Lamellar globularization in the dual-phase titanium alloy is the key to improving plasticity and strength.However,the mechanism has not been fully elucidated so far.In this work,the role of phase/grain bound-ary in th...Lamellar globularization in the dual-phase titanium alloy is the key to improving plasticity and strength.However,the mechanism has not been fully elucidated so far.In this work,the role of phase/grain bound-ary in the static globularization of TC17 alloy was systematically studied by setting differentαphase con-tent before annealing through low-and high-temperature deformation.Isothermal compression causes the parallel distribution and fragmentation of 3Dαplates and few globularαparticles are formed at a strain rate of 1 s^(-1).Post-deformation annealing promotes the static globularization ofαphase while it is affected by initialαphase content.After 730°C deformation,the development ofα/αinterface by absorbing dislocations promotes the formation of globularαgrains based on the nucleation of sepa-ratedαparticles and pre-recoveryαsubgrain during subsequent annealing.Theα/α/βandα/β/βtriple junctions formed due to highαcontent with about 36%volume fraction are favorable for the further nucleation and growth of globularαgrains by reducing interface energy,forming a 3D irregularαplate.Then nucleation and growth of theβphase dominate the microstructure evolution during subsequent an-nealing,resulting in the local dissolution of the plate and formation ofαrods.After 850°C deformation,theαphase tends to nucleate at theβ/β/βtriple junctions and grow into a lamellar shape along the high energyβ/βgrain boundary due to lowαcontent with about 7%volume fraction.Theαnucleation that maintains the Burgers orientation relationship(BOR)with the surroundingβphase grows along the habit plane and thickens slowly,resulting in the formation of a precipitatedαplate with a flat surface and the suppression of static globularization.The comprehensive investigation of lamellar globularization provides guidance for optimizing the 3D microstructure and properties of dual-phase titanium alloy.展开更多
Microscale metallic structures enhanced by additive manufacturing technology have attracted extensive attention especially in microelectronics and electromechanical devices.Meniscus-confined electrodeposition(MCED)adv...Microscale metallic structures enhanced by additive manufacturing technology have attracted extensive attention especially in microelectronics and electromechanical devices.Meniscus-confined electrodeposition(MCED)advances microscale 3D metal printing,enabling simpler fabrication of superior metallic microstructures in air without complex equipment or post-processing.However,accurately predicting growth rates with current MCED techniques remain challenging,which is essential for precise structure fabrication and preventing nozzle clogging.In this work,we present a novel approach to electrochemical 3D printing that utilizes a self-adjusting,voxelated method for fabricating metallic microstructures.Diverging from conventional voxelated printing which focuses on monitoring voxel thickness for structure control,this technique adopts a holistic strategy.It ensures each voxel’s position is in alignment with the final structure by synchronizing the micropipette’s trajectory during deposition with the intended design,thus facilitating self-regulation of voxel position and reducing errors associated with environmental fluctuations in deposition parameters.The method’s ability to print micropillars with various tilt angles,high density,and helical arrays demonstrates its refined control over the deposition process.Transmission electron microscopy analysis reveals that the deposited structures,which are fabricated through layer-by-layer(voxel)printing,contain nanotwins that are widely known to enhance the material’s mechanical and electrical properties.Correspondingly,in situ scanning electron microscopy(SEM)microcompression tests confirm this enhancement,showing these structures exhibit a compressive yield strength exceeding 1 GPa.The indentation tests provided an average hardness of 3.71 GPa,which is the highest value reported in previous work using MCED.The resistivity measured by the four-point probe method was(1.95±0.01)×10^(−7)Ω·m,nearly 11 times that of bulk copper.These findings demonstrate the considerable advantage of this technique in fabricating complex metallic microstructures with enhanced mechanical properties,making it suitable for advanced applications in microsensors,microelectronics,and micro-electromechanical systems.展开更多
