CsPbBr_(3)perovskite solar cells(PSCs)have attracted significant interest for their remarkable stability under high temperatures and humidity.However,challenges such as energy loss at the CsPbBr_(3)/oxide buried inter...CsPbBr_(3)perovskite solar cells(PSCs)have attracted significant interest for their remarkable stability under high temperatures and humidity.However,challenges such as energy loss at the CsPbBr_(3)/oxide buried interface and imperfect band alignment have impeded further efficiency enhancements.In this study,TiO_(2),SnO_(2),or ZnO was employed as electron transport layer(ETL)materials,respectively,in CsPbBr_(3)-based PSCs to optimize the band alignment at the ETL/CsPbBr_(3)interface and enhance the film quality of CsPbBr_(3)materials.The research findings indicate that the power conversion efficiency(PCE)of PSCs is influenced by the choice of ETL material.Specifically,TiO_(2)-based PSCs achieved a PCE of 10.37%efficiency,higher than SnO_(2)-or ZnO-based PSCs.This disparity in PCE can be attributed to variations in open-circuit voltage,which stem from different band alignments at the ETL/CsPbBr_(3)interface.Notably,superior photovoltaic performance was consistently observed in TiO_(2)-based PSCs due to the substantial conduction band offset(∆Ec)at the TiO_(2)/CsPbBr_(3)interface and the high quality of the CsPbBr_(3)film.This not only enhances electron extraction at the TiO_(2)/CsPbBr_(3)interface but also diminishes non-radiative recombination at the interface,as confirmed by density functional theory(DFT)calculations and experiments.Furthermore,photodetectors(PDs)based on TiO_(2)/CsPbBr_(3)heterojunction exhibit high photoresponse and photodetectivity.In conclusion,this study underscores the critical importance of the buried interface contact in CsPbBr_(3)and offers a direct approach for fabricating efficient and stable inorganic PSCs and PDs.展开更多
The 2D/3D heterojunction perovskites have garnered increasing attention due to their exceptional moisture and thermal stability.However,few works have paid attention to the influence of the subsequent change process o...The 2D/3D heterojunction perovskites have garnered increasing attention due to their exceptional moisture and thermal stability.However,few works have paid attention to the influence of the subsequent change process of 2D/3D heterojunction PSC on the stability of PSCs.Moreover,the evolution of the interface and carrier dynamic behavior of the 2D/3D perovskite films with long-term operation has not been systematically developed befo re.In this work,the effects of 2D/3 D heterojunction evolution on the interface of perovskite films and different carrier dynamics during 2D/3D evolution are systematically analyzed for the first time.The decomposition of 2D/3D heterojunction in the perovskite film will have a certain impact on the surface and carrier dynamics behavior of perovskite.During the evolution of 2D/3D heterojunction,PbI_(2)crystals will appear,which will improve the interfacial energy level matching between the electron transport layer and perovskite film.With a long evolution time,some holes will appear on the surface of perovskite film.The open circuit voltage(V_(OC))of PSCs increased from 1.14 to1.18 V and the PCE increased to 23.21%after 300 h storage in the nitrogen atmosphere,and maintained 89%initial performance for with 3000 h stability test in N_(2)box.This discovery has a significant role in promoting the development of inverted heterojunction PSCs and constructing the revolution mechanism of charge carrier dynamic.展开更多
Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic lo...Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic low carrier density of P3 HT and poor contact between the P3HT/perovskite interface always lead to a low performance of the solar cell,while conventional chemical doping always makes the films unstable and limits the scalability.In this work,for the first time,we simultaneously enhanced the hole transporting properties of P3HT film and the interface of perovskite by doping it with a judiciously designed oxidized small molecule organic semiconductor.The organic salt not only can promote the lamellar crystallinity of P3HT to obtain better charge transport properties,but also reduce the defects of perovskite.As a result,we achieved champion efficiencies of 23.0%for small-area solar cells and 18.8%for larger-area modules(48.0 cm^(2)).This efficiency is the highest value for P3HT-based perovskite modules.Moreover,the solar cells show excellent operational stability,retaining over 95%of their initial efficiencies after1200 h of continuous operation.展开更多
Virtual reality(VR)is an emerging communication means and creates extensive opportunities in interacting scenarios such as remote collaboration and metaverse.Human-machine interfaces(HMIs)play important roles in VR as...Virtual reality(VR)is an emerging communication means and creates extensive opportunities in interacting scenarios such as remote collaboration and metaverse.Human-machine interfaces(HMIs)play important roles in VR as they provide interaction platforms between users and virtual environments.However,traditional VR HMIs based on handheld devices or keyboards cannot recognize diverse three-dimensional(3D)gestures,which results in limited freedom of VR interactions.Here,we report a noncontact VR HMI enabled by an electret-nanofiber-based triboelectric sensor(ETS),which is fabricated by the electrospun polylactic acid/thermoplastic polyurethane(PLA/TPU)electret nanofiber film.The nanofiber structure of PLA/TPU electret enhanced the charge retention ability of triboelectric sensor and thus significantly improved its signal strength and stability.Integrated with a deep learning-based multilayer perceptron neural network,the ETS realizes the recognition of 18 different types of 3D gestures with a high average accuracy of 97.3%.An intelligent noncontact VR interactive system based on the ETS is further developed,which is used to manipulate game characters for performing different actions by 3D gestures.Compared with traditional VR HMIs,the proposed VR HMI based on PLA/TPU electret nanofiber film can detect various 3D gestures and offers a superior interaction freedom.This work for the first time introduces the triboelectric 3D gesture recognition method to the VR HMIs,and could make the interaction between human and virtual environments become more efficient and fascinating.展开更多
