The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electrom...The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.展开更多
In photolithography,shortening the exposure wavelength from ultraviolet to extreme ultraviolet(EUV,13.5 nm)and soft X-ray region in terms of beyond EUV(BEUV,6.X nm)and water window X-ray(WWX,2.2–4.4 nm)is expected to...In photolithography,shortening the exposure wavelength from ultraviolet to extreme ultraviolet(EUV,13.5 nm)and soft X-ray region in terms of beyond EUV(BEUV,6.X nm)and water window X-ray(WWX,2.2–4.4 nm)is expected to further miniaturize the technology node down to sub-5 nm level.However,the absorption ability of molecules in these ranges,especially WWX region,is unknown,which should be very important for the utilization of energy.Herein,the molar absorption cross sections of different elements at 2.4 nm of WWX were firstly calculated and compared with the wavelengths of 13.5 nm and 6.7 nm.Based on the absorption cross sections in these ranges and density estimation results from the density-functional theory calculation,the linear absorption coefficients of typical resist materials,including metal-oxy clusters,organic small molecules,polymers,and photoacid generators(PAGs),are evaluated.The analysis suggests that the Zn cluster has higher absorption in BEUV,whereas the Sn cluster has higher absorption in WWX.Doping PAGs with high EUV absorption atoms improves chemically amplified photoresist(CAR)polymer absorption performance.However,for WWX,it is necessary to introduce an absorption layer containing high WWX absorption elements such as Zr,Sn,and Hf to increase the WWX absorption.展开更多
To minimize the calculation errors in the sound absorption coefficient resulting from inaccurate measurements of flow resistivity,a simple method for determining the sound absorption coefficient of soundabsorbing mate...To minimize the calculation errors in the sound absorption coefficient resulting from inaccurate measurements of flow resistivity,a simple method for determining the sound absorption coefficient of soundabsorbing materials is proposed.Firstly,the sound absorption coefficients of a fibrous sound-absorbing material are measured at two different frequencies using the impedance tube method.Secondly,utilizing the empirical formulas for the wavenumber and acoustic impedance in the fibrous material,the flow resistivity and porosity of the sound-absorbing materials are calculated using the MATLAB cycle program.Thirdly,based on the values obtained through reverse calculations,the sound absorption coefficient,the real and the imaginary parts of the acoustic impedance of the sound-absorbing material at different frequencies are theoretically computed.Finally,the accuracy of these theoretical calculations is verified through experiments.The experimental results indicate that the calculated values are basically consistent with the measured values,demonstrating the feasibility and reliability of this method.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbi...The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.展开更多
Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a ...Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o（λ）], consists of the absorption coefficient of pure water [ACPW, a_w（λ）], plankton [ACP, a_（ph）（λ）], colored scraps [ACCS, a_（d,g）（λ）], and petroleum substance [ACPS, a_（oil）（λ）]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d（λ）] and colored dissolved organic matter [ACCDOM, a_g（λ）]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_（d,g,oil）（λ）]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm（QAA）, with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_（bp）（555）] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g（440）, the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.展开更多
This paper suggests a group of statistical algorithms for calculating the total absorption coefficients based on in situ data of apparent optical property and inherent optical property collected with strict quality as...This paper suggests a group of statistical algorithms for calculating the total absorption coefficients based on in situ data of apparent optical property and inherent optical property collected with strict quality assurance according to NASA ocean bio-optic protocols in the Yellow Sea and the East China Sea in spring 2003. The band-ratios ofRrs412/Rrs555, Rrs49o/Rrs555 are used in the algorithms to derive the total absorption coefficients （at） at 412, 440, 488, 510, 532 and 555nm bands, respectively. The average relative errors between inversed and measured values are less than 25.8%, with the correlative coefficients （R2） being 0.75-0.85. Error sensitivity analysis shows that the maximum retrieval error is less than 24.0% at ＋5% error in Rrs＇s. So the statistical algorithms of this paper are practicable. In this paper, the relations between the total absorption coefficients at 412, 488, 510, 532, 555 nm and that of 440nm are also studied. The results show that the relations between the total absorption coefficients of 400-600 nm and that of 440 nm are correlated well and all of their correlative coefficients R2 are greater than 0.99. Furthermore, a regression analysis is also done for the slope of the linear relations and wavelengths, and the R2 is also 0.99. Thus it is possible to retrieve other bands＇ total absorption coefficients with only one band absorption value, which significantly reduce the number of unknown parameters in studying other ocean color related problems.展开更多
The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of...The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented, showing these features in typical summer and winter seasons. The absorption coefficient aCDOM, aNAp and aphy of colored dissolved organic matter, non-algal particle, and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf. According to the aeDOM distribution at 440 nm, the Changjiang River plume shows an abnormal southeastward transport. An extremely high aNaP value patch at 440 nm is present in the middle coast. The chlorophyll-a-specific phytoplankton pigment absorption （a^hy） is much higher in winter than in summer, which may cause serious underestimated results when applying the averaged aphy into remote-sensing algorithms for chlorophyll concentration retrieval. The importance of phytoplankton size was evident in outer shelf waters. The absorption of aCDOM （440） is a dominant component accounting for over half of the total seawater absorption in summer. The aNAP（440） accounts for 64% of the absorption of the ECS coastal area in winter.展开更多
