing trends that were significantly （P ≤ 0.001） correlated. The distribution characteristics of a scatter diagram between estimated δ13C series of CF-2 from modeling and the atmospheric CO2 concentration extracted from the Law Dome ice core from 1840 to 1978 were analyzed and a curvilinear regression equation for reconstructing atmospheric CO2 concentration was established with R2 = 0.98. Also, a test of independent samples indicated that between 1685 and 1839 the reconstructed atmospheric CO2 concentration .using the δ13C series of CF-2 had a close relationship with the Law Dome and Siple ice cores, with a standard deviation of 1.98. The general increasing trend of the reconstructed atmospheric CO2 concentration closely reflected the 10ng-term variation of atmospheric CO2 concentration recorded both before and after the Industrial Revolution. Between 1685 and 1840 the evaluated atmospheric CO2 concentration was stable, but after 1840 it exhibited a rapid increase. Given a longer δ13C annual time series of tree rings, it was feasible to rebuild a representative time series to describe the atmospheric CO2 concentration for an earlier period and for years that were not in the ice core record.展开更多
The regional air quality modeling system RAMS-CMAQ(Regional Atmospheric Modeling System and Models-3 Community Multi-scale Air Quality) was developed by incorporating a vegetation photosynthesis and respiration module...The regional air quality modeling system RAMS-CMAQ(Regional Atmospheric Modeling System and Models-3 Community Multi-scale Air Quality) was developed by incorporating a vegetation photosynthesis and respiration module(VPRM) and used to simulate temporal-spatial variations in atmospheric CO2 concentrations in East Asia,with prescribed surface CO2 fluxes(i.e.,fossil fuel emission,biomass burning,sea-air CO2 exchange,and terrestrial biosphere CO2 flux).Comparison of modeled CO2 mixing ratios with eight ground-based in-situ measurements demonstrated that the model was able to capture most observed CO2 temporal-spatial features.Simulated CO2 concentrations were generally in good agreement with observed concentrations.Results indicated that the accumulated impacts of anthropogenic emissions contributed more to increased CO2 concentrations in urban regions relative to remote locations.Moreover,RAMS-CMAQ analysis demonstrates that surface CO2 concentrations in East Asia are strongly influenced by terrestrial ecosystems.展开更多
Horizontal and vertical variations of daily average CO 2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000 The primary purpose was to study spatial distr...Horizontal and vertical variations of daily average CO 2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000 The primary purpose was to study spatial distribution characteristics of CO 2 concentration on the four levels of height(0 1 m, 0 6 m, 1 2 m and 2 m) and compare the differences of CO 2 concentration under different land covers. Results showed that daily average CO 2 concentration above wetland surface in Xianghai National Natural Reserve was lower than that above other wetlands in northeast China as well as the worldwide average, suggesting that Xianghai wetland absorbed CO 2 in August and acted as “sink” of CO 2 The horizontal variations on the four levels of height along the latitude were distinct, and had the changing tendency of “decreasing after increasing” with the increase of height. The areas with obvious variations were consistent on different levels of height, and those with the highest variations appeared above surface of shore, sloping field, Typha wetland and Phragmites wetland; the vertical variations were greatly different, with the higher variations in Phragmites wetland and Typha wetland, and the lands near the shore and the sloping field with the lower variations. Spatial variations of daily average CO 2 concentrations above wetland surface were affected by surface qualities and land covers.展开更多
Hoagland＇s solution was used as water culture medium to study the effect of CO2 concentration on nitrate metabolism of wheat under natural light and light-shaded conditions. NO3^-N, NH4^＋-N, nitrate reductase activi...Hoagland＇s solution was used as water culture medium to study the effect of CO2 concentration on nitrate metabolism of wheat under natural light and light-shaded conditions. NO3^-N, NH4^＋-N, nitrate reductase activity, total uptake N by wheat plants during solution cultural period and total N in plants were determined for comprehensive evaluation of the effect. Results showed that under both natural light and light-shaded conditions, addition of CO2 increased NO3^-N uptake and its assimilative capabilities by plants. However, there were some difference between shoots and roots. With increase of CO2 concentration, the concentration of NO3^-N and NH4^＋-N as well as nitrate reductase activity were all decreased for shoots while the difference was not so distinct in roots, and the nitrate reductase activity was not decreased, but increased. Since NO3^-N uptake by plants from the solution and the total N in plants were much higher by CO2 addition, it may be concluded that addition of CO2 has resulted in rise of nitrate absorption, assimilation and metabolism of wheat.展开更多
Impacts of climatic change on agriculture and adaptation are of key concern of scientific research. However, vast uncertainties exist among global climates model output, emission scenarios, scale transformation and cr...Impacts of climatic change on agriculture and adaptation are of key concern of scientific research. However, vast uncertainties exist among global climates model output, emission scenarios, scale transformation and crop model parameterization. In order to reduce these uncertainties, we integrate output results of four IPCC emission scenarios of A1 FI, A2, B1 and B2, and five global climatic patterns of HadCM3, PCM, CGCM2, CSIRO2 and ECHAM4 in this study. Based on 20 databases of future climatic change scenarios from the Climatic Research Unit （CRU） , the scenario data of the climatic daily median values are generated on research sites with the global mean temperature increase of 1℃（GMT＋ID）, 2℃（GMT＋2D） and 3℃（GMT＋3D）. The impact of CO2 fertilization effect on wheat biomass for GMT＋I D, GMT＋2D and GMT＋3D in China＇s wheat-producing areas is studied in the process model, CERES-Wheat and probabilistic forecasting method. The research results show the CO2 fertilization effect can compensate reduction of wheat biomass with warming temperature in a strong compensating effect. Under the CO2 fertilization effect, the rain-fed and irrigated wheat biomasses increase respectively, and the increment of biomass goes up with temperature rising. The rain-fed wheat biomass increase is greater than the irrigated wheat biomass. Without consideration of CO2 fertilization effect, both irrigated and rain-fed wheat biomasses reduce, and there is a higher probability for the irrigated wheat biomass than that of the rain-fed wheat biomass.展开更多