Metal-ceramic composites combine the excellent properties of metals and ceramics,which have high strength,stability,and corrosion re-sistance.Al_(2)O_(3)/FeCo composites have been proven to be useful in ap-plications ...Metal-ceramic composites combine the excellent properties of metals and ceramics,which have high strength,stability,and corrosion re-sistance.Al_(2)O_(3)/FeCo composites have been proven to be useful in ap-plications such as catalysts,mi-crowave absorption materials,and enhanced permeability dielectric.The understanding of the mechani-cal properties and dynamics at the atomic scale of the Al_(2)O_(3)/FeCo in-terface can promote the design and exploitment of metal-ceramic composites.In this work,we have obtained Young’s modulus and diffusion coefficient of the Al_(2)O_(3)/FeCo interface using molecular dynamics simulation,elucidated the structural characteristics of the Al_(2)O_(3)/FeCo interface at the atomic scale,and investigated the impact of atomic magnetism and the exter-nal magnetic field on the interface.Simulated results show that Young’s modulus of the Al_(2)O_(3)/FeCo interface is significantly improved compared with pure Al_(2)O_(3)and FeCo alloy at room and high temperatures.When the atomic magnetism and the external magnetic field are applied,Young’s modulus of the Al_(2)O_(3)/FeCo interface further increases to 612 GPa at 300 K and 602 GPa at 500 K.Moreover,the average density,diffusion coefficient,and radial distri-bution function are found to be modified substantially.This study will shed light on the atom-istic investigations of the metal-ceramic composites.展开更多
The interaction of MgO-MgAl_(2)O_(4)-based and MgO-Cr_(2)O_(3)-based refractories with X70 molten steel was studied by immersion experiments at 1560℃.The effects of immersion time(30 and 60 min)on the contents of tot...The interaction of MgO-MgAl_(2)O_(4)-based and MgO-Cr_(2)O_(3)-based refractories with X70 molten steel was studied by immersion experiments at 1560℃.The effects of immersion time(30 and 60 min)on the contents of total oxygen(TO),Al,Nb,Si,Mn,and Cr as well as the composition,number density,and size distribution of inclusions in the molten steel were investigated.The influence of the penetration and erosion degree of the molten steel to the refractory on the steel-refractory interface layer was analyzed.The results show that,at 1560℃,the MgO-MgAl_(2)O_(4)-based refractory can better control the contents of TO and the composition of molten steel compared with the MgO-Cr_(2)O_(3)-based refractory.The TO content is only 16×10^(-4) wt.%in the molten steel after reacted with the Mg0-MgAl_(2)O_(4)-based refractory at the end point of refining,4 accounting for 11.5%of that reacted with the MgO-Cr_(2)O_(3)-based refractory(139×10^(-4) wt.%).The number density of inclusions is only 14 mm^(-2),and the average size ofinclusions is only 1.31μm,with thelargest proportion of inclusions in 1-2μm(70%).The Al_(2)O_(3)-MnS-CaO complex inclusions in the original steel changed to complex inclusions dominated by Cr-Nb-Mn-S-O and MgO.Al_(2)O_(3),corresponding to the MgO-Cr_(2)O_(3)-based and MgO-MgAl_(2)O_(4)-based refractories,respectively.The MgO.Al_(2)O_(3) layer was formed at the reaction interface between MgO-MgAl_(2)O_(4)-based refractory and molten steel,which is helpful to restrict the erosion of refractories and the pollution of molten steel.The damage mechanism of the MgO-Cr_(2)O_(3)-based refractory is mainly permeation and chemical reaction,while the damage of the MgO-MgAl_(2)O_(4)-based refractory is mainlyscouring erosion.展开更多
The shear characteristics of the interface formed between a cemented tailings backfill(CTB)and surrounding rocks play a cru-cial role in the design and stability of underground goafs.To investigate the shear behavior ...The shear characteristics of the interface formed between a cemented tailings backfill(CTB)and surrounding rocks play a cru-cial role in the design and stability of underground goafs.To investigate the shear behavior of CTB-rock interfaces,rock samples repres-enting the topography of surrounding rocks were constructed using 3D morphology scanning and engraving techniques.A series of direct shear tests were conducted on the CTB rock samples to examine the influence of the cement-tailings ratio on the interfacial shear behavi-or.The results showed that the compressive strength of the CTB and shear strength of the CTB-rock interface decreased with decreasing cement proportion.With deceasing cement content,the failure area of the CTB after the test increased,and the roughness of the newly generated interface reduced.A digital image correlation analysis revealed that the compressive stress concentration in the region with an obtuse angle with respect to the shear direction was the primary cause of CTB failure.Moreover,the correlation between the wear area and the silicon-dense area helped confirm that the silicon particles are more prone to failure in these areas than in other regions.Our find-ings provide new insights into the shear sliding mechanism at CTB-rock interfaces and can aid in the selection of the cement-tailings ra-tio at engineering sites.For example,if the horizontal principal stress of the surrounding rock mass in a backfilling area is relatively high,the cement content can be reduced for CTB applications.展开更多
Accurate water level measurement in nuclear reactors,particularly in PWRs(pressurized water reactors)and BWRs(boiling water reactors),is essential for ensuring the safety and efficiency of reactor operations.K-type HJ...Accurate water level measurement in nuclear reactors,particularly in PWRs(pressurized water reactors)and BWRs(boiling water reactors),is essential for ensuring the safety and efficiency of reactor operations.K-type HJTCs(heated junction thermocouples)are widely used for this purpose due to their ability to withstand extreme temperatures and radiation conditions.This article explores the role of HJTCs in reactor water level measurement and compares the performance of 2-wire and 3-wire connections.While the 2-wire connection is simple and cost-effective,it can introduce measurement inaccuracies due to wire resistance.In contrast,the 3-wire connection compensates for lead resistance,offering more precise and reliable measurements,particularly in long-distance applications.This paper discusses the operational considerations of these wiring configurations in the context of nuclear reactors and highlights the importance of choosing the appropriate connection type to optimize safety and measurement accuracy in PWR and BWR reactors.展开更多