The temporal and spatial variabilities of phytoplankton absorption coefficients （a ph （λ）） and their relationships with physical processes in the northern South China Sea were examined, based on in situ data coll...The temporal and spatial variabilities of phytoplankton absorption coefficients （a ph （λ）） and their relationships with physical processes in the northern South China Sea were examined, based on in situ data collected from two cruise surveys during May 14 to 25, 2001 and November 2 to 21, 2002. Significant changes in the surface water in a ph values and B/R ratios （a ph （440）/a ph （675）） were observed in May, which were caused by a phytoplankton bloom on the inner shelf stimulated by a large river plume due to heavy precipitation. This is consistent with the observed one order of magnitude elevation of chlorophyll a and a shift from a pico/nano dominated phytoplankton community to one dominated by micro-algae. Enhanced vertical mixing due to strengthened northeast monsoon in November has been observed to result in higher surface a ph （675） （0.002–0.006 m-1 higher） and less pronounced subsurface maximum on the outer shelf/slope in November as compared with that in May. Measurements of a ph and B/R ratios from three transects in November revealed a highest surface a ph （675） immediately outside the mouth of the Zhujiang （Pearl） River Estuary, whereas lower a ph （675） and higher B/R ratios were featured in the outer shelf/slope waters, demonstrating the respective influence of the Zhujiang River plume and the oligotrophic water of the South China Sea. The difference in spectral shapes of phytoplankton absorption （measured by B/R ratios and bathochromic shifts） on these three transects infers that picoprocaryotes are the major component of the phytoplankton community on the outer shelf/slope rather than on the inner shelf. A regional tuning of the phytoplankton absorption spectral model （Carder et al., 1999） was attempted, demonstrating a greater spatial variation than temporal variation in the lead parameter a 0 （λ）. It was thus implicated that region-based parameterization of ocean color remote sensing algorithms in the northern South China Sea was mandatory.展开更多
Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex. In this paper, we used 77 groups of field data of AOPs （apparent optical properties） and IOPs （inherent optical proper...Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex. In this paper, we used 77 groups of field data of AOPs （apparent optical properties） and IOPs （inherent optical properties） collected in June, August, and September of 2005 in the Bohai Sea, to retrieve the spectral total absorption coefficient a（2） with the quasi-analytical algorithm （QAA）. For QAA implementation, different bands in the region 680-730 nm （in 5 nm intervals） were selected and compared, to determine the optimal band domain of the reference wavelength. On this basis, we proposed a new algorithm （QAA-Com）, a combination of QAA-685 and QAA-715, according to turbidity characterized by a（440）. The percentage difference of model retrievals in the visible domain was between 4.5%-45.1%, in average of 18.8% for a（2）. The QAA model was then applied to Medium Resolution Imaging Spectrometer （MERIS） radiometric products, which were temporally and spatially matched with in-situ optical measurements. Differences between MERIS retrievals and in-situ values were in the range 9.2%-27.8% for a（2） in the visible domain. Major errors in satellite retrieval are attributable to uncertainties of QAA model parameters and in-situ measurements, as well as imperfect atmospheric correction of MERIS data by the European Space Agency （ESA）. During a storm surge in April 2009, time series of MERIS images together with the QAA model were used to analyze spatial and temporal variability of the total absorption coefficient pattern in the Bohai Sea. It is necessary to collect more independent field data to improve this algorithm.展开更多
The monochromatic absorption coefficient of silicon, inducing the light penetration depth into the base of the solar cell, is used to determine the optimum thickness necessary for the production of a large photocurren...The monochromatic absorption coefficient of silicon, inducing the light penetration depth into the base of the solar cell, is used to determine the optimum thickness necessary for the production of a large photocurrent. The absorption-generation-diffusion and recombination (bulk and surface) phenomena are taken into account in the excess minority carrier continuity equation. The solution of this equation gives the photocurrent according to ab</span><span style="font-family:Verdana;">sorption and electronic parameters. Then from the obtained short circuit</span><span style="font-family:Verdana;"> photocurrent expression, excess minority carrier back surface recombination velocity is determined, function of the monochromatic absorption coefficient at a given wavelength. This latter plotted versus base thickness yields the optimum thickness of an n</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-p-p</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;"> solar cell, for each wavelength, which is in the range close to the energy band gap of the silicon material. This study provides a tool for improvement solar cell manufacture processes, through the mathematical relationship obtained from the thickness limit according to the absorption coefficient that allows base width optimization.展开更多
Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile so...Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile solvents such as aromatic hydrocarbons. The present work evaluates the CO mass transfer rates from the gas phase to the ionic liquid solutions in the absence of chemical reaction. To that end, carbon dioxide was employed as an inert model gas and absorption experiments were performed to assess the influence of different process variables in a batch reactor with fiat gas-liquid interface. The experimental mass transfer coefficients showed significant var- iation with temperature, （3.4-10.9） × 10^-7 m·s^-1 between 293 and 313 K; stirring speed, （10.2- 33.1）× 10^-7 m.s 1 between 100 and 300 r·min^-1; and concentration of copper（1）, （6.6-10.2） × 10^-7 m·s^-1 between 0.25 and 2 mol· L^- 1. In addition, the mass transfer coefficients were eventually found to follow a poten- tial proportionality of the type kL ∝μ^-0.5 and the dimensionless correlation that makes the estimation of the mass transfer coefficients possible in the studied range of process variables was obtained： Sh=10^-2.64 Re^1.07 , Sc^0.75,These results constitute the first step in the kinetic analysis of the reaction between CO and imidazolium chlorocuprate（I） ionic liquid that determines the design of the separation units.展开更多
For acoustic applications such as theaters, cinema halls, auditoriums the data on acoustic properties i.e. sound absorption coefficient and sound transmission loss are required to evaluate the acoustic behavior of pan...For acoustic applications such as theaters, cinema halls, auditoriums the data on acoustic properties i.e. sound absorption coefficient and sound transmission loss are required to evaluate the acoustic behavior of panel products and to facilitate the necessary design computations. Fibre boards are widely used in private and commercial buildings, but not much data are available on acoustic efficiency of fibre boards. The study was carried using acoustic pulse tester based on standing wave method for evaluating sound absorption coefficient. Wood fibre boards of different densities ranging from 200 to 800 kg/m3 were taken and their sound absorption coefficients at frequencies ranging from 125 Hz to 4000 Hz were evaluated in third octave band. Noise reduction coefficient of the samples was also computed. From the study, it is observed that low density fibre board possess high sound absorption coefficient and noise reduction coefficient when compared with high density fibre boards. It was seen that sound absorption coefficient increases with decrease in density and vice versa.展开更多
For physical ozone absorption without reaction,two parametric estimation methods,i.e.the common linear least square fitting and non-linear Simplex search methods,were applied,respectively,to determine the ozone mass t...For physical ozone absorption without reaction,two parametric estimation methods,i.e.the common linear least square fitting and non-linear Simplex search methods,were applied,respectively,to determine the ozone mass transfer coefficient during absorption and both methods give almost the same mass transfer coefficient.While for chemical absorption with ozone decomposition reaction,the common linear least square fitting method is not applicable for the evaluation of ozone mass transfer coefficient due to the difficulty of model linearization for describing ozone concentration dissolved in water.The nonlinear Simplex method obtains the mass transfer coefficient by minimizing the sum of the differences between the simulated and experimental ozone concentration during the whole absorption process,without the limitation of linear relationship between the dissolved ozone concentration and absorption time during the initial stage of absorption.Comparison of the ozone concentration profiles between the simulation and experimental data demonstrates that Simplex method may determine ozone mass transfer coefficient during absorption in an accurate and high efficiency way with wide applicability.展开更多
As a reentry vehicle traveling through atmosphere with a very high Mach number, the ultraviolet, visible light and infrared signatures, produced from its head shock-wave layer and wake, are the foundation of detecting...As a reentry vehicle traveling through atmosphere with a very high Mach number, the ultraviolet, visible light and infrared signatures, produced from its head shock-wave layer and wake, are the foundation of detecting and identifying for the ground monitoring and the antimissile controlling and guiding system. At the same time, the gas layer radiation is also an important source of heating flux to the wall. The absorption coefficients of high temperature gas in the head shock-wave layer are basic parameters for calculations of the target ultraviolet, visible light and infrared optical characteristics, the heat shield and the aerodynamic flow-field coupling with thermal radiation. In this paper, after the thermo-chemical non-equilibrium phenomenon of hypersonic rarefied flow during reentry stage is discussed, a three-temperature model (electronic temperature Te, vibrational temperature TV and rotational-transitional temperature TR) is used to characterize energy levels population of non-equilibrium air species in the shock-wave layer and the contribution of 11-species such as N2, N2+, N, N+, O2, O2+, O, O+, NO, NO+ and e- is directly calculated by using the atomic and molecular radiation theory. At last, a model is established, which calculates the absorption coefficient of high-temperature equilibrium or non-equilibrium air. The results are in good agreement with experimentally measured data in the visible region, but are slightly bad in the ultraviolet and infrared regions.展开更多
