Heteroatom doping is an efficient approach to regulate the fluorescence properties of carbon dots.Using aminophenylboronic acid as the raw material,a combustion method was developed for the synthesis of boron,nitrogen...Heteroatom doping is an efficient approach to regulate the fluorescence properties of carbon dots.Using aminophenylboronic acid as the raw material,a combustion method was developed for the synthesis of boron,nitrogen-doped carbon dots（B,N-carbon dots）.The B,N-carbon dots emitted green fluorescence and displayed high resistance to both photo bleaching and ionic strength.A facile fluorescence sensing approach for Cu^2＋ was fabricated via static fluorescence quenching.Under optimal conditions,a rapid detection of Cu^2＋ could be completed in 2 min with a linearity ranging from 1 μmol/L to 25 μmol/L and a detection limit of 0.3 μmol/L Furthermore,the proposed method showed potential applications for the detection of Cu^2＋ in natural water samples.展开更多
TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface w...TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface water, we herein examined the preparation of a P25-TiO2 composite film on a cement substrate via a sol–gel method. In this case, Rhodamine B（Rh B）was employed as the target organic pollutant. The self-generated TiO2 film and the P25-TiO2 composite film were characterized by X-ray diffraction（XRD）, N2 adsorption/desorption measurements, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, and diffuse reflectance spectroscopy（DRS）. The photodegradation efficiencies of the two films were studied by Rh B removal in water under UV（ultraviolet） irradiation. Over 4 day exposure, the P25-TiO2 composite film exhibited higher photocatalytic performance than the self-generated TiO2 film. The photodegradation rate indicated that the efficiency of the P25-TiO2 composite film was enhanced by the addition of the rutile phase Degussa P25 powder. As such, cooperation between the anatase TiO2 and rutile P25 nanoparticles was beneficial for separation of the photo-induced electrons and holes. In addition, the influence of P25 doping on the P25-TiO2 composite films was evaluated. We found that up to a certain saturation point, increased doping enhanced the photodegradation ability of the composite film. Thus, we herein demonstrated that the doping of P25 powders is a simple but effective strategy to prepare a P25-TiO2 composite film on a cement substrate, and the resulting film exhibits excellent removal efficiency in the degradation of organic pollutants.展开更多
Isoparametric quadrilateral elements are widely used in the finite element method, but the accuracy of the isoparametric quadrilateral elements will drop obviously deteriorate due to mesh distortions. Spline functions...Isoparametric quadrilateral elements are widely used in the finite element method, but the accuracy of the isoparametric quadrilateral elements will drop obviously deteriorate due to mesh distortions. Spline functions have some properties of simplicity and conformality. Two 8-node quadrilateral elements have been developed using the trian- gular area coordinates and the B-net method, which can ex- actly model the quadratic field for both convex and concave quadrangles. Some appropriate examples are employed to evaluate the performance of the proposed elements. The nu- merical results show that the two spline elements can obtain solutions which are highly accurate and insensitive to mesh distortions.展开更多
The quadrilateral discrete Kirchhoff thin plate bending element DKQ is based on the isoparametric element Q8, however, the accuracy of the isoparametric quadrilateral elements will drop significantly due to mesh disto...The quadrilateral discrete Kirchhoff thin plate bending element DKQ is based on the isoparametric element Q8, however, the accuracy of the isoparametric quadrilateral elements will drop significantly due to mesh distortions. In a previous work, we constructed an 8-node quadrilateral spline element L8 using the triangular area coordinates and the B- net method, which can be insensitive to mesh distortions and possess the second order completeness in the Cartesian co- ordinates. In this paper, a thin plate spline element is devel- oped based on the spline element L8 and the refined tech- nique. Numerical examples show that the present element indeed possesses higher accuracy than the DKQ element for distorted meshes.展开更多
In this paper, the bicubic splines in product form are used to construct the multi-field functions for bending moments, twisting moment and transverse displacement of the plate on elastic foundation. The multivariable...In this paper, the bicubic splines in product form are used to construct the multi-field functions for bending moments, twisting moment and transverse displacement of the plate on elastic foundation. The multivariable spline element equations are derived, based on the mixed variational principle. The analysis and calculations of bending, vibration and stability of the plates on elastic foundation are presented in the paper. Because the field functions of plate on elastic foundation are assumed independently, the precision of the field variables of bending moments and displacement is high.展开更多
A new numerical manifold （NMM） method is derived on the basis of quartic uniform B-spline interpolation. The analysis shows that the new interpolation function possesses higher-order continuity and polynomial consis...A new numerical manifold （NMM） method is derived on the basis of quartic uniform B-spline interpolation. The analysis shows that the new interpolation function possesses higher-order continuity and polynomial consistency compared with the conven- tional NMM. The stiffness matrix of the new element is well-conditioned. The proposed method is applied for the numerical example of thin plate bending. Based on the prin- ciple of minimum potential energy, the manifold matrices and equilibrium equation are deduced. Numerical results reveal that the NMM has high interpolation accuracy and rapid convergence for the global cover function and its higher-order partial derivatives.展开更多
基金financially supported by the National Natural Science Foundation of China(No.21375112)the Marine hightech industry development projects of Fujian Province(No.2015-19)
文摘Heteroatom doping is an efficient approach to regulate the fluorescence properties of carbon dots.Using aminophenylboronic acid as the raw material,a combustion method was developed for the synthesis of boron,nitrogen-doped carbon dots（B,N-carbon dots）.The B,N-carbon dots emitted green fluorescence and displayed high resistance to both photo bleaching and ionic strength.A facile fluorescence sensing approach for Cu^2＋ was fabricated via static fluorescence quenching.Under optimal conditions,a rapid detection of Cu^2＋ could be completed in 2 min with a linearity ranging from 1 μmol/L to 25 μmol/L and a detection limit of 0.3 μmol/L Furthermore,the proposed method showed potential applications for the detection of Cu^2＋ in natural water samples.