The functions,applications,developments and current application mode of IDS3.x system are generally introduced in this paper.Then the development mode of spacecraft based on IDS3.x system is described.The existing pro...The functions,applications,developments and current application mode of IDS3.x system are generally introduced in this paper.Then the development mode of spacecraft based on IDS3.x system is described.The existing problems especially the information redundancy of mechanical interface and their effects are pointed out.A new solution is proposed by developing 3D-IDS system.The central functions of 3D-IDS system are shown in this study.A new application mode of 3D-IDS system is explored and described by showing how to fill in,countersign and apply with 3D-IDS file.The 2D drawing and sketch are removed from 3D-IDS system to avoid information redundancy of mechanical interface.The consistency between 3D model and the parameters of IDS file can be guaranteed by the interface tool.The efficiency of filling in,countersigning and applying,has been improved significantly,which greatly promotes the coordination and total efficiency of spacecraft system design departments and unit design departments.展开更多
Lithium-carbon dioxide(Li-CO_(2))batteries with high theoretical energy density are regarded as promising energy storage system toward carbon neutrality.However,bidirectional catalysts design for improving the sluggis...Lithium-carbon dioxide(Li-CO_(2))batteries with high theoretical energy density are regarded as promising energy storage system toward carbon neutrality.However,bidirectional catalysts design for improving the sluggish CO_(2)reduction reaction(CO_(2)RR)/CO_(2)evolution reaction(CO_(2)ER)kinetics remains a huge challenge.In this work,an advanced catalyst with fast-interfacial charge transfer was subtly synthesized through element segregation,which significantly improves the electrocatalytic activity for both CO_(2)RR and CO_(2)ER.Theoretical calculations and characterization analysis demonstrate local charge redistribution at the constructed interface,which leads to optimized binding affinity towards reactants and preferred Li_(2)CO_(3)decomposition behavior,enabling excellent catalytic activity during CO_(2)redox.Benefiting from the enhanced charge transfer ability,the designed highly efficient catalyst with dual active centers and large exposed catalytic area can maintain an ultra-small voltage gap of 0.33 V and high energy efficiency of 90.2%.This work provides an attractive strategy to construct robust catalysts by interface engineering,which could inspire further design of superior bidirectional catalysts for Li-CO_(2)batteries.展开更多
Sodium(Na)metal batteries have gained increasing attention more recently,owing to their high energy densities and cost efficiencies,but are severely handicapped by the unsatisfactory Coulombic efficiency(CE)and cyclin...Sodium(Na)metal batteries have gained increasing attention more recently,owing to their high energy densities and cost efficiencies,but are severely handicapped by the unsatisfactory Coulombic efficiency(CE)and cycling stability stemming from dendrite growth on Na anodes.In this study,we developed a strategy of direct ink writing(DIW)3D printing combined with electroless deposition to construct a hierarchical Cu grid coated with a dense nanoscale Ag interfacial layer as the host material for Na plating.The sodiophilic Ag interface contributes to a fall in the Na nucleation energy,hence enabling uniform Na deposition on each 3D-printed filament.The constructed 3D-printed structure can effectively moderate the electric-field distribution and lower the local current density for relieving Na inhomogeneous growth,as confirmed by finite element simulation and Na plating/stripping morphology evolution results.In particular,the unique 3D structure also promotes the lateral growth of Na,thus the volume change of Na metal was accommodated to stabilize the solid electrolyte interphase(SEI).As a result,the CE of the half-cell can reach 99.9%at the current density of 1 m A/cm^(2)after 300 cycles and the full-cell exhibits outstanding electrochemical performance(capacity retention of 91.0%after 500 cycles at 2 C).展开更多
Rechargeable magnesium-ion(Mg-ion)batteries have attracted wide attention for energy storage.However,magnesium anode is still limited by the irreversible Mg plating/stripping procedure.Herein,a well-designed binary Bi...Rechargeable magnesium-ion(Mg-ion)batteries have attracted wide attention for energy storage.However,magnesium anode is still limited by the irreversible Mg plating/stripping procedure.Herein,a well-designed binary Bi_(2)O_(3)-Bi_(2)S_(3)(BO-BS)heterostructure is fulfilled by virtue of the cooperative interface and energy band engineering targeted fast Mg-ion storage.The built-in electronic field resulting from the asymmetrical electron distribution at the interface of electron-rich S center at Bi_(2)S_(3) side and electron-poor O center at Bi_(2)O_(3) side effectively accelerates the electrochemical reaction kinetics in the Mg-ion battery system.Moreover,the as-designed heterogenous interface also benefits to maintaining the electrode integrity.With these advantages,the BO-BS electrode displays a remarkable capacity of 150.36 mAh g^(−1) at 0.67 A g^(-1) and a superior cycling stability.This investigation would offer novel insights into the rational design of functional heterogenous electrode materials targeted the fast reaction kinetics for energy storage systems.展开更多
Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of f...Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of flexible Sb_(2)Se_(3) photovoltaic devices is temporarily limited by the complicated intrinsic defects and the undesirable contact interfaces.Herein,a high-quality Sb_(2)Se_(3) absorber layer with large crystal grains and benign [hkl] growth orientation can be first prepared on a Mo foil substrate.Then NaF intermediate layer is introduced between Mo and Sb_(2)Se_(3),which can further optimize the growth of Sb_(2)Se_(3)thin film.Moreover,positive Na ion diffusion enables it to dramatically lower barrier height at the back contact interface and passivate harmful defects at both bulk and heterojunction.As a result,the champion substrate structured Mo-foil/Mo/NaF/Sb_(2)Se_(3)/CdS/ITO/Ag flexible thin-film solar cell delivers an obviously higher efficiency of 8.03% and a record open-circuit voltage(V_(OC)) of 0.492 V.This flexible Sb_(2)Se_(3) device also exhibits excellent stability and flexibility to stand large bending radius and multiple bending times,as well as superior weak light photo-response with derived efficiency of 12.60%.This work presents an effective strategy to enhance the flexible Sb_(2)Se_(3) device performance and expand its potential photovoltaic applications.展开更多