CO_(2)capture with a low energy consumption is of important application significance for reducing CO_(2)emission.The phase-change absorbent developed in recent years shows its potential for low-energy CO_(2)capture.Th...CO_(2)capture with a low energy consumption is of important application significance for reducing CO_(2)emission.The phase-change absorbent developed in recent years shows its potential for low-energy CO_(2)capture.The unclear phase-splitting rule hinders the efficient development of CO_(2)phase-change absorbents.To predict phase-splitting behaviors of mono/poly-amine-organic solvent-water system with various concentrations,a quasi-activity coefficient was developed based on Debye&Mc Aulay equation and some Density function theory descriptors.Six models based on Debye&Mc Aulay equation were developed with different ion radius,descriptors or poly-amine-CO_(2)products.The phase-splitting boundary was drawn on the model with the best predictability.This quasi-activity coefficient would provide guidance for the phase-splitting systems development,especially for polyamines.展开更多
China’s coastal waters are turbid and the properties of the seabed are complex. This negatively impacts the performance of underwater detection equipment. The properties of sound absorption in turbid water are not we...China’s coastal waters are turbid and the properties of the seabed are complex. This negatively impacts the performance of underwater detection equipment. The properties of sound absorption in turbid water are not well understood. In this paper, the coefficient of sound absorption in turbid water was measured by the reverberation technique. All work was done in a reverberation barrel made of seamless aluminum. First, pure water was poured into the reverberation barrel and its reverberation time measured. Next, various concentrations of turbid water were poured into the barrel and their reverberation time measured. After all data had been gathered, the coefficient of sound absorption in turbid water of different concentrations was calculated. From this we determined a law of sound absorption in turbid water as summarized in the paper.展开更多
This paper discusses the principle and mathematical method to measure the phase fractions of multiphase flows by using a dual-energy gamma-ray system. The dual-energy gamma-ray device is composed of radioactive isotop...This paper discusses the principle and mathematical method to measure the phase fractions of multiphase flows by using a dual-energy gamma-ray system. The dual-energy gamma-ray device is composed of radioactive isotopes of 241Am and 137Cs with emission energies of 59.5 keV and 662 keV respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The statistical error has been analyzed on the basis of the accurate absorption coefficient which enables determination phrase fractions almost independent of the flow regime. Improvement has been achieved on the measurement accuracy of phase fractions.展开更多
The band structures of rectangular GaN/AlGaN quantum wires are modeled by using a parabolic effective-mass theory. The absorption coefficients are calculated in a contact-density matrix approach based on the band stru...The band structures of rectangular GaN/AlGaN quantum wires are modeled by using a parabolic effective-mass theory. The absorption coefficients are calculated in a contact-density matrix approach based on the band structure. The results obtained indicate that the peak absorption coefficients augment with the increase of the injected carrier density, and the optical gain caused by interband transition is polarization anisotropic. For the photon energy near 1.55 eV, we can obtain relatively large peak gain. The calculations support the previous results published in the recent literature.展开更多
The absorption coefficient of magnesium-doped near-stoichiometric lithium niobate crystal is measured by terahertz time-domain spectroscopy in a frequency range of 0.2 THz^0.9 THz at room temperature. The absorption c...The absorption coefficient of magnesium-doped near-stoichiometric lithium niobate crystal is measured by terahertz time-domain spectroscopy in a frequency range of 0.2 THz^0.9 THz at room temperature. The absorption coefficient is modulated by external optical pump fields. Experimental results show that the absorption coefficient of near-SLN：Mg crystal is approximately in a range of 22 cm- 1_35 cm- 1 in a frequency range of 0.2 THz-0.9 THz and tunable up to nearly 15%. Further theoretical analysis reveals that the variation of absorption coefficient is related to the number of light-induced carriers, domain reversal process, and OH- absorption in this crystal.展开更多
基金support for this work by Key Research and Development Project of Henan Province(Grant.No.241111232300)the National Natural Science Foundation of China(Grant.No.52273085 and 52303113)the Open Fund of Yaoshan Laboratory(Grant.No.2024003).
文摘The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.
基金supported by the National Natural Science Foundation of China(22090011,22378052)the Fundamental Research Funds for China Central Universities(DUT22LAB608 and DUT20RC(3)030)+1 种基金Liaoning Binhai Laboratory(LBLB-2023-03)Key R&D Program of Shandong Province(2021CXGC010308).
文摘In photolithography,shortening the exposure wavelength from ultraviolet to extreme ultraviolet(EUV,13.5 nm)and soft X-ray region in terms of beyond EUV(BEUV,6.X nm)and water window X-ray(WWX,2.2–4.4 nm)is expected to further miniaturize the technology node down to sub-5 nm level.However,the absorption ability of molecules in these ranges,especially WWX region,is unknown,which should be very important for the utilization of energy.Herein,the molar absorption cross sections of different elements at 2.4 nm of WWX were firstly calculated and compared with the wavelengths of 13.5 nm and 6.7 nm.Based on the absorption cross sections in these ranges and density estimation results from the density-functional theory calculation,the linear absorption coefficients of typical resist materials,including metal-oxy clusters,organic small molecules,polymers,and photoacid generators(PAGs),are evaluated.The analysis suggests that the Zn cluster has higher absorption in BEUV,whereas the Sn cluster has higher absorption in WWX.Doping PAGs with high EUV absorption atoms improves chemically amplified photoresist(CAR)polymer absorption performance.However,for WWX,it is necessary to introduce an absorption layer containing high WWX absorption elements such as Zr,Sn,and Hf to increase the WWX absorption.