Successive filtration and comparison show that the stratosphere air temperature in 10 hPa-layer of the Northern Hemisphere （NH） in July continuously increases,which is associated to the increases in greenhouse gases...Successive filtration and comparison show that the stratosphere air temperature in 10 hPa-layer of the Northern Hemisphere （NH） in July continuously increases,which is associated to the increases in greenhouse gases mostly CO2,volcanic activities,and solar activity,demonstrating the follows.（a） The increase in CO2 concentration is largely consistent with that of the stratosphere air temperature in 10 hPa-layer of the NH in July.However,the increase in the air temperature is not in a linear pattern,during which several cooling events interrupt.The cooling events between late 1960s and late 1970s are remarkable ones and so is the one before mid 1990s.Analysis shows that these events are induced by volcanic activities and solar activity.（b） The CO2-free variation in the stratosphere air temperature in 10 hPa-layer of the NH is consistent with that of the solar magnetic index.The wave crests and wave troughs of the two curves are consistent in phase,and the curve of solar magnetic index leads the other slightly.In other words,when the solar magnetic pole is southward,a warming in the NH stratosphere corresponds;and on the contrary,the northward solar magnetic pole corresponds to a cooling event.The variation in solar magnetic polarity strongly impacts the variation in the stratosphere temperature.展开更多
There is limited information available on CO2 concentration and flux over marsh. The objective of this work was to characterize CO2 concentration and flux within and above marsh plant (Cares lasiocarpa Ehrh. and C. ps...There is limited information available on CO2 concentration and flux over marsh. The objective of this work was to characterize CO2 concentration and flux within and above marsh plant (Cares lasiocarpa Ehrh. and C. pseudoucuaica F. Schm) canopy at heights 0. 5, 1. 0 and 1. 5 m.CO2 concentration was measured sequentially every 3 bars by using an infrared gas analyzer. Soil and air temperature, wind speed, net radiation and soil heat flux were also measured simultaneously. Extremely drily minimum and maximum CO2 concentration rangal from 250 to 754 μmd/mol for the 4-year work. The typical minimum and maximum values ranged from 314 to 464 μmol/mol at the height of marsh plant (about 0. 5 m) during the fruiting perioed and mature date. The seasonal changes in CO2 concentration show that the minimum CO2 concentration occurred in the fruiting period and mature date, and both of their minimum values were 314 μmol/mol. This illustrates that CO2 consumed by photosynthesis was stable during the period. The flux of CO2 can be thought as a turbulent diffusion phenomenon. By micrometeorological methods, the diurnal CO2 fluxes were measured in the flowering peried, fruiting period, early mature date, late mature date and yellow-ripe stage. Their values were -0. 18, 38. 15,24. 13, 10. 9 and 4. 91 μmol/mol respectively.展开更多
The global rise in CO_(2)concentration is having a profound impact on the structure and function of aquatic ecosystems.However,little information is available on the responses of odorproducing cyanobacteria to the inc...The global rise in CO_(2)concentration is having a profound impact on the structure and function of aquatic ecosystems.However,little information is available on the responses of odorproducing cyanobacteria to the increase in CO_(2)concentration.In this study,the effects of different CO_(2)concentrations on 2-methylisoborneol(MIB)-producing Pseudanabaena and non-2-MIB-producing Pseudanabaena under monoculture and co-culture conditions were investigated.Results show that the specific growth rate of Pseudanabaena gradually increased with the rise in CO_(2)concentration,and for the 2-MIB-producing strain,this increase was significantly higher than the non-2-MIB-producing strain.Under co-culture conditions,the proportion of non-2-MIB-producing Pseudanabaena was significantly higher than that of 2-MIB-producing Pseudanabaena,suggesting a superior competitive ability of non-2-MIB-producing Pseudanabaena over 2-MIB-producing Pseudanabaena.Under monoculture conditions,the total 2-MIB production at the 300-μg/g CO_(2)concentration was significantly higher than that at 600-and 1200-μg/g CO_(2)concentrations.The 2-MIB concentration produced by Pseudanabaena decreased with the increasing in CO_(2)concentration.Therefore,we believe that with the future increase in CO_(2)concentration,2-MIB concentration would be decreased and so would the risk of 2-MIB outbreaks.展开更多
Electrochemical nitrate(NO_(3)^(-))reduction reaction(eNO_(3)RR)to ammonia(NH3)provides a promising route for both water conservation and green ammonia synthesis.Although various catalysts were designed for the eNO_(3...Electrochemical nitrate(NO_(3)^(-))reduction reaction(eNO_(3)RR)to ammonia(NH3)provides a promising route for both water conservation and green ammonia synthesis.Although various catalysts were designed for the eNO_(3)RR and great achievements have been achieved,it is still a challenge to realize selective eNO_(3)RR to NH3at low concentration for the competing hydrogen evolution reaction(HER)and poor mass transfer of NO_(3)^(-).Herein,we designed a tandem catalyst of Pd nanoparticle loaded Cu_(2)O hierarchical nanofiber(Pd-Cu_(2)O)to improve eNO_(3)RR performance at low nitrate concentration.The Pd-Cu_(2)O shows a faraday efficiency(FE)of 95.80%and an ammonia selectivity of 97.34%at a comparatively low applied potential of-0.15 V versus RHE with low concentration.Besides,it exhibits excellent nitrate removal effects,the residual concentration of nitrate-N was only 7.22 ppm at-0.15 V.Electrochemical characterizations indicate that the abundant secondary heterojunction structures and the tandem effects of Pd-Cu_(2)O synergistic ally accelerate the transfer and conversion of NO_(3)^(-)and improve the dynamic of eNO_(3)RR at low concentration.Furthermore,the operando electrochemical impedance spectroscopy(EIS)and density functional theory(DFT)calculations suggested the tandem effects of Pd-Cu_(2)O improved the adsorption of NO_(3)^(-)and*H and thus promoted the dynamics of eNO_(3)RR at low concentration.The findings highlight the tandem effects of Pd-Cu_(2)O and provide an effective strategy for designing electrocatalysts that can be applied to low concentration and low applied potential conditions.展开更多