In the quest for the development of thermally stable,highly active and low-cost catalysts for use in catalyzed diesel particulate filter,nano-composites are new areas of research.Therefore,we reported the easy synthes...In the quest for the development of thermally stable,highly active and low-cost catalysts for use in catalyzed diesel particulate filter,nano-composites are new areas of research.Therefore,we reported the easy synthesis of spinel NiCo_(2)O_(4)/perovskite LaCoO_(3) nano-composite,and its individual oxides NiCo_(2)O_(4)and LaCoO_(3) for comparison.The detailed insights into the physio-chemical characteristics of formed NiCo_(2)O_(4)/LaCoO_(3) nano-composite were done based on various characterization analysis such as X-ray diffraction(XRD),Fourier transform infrared(FT-IR),N_(2) physiosorption,scanning electron microscopy-energy dispersive spectroscopy(SEM-EDX),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).The characterization analysis of NiCo_(2)O_(4)/LaCoO_(3) revealed the successful formation of a chemical interface possessing strong interfacial interaction,resulting in desirable physicochemical characteristics such as small crystallite size,abundant mesoporosity,high specific surface area and activation of surface lattice oxygen.Owing to the desirable characteristics,the activity results over NiCo_(2)O_(4)/LaCoO_(3) nano-composite showed the excellent CO oxidation performance and high soot oxidation activity,recyclability and thermal stability.This work mainly attempts to emphasize the effectiveness of the facile,inexpensive and conventionally used precipitation method for the successful formation of highly efficient nano-composites.展开更多
Interface engineering is widely employed to enhance the performance of formamidinium lead triiodide(FAPbI_(3))perovskite solar cells.In this study,six different FAPbI_(3)/PbX(X=S,Se and Te)heterostructures are constru...Interface engineering is widely employed to enhance the performance of formamidinium lead triiodide(FAPbI_(3))perovskite solar cells.In this study,six different FAPbI_(3)/PbX(X=S,Se and Te)heterostructures are constructed,including the PbI interface and I interface perovskite.In addition,the lead vacancies(V-Pb)and iodine vacancies(V-I)are designed at the perovskite interface.The results show that the PbI interface is more stable than I interface in the heterostructures.The PbX covering layer on the surface of the FAPbI_(3) perovskite stabilizes the perovskite octahedral structure by interface interactions and charge reconstruction that are beneficial to passivate perovskite interface defects and inhibit the phase transition.It shows that the PbTe covering layer exhibits the best passivation effect for lead vacancy defects,while PbS covering layer shows the best passivation effect for iodine vacancy defects.Additionally,appropriate structural stress can strengthen the thermal stability of defective perovskite.This work reveals the FAPbI_(3)/PbX interface engineering,and offers new insights into effectively passivating defects and improving the stability of FAPbI_(3).展开更多
The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial microstructure.Designing thermoelectric materials with a simple,structurally-uniform int...The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial microstructure.Designing thermoelectric materials with a simple,structurally-uniform interface provides a facile way to understand how these interfaces influence the transport properties.Here,we synthesized Bi_(2−x)Sb_(x)Te_(3)(x=0,0.1,0.2,0.4)nanoflakes using a hydrothermal method,and prepared Bi_(2−x)Sb_(x)Te_(3) thin films with predominantly(0001)interfaces by stacking the nanoflakes through spin coating.The influence of the annealing temperature and Sb content on the(0001)interface structure was systematically investigated at atomic scale using aberration-corrected scanning transmission electron microscopy.Annealing and Sb doping facilitate atom diffusion and migration between adjacent nanoflakes along the(0001)interface.As such it enhances interfacial connectivity and improves the electrical transport properties.Interfac reactions create new interfaces that increase the scattering and the Seebeck coefficient.Due to the simultaneous optimization of electrical conductivity and Seebeck coefficient,the maximum power factor of the Bi_(1.8)Sb_(0.2)Te_(3) nanoflake films reaches 1.72 mW m^(−1)K^(−2),which is 43%higher than that of a pure Bi_(2)Te_(3) thin film.展开更多
基金supported by the National Natural Science Foundation of China(Nos.62304171 and 62374128)the China Postdoctoral Science Foundation(No.2022M722500)+2 种基金the Key Research and Development Program of Shaanxi Province(No.2024GX-YBXM-512)Xidian University Specially Funded Project for Interdisciplinary Exploration(Nos.TZJH2024052 and TZJH2024050)the Fundamental Research Funds for the Central Universities,the open fund of State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology(No.2024-KF-12).
文摘CsPbBr_(3)perovskite solar cells(PSCs)have attracted significant interest for their remarkable stability under high temperatures and humidity.However,challenges such as energy loss at the CsPbBr_(3)/oxide buried interface and imperfect band alignment have impeded further efficiency enhancements.In this study,TiO_(2),SnO_(2),or ZnO was employed as electron transport layer(ETL)materials,respectively,in CsPbBr_(3)-based PSCs to optimize the band alignment at the ETL/CsPbBr_(3)interface and enhance the film quality of CsPbBr_(3)materials.The research findings indicate that the power conversion efficiency(PCE)of PSCs is influenced by the choice of ETL material.Specifically,TiO_(2)-based PSCs achieved a PCE of 10.37%efficiency,higher than SnO_(2)-or ZnO-based PSCs.This disparity in PCE can be attributed to variations in open-circuit voltage,which stem from different band alignments at the ETL/CsPbBr_(3)interface.Notably,superior photovoltaic performance was consistently observed in TiO_(2)-based PSCs due to the substantial conduction band offset(∆Ec)at the TiO_(2)/CsPbBr_(3)interface and the high quality of the CsPbBr_(3)film.This not only enhances electron extraction at the TiO_(2)/CsPbBr_(3)interface but also diminishes non-radiative recombination at the interface,as confirmed by density functional theory(DFT)calculations and experiments.Furthermore,photodetectors(PDs)based on TiO_(2)/CsPbBr_(3)heterojunction exhibit high photoresponse and photodetectivity.In conclusion,this study underscores the critical importance of the buried interface contact in CsPbBr_(3)and offers a direct approach for fabricating efficient and stable inorganic PSCs and PDs.