基金National Natural Science Foundation of China(No.51705545)。
文摘To minimize the calculation errors in the sound absorption coefficient resulting from inaccurate measurements of flow resistivity,a simple method for determining the sound absorption coefficient of soundabsorbing materials is proposed.Firstly,the sound absorption coefficients of a fibrous sound-absorbing material are measured at two different frequencies using the impedance tube method.Secondly,utilizing the empirical formulas for the wavenumber and acoustic impedance in the fibrous material,the flow resistivity and porosity of the sound-absorbing materials are calculated using the MATLAB cycle program.Thirdly,based on the values obtained through reverse calculations,the sound absorption coefficient,the real and the imaginary parts of the acoustic impedance of the sound-absorbing material at different frequencies are theoretically computed.Finally,the accuracy of these theoretical calculations is verified through experiments.The experimental results indicate that the calculated values are basically consistent with the measured values,demonstrating the feasibility and reliability of this method.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金supported by the National Natural Science Foundation of China(No.52436008)the Inner Mongolia Science and Technology Projects,China(Nos.JMRHZX20210003 and 2023YFCY0009)+3 种基金the Huaneng Group Co Ltd.,China(No.HNKJ23-H50)the National Natural Science Foundation of China(No.22408044)the China Postdoctoral Science Foundation(No.2024M761877)the National Key R&D Program of China(No.SQ2024YFD2200039)。
文摘The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.
基金The National Natural Science Foundation of China under contract No.41271364the Key Projects in the National Science and Technology Pillar Program of China under contract No.2012BAH32B01-4the Program for Scientific Research Start-up Funds of Guangdong Ocean University under contract No.E16187
文摘Establishing the remote sensing algorithm of retrieving the absorption coefficient of seawater petroleum substances is an efficient way to improve the accuracy of retrieving a seawater petroleum concentration using a remote sensing technology. A remote sensing reflectance is a basic physical parameter in water color remote sensing. Apply it to directly retrieve the absorption coefficient of seawater petroleum substances is of potential advantage. The absorption coefficient of waters containing petroleum [ACWCP, a_o（λ）], consists of the absorption coefficient of pure water [ACPW, a_w（λ）], plankton [ACP, a_（ph）（λ）], colored scraps [ACCS, a_（d,g）（λ）], and petroleum substance [ACPS, a_（oil）（λ）]. Among those, ACCS consists of the absorption coefficient of nonalgal particle [ACNP, a_d（λ）] and colored dissolved organic matter [ACCDOM, a_g（λ）]. For waters containing petroleum, the retrieved ACCS using the existing method is a combination absorption coefficient of ACNP,ACCDOM and ACPA [CAC, a_（d,g,oil）（λ）]. Therefore, the principle question is how to extract ACPS from CAC.Through the analysis of the three proportion tests conducted between the year of 2013 and 2015 and the corresponding remote sensing data, an algorithm of retrieving the absorption coefficient of petroleum substances is proposed based on remote sensing reflectance. First of all, ACPS and CAC are retrieved from the reflectance using the quasi-analytical algorithm（QAA）, with some parameter modified. Secondly, given the fact that the backscatter coefficient [BC, b_（bp）（555）] of total particles at 555 nm can be obtained completely from the reflectance, the relation between BC and ACNP in petroleum contaminated water can be established. As a result, ACNP can be calculated. Then, combining the remote sensing retrieving algorithm of a_g（440）, the method of achieving the spectral slope of the absorption coefficient can be established, from which ACCDOM,can be calculated. Finally, ACPS can be computed as the residual. The accuracy of ACPS based on this algorithm is 86% compared with the in situ measurements.
基金Supported by the Subsystem of Calibration and Validation, HY-1 Ground Application System, National Satellite Ocean Application Ser-vice (NSOAS). China High-Tech "863" Project (Nos. 2001AA636010, 2002AA639160 and 2002AA639200). The Ocean Science Fund Sponsor Project for the Youth, State Oceanic Administration (No. 2005415). The Director’s Science and Technology Fund Sponsor Project for the Youth, NSOAS.