The removal and recovery of low-concentration phosphates from water have become crucial due to the dual challenges of eutrophication and the phosphorus crisis.Herein,we engineered a highly efficient and recyclable pho...The removal and recovery of low-concentration phosphates from water have become crucial due to the dual challenges of eutrophication and the phosphorus crisis.Herein,we engineered a highly efficient and recyclable phosphate trapping agent of La_(2-x)CexO_(2)CO_(3) solid solution.The incorporation of Ce enhances the surface area and surface potential of La_(2-x)CexO_(2)CO_(3),providing abundant adsorption sites for phosphate.Surprisingly,we found that adjusting the Ce proportion affects the carbonate content,thereby influencing the anion-exchange capacity between carbonate and phosphate.Specifically,at 3% Ce content(3%-CeL),the carbonate ratio is maximized,resulting in an optimal sorption capacity(196.4mg P/g)and a rapid removal rate(under 40min)for phosphate,unaffected by interfering ions.Remarkably,3%-CeL achieved nearly 100%phosphate removal efficiency in diverse water samples from sewage treatment plants,rivers,reservoirs,and groundwater.After five adsorption-desorption cycles,the phosphate removal and recovery efficiency of 3%-CeL remained above 90%.Mechanistic studies revealed that 3%Ce content yielded the highest proportion of Ce^(4+)/Ce^(3+),enabling greater carbonate binding for anion-exchange.This study proposes a high-performance phosphate trapping agentwith broad applicability for treating actual waters and provides a new perspective on enhancing low-concentration phosphate removal in La-based materials through manipulating Ce ratio and valence.展开更多
Atmospheric CO2 concentration （CC） near land surface and meteorological variables have been measured at four sites, named Yeniugou （alpine meadow and permafrost）, Xishui （mountainous forest）, Linze （oasis edge...Atmospheric CO2 concentration （CC） near land surface and meteorological variables have been measured at four sites, named Yeniugou （alpine meadow and permafrost）, Xishui （mountainous forest）, Linze （oasis edge） and Ejina （lower desert）, respectively, in Heihe River Basin, northwest China. The results showed that, the half hourly CC at night was larger than in daytime, and the daily averaged CC was the largest in winter. The averaged CC of 932 d at the Linze was about 418 ppm, was about 366 ppm in the 762 d at the Ejina. In the same period from September 23 to November 9, 2004, the averaged CC was about 625,334, 436 and 353 ppm, at Yeniugou, Xishui, Linze and Ejina, respectively. The linear relationship between daily averaged CC and air temperature T was negative, between CC and relative humidity （RH） was positive. The linear CC-atmospheric pressure （A P） relationship was negative at the Linze and Yeniugou, was positive at the Ejina. The relationship between CC and global radiation R was exponent, and soil temperature Ts was negative linear, and soil water content was complex. The correlation between CC and wind speed was not existent. Using meteorological variables together to simulate CC, could give good results.展开更多
Rapid increases in Carbon dioxide(CO_(2))levels could trigger unpredictable climate change.The assessment of spatiotempor-al variation and influencing factors of CO_(2) concentration are helpful in understanding the s...Rapid increases in Carbon dioxide(CO_(2))levels could trigger unpredictable climate change.The assessment of spatiotempor-al variation and influencing factors of CO_(2) concentration are helpful in understanding the source/sink balance and supporting the formu-lation of climate policy.In this study,Greenhouse Gases Observing Satellite(GOSAT)data were used to explore the variability of CO_(2) concentrations in China from 2009 to 2020.Meteorological parameters,vegetation cover,and anthropogenic activities were combined to explain the increase in CO_(2) concentration,using pixel-based correlations and Covariance Based Structural Equation Modeling(CB-SEM)analysis.The results showed that the influence of vertical CO_(2) transport diminished with altitude,with a distinct inter-annual in-crease in CO_(2) concentrations at 17 vertical levels.Spatially,the highest values were observed in East China,whereas the lowest were observed in Northwest China.There were significant seasonal variations in CO_(2) concentration,with maximum and minimum values in spring(April)and summer(August),respectively.According to the pixel-based correlation analysis,the near-surface CO_(2) concentration was positively correlated with population(r=0.99,P<0.001),Leaf Area Index(LAI,r=0.95,P<0.001),emissions(r=0.91,P<0.001),temperature(r=0.60,P<0.05),precipitation(r=0.34,P>0.05),soil water(r=0.29,P>0.05),nightlight(r=0.28,P>0.05);and negatively correlated with wind speed(r=−0.58,P<0.05).CB-SEM analysis revealed that LAI was the most important con-trolling factor explaining CO_(2) concentration variation(total effect of 0.66),followed by emissions(0.58),temperature(0.45),precipita-tion(0.30),wind speed(−0.28),and soil water(−0.07).The model explained 93% of the increase in CO_(2) concentration.Our results provide crucial information on the patterns of CO_(2) concentrations and their driving mechanisms,which are particularly significant in the context of climate change.展开更多
基金State Grid Gansu Electric Power Company Science and Technology Program(Grant No.W24FZ2730008)National Natural Science Foundation of China(Grant No.51767017).