基金financial support provided by the Sichuan Science and Technology Program(No.2022NSFSC0226)Sichuan Science and Technology Program(No.2023ZYD0163)+6 种基金the Production-Education Integration Demonstration Project of Sichuan Provincethe Photovoltaic Industry Production-Education Integration Comprehensive Demonstration Base of Sichuan Province(Sichuan Financial Education[2022]No.106)China Tianfu Yongxing Laboratory Science and Technology Key Project(2023KJGG15)National Key Research and Development Program of China(2022YFB3803300)Beijing Natural Science Foundation(IS23037)the Department for Energy Security and Net Zero(project ID:NEXTCCUS)the ACT program(Accelerating CCS Technologies,Horizon2020 project NO.691712)。
文摘The 2D/3D heterojunction perovskites have garnered increasing attention due to their exceptional moisture and thermal stability.However,few works have paid attention to the influence of the subsequent change process of 2D/3D heterojunction PSC on the stability of PSCs.Moreover,the evolution of the interface and carrier dynamic behavior of the 2D/3D perovskite films with long-term operation has not been systematically developed befo re.In this work,the effects of 2D/3 D heterojunction evolution on the interface of perovskite films and different carrier dynamics during 2D/3D evolution are systematically analyzed for the first time.The decomposition of 2D/3D heterojunction in the perovskite film will have a certain impact on the surface and carrier dynamics behavior of perovskite.During the evolution of 2D/3D heterojunction,PbI_(2)crystals will appear,which will improve the interfacial energy level matching between the electron transport layer and perovskite film.With a long evolution time,some holes will appear on the surface of perovskite film.The open circuit voltage(V_(OC))of PSCs increased from 1.14 to1.18 V and the PCE increased to 23.21%after 300 h storage in the nitrogen atmosphere,and maintained 89%initial performance for with 3000 h stability test in N_(2)box.This discovery has a significant role in promoting the development of inverted heterojunction PSCs and constructing the revolution mechanism of charge carrier dynamic.
基金financially supported by the National Natural Science Foundation of China(52472248 and 22075221)the Key Research and Development Project of Shanxi Province(202202060301003 and 202202060301015)the Innovation Program of Wuhan-Shuguang Project(2023010201020367)。
文摘Poly(3-hexylthiophene)(P3HT)is one of the most promising hole-transporting materials in the pursuit of efficient and stable perovskite solar cells due to its outstanding stability and low cost.However,the intrinsic low carrier density of P3 HT and poor contact between the P3HT/perovskite interface always lead to a low performance of the solar cell,while conventional chemical doping always makes the films unstable and limits the scalability.In this work,for the first time,we simultaneously enhanced the hole transporting properties of P3HT film and the interface of perovskite by doping it with a judiciously designed oxidized small molecule organic semiconductor.The organic salt not only can promote the lamellar crystallinity of P3HT to obtain better charge transport properties,but also reduce the defects of perovskite.As a result,we achieved champion efficiencies of 23.0%for small-area solar cells and 18.8%for larger-area modules(48.0 cm^(2)).This efficiency is the highest value for P3HT-based perovskite modules.Moreover,the solar cells show excellent operational stability,retaining over 95%of their initial efficiencies after1200 h of continuous operation.
基金supported by the National Natural Science Foundation of China(No.52303112)the Henan Province Science and Technology Research and Development Program Joint Fund Advantageous Discipline Cultivation Project(No.232301420033)+1 种基金the China Postdoctoral Science Foundation(Nos.2022TQ0281 and 2023M733213)the Key R&D and Promotion Special(Scientific Problem Tackling)Project of Henan Province(No.242102231014).
文摘Virtual reality(VR)is an emerging communication means and creates extensive opportunities in interacting scenarios such as remote collaboration and metaverse.Human-machine interfaces(HMIs)play important roles in VR as they provide interaction platforms between users and virtual environments.However,traditional VR HMIs based on handheld devices or keyboards cannot recognize diverse three-dimensional(3D)gestures,which results in limited freedom of VR interactions.Here,we report a noncontact VR HMI enabled by an electret-nanofiber-based triboelectric sensor(ETS),which is fabricated by the electrospun polylactic acid/thermoplastic polyurethane(PLA/TPU)electret nanofiber film.The nanofiber structure of PLA/TPU electret enhanced the charge retention ability of triboelectric sensor and thus significantly improved its signal strength and stability.Integrated with a deep learning-based multilayer perceptron neural network,the ETS realizes the recognition of 18 different types of 3D gestures with a high average accuracy of 97.3%.An intelligent noncontact VR interactive system based on the ETS is further developed,which is used to manipulate game characters for performing different actions by 3D gestures.Compared with traditional VR HMIs,the proposed VR HMI based on PLA/TPU electret nanofiber film can detect various 3D gestures and offers a superior interaction freedom.This work for the first time introduces the triboelectric 3D gesture recognition method to the VR HMIs,and could make the interaction between human and virtual environments become more efficient and fascinating.