In this paper,we design and fabricate a novel three-dimensional passive-micro-mixer by using Polymethyl methacrylate( PMMA). The mixer is fabricated by using ultra-precision engraving machine and bonded by an organic ...In this paper,we design and fabricate a novel three-dimensional passive-micro-mixer by using Polymethyl methacrylate( PMMA). The mixer is fabricated by using ultra-precision engraving machine and bonded by an organic solvent fumigation bonding method. The mixer combines two fluid streams into a mixing chamber integrated with T-shaped pre-mixing and six tortuous shaped mixing elements. We have employed three-dimensional numerical simulations to evaluate the mixing efficiency. The simulation results indicate,under inlet fluid pressure p = 10( Pa), compared to the planar serpentine mixer and tortuous mixer,the concentration fluctuation range at the outlet diagonal reduce to 48% and 71. 6% respectively. And the mixing concentration variances also show that the mixing efficiency has a significant increase. We characterize the device by using visualization microscope,and the results are consistent with the simulation data. The device demonstrates the promising capabilities for micro total analysis system integration.展开更多
Solid oxide cells(SOCs),capable of interconverting electrical and chemical energy,have emerged as one of the key technologies for the future multi-energy complementary grid.However,the commercialization of SOCs is hin...Solid oxide cells(SOCs),capable of interconverting electrical and chemical energy,have emerged as one of the key technologies for the future multi-energy complementary grid.However,the commercialization of SOCs is hindered by poor long-term stability,attributed in large part to the microstructural evolution of the electrodes,which results in the loss of active reaction sites,blockage of gas transport pathways,and degradation of mechanical properties.Owing to recently developed three-dimensional(3D)microstructure reconstruction techniques,the microstructural evolution of SOC electrodes can now be investigated quantitatively.This review highlights insights gained from studies of the microstructural evolution of porous cermet SOC electrodes during long-term operation and redox cycling,and the corresponding effects on electrochemical and mechanical performance,with particular attention to investigations using 3D reconstruction technologies.The influencing parameters and the possible strategies to mitigate microstructure evolution-induced degradation are also summarized.The challenges and opportunities for the future development of stable and active SOC electrode microstructures are analyzed,and the corresponding prospects for commercial application are provided.展开更多
基金the financial support from the National Key R&D Program of China(Grant No.2022YFB3707201)the Science Fund for Distinguished Young Scholars from Shaanxi Province(No.2020JC-17)+2 种基金NPU AoXiang Distinguished Young Schol-ars(Grant Nos.0604022GH0202143,0604022SH0201143)the Funding of Young Top-notch Talent of the National Ten Thousand Talent Program,the Fundamental Research Funds for the Central Universities(No.3102022gxb004)Science Center for Gas Tur-bine Project(No.P2022-A-IV-001-002)。
文摘Lamellar globularization in the dual-phase titanium alloy is the key to improving plasticity and strength.However,the mechanism has not been fully elucidated so far.In this work,the role of phase/grain bound-ary in the static globularization of TC17 alloy was systematically studied by setting differentαphase con-tent before annealing through low-and high-temperature deformation.Isothermal compression causes the parallel distribution and fragmentation of 3Dαplates and few globularαparticles are formed at a strain rate of 1 s^(-1).Post-deformation annealing promotes the static globularization ofαphase while it is affected by initialαphase content.After 730°C deformation,the development ofα/αinterface by absorbing dislocations promotes the formation of globularαgrains based on the nucleation of sepa-ratedαparticles and pre-recoveryαsubgrain during subsequent annealing.Theα/α/βandα/β/βtriple junctions formed due to highαcontent with about 36%volume fraction are favorable for the further nucleation and growth of globularαgrains by reducing interface energy,forming a 3D irregularαplate.Then nucleation and growth of theβphase dominate the microstructure evolution during subsequent an-nealing,resulting in the local dissolution of the plate and formation ofαrods.After 850°C deformation,theαphase tends to nucleate at theβ/β/βtriple junctions and grow into a lamellar shape along the high energyβ/βgrain boundary due to lowαcontent with about 7%volume fraction.Theαnucleation that maintains the Burgers orientation relationship(BOR)with the surroundingβphase grows along the habit plane and thickens slowly,resulting in the formation of a precipitatedαplate with a flat surface and the suppression of static globularization.The comprehensive investigation of lamellar globularization provides guidance for optimizing the 3D microstructure and properties of dual-phase titanium alloy.
基金supported in part by National Key R&D Program of China under Grant 2023YFB4705600in part by the National Natural Science Foundation of China under Grants 61925304,62127810 and 62203138+1 种基金in part by the National Postdoctoral Program for Innovative Talents under Grant BX20200107in part by the Self-Planned Task(No.SKLRS202205C)of State Key Laboratory of Robotics and System(HIT).