基金supported by the National Science Funds for Creative Research Groups of China (No. 51421006)the National Major Projects of Water Pollution Control and Management Technology (No. 2017ZX07204003)+2 种基金the National Key Plan for Research and Development of China (2016YFC0502203)the Key Program of National Natural Science Foundation of China (No. 91647206)the Qing Lan Project of Jiangsu Province, and PAPD
文摘TiO2 films have received increasing attention for the removal of organic pollutants via photocatalysis. To develop a simple and effective method for improving the photodegradation efficiency of pollutants in surface water, we herein examined the preparation of a P25-TiO2 composite film on a cement substrate via a sol–gel method. In this case, Rhodamine B（Rh B）was employed as the target organic pollutant. The self-generated TiO2 film and the P25-TiO2 composite film were characterized by X-ray diffraction（XRD）, N2 adsorption/desorption measurements, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, and diffuse reflectance spectroscopy（DRS）. The photodegradation efficiencies of the two films were studied by Rh B removal in water under UV（ultraviolet） irradiation. Over 4 day exposure, the P25-TiO2 composite film exhibited higher photocatalytic performance than the self-generated TiO2 film. The photodegradation rate indicated that the efficiency of the P25-TiO2 composite film was enhanced by the addition of the rutile phase Degussa P25 powder. As such, cooperation between the anatase TiO2 and rutile P25 nanoparticles was beneficial for separation of the photo-induced electrons and holes. In addition, the influence of P25 doping on the P25-TiO2 composite films was evaluated. We found that up to a certain saturation point, increased doping enhanced the photodegradation ability of the composite film. Thus, we herein demonstrated that the doping of P25 powders is a simple but effective strategy to prepare a P25-TiO2 composite film on a cement substrate, and the resulting film exhibits excellent removal efficiency in the degradation of organic pollutants.
基金supported by the National Natural Science Foundation of China(11001037,11102037 and 11290143)the Fundamental Research Funds for the Central Universities
文摘Isoparametric quadrilateral elements are widely used in the finite element method, but the accuracy of the isoparametric quadrilateral elements will drop obviously deteriorate due to mesh distortions. Spline functions have some properties of simplicity and conformality. Two 8-node quadrilateral elements have been developed using the trian- gular area coordinates and the B-net method, which can ex- actly model the quadratic field for both convex and concave quadrangles. Some appropriate examples are employed to evaluate the performance of the proposed elements. The nu- merical results show that the two spline elements can obtain solutions which are highly accurate and insensitive to mesh distortions.
基金supported by the National Natural Science Foundation of China(11001037,11102037,11290143)the Fundamental Research Funds for the Central Universities(DUT13LK07)
文摘The quadrilateral discrete Kirchhoff thin plate bending element DKQ is based on the isoparametric element Q8, however, the accuracy of the isoparametric quadrilateral elements will drop significantly due to mesh distortions. In a previous work, we constructed an 8-node quadrilateral spline element L8 using the triangular area coordinates and the B- net method, which can be insensitive to mesh distortions and possess the second order completeness in the Cartesian co- ordinates. In this paper, a thin plate spline element is devel- oped based on the spline element L8 and the refined tech- nique. Numerical examples show that the present element indeed possesses higher accuracy than the DKQ element for distorted meshes.
文摘In this paper, the bicubic splines in product form are used to construct the multi-field functions for bending moments, twisting moment and transverse displacement of the plate on elastic foundation. The multivariable spline element equations are derived, based on the mixed variational principle. The analysis and calculations of bending, vibration and stability of the plates on elastic foundation are presented in the paper. Because the field functions of plate on elastic foundation are assumed independently, the precision of the field variables of bending moments and displacement is high.
基金supported by the Fund of National Engineering and Research Center for Highways in Mountain Area(No.gsgzj-2012-05)the Fundamental Research Funds for the Central Universities of China(No.CDJXS12240003)the Scientific Research Foundation of State Key Laboratory of Coal Mine Disaster Dynamics and Control(No.2011DA105287-MS201213)
文摘A new numerical manifold （NMM） method is derived on the basis of quartic uniform B-spline interpolation. The analysis shows that the new interpolation function possesses higher-order continuity and polynomial consistency compared with the conven- tional NMM. The stiffness matrix of the new element is well-conditioned. The proposed method is applied for the numerical example of thin plate bending. Based on the prin- ciple of minimum potential energy, the manifold matrices and equilibrium equation are deduced. Numerical results reveal that the NMM has high interpolation accuracy and rapid convergence for the global cover function and its higher-order partial derivatives.