基金supported by the National Natural Science Foundation of China(Nos.22173057,52130204,12074241,11929401,12311530675)Science and Technology Commission of Shanghai Municipality(Nos.21JC1402700,22XD1400900,20501130600,21JC1402600)High-Performance Computing Center,Shanghai Technical Service Center of Science and Engineering Computing,Shanghai University。
文摘Metal-ceramic composites combine the excellent properties of metals and ceramics,which have high strength,stability,and corrosion re-sistance.Al_(2)O_(3)/FeCo composites have been proven to be useful in ap-plications such as catalysts,mi-crowave absorption materials,and enhanced permeability dielectric.The understanding of the mechani-cal properties and dynamics at the atomic scale of the Al_(2)O_(3)/FeCo in-terface can promote the design and exploitment of metal-ceramic composites.In this work,we have obtained Young’s modulus and diffusion coefficient of the Al_(2)O_(3)/FeCo interface using molecular dynamics simulation,elucidated the structural characteristics of the Al_(2)O_(3)/FeCo interface at the atomic scale,and investigated the impact of atomic magnetism and the exter-nal magnetic field on the interface.Simulated results show that Young’s modulus of the Al_(2)O_(3)/FeCo interface is significantly improved compared with pure Al_(2)O_(3)and FeCo alloy at room and high temperatures.When the atomic magnetism and the external magnetic field are applied,Young’s modulus of the Al_(2)O_(3)/FeCo interface further increases to 612 GPa at 300 K and 602 GPa at 500 K.Moreover,the average density,diffusion coefficient,and radial distri-bution function are found to be modified substantially.This study will shed light on the atom-istic investigations of the metal-ceramic composites.
基金support from the National Natural Science Foundation of China(Grant Nos.U1860205 and 52204352)Youth Project of Hubei Natural Science Foundation(Grant No.2022CFB593)+1 种基金Key R&D Project of Hubei Province(Grant No.2022BAA021)Guiding Project of Scientific Research Plan of Hubei Provincial Department of Education(Grant No.B2022019).
文摘The interaction of MgO-MgAl_(2)O_(4)-based and MgO-Cr_(2)O_(3)-based refractories with X70 molten steel was studied by immersion experiments at 1560℃.The effects of immersion time(30 and 60 min)on the contents of total oxygen(TO),Al,Nb,Si,Mn,and Cr as well as the composition,number density,and size distribution of inclusions in the molten steel were investigated.The influence of the penetration and erosion degree of the molten steel to the refractory on the steel-refractory interface layer was analyzed.The results show that,at 1560℃,the MgO-MgAl_(2)O_(4)-based refractory can better control the contents of TO and the composition of molten steel compared with the MgO-Cr_(2)O_(3)-based refractory.The TO content is only 16×10^(-4) wt.%in the molten steel after reacted with the Mg0-MgAl_(2)O_(4)-based refractory at the end point of refining,4 accounting for 11.5%of that reacted with the MgO-Cr_(2)O_(3)-based refractory(139×10^(-4) wt.%).The number density of inclusions is only 14 mm^(-2),and the average size ofinclusions is only 1.31μm,with thelargest proportion of inclusions in 1-2μm(70%).The Al_(2)O_(3)-MnS-CaO complex inclusions in the original steel changed to complex inclusions dominated by Cr-Nb-Mn-S-O and MgO.Al_(2)O_(3),corresponding to the MgO-Cr_(2)O_(3)-based and MgO-MgAl_(2)O_(4)-based refractories,respectively.The MgO.Al_(2)O_(3) layer was formed at the reaction interface between MgO-MgAl_(2)O_(4)-based refractory and molten steel,which is helpful to restrict the erosion of refractories and the pollution of molten steel.The damage mechanism of the MgO-Cr_(2)O_(3)-based refractory is mainly permeation and chemical reaction,while the damage of the MgO-MgAl_(2)O_(4)-based refractory is mainlyscouring erosion.
基金supported by the National Natural Science Foundation of China(No.52374153).
文摘The shear characteristics of the interface formed between a cemented tailings backfill(CTB)and surrounding rocks play a cru-cial role in the design and stability of underground goafs.To investigate the shear behavior of CTB-rock interfaces,rock samples repres-enting the topography of surrounding rocks were constructed using 3D morphology scanning and engraving techniques.A series of direct shear tests were conducted on the CTB rock samples to examine the influence of the cement-tailings ratio on the interfacial shear behavi-or.The results showed that the compressive strength of the CTB and shear strength of the CTB-rock interface decreased with decreasing cement proportion.With deceasing cement content,the failure area of the CTB after the test increased,and the roughness of the newly generated interface reduced.A digital image correlation analysis revealed that the compressive stress concentration in the region with an obtuse angle with respect to the shear direction was the primary cause of CTB failure.Moreover,the correlation between the wear area and the silicon-dense area helped confirm that the silicon particles are more prone to failure in these areas than in other regions.Our find-ings provide new insights into the shear sliding mechanism at CTB-rock interfaces and can aid in the selection of the cement-tailings ra-tio at engineering sites.For example,if the horizontal principal stress of the surrounding rock mass in a backfilling area is relatively high,the cement content can be reduced for CTB applications.
文摘Accurate water level measurement in nuclear reactors,particularly in PWRs(pressurized water reactors)and BWRs(boiling water reactors),is essential for ensuring the safety and efficiency of reactor operations.K-type HJTCs(heated junction thermocouples)are widely used for this purpose due to their ability to withstand extreme temperatures and radiation conditions.This article explores the role of HJTCs in reactor water level measurement and compares the performance of 2-wire and 3-wire connections.While the 2-wire connection is simple and cost-effective,it can introduce measurement inaccuracies due to wire resistance.In contrast,the 3-wire connection compensates for lead resistance,offering more precise and reliable measurements,particularly in long-distance applications.This paper discusses the operational considerations of these wiring configurations in the context of nuclear reactors and highlights the importance of choosing the appropriate connection type to optimize safety and measurement accuracy in PWR and BWR reactors.