文摘In the background of the low-carbon transformation of the energy structure,the problem of operational uncertainty caused by the high proportion of renewable energy sources and diverse loads in the integrated energy systems(IES)is becoming increasingly obvious.In this case,to promote the low-carbon operation of IES and renewable energy consumption,and to improve the IES anti-interference ability,this paper proposes an IES scheduling strategy that considers CCS-P2G and concentrating solar power(CSP)station.Firstly,CSP station,gas hydrogen doping mode and variable hydrogen doping ratio mode are applied to IES,and combined with CCS-P2G coupling model,the IES low-carbon economic dispatch model is established.Secondly,the stepped carbon trading mechanism is applied,and the sensitivity analysis of IES carbon trading is carried out.Finally,an IES optimal scheduling strategy based on fuzzy opportunity constraints and an IES risk assessment strategy based on CVaR theory are established.The simulation shows that the gas-hydrogen doping model proposed in this paper reduces the operating cost and carbon emission of IES by 1.32%and 7.17%,and improves the carbon benefit by 5.73%;variable hydrogen doping ratio model reduces the operating cost and carbon emission of IES by 3.75%and 1.70%,respectively;CSP stations reduce 19.64%and 38.52%of the operating costs of IES and 1.03%and 1.80%of the carbon emissions of IES respectively compared to equal-capacity photovoltaic and wind turbines;the baseline price of carbon trading of IES and its rate of change jointly affect the carbon emissions of IES;evaluating the anti-interference capability of IES through trapezoidal fuzzy number and weighting coefficients,enabling IES to guarantee operation at the lowest cost.
文摘Sweet cherries ( Prunus avium L. cv. Napoleon) were stored in controlled atmospheres (CA) of high O(2) (70% O(2) + 0% CO(2)) or high CO(2) (5% O(2) + 10% CO(2)), in modified atmosphere package (MAP, (13% - 18%) O(2) + (2% -4%) CO(2)) and in air (control) at 1 degreesC to investigate the effects of different O(2) and CO(2) concentrations on physiological properties, quality and storability of the fruits during storage. The results indicated that compared with other treatments, CA with high O(2) concentration decreased fruit decay and ethanol content, but increased the accumulation of malondialdehyde (MDA) and stimulated browning. CA with high CO(2) concentration inhibited polyphenol oxidase (PPO) activity, reduced MDA content, maintained vitamin C content and firmness, decreased fruit decay and browning. Soluble solids contents (SSC) were not significantly affected by different atmosphere treatments. 'Napoleon' fruits stored in 5% O(2) + 10% CO(2) for as long as 80 d were of good quality, but only 40, 20 and 30 d stored in MAP, 70% O(2) + 0% CO(2) and air, re-spectively.
文摘The effects of CO 2 concentration on the morphological and anatomical characters of soybean (Glycine max) leaf were investigated by means of light microscopy and SEM.It was noticed that exomorphology did not show dramatic change,while stomatal density decreased with increasing CO 2 concentration.Under SEM,no epicuticular wax was observed on both abaxial and adaxial sides of the control group as well as on adaxial side of the treatment group.However,leaf surface of abaxial side was noticed to be densely covered with microasterisk epicuticular wax when they were exposed to CO 2 enriched environment.The epicuticular wax deposition was present in equal abundance on both stomatal and nonstomatal areas.Furthermore,leaf thickness increased significantly due largely to the origin of an extra layer of palisade in the treatment group.The results confirmed that CO 2 enrichment might enhance cell division and induce greater quantity of epicuticular wax.
文摘Wheat ( Triticum aestivum L.) plants were grown under ambient and doubled_CO 2(plus 350 μL/L) concentration in cylindrical open_top chamber to examine their effects on the ultrastructure, supramolecular architecture, absorption spectrum and low temperature (77 K) fluorescence emission spectrum of the chloroplasts from wheat leaves. The results were briefly summarized as follows: (1) The wheat leaves possessed normally developed chloroplasts with intact grana and stroma thylakoid membranes; The grana intertwined with stroma thylakoid membranes and increased slightly in stacking degree and the width of granum, in spite of more accumulated starch grains within the chloroplasts than those in control; (2) The particle density in the stacked region of the endoplasmic fracture face (EFs) and protoplasmic fracture face (PFs) and in the unstacked region the endoplasmic fracture face (EFu) and the protoplasmic fracture face (PFu) was significantly higher than that of control. Furthermore, in some cases many more particles on EFs faces of thylakoid membranes appeared as a paracrystalline particle array; (3) The variations in the structure of chloroplasts were consistent with the absorption spectra and the low temperature (77 K) fluorescence emission spectra of the chloroplasts developed under the doubled_CO 2 concentration. Results indicate that the capability of light energy absorption of chloroplasts and regulative capability of excitation energy distribution between PSⅡ and PSⅠ were raised by doubled_CO 2 concentration. This is very favorable for final productivity of wheat.