文摘This paper suggests a group of statistical algorithms for calculating the total absorption coefficients based on in situ data of apparent optical property and inherent optical property collected with strict quality assurance according to NASA ocean bio-optic protocols in the Yellow Sea and the East China Sea in spring 2003. The band-ratios ofRrs412/Rrs555, Rrs49o/Rrs555 are used in the algorithms to derive the total absorption coefficients （at） at 412, 440, 488, 510, 532 and 555nm bands, respectively. The average relative errors between inversed and measured values are less than 25.8%, with the correlative coefficients （R2） being 0.75-0.85. Error sensitivity analysis shows that the maximum retrieval error is less than 24.0% at ＋5% error in Rrs＇s. So the statistical algorithms of this paper are practicable. In this paper, the relations between the total absorption coefficients at 412, 488, 510, 532, 555 nm and that of 440nm are also studied. The results show that the relations between the total absorption coefficients of 400-600 nm and that of 440 nm are correlated well and all of their correlative coefficients R2 are greater than 0.99. Furthermore, a regression analysis is also done for the slope of the linear relations and wavelengths, and the R2 is also 0.99. Thus it is possible to retrieve other bands＇ total absorption coefficients with only one band absorption value, which significantly reduce the number of unknown parameters in studying other ocean color related problems.
基金The National Basic Research Program ("973" Program) of China under contract No.2009CB421202the National Natural Science Foundation of China under contract Nos 40976110 and 40706061the National High Technology Research and Development Program ("863" Program) of China under contract No.2008AA09Z104
文摘The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented, showing these features in typical summer and winter seasons. The absorption coefficient aCDOM, aNAp and aphy of colored dissolved organic matter, non-algal particle, and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf. According to the aeDOM distribution at 440 nm, the Changjiang River plume shows an abnormal southeastward transport. An extremely high aNaP value patch at 440 nm is present in the middle coast. The chlorophyll-a-specific phytoplankton pigment absorption （a^hy） is much higher in winter than in summer, which may cause serious underestimated results when applying the averaged aphy into remote-sensing algorithms for chlorophyll concentration retrieval. The importance of phytoplankton size was evident in outer shelf waters. The absorption of aCDOM （440） is a dominant component accounting for over half of the total seawater absorption in summer. The aNAP（440） accounts for 64% of the absorption of the ECS coastal area in winter.
基金The National Basic Research Program of China under contract Nos 2009CB421200, 2009CB421201the National Natural Science Foundation of China under contract No40821063High-Tech R&D Program of China under contract Nos2006AA09A302 and 2008AA09Z108
文摘The temporal and spatial variabilities of phytoplankton absorption coefficients （a ph （λ）） and their relationships with physical processes in the northern South China Sea were examined, based on in situ data collected from two cruise surveys during May 14 to 25, 2001 and November 2 to 21, 2002. Significant changes in the surface water in a ph values and B/R ratios （a ph （440）/a ph （675）） were observed in May, which were caused by a phytoplankton bloom on the inner shelf stimulated by a large river plume due to heavy precipitation. This is consistent with the observed one order of magnitude elevation of chlorophyll a and a shift from a pico/nano dominated phytoplankton community to one dominated by micro-algae. Enhanced vertical mixing due to strengthened northeast monsoon in November has been observed to result in higher surface a ph （675） （0.002–0.006 m-1 higher） and less pronounced subsurface maximum on the outer shelf/slope in November as compared with that in May. Measurements of a ph and B/R ratios from three transects in November revealed a highest surface a ph （675） immediately outside the mouth of the Zhujiang （Pearl） River Estuary, whereas lower a ph （675） and higher B/R ratios were featured in the outer shelf/slope waters, demonstrating the respective influence of the Zhujiang River plume and the oligotrophic water of the South China Sea. The difference in spectral shapes of phytoplankton absorption （measured by B/R ratios and bathochromic shifts） on these three transects infers that picoprocaryotes are the major component of the phytoplankton community on the outer shelf/slope rather than on the inner shelf. A regional tuning of the phytoplankton absorption spectral model （Carder et al., 1999） was attempted, demonstrating a greater spatial variation than temporal variation in the lead parameter a 0 （λ）. It was thus implicated that region-based parameterization of ocean color remote sensing algorithms in the northern South China Sea was mandatory.
基金Supported by the National Natural Science Foundation of China(Nos. 60802089,40801176,40706060)the National High Technology Research and Development Program of China(863 Program)(No. 2007AA092102)
文摘Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex. In this paper, we used 77 groups of field data of AOPs （apparent optical properties） and IOPs （inherent optical properties） collected in June, August, and September of 2005 in the Bohai Sea, to retrieve the spectral total absorption coefficient a（2） with the quasi-analytical algorithm （QAA）. For QAA implementation, different bands in the region 680-730 nm （in 5 nm intervals） were selected and compared, to determine the optimal band domain of the reference wavelength. On this basis, we proposed a new algorithm （QAA-Com）, a combination of QAA-685 and QAA-715, according to turbidity characterized by a（440）. The percentage difference of model retrievals in the visible domain was between 4.5%-45.1%, in average of 18.8% for a（2）. The QAA model was then applied to Medium Resolution Imaging Spectrometer （MERIS） radiometric products, which were temporally and spatially matched with in-situ optical measurements. Differences between MERIS retrievals and in-situ values were in the range 9.2%-27.8% for a（2） in the visible domain. Major errors in satellite retrieval are attributable to uncertainties of QAA model parameters and in-situ measurements, as well as imperfect atmospheric correction of MERIS data by the European Space Agency （ESA）. During a storm surge in April 2009, time series of MERIS images together with the QAA model were used to analyze spatial and temporal variability of the total absorption coefficient pattern in the Bohai Sea. It is necessary to collect more independent field data to improve this algorithm.