文摘The functions,applications,developments and current application mode of IDS3.x system are generally introduced in this paper.Then the development mode of spacecraft based on IDS3.x system is described.The existing problems especially the information redundancy of mechanical interface and their effects are pointed out.A new solution is proposed by developing 3D-IDS system.The central functions of 3D-IDS system are shown in this study.A new application mode of 3D-IDS system is explored and described by showing how to fill in,countersign and apply with 3D-IDS file.The 2D drawing and sketch are removed from 3D-IDS system to avoid information redundancy of mechanical interface.The consistency between 3D model and the parameters of IDS file can be guaranteed by the interface tool.The efficiency of filling in,countersigning and applying,has been improved significantly,which greatly promotes the coordination and total efficiency of spacecraft system design departments and unit design departments.
基金supported by the National Key Research and Development Program of China(2019YFA0705700)Guangdong Innovative and Entrepreneurial Research Team Program(2021ZT09L197)+2 种基金Shenzhen Science and Technology Program(KQTD20210811090112002)Interdisciplinary Research and Innovation Fund of Tsinghua Shenzhen International Graduate School,National Natural Science Foundation of China(No.52373233)the SIAT International Joint Lab Project(No.E3G113).
文摘Lithium-carbon dioxide(Li-CO_(2))batteries with high theoretical energy density are regarded as promising energy storage system toward carbon neutrality.However,bidirectional catalysts design for improving the sluggish CO_(2)reduction reaction(CO_(2)RR)/CO_(2)evolution reaction(CO_(2)ER)kinetics remains a huge challenge.In this work,an advanced catalyst with fast-interfacial charge transfer was subtly synthesized through element segregation,which significantly improves the electrocatalytic activity for both CO_(2)RR and CO_(2)ER.Theoretical calculations and characterization analysis demonstrate local charge redistribution at the constructed interface,which leads to optimized binding affinity towards reactants and preferred Li_(2)CO_(3)decomposition behavior,enabling excellent catalytic activity during CO_(2)redox.Benefiting from the enhanced charge transfer ability,the designed highly efficient catalyst with dual active centers and large exposed catalytic area can maintain an ultra-small voltage gap of 0.33 V and high energy efficiency of 90.2%.This work provides an attractive strategy to construct robust catalysts by interface engineering,which could inspire further design of superior bidirectional catalysts for Li-CO_(2)batteries.
基金supported by the China Scholarship Council(No.202006120422)the National Natural Science Foundation of China(Nos.51874110,51604089)+5 种基金Natural Science Foundation of Heilongjiang Province(No.LH2021B011)Open Project of State Key Laboratory of Urban Water Resource and Environment(No QA202138)the support by the Singapore Ministry of Education(MOE,No.MOE2018-T2-2-095)for research conducted at the National University of Singaporethe Green Energy Programme(No.R284-000-185-731)funded by the National University of Singapore。
文摘Sodium(Na)metal batteries have gained increasing attention more recently,owing to their high energy densities and cost efficiencies,but are severely handicapped by the unsatisfactory Coulombic efficiency(CE)and cycling stability stemming from dendrite growth on Na anodes.In this study,we developed a strategy of direct ink writing(DIW)3D printing combined with electroless deposition to construct a hierarchical Cu grid coated with a dense nanoscale Ag interfacial layer as the host material for Na plating.The sodiophilic Ag interface contributes to a fall in the Na nucleation energy,hence enabling uniform Na deposition on each 3D-printed filament.The constructed 3D-printed structure can effectively moderate the electric-field distribution and lower the local current density for relieving Na inhomogeneous growth,as confirmed by finite element simulation and Na plating/stripping morphology evolution results.In particular,the unique 3D structure also promotes the lateral growth of Na,thus the volume change of Na metal was accommodated to stabilize the solid electrolyte interphase(SEI).As a result,the CE of the half-cell can reach 99.9%at the current density of 1 m A/cm^(2)after 300 cycles and the full-cell exhibits outstanding electrochemical performance(capacity retention of 91.0%after 500 cycles at 2 C).
基金supported by the National Natural Science Foundation of China(52172239)Project of State Key Laboratory of Environment-Friendly Energy Materials(SWUST,Grant Nos.22fksy23 and 18ZD320304)+3 种基金the Frontier Project of Chengdu Tianfu New Area Institute(SWUST,Grand No.2022ZY017)Chongqing Talents:Exceptional Young Talents Project(Grant No.CQYC201905041)Natural Science Foundation of Chongqing China(Grant No.cstc2021jcyj-jqX0031)Interdiscipline Team Project under auspices of“Light of West”Program in Chinese Academy of Sciences(Grant No.xbzg-zdsys-202106).
文摘Rechargeable magnesium-ion(Mg-ion)batteries have attracted wide attention for energy storage.However,magnesium anode is still limited by the irreversible Mg plating/stripping procedure.Herein,a well-designed binary Bi_(2)O_(3)-Bi_(2)S_(3)(BO-BS)heterostructure is fulfilled by virtue of the cooperative interface and energy band engineering targeted fast Mg-ion storage.The built-in electronic field resulting from the asymmetrical electron distribution at the interface of electron-rich S center at Bi_(2)S_(3) side and electron-poor O center at Bi_(2)O_(3) side effectively accelerates the electrochemical reaction kinetics in the Mg-ion battery system.Moreover,the as-designed heterogenous interface also benefits to maintaining the electrode integrity.With these advantages,the BO-BS electrode displays a remarkable capacity of 150.36 mAh g^(−1) at 0.67 A g^(-1) and a superior cycling stability.This investigation would offer novel insights into the rational design of functional heterogenous electrode materials targeted the fast reaction kinetics for energy storage systems.