基金supported by the Chinese Academy of Sciences (No KZCX2-YW-309)the National Basic Research Program (973) of China (No 2004CB418507)
文摘An experiments were carried out with treatments differing in nitrogen supply （0, 5 and 15 g N/m^2） and CO2 levels （350 and 700 μmol/mol） using OTC （open top chamber） equipment to investigate the biomass of Calamagrostis angustifolia and soil active carbon contents after two years. The results showed that elevated CO2 concentration increased the biomass of C. angustifolia and the magnitude of response varied with each growth period. Elevated CO2 concentration has increased aboveground biomass by 16.7% and 17.6% during the jointing and heading periods and only 3.5% and 9.4% during dough and maturity periods. The increases in belowground biomass due to CO2 elevation was 26.5%, 34.0% and 28.7% during the heading, dough and maturity periods, respectively. The responses of biomass to enhanced CO2 concentrations are differed in N levels. Both the increase of aboveground biomass and belowground biomass were greater under high level of N supply （15 g N/m^2）. Elevated CO2 concentration also increased the allocation of biomass and carbon in root. Under elevated CO2 concentration, the average values of active carbon tended to increase. The increases of soil active soil contents followed the sequence of microbial biomass carbon （10.6%） 〉 dissolved organic carbon （7.5%） 〉 labile oxidable carbon （6.6%） 〉 carbohydrate carbon （4.1%）. Stepwise regressions indicated there were significant correlations between the soil active carbon contents and plant biomass. Particularly, microbial biomass carbon, labile oxidable carbon and carbohydrate carbon were found to be correlated with belowground biomass, while dissolved organic carbon has correlation with aboveground biomass. Therefore, increased biomass was regarded as the main driving force for the increase in soil active organic carbon under elevated CO2 concentration.
基金Project supported by the Knowledge Innovation Project of the Chinese Academy of Sciences (No.KZCX2-YW-416)National NaturM Science Foundation of China (No.90411020)
文摘The objectives of this study were to investigate the effect of higher CO2 concentrations （500 and 700 μmol mol^-1） in atmosphere on total soil respiration and the contribution of root respiration to total soil respiration during seedling growth of Pinus sylvestris vat. sylvestriformis. During the four growing seasons （May-October） from 1999 to 2003, the seedlings were exposed to elevated concentrations of CO2 in open-top chambers. The total soil respiration and contribution of root respiration were measured using an LI-6400-09 soil CO2 flux chamber on June 15 and October 8, 2003. To separate root respiration from total soil respiration, three PVC cylinders were inserted approximately 30 cm deep into the soil in each chamber. There were marked diurnal changes in air and soil temperatures on June 15. Both the total soil respiration and the soil respiration without roots showed a strong diurnal pattern, increasing from before sunrise to about 14：00 in the afternoon and then decreasing before the next sunrise. No increase in the mean total soil respiration and mean soil respiration with roots severed was observed under the elevated CO2 treatments on June 15, 2003, as compared to the open field and control chamber with ambient CO2. However, on October 8, 2003, the total soil respiration and soil respiration with roots severed in the open field were lower than those in the control and elevated CO2 chambers. The mean contribution of root respiration measured on June 15, 2003, ranged from 8.3% to 30.5% and on October 8, 2003, from 20.6% to 48.6%.
文摘A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0.1 MPa to 0.4 MPa, and the maximum NH3 mass fraction up to 0.4 are provided. This model agrees with experimental data well (average relative error < 1%) and is useful for analysis of industrial urea production.
基金supported by the National Natural Science Fundation of China(U1361202,51276120)~~
文摘The CO2reforming of CH4is studied over MgO‐promoted Ni catalysts,which were supported on alumina prepared from hydrotalcite.This presents an improved stability compared with non‐promoted catalysts.The introduction of the MgO promoter was achieved through the‘‘memory effect’’of the Ni‐Al hydrotalcite structure,and ICP‐MS confirmed that only0.42wt.%of Mg2+ions were added into the Ni‐Mg/Al catalyst.Although no differences in the Ni particle size and basicity strength were observed,the Ni‐Mg/Al catalyst showed a higher catalytic stability than the Ni/Al catalyst.A series of surface reaction experiments were used and showed that the addition of a MgO promoter with low concentration can promote CO2dissociation to form active surface oxygen arising from the formation of the Ni‐MgO interface sites.Therefore,the carbon‐resistance promotion by nature was suggested to contribute to an oxidative environment around Ni particles,which would increase the conversion of carbon residues from CH4cracking to yield CO on the Ni metal surface.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
基金Project supported by the National Natural Science Foundation of China (No. 49771001).
文摘The annual series of δ13C were measured in tree rings of three Cryptomeria fortunei disks （OF-1, OF-2, and OF- 3） collected from West Tianmu Mountain, Zhejiang Province, China, according to cross-dating tree ring ages. There was no obvious decreasing trend of the δ13C annual time series of CF-2 before 1835. However, from 1835 to 1982 the three tree ring δ13C annual series exhibited similar decreasing trends that were significantly （P ≤ 0.001） correlated. The distribution characteristics of a scatter diagram between estimated δ13C series of CF-2 from modeling and the atmospheric CO2 concentration extracted from the Law Dome ice core from 1840 to 1978 were analyzed and a curvilinear regression equation for reconstructing atmospheric CO2 concentration was established with R2 = 0.98. Also, a test of independent samples indicated that between 1685 and 1839 the reconstructed atmospheric CO2 concentration .using the δ13C series of CF-2 had a close relationship with the Law Dome and Siple ice cores, with a standard deviation of 1.98. The general increasing trend of the reconstructed atmospheric CO2 concentration closely reflected the 10ng-term variation of atmospheric CO2 concentration recorded both before and after the Industrial Revolution. Between 1685 and 1840 the evaluated atmospheric CO2 concentration was stable, but after 1840 it exhibited a rapid increase. Given a longer δ13C annual time series of tree rings, it was feasible to rebuild a representative time series to describe the atmospheric CO2 concentration for an earlier period and for years that were not in the ice core record.
