A low-viscosity emulsion of crude oil in water can be believed to be the bulk of a flow regime in a pipeline.To differentiate which crude oil would and which would not counter the blockage of flow due to gas hydrate f...A low-viscosity emulsion of crude oil in water can be believed to be the bulk of a flow regime in a pipeline.To differentiate which crude oil would and which would not counter the blockage of flow due to gas hydrate formation in flow channels,varying amount of crude oil in water emulsion without any other extraneous additives has undergone methane gas hydrate formation in an autoclave cell.Crude oil was able to thermodynamically inhibit the gas hydrate formation as observed from its hydrate stability zone.The normalized rate of hydrate formation in the emulsion has been calculated from an illustrative chemical affinity model,which showed a decrease in the methane consumption(decreased normalized rate constant) with an increase in the oil content in the emulsion.Fourier transform infrared spectroscopy(FTIR) of the emulsion and characteristic properties of the crude oil have been used to find the chemical component that could be pivotal in selfinhibitory characteristic of the crude oil collected from Ankleshwar,India,against a situation of clogged flow due to formation of gas hydrate and establish flow assurance.展开更多
Let θ∈^d be a unit vector and let X, X1, X2,…… be a sequence of i.i.d. Xd-valued random vectors attracted to operator semi-stable laws. For each integer n ≥1, let X1,≤……≤ Xn,n denote the order statistics of X...Let θ∈^d be a unit vector and let X, X1, X2,…… be a sequence of i.i.d. Xd-valued random vectors attracted to operator semi-stable laws. For each integer n ≥1, let X1,≤……≤ Xn,n denote the order statistics of X1, X2,..., Xn according to priority of index, namely |(X1,nθ)|≥…≥ [(Xn,n,θ)1, where (., .) is an inner product on Rd. For all integers r ≥ 0, define by (r)Sn =∑n-r i=1Xi,n the trimmed sum. In this paper we investigate a law of the iterated logarithm and limit distributions for trimmed sums (r)Sn. Our results give information about the maximal growth rate of sample paths for partial sums of X when r extreme terms are excluded. A stochastically compactness of (r)Sn is obtained.展开更多
基金the financial assistance provided by University Grants Commission, New Delhi, India, under Special Assistance Program (SAP) to the Department of Petroleum Engineering, Indian School of Mines, Dhanbad, India
文摘A low-viscosity emulsion of crude oil in water can be believed to be the bulk of a flow regime in a pipeline.To differentiate which crude oil would and which would not counter the blockage of flow due to gas hydrate formation in flow channels,varying amount of crude oil in water emulsion without any other extraneous additives has undergone methane gas hydrate formation in an autoclave cell.Crude oil was able to thermodynamically inhibit the gas hydrate formation as observed from its hydrate stability zone.The normalized rate of hydrate formation in the emulsion has been calculated from an illustrative chemical affinity model,which showed a decrease in the methane consumption(decreased normalized rate constant) with an increase in the oil content in the emulsion.Fourier transform infrared spectroscopy(FTIR) of the emulsion and characteristic properties of the crude oil have been used to find the chemical component that could be pivotal in selfinhibitory characteristic of the crude oil collected from Ankleshwar,India,against a situation of clogged flow due to formation of gas hydrate and establish flow assurance.
基金Supported by National Natural Science Foundation of China(Grant No.11071076)NSF of Zhejiang Province(Grant No.LY14A010025)
文摘Let θ∈^d be a unit vector and let X, X1, X2,…… be a sequence of i.i.d. Xd-valued random vectors attracted to operator semi-stable laws. For each integer n ≥1, let X1,≤……≤ Xn,n denote the order statistics of X1, X2,..., Xn according to priority of index, namely |(X1,nθ)|≥…≥ [(Xn,n,θ)1, where (., .) is an inner product on Rd. For all integers r ≥ 0, define by (r)Sn =∑n-r i=1Xi,n the trimmed sum. In this paper we investigate a law of the iterated logarithm and limit distributions for trimmed sums (r)Sn. Our results give information about the maximal growth rate of sample paths for partial sums of X when r extreme terms are excluded. A stochastically compactness of (r)Sn is obtained.