文摘The monochromatic absorption coefficient of silicon, inducing the light penetration depth into the base of the solar cell, is used to determine the optimum thickness necessary for the production of a large photocurrent. The absorption-generation-diffusion and recombination (bulk and surface) phenomena are taken into account in the excess minority carrier continuity equation. The solution of this equation gives the photocurrent according to ab</span><span style="font-family:Verdana;">sorption and electronic parameters. Then from the obtained short circuit</span><span style="font-family:Verdana;"> photocurrent expression, excess minority carrier back surface recombination velocity is determined, function of the monochromatic absorption coefficient at a given wavelength. This latter plotted versus base thickness yields the optimum thickness of an n</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-p-p</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;"> solar cell, for each wavelength, which is in the range close to the energy band gap of the silicon material. This study provides a tool for improvement solar cell manufacture processes, through the mathematical relationship obtained from the thickness limit according to the absorption coefficient that allows base width optimization.
基金the projects ENE2010-15585 and CTQ2012-31639the FPI postgraduate research grant(BES-2011-046279)
文摘Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile solvents such as aromatic hydrocarbons. The present work evaluates the CO mass transfer rates from the gas phase to the ionic liquid solutions in the absence of chemical reaction. To that end, carbon dioxide was employed as an inert model gas and absorption experiments were performed to assess the influence of different process variables in a batch reactor with fiat gas-liquid interface. The experimental mass transfer coefficients showed significant var- iation with temperature, （3.4-10.9） × 10^-7 m·s^-1 between 293 and 313 K; stirring speed, （10.2- 33.1）× 10^-7 m.s 1 between 100 and 300 r·min^-1; and concentration of copper（1）, （6.6-10.2） × 10^-7 m·s^-1 between 0.25 and 2 mol· L^- 1. In addition, the mass transfer coefficients were eventually found to follow a poten- tial proportionality of the type kL ∝μ^-0.5 and the dimensionless correlation that makes the estimation of the mass transfer coefficients possible in the studied range of process variables was obtained： Sh=10^-2.64 Re^1.07 , Sc^0.75,These results constitute the first step in the kinetic analysis of the reaction between CO and imidazolium chlorocuprate（I） ionic liquid that determines the design of the separation units.
文摘For acoustic applications such as theaters, cinema halls, auditoriums the data on acoustic properties i.e. sound absorption coefficient and sound transmission loss are required to evaluate the acoustic behavior of panel products and to facilitate the necessary design computations. Fibre boards are widely used in private and commercial buildings, but not much data are available on acoustic efficiency of fibre boards. The study was carried using acoustic pulse tester based on standing wave method for evaluating sound absorption coefficient. Wood fibre boards of different densities ranging from 200 to 800 kg/m3 were taken and their sound absorption coefficients at frequencies ranging from 125 Hz to 4000 Hz were evaluated in third octave band. Noise reduction coefficient of the samples was also computed. From the study, it is observed that low density fibre board possess high sound absorption coefficient and noise reduction coefficient when compared with high density fibre boards. It was seen that sound absorption coefficient increases with decrease in density and vice versa.
基金Project(2011467001)supported by the Ministry of Environment Protection of ChinaProject(2010DFB94130)supported by the Ministry of Science and Technology of China
文摘For physical ozone absorption without reaction,two parametric estimation methods,i.e.the common linear least square fitting and non-linear Simplex search methods,were applied,respectively,to determine the ozone mass transfer coefficient during absorption and both methods give almost the same mass transfer coefficient.While for chemical absorption with ozone decomposition reaction,the common linear least square fitting method is not applicable for the evaluation of ozone mass transfer coefficient due to the difficulty of model linearization for describing ozone concentration dissolved in water.The nonlinear Simplex method obtains the mass transfer coefficient by minimizing the sum of the differences between the simulated and experimental ozone concentration during the whole absorption process,without the limitation of linear relationship between the dissolved ozone concentration and absorption time during the initial stage of absorption.Comparison of the ozone concentration profiles between the simulation and experimental data demonstrates that Simplex method may determine ozone mass transfer coefficient during absorption in an accurate and high efficiency way with wide applicability.