基金supported by the Strategic Priority Research Program-Climate Change:Carbon Budget and Relevant Issues (Grant No.XDA05040404)the National Natural Science Foundation of China (Grant No.41130528)
文摘The regional air quality modeling system RAMS-CMAQ(Regional Atmospheric Modeling System and Models-3 Community Multi-scale Air Quality) was developed by incorporating a vegetation photosynthesis and respiration module(VPRM) and used to simulate temporal-spatial variations in atmospheric CO2 concentrations in East Asia,with prescribed surface CO2 fluxes(i.e.,fossil fuel emission,biomass burning,sea-air CO2 exchange,and terrestrial biosphere CO2 flux).Comparison of modeled CO2 mixing ratios with eight ground-based in-situ measurements demonstrated that the model was able to capture most observed CO2 temporal-spatial features.Simulated CO2 concentrations were generally in good agreement with observed concentrations.Results indicated that the accumulated impacts of anthropogenic emissions contributed more to increased CO2 concentrations in urban regions relative to remote locations.Moreover,RAMS-CMAQ analysis demonstrates that surface CO2 concentrations in East Asia are strongly influenced by terrestrial ecosystems.
文摘Horizontal and vertical variations of daily average CO 2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000 The primary purpose was to study spatial distribution characteristics of CO 2 concentration on the four levels of height(0 1 m, 0 6 m, 1 2 m and 2 m) and compare the differences of CO 2 concentration under different land covers. Results showed that daily average CO 2 concentration above wetland surface in Xianghai National Natural Reserve was lower than that above other wetlands in northeast China as well as the worldwide average, suggesting that Xianghai wetland absorbed CO 2 in August and acted as “sink” of CO 2 The horizontal variations on the four levels of height along the latitude were distinct, and had the changing tendency of “decreasing after increasing” with the increase of height. The areas with obvious variations were consistent on different levels of height, and those with the highest variations appeared above surface of shore, sloping field, Typha wetland and Phragmites wetland; the vertical variations were greatly different, with the higher variations in Phragmites wetland and Typha wetland, and the lands near the shore and the sloping field with the lower variations. Spatial variations of daily average CO 2 concentrations above wetland surface were affected by surface qualities and land covers.
基金the projects(30230230 ,30070429)supported by the National Natural Science Foundation of China(NSFC) the project(G1999011707)supported by the National Key Basic Research Support Funds(NKBRSF)the NSFC and the NKBRSF for their kindness of supporting theseprojects.
文摘Hoagland＇s solution was used as water culture medium to study the effect of CO2 concentration on nitrate metabolism of wheat under natural light and light-shaded conditions. NO3^-N, NH4^＋-N, nitrate reductase activity, total uptake N by wheat plants during solution cultural period and total N in plants were determined for comprehensive evaluation of the effect. Results showed that under both natural light and light-shaded conditions, addition of CO2 increased NO3^-N uptake and its assimilative capabilities by plants. However, there were some difference between shoots and roots. With increase of CO2 concentration, the concentration of NO3^-N and NH4^＋-N as well as nitrate reductase activity were all decreased for shoots while the difference was not so distinct in roots, and the nitrate reductase activity was not decreased, but increased. Since NO3^-N uptake by plants from the solution and the total N in plants were much higher by CO2 addition, it may be concluded that addition of CO2 has resulted in rise of nitrate absorption, assimilation and metabolism of wheat.
基金National Natural Science Foundation of China, No.41071030
文摘Impacts of climatic change on agriculture and adaptation are of key concern of scientific research. However, vast uncertainties exist among global climates model output, emission scenarios, scale transformation and crop model parameterization. In order to reduce these uncertainties, we integrate output results of four IPCC emission scenarios of A1 FI, A2, B1 and B2, and five global climatic patterns of HadCM3, PCM, CGCM2, CSIRO2 and ECHAM4 in this study. Based on 20 databases of future climatic change scenarios from the Climatic Research Unit （CRU） , the scenario data of the climatic daily median values are generated on research sites with the global mean temperature increase of 1℃（GMT＋ID）, 2℃（GMT＋2D） and 3℃（GMT＋3D）. The impact of CO2 fertilization effect on wheat biomass for GMT＋I D, GMT＋2D and GMT＋3D in China＇s wheat-producing areas is studied in the process model, CERES-Wheat and probabilistic forecasting method. The research results show the CO2 fertilization effect can compensate reduction of wheat biomass with warming temperature in a strong compensating effect. Under the CO2 fertilization effect, the rain-fed and irrigated wheat biomasses increase respectively, and the increment of biomass goes up with temperature rising. The rain-fed wheat biomass increase is greater than the irrigated wheat biomass. Without consideration of CO2 fertilization effect, both irrigated and rain-fed wheat biomasses reduce, and there is a higher probability for the irrigated wheat biomass than that of the rain-fed wheat biomass.
