This study demonstrated the impacts of the synthesis methods on the textural structures,chemical properties,and Hg^(0)capture capability of the MnO_(x)system.Compared with the samples synthesized using the precipitati...This study demonstrated the impacts of the synthesis methods on the textural structures,chemical properties,and Hg^(0)capture capability of the MnO_(x)system.Compared with the samples synthesized using the precipitation(PR)and hydrothermal(HT)methods,the adsorbent prepared via the sol-gel(SG)technique gave the best performance.At 150℃,ca.90%Hg^(0)removal efficiency was reached after 7.5 h for MnO_(x)prepared by the SG method,ca.40%higher than that of the other two methods.The specific surface area of the adsorbent synthesized via the SG technique(23 m^(2)/g)was almost double that of the adsorbent prepared by the HT method(12 m^(2)/g)and three times that of the one prepared by the PR method(7 m^(2)/g).The presence of plentiful acid sites from the SG method facilitated the physisorption of Hg^(0),making more Hg^(0)available to be oxidized to HgO by the redox sites and thus giving the adsorbent prepared by the SG method the highest Hg^(0)removal efficiency.The strong oxidative ability accelerated the oxidation of the physically adsorbed Hg^(0)to HgO,which explained the higher Hg^(0)removal efficiency of the sample prepared using the HT method than that of the one synthesized by the PR technique.During the whole Hg^(0)removal cycles,chemisorption dominated,with the initial adsorption stage and the external mass-transfer process playing important roles.展开更多
Legendre polynomial method is well-known in modeling acoustic wave characteristics.This method uses for the mechanical displacements a single polynomial expansion over the entire sandwich layers.This results in a limi...Legendre polynomial method is well-known in modeling acoustic wave characteristics.This method uses for the mechanical displacements a single polynomial expansion over the entire sandwich layers.This results in a limitation in the accuracy of the field profile restitution.Thus,it can deal with the guided waves in layered sandwich only when the material properties of adjacent layers do not change significantly.Despite the great efforts regarding this issue in the literature,there remain open questions.One of them is:“what is the exact threshold of contrasting material properties of adjacent layers for which this polynomial method cannot correctly restitute the roots of guided waves?”We investigated this numerical issue using the calculated guided phase velocities in 0°/φ/0°-carbon fibre reinforced plastics(CFRP)sandwich plates with gradually increasing angleφ.Then,we approached this numerical problem by varying the middle layer thickness h90°for the 0°/90°/0°-CFRP sandwich structure,and we proposed an exact thickness threshold of the middle layer for the Legendre polynomial method limitations.We showed that the polynomial method fails to calculate the quasi-symmetric Lamb mode in 0°/φ/0°-CFRP whenφ>25°.Moreover,we introduced a new Lamb mode so-called minimum-group-velocity that has never been addressed in literature.展开更多
基金This work is supported by the Fundamental Research Funds of China Jiliang University and the Zhejiang Provincial Natural Science Foundation of China(No.LQ22E060003).
文摘This study demonstrated the impacts of the synthesis methods on the textural structures,chemical properties,and Hg^(0)capture capability of the MnO_(x)system.Compared with the samples synthesized using the precipitation(PR)and hydrothermal(HT)methods,the adsorbent prepared via the sol-gel(SG)technique gave the best performance.At 150℃,ca.90%Hg^(0)removal efficiency was reached after 7.5 h for MnO_(x)prepared by the SG method,ca.40%higher than that of the other two methods.The specific surface area of the adsorbent synthesized via the SG technique(23 m^(2)/g)was almost double that of the adsorbent prepared by the HT method(12 m^(2)/g)and three times that of the one prepared by the PR method(7 m^(2)/g).The presence of plentiful acid sites from the SG method facilitated the physisorption of Hg^(0),making more Hg^(0)available to be oxidized to HgO by the redox sites and thus giving the adsorbent prepared by the SG method the highest Hg^(0)removal efficiency.The strong oxidative ability accelerated the oxidation of the physically adsorbed Hg^(0)to HgO,which explained the higher Hg^(0)removal efficiency of the sample prepared using the HT method than that of the one synthesized by the PR technique.During the whole Hg^(0)removal cycles,chemisorption dominated,with the initial adsorption stage and the external mass-transfer process playing important roles.
基金supported by the National Natural Science Foundation of China(Grant No.12102131).
文摘Legendre polynomial method is well-known in modeling acoustic wave characteristics.This method uses for the mechanical displacements a single polynomial expansion over the entire sandwich layers.This results in a limitation in the accuracy of the field profile restitution.Thus,it can deal with the guided waves in layered sandwich only when the material properties of adjacent layers do not change significantly.Despite the great efforts regarding this issue in the literature,there remain open questions.One of them is:“what is the exact threshold of contrasting material properties of adjacent layers for which this polynomial method cannot correctly restitute the roots of guided waves?”We investigated this numerical issue using the calculated guided phase velocities in 0°/φ/0°-carbon fibre reinforced plastics(CFRP)sandwich plates with gradually increasing angleφ.Then,we approached this numerical problem by varying the middle layer thickness h90°for the 0°/90°/0°-CFRP sandwich structure,and we proposed an exact thickness threshold of the middle layer for the Legendre polynomial method limitations.We showed that the polynomial method fails to calculate the quasi-symmetric Lamb mode in 0°/φ/0°-CFRP whenφ>25°.Moreover,we introduced a new Lamb mode so-called minimum-group-velocity that has never been addressed in literature.