基金Chinese N ational Science Fund for Distinguished Young Scholars ( No.5 972 5 6 17) the National Natural Science Foun-dation of China ( No.5 980 6 0 0 3) and F ok Ying Tung Education Foundation ( No.710 5 3)
文摘As a reentry vehicle traveling through atmosphere with a very high Mach number, the ultraviolet, visible light and infrared signatures, produced from its head shock-wave layer and wake, are the foundation of detecting and identifying for the ground monitoring and the antimissile controlling and guiding system. At the same time, the gas layer radiation is also an important source of heating flux to the wall. The absorption coefficients of high temperature gas in the head shock-wave layer are basic parameters for calculations of the target ultraviolet, visible light and infrared optical characteristics, the heat shield and the aerodynamic flow-field coupling with thermal radiation. In this paper, after the thermo-chemical non-equilibrium phenomenon of hypersonic rarefied flow during reentry stage is discussed, a three-temperature model (electronic temperature Te, vibrational temperature TV and rotational-transitional temperature TR) is used to characterize energy levels population of non-equilibrium air species in the shock-wave layer and the contribution of 11-species such as N2, N2+, N, N+, O2, O2+, O, O+, NO, NO+ and e- is directly calculated by using the atomic and molecular radiation theory. At last, a model is established, which calculates the absorption coefficient of high-temperature equilibrium or non-equilibrium air. The results are in good agreement with experimentally measured data in the visible region, but are slightly bad in the ultraviolet and infrared regions.
基金financial support from National Natural Science Foundation of China(21878190)China Petrochemical Corporation(419033-1)the Engineering Experimental Teaching Center,School of Chemical Engineering,Sichuan University for the Nuclear Magnetic Resonance(NMR,JNM-ECZ400S/L1,JEOL Ltd.)support and the compute server support。
文摘CO_(2)capture with a low energy consumption is of important application significance for reducing CO_(2)emission.The phase-change absorbent developed in recent years shows its potential for low-energy CO_(2)capture.The unclear phase-splitting rule hinders the efficient development of CO_(2)phase-change absorbents.To predict phase-splitting behaviors of mono/poly-amine-organic solvent-water system with various concentrations,a quasi-activity coefficient was developed based on Debye&Mc Aulay equation and some Density function theory descriptors.Six models based on Debye&Mc Aulay equation were developed with different ion radius,descriptors or poly-amine-CO_(2)products.The phase-splitting boundary was drawn on the model with the best predictability.This quasi-activity coefficient would provide guidance for the phase-splitting systems development,especially for polyamines.
文摘China’s coastal waters are turbid and the properties of the seabed are complex. This negatively impacts the performance of underwater detection equipment. The properties of sound absorption in turbid water are not well understood. In this paper, the coefficient of sound absorption in turbid water was measured by the reverberation technique. All work was done in a reverberation barrel made of seamless aluminum. First, pure water was poured into the reverberation barrel and its reverberation time measured. Next, various concentrations of turbid water were poured into the barrel and their reverberation time measured. After all data had been gathered, the coefficient of sound absorption in turbid water of different concentrations was calculated. From this we determined a law of sound absorption in turbid water as summarized in the paper.
文摘This paper discusses the principle and mathematical method to measure the phase fractions of multiphase flows by using a dual-energy gamma-ray system. The dual-energy gamma-ray device is composed of radioactive isotopes of 241Am and 137Cs with emission energies of 59.5 keV and 662 keV respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The statistical error has been analyzed on the basis of the accurate absorption coefficient which enables determination phrase fractions almost independent of the flow regime. Improvement has been achieved on the measurement accuracy of phase fractions.
基金supported by the National High Technology Research and Development Program of China (Grant No. 2009AA03Z405)the National Natural Science Foundation of China (Grant Nos. 60908028,60971068 and 60644004)
文摘The band structures of rectangular GaN/AlGaN quantum wires are modeled by using a parabolic effective-mass theory. The absorption coefficients are calculated in a contact-density matrix approach based on the band structure. The results obtained indicate that the peak absorption coefficients augment with the increase of the injected carrier density, and the optical gain caused by interband transition is polarization anisotropic. For the photon energy near 1.55 eV, we can obtain relatively large peak gain. The calculations support the previous results published in the recent literature.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.10974063,61205096,and 61177095)the Natural Science Foundation of Hubei Province,China (Grant Nos.02-16-230008,2010CDA001,and 2012FFA074)+2 种基金the Research Foundation of Huazhong University of Science and Technology,China (Grant No.01-09-230904)the Ph.D.Program Foundation of Ministry of Education of China (Grant No.20100142110042)the Fundamental Research Funds for the Central Universities,China (Grant Nos.2010MS041 and 2011TS001)
文摘The absorption coefficient of magnesium-doped near-stoichiometric lithium niobate crystal is measured by terahertz time-domain spectroscopy in a frequency range of 0.2 THz^0.9 THz at room temperature. The absorption coefficient is modulated by external optical pump fields. Experimental results show that the absorption coefficient of near-SLN：Mg crystal is approximately in a range of 22 cm- 1_35 cm- 1 in a frequency range of 0.2 THz-0.9 THz and tunable up to nearly 15%. Further theoretical analysis reveals that the variation of absorption coefficient is related to the number of light-induced carriers, domain reversal process, and OH- absorption in this crystal.