基金supported by the National Natural Science Foundation of China (Nos. 40875041,40631006,40975038)
文摘Successive filtration and comparison show that the stratosphere air temperature in 10 hPa-layer of the Northern Hemisphere （NH） in July continuously increases,which is associated to the increases in greenhouse gases mostly CO2,volcanic activities,and solar activity,demonstrating the follows.（a） The increase in CO2 concentration is largely consistent with that of the stratosphere air temperature in 10 hPa-layer of the NH in July.However,the increase in the air temperature is not in a linear pattern,during which several cooling events interrupt.The cooling events between late 1960s and late 1970s are remarkable ones and so is the one before mid 1990s.Analysis shows that these events are induced by volcanic activities and solar activity.（b） The CO2-free variation in the stratosphere air temperature in 10 hPa-layer of the NH is consistent with that of the solar magnetic index.The wave crests and wave troughs of the two curves are consistent in phase,and the curve of solar magnetic index leads the other slightly.In other words,when the solar magnetic pole is southward,a warming in the NH stratosphere corresponds;and on the contrary,the northward solar magnetic pole corresponds to a cooling event.The variation in solar magnetic polarity strongly impacts the variation in the stratosphere temperature.
文摘There is limited information available on CO2 concentration and flux over marsh. The objective of this work was to characterize CO2 concentration and flux within and above marsh plant (Cares lasiocarpa Ehrh. and C. pseudoucuaica F. Schm) canopy at heights 0. 5, 1. 0 and 1. 5 m.CO2 concentration was measured sequentially every 3 bars by using an infrared gas analyzer. Soil and air temperature, wind speed, net radiation and soil heat flux were also measured simultaneously. Extremely drily minimum and maximum CO2 concentration rangal from 250 to 754 μmd/mol for the 4-year work. The typical minimum and maximum values ranged from 314 to 464 μmol/mol at the height of marsh plant (about 0. 5 m) during the fruiting perioed and mature date. The seasonal changes in CO2 concentration show that the minimum CO2 concentration occurred in the fruiting period and mature date, and both of their minimum values were 314 μmol/mol. This illustrates that CO2 consumed by photosynthesis was stable during the period. The flux of CO2 can be thought as a turbulent diffusion phenomenon. By micrometeorological methods, the diurnal CO2 fluxes were measured in the flowering peried, fruiting period, early mature date, late mature date and yellow-ripe stage. Their values were -0. 18, 38. 15,24. 13, 10. 9 and 4. 91 μmol/mol respectively.
基金Supported by the National Key R&D Program of China(No.2021YFC3200900)the National Natural Science Foundation of China(No.31971477)。
文摘The global rise in CO_(2)concentration is having a profound impact on the structure and function of aquatic ecosystems.However,little information is available on the responses of odorproducing cyanobacteria to the increase in CO_(2)concentration.In this study,the effects of different CO_(2)concentrations on 2-methylisoborneol(MIB)-producing Pseudanabaena and non-2-MIB-producing Pseudanabaena under monoculture and co-culture conditions were investigated.Results show that the specific growth rate of Pseudanabaena gradually increased with the rise in CO_(2)concentration,and for the 2-MIB-producing strain,this increase was significantly higher than the non-2-MIB-producing strain.Under co-culture conditions,the proportion of non-2-MIB-producing Pseudanabaena was significantly higher than that of 2-MIB-producing Pseudanabaena,suggesting a superior competitive ability of non-2-MIB-producing Pseudanabaena over 2-MIB-producing Pseudanabaena.Under monoculture conditions,the total 2-MIB production at the 300-μg/g CO_(2)concentration was significantly higher than that at 600-and 1200-μg/g CO_(2)concentrations.The 2-MIB concentration produced by Pseudanabaena decreased with the increasing in CO_(2)concentration.Therefore,we believe that with the future increase in CO_(2)concentration,2-MIB concentration would be decreased and so would the risk of 2-MIB outbreaks.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB4000604)National Natural Science Foundation of China(No.52271220)+2 种基金The Program of the Ministry of Education of China for Introducing Talents of Discipline to Universities(No.B12015)the Fundamental Research Funds for the Central UniversitiesHaihe Laboratory of Sustainable Chemical Transformations,Guangxi Collaborative Innovation Centre of Structure and Property for New Energy and Materials,Science Research and Technology Development Project of Guilin(No.20210102-4)
文摘Electrochemical nitrate(NO_(3)^(-))reduction reaction(eNO_(3)RR)to ammonia(NH3)provides a promising route for both water conservation and green ammonia synthesis.Although various catalysts were designed for the eNO_(3)RR and great achievements have been achieved,it is still a challenge to realize selective eNO_(3)RR to NH3at low concentration for the competing hydrogen evolution reaction(HER)and poor mass transfer of NO_(3)^(-).Herein,we designed a tandem catalyst of Pd nanoparticle loaded Cu_(2)O hierarchical nanofiber(Pd-Cu_(2)O)to improve eNO_(3)RR performance at low nitrate concentration.The Pd-Cu_(2)O shows a faraday efficiency(FE)of 95.80%and an ammonia selectivity of 97.34%at a comparatively low applied potential of-0.15 V versus RHE with low concentration.Besides,it exhibits excellent nitrate removal effects,the residual concentration of nitrate-N was only 7.22 ppm at-0.15 V.Electrochemical characterizations indicate that the abundant secondary heterojunction structures and the tandem effects of Pd-Cu_(2)O synergistic ally accelerate the transfer and conversion of NO_(3)^(-)and improve the dynamic of eNO_(3)RR at low concentration.Furthermore,the operando electrochemical impedance spectroscopy(EIS)and density functional theory(DFT)calculations suggested the tandem effects of Pd-Cu_(2)O improved the adsorption of NO_(3)^(-)and*H and thus promoted the dynamics of eNO_(3)RR at low concentration.The findings highlight the tandem effects of Pd-Cu_(2)O and provide an effective strategy for designing electrocatalysts that can be applied to low concentration and low applied potential conditions.