文摘Microscale metallic structures enhanced by additive manufacturing technology have attracted extensive attention especially in microelectronics and electromechanical devices.Meniscus-confined electrodeposition(MCED)advances microscale 3D metal printing,enabling simpler fabrication of superior metallic microstructures in air without complex equipment or post-processing.However,accurately predicting growth rates with current MCED techniques remain challenging,which is essential for precise structure fabrication and preventing nozzle clogging.In this work,we present a novel approach to electrochemical 3D printing that utilizes a self-adjusting,voxelated method for fabricating metallic microstructures.Diverging from conventional voxelated printing which focuses on monitoring voxel thickness for structure control,this technique adopts a holistic strategy.It ensures each voxel’s position is in alignment with the final structure by synchronizing the micropipette’s trajectory during deposition with the intended design,thus facilitating self-regulation of voxel position and reducing errors associated with environmental fluctuations in deposition parameters.The method’s ability to print micropillars with various tilt angles,high density,and helical arrays demonstrates its refined control over the deposition process.Transmission electron microscopy analysis reveals that the deposited structures,which are fabricated through layer-by-layer(voxel)printing,contain nanotwins that are widely known to enhance the material’s mechanical and electrical properties.Correspondingly,in situ scanning electron microscopy(SEM)microcompression tests confirm this enhancement,showing these structures exhibit a compressive yield strength exceeding 1 GPa.The indentation tests provided an average hardness of 3.71 GPa,which is the highest value reported in previous work using MCED.The resistivity measured by the four-point probe method was(1.95±0.01)×10^(−7)Ω·m,nearly 11 times that of bulk copper.These findings demonstrate the considerable advantage of this technique in fabricating complex metallic microstructures with enhanced mechanical properties,making it suitable for advanced applications in microsensors,microelectronics,and micro-electromechanical systems.
基金Sponsored by the Natural Science Foundation of Heilongjiang Province(Grant No.F201007)the Fundamental Research Funds for the Central Universities(Grant No.HIT.NSRIF.2010077)
文摘In this paper,we design and fabricate a novel three-dimensional passive-micro-mixer by using Polymethyl methacrylate( PMMA). The mixer is fabricated by using ultra-precision engraving machine and bonded by an organic solvent fumigation bonding method. The mixer combines two fluid streams into a mixing chamber integrated with T-shaped pre-mixing and six tortuous shaped mixing elements. We have employed three-dimensional numerical simulations to evaluate the mixing efficiency. The simulation results indicate,under inlet fluid pressure p = 10( Pa), compared to the planar serpentine mixer and tortuous mixer,the concentration fluctuation range at the outlet diagonal reduce to 48% and 71. 6% respectively. And the mixing concentration variances also show that the mixing efficiency has a significant increase. We characterize the device by using visualization microscope,and the results are consistent with the simulation data. The device demonstrates the promising capabilities for micro total analysis system integration.
基金funding from National Natural Science Foundation of China,China(52102226,12472173)Guangdong Basic and Applied Basic Research Foundation,China(2023A1515011003,2023A1515010723)+2 种基金Science,Technology and Innovation Commission of Shenzhen Municipality,China(GJHZ20220913143009017,GJHZ20210705141401004)the Talent Recruitment Project of Guangdong Province,China(2019QN01G098)Development and Reform Commission of Shenzhen Municipality,China(XMHT20220103004).
文摘Solid oxide cells(SOCs),capable of interconverting electrical and chemical energy,have emerged as one of the key technologies for the future multi-energy complementary grid.However,the commercialization of SOCs is hindered by poor long-term stability,attributed in large part to the microstructural evolution of the electrodes,which results in the loss of active reaction sites,blockage of gas transport pathways,and degradation of mechanical properties.Owing to recently developed three-dimensional(3D)microstructure reconstruction techniques,the microstructural evolution of SOC electrodes can now be investigated quantitatively.This review highlights insights gained from studies of the microstructural evolution of porous cermet SOC electrodes during long-term operation and redox cycling,and the corresponding effects on electrochemical and mechanical performance,with particular attention to investigations using 3D reconstruction technologies.The influencing parameters and the possible strategies to mitigate microstructure evolution-induced degradation are also summarized.The challenges and opportunities for the future development of stable and active SOC electrode microstructures are analyzed,and the corresponding prospects for commercial application are provided.