基金supported by the National Natural Science Foundation of China(Grant Nos.62104156,62074102)the Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2023A1515011256,2022A1515010979)China+1 种基金Science and Technology plan project of Shenzhen(Grant Nos.20220808165025003,20200812000347001)Chinasupported by the open foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials,State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures,Guangxi University(Grant No.2022GXYSOF13)。
文摘Sb_(2)Se_(3) with unique one-dimensional(1D) crystal structure exhibits exceptional deformation tolerance,demonstrating great application potential in flexible devices.However,the power conversion efficiency(PCE) of flexible Sb_(2)Se_(3) photovoltaic devices is temporarily limited by the complicated intrinsic defects and the undesirable contact interfaces.Herein,a high-quality Sb_(2)Se_(3) absorber layer with large crystal grains and benign [hkl] growth orientation can be first prepared on a Mo foil substrate.Then NaF intermediate layer is introduced between Mo and Sb_(2)Se_(3),which can further optimize the growth of Sb_(2)Se_(3)thin film.Moreover,positive Na ion diffusion enables it to dramatically lower barrier height at the back contact interface and passivate harmful defects at both bulk and heterojunction.As a result,the champion substrate structured Mo-foil/Mo/NaF/Sb_(2)Se_(3)/CdS/ITO/Ag flexible thin-film solar cell delivers an obviously higher efficiency of 8.03% and a record open-circuit voltage(V_(OC)) of 0.492 V.This flexible Sb_(2)Se_(3) device also exhibits excellent stability and flexibility to stand large bending radius and multiple bending times,as well as superior weak light photo-response with derived efficiency of 12.60%.This work presents an effective strategy to enhance the flexible Sb_(2)Se_(3) device performance and expand its potential photovoltaic applications.
文摘In the quest for the development of thermally stable,highly active and low-cost catalysts for use in catalyzed diesel particulate filter,nano-composites are new areas of research.Therefore,we reported the easy synthesis of spinel NiCo_(2)O_(4)/perovskite LaCoO_(3) nano-composite,and its individual oxides NiCo_(2)O_(4)and LaCoO_(3) for comparison.The detailed insights into the physio-chemical characteristics of formed NiCo_(2)O_(4)/LaCoO_(3) nano-composite were done based on various characterization analysis such as X-ray diffraction(XRD),Fourier transform infrared(FT-IR),N_(2) physiosorption,scanning electron microscopy-energy dispersive spectroscopy(SEM-EDX),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).The characterization analysis of NiCo_(2)O_(4)/LaCoO_(3) revealed the successful formation of a chemical interface possessing strong interfacial interaction,resulting in desirable physicochemical characteristics such as small crystallite size,abundant mesoporosity,high specific surface area and activation of surface lattice oxygen.Owing to the desirable characteristics,the activity results over NiCo_(2)O_(4)/LaCoO_(3) nano-composite showed the excellent CO oxidation performance and high soot oxidation activity,recyclability and thermal stability.This work mainly attempts to emphasize the effectiveness of the facile,inexpensive and conventionally used precipitation method for the successful formation of highly efficient nano-composites.
基金Projects(51673214,62004225)supported by the National Natural Science Foundation of ChinaProject(2022YFB3803300)supported by the National Key Research and Development Program of ChinaProject(2024ZZTS0776)supported by the Key Innovation Project of Graduate of Central South University,China。
文摘Interface engineering is widely employed to enhance the performance of formamidinium lead triiodide(FAPbI_(3))perovskite solar cells.In this study,six different FAPbI_(3)/PbX(X=S,Se and Te)heterostructures are constructed,including the PbI interface and I interface perovskite.In addition,the lead vacancies(V-Pb)and iodine vacancies(V-I)are designed at the perovskite interface.The results show that the PbI interface is more stable than I interface in the heterostructures.The PbX covering layer on the surface of the FAPbI_(3) perovskite stabilizes the perovskite octahedral structure by interface interactions and charge reconstruction that are beneficial to passivate perovskite interface defects and inhibit the phase transition.It shows that the PbTe covering layer exhibits the best passivation effect for lead vacancy defects,while PbS covering layer shows the best passivation effect for iodine vacancy defects.Additionally,appropriate structural stress can strengthen the thermal stability of defective perovskite.This work reveals the FAPbI_(3)/PbX interface engineering,and offers new insights into effectively passivating defects and improving the stability of FAPbI_(3).
基金supported by the National Natural Science Foundation of China(52272235)supported by the Fundamental Research Funds for the Central Universities(WUT:2021III016GX).
文摘The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial microstructure.Designing thermoelectric materials with a simple,structurally-uniform interface provides a facile way to understand how these interfaces influence the transport properties.Here,we synthesized Bi_(2−x)Sb_(x)Te_(3)(x=0,0.1,0.2,0.4)nanoflakes using a hydrothermal method,and prepared Bi_(2−x)Sb_(x)Te_(3) thin films with predominantly(0001)interfaces by stacking the nanoflakes through spin coating.The influence of the annealing temperature and Sb content on the(0001)interface structure was systematically investigated at atomic scale using aberration-corrected scanning transmission electron microscopy.Annealing and Sb doping facilitate atom diffusion and migration between adjacent nanoflakes along the(0001)interface.As such it enhances interfacial connectivity and improves the electrical transport properties.Interfac reactions create new interfaces that increase the scattering and the Seebeck coefficient.Due to the simultaneous optimization of electrical conductivity and Seebeck coefficient,the maximum power factor of the Bi_(1.8)Sb_(0.2)Te_(3) nanoflake films reaches 1.72 mW m^(−1)K^(−2),which is 43%higher than that of a pure Bi_(2)Te_(3) thin film.