基金supported by the National Key Research and Development Program of China(Nos.2022YFC3703700,2021YFA0910300,and 2021YFC3200902)the National Natural Science Foundation of China(No.22125606)+1 种基金the Special Project of Ecological Environmental Technology for Carbon Dioxide Emissions Peak and Carbon Neutrality(No.RCEESTDZ-2021-21)China South-to-North Water Diversion Corporation Limited Research Project(No.NSBDZX/SH/KY/2022-001).
文摘The removal and recovery of low-concentration phosphates from water have become crucial due to the dual challenges of eutrophication and the phosphorus crisis.Herein,we engineered a highly efficient and recyclable phosphate trapping agent of La_(2-x)CexO_(2)CO_(3) solid solution.The incorporation of Ce enhances the surface area and surface potential of La_(2-x)CexO_(2)CO_(3),providing abundant adsorption sites for phosphate.Surprisingly,we found that adjusting the Ce proportion affects the carbonate content,thereby influencing the anion-exchange capacity between carbonate and phosphate.Specifically,at 3% Ce content(3%-CeL),the carbonate ratio is maximized,resulting in an optimal sorption capacity(196.4mg P/g)and a rapid removal rate(under 40min)for phosphate,unaffected by interfering ions.Remarkably,3%-CeL achieved nearly 100%phosphate removal efficiency in diverse water samples from sewage treatment plants,rivers,reservoirs,and groundwater.After five adsorption-desorption cycles,the phosphate removal and recovery efficiency of 3%-CeL remained above 90%.Mechanistic studies revealed that 3%Ce content yielded the highest proportion of Ce^(4+)/Ce^(3+),enabling greater carbonate binding for anion-exchange.This study proposes a high-performance phosphate trapping agentwith broad applicability for treating actual waters and provides a new perspective on enhancing low-concentration phosphate removal in La-based materials through manipulating Ce ratio and valence.
文摘Atmospheric CO2 concentration （CC） near land surface and meteorological variables have been measured at four sites, named Yeniugou （alpine meadow and permafrost）, Xishui （mountainous forest）, Linze （oasis edge） and Ejina （lower desert）, respectively, in Heihe River Basin, northwest China. The results showed that, the half hourly CC at night was larger than in daytime, and the daily averaged CC was the largest in winter. The averaged CC of 932 d at the Linze was about 418 ppm, was about 366 ppm in the 762 d at the Ejina. In the same period from September 23 to November 9, 2004, the averaged CC was about 625,334, 436 and 353 ppm, at Yeniugou, Xishui, Linze and Ejina, respectively. The linear relationship between daily averaged CC and air temperature T was negative, between CC and relative humidity （RH） was positive. The linear CC-atmospheric pressure （A P） relationship was negative at the Linze and Yeniugou, was positive at the Ejina. The relationship between CC and global radiation R was exponent, and soil temperature Ts was negative linear, and soil water content was complex. The correlation between CC and wind speed was not existent. Using meteorological variables together to simulate CC, could give good results.
基金Under the auspices of National Natural Science Foundation of China(No.41871193,U1910207)Program for the Philosophy and Social Science of Shanxi Province(No.2023YJ107)。
文摘Rapid increases in Carbon dioxide(CO_(2))levels could trigger unpredictable climate change.The assessment of spatiotempor-al variation and influencing factors of CO_(2) concentration are helpful in understanding the source/sink balance and supporting the formu-lation of climate policy.In this study,Greenhouse Gases Observing Satellite(GOSAT)data were used to explore the variability of CO_(2) concentrations in China from 2009 to 2020.Meteorological parameters,vegetation cover,and anthropogenic activities were combined to explain the increase in CO_(2) concentration,using pixel-based correlations and Covariance Based Structural Equation Modeling(CB-SEM)analysis.The results showed that the influence of vertical CO_(2) transport diminished with altitude,with a distinct inter-annual in-crease in CO_(2) concentrations at 17 vertical levels.Spatially,the highest values were observed in East China,whereas the lowest were observed in Northwest China.There were significant seasonal variations in CO_(2) concentration,with maximum and minimum values in spring(April)and summer(August),respectively.According to the pixel-based correlation analysis,the near-surface CO_(2) concentration was positively correlated with population(r=0.99,P<0.001),Leaf Area Index(LAI,r=0.95,P<0.001),emissions(r=0.91,P<0.001),temperature(r=0.60,P<0.05),precipitation(r=0.34,P>0.05),soil water(r=0.29,P>0.05),nightlight(r=0.28,P>0.05);and negatively correlated with wind speed(r=−0.58,P<0.05).CB-SEM analysis revealed that LAI was the most important con-trolling factor explaining CO_(2) concentration variation(total effect of 0.66),followed by emissions(0.58),temperature(0.45),precipita-tion(0.30),wind speed(−0.28),and soil water(−0.07).The model explained 93% of the increase in CO_(2) concentration.Our results provide crucial information on the patterns of CO_(2) concentrations and their driving mechanisms,which are particularly significant in the context of climate change.